Seasonal variability of total and easily leachable element contents in topsoils (0-5 cm) from eight catchments in the European Arctic (Finland, Norway and Russia)

Frozen topsoil samples (0-5 cm) were collected during March/April 1994 in eight Arctic catchments in northern Europe (4 in Russia, 3 in Finland, 1 in Norway) at varying distances and wind directions from the emissions of the Russian nickel ore mining, roasting and smelting industry on the Kola Peninsula. Between 14 and 25 sites were sampled in catchment basins ranging in size from 12 to 35 km(2). Sampling was repeated in spring immediately after the snow melted, in summer and in autumn to study seasonal variability and the fate of elements when the snow melts. The <2 mm fraction of air-dried topsoils was analysed for total (aqua regia extraction) and easily leachable (in 1 m ammonium acetate, buffered at pH 4.5) element concentrations using ICP-AES and GFAAS for up to 35 elements. Results for selected elements are presented here. Soil organic matter can be shown to be the controlling factor determining element contents and fate. In catchments close to the Russian nickel industry, the topsoils have low carbon and nitrogen contents. Using both extraction methods most elements reach maximum concentrations in winter; lowest concentrations are observed in midsummer. Soil organic matter and elements associated with it are thus leached out of the soils together with soluble elements when the snow melts. This process continues in summer. Elements will enrich surface waters, the lower layers of podzol profiles, or reach the groundwater. The use of the two extractions described provides a simple method to study the mobilities and pathways of elements in the topsoils during the arctic year. Using the proportions of easily leachable to total concentration, a good estimation of the status of the topsoil in the study area can be given.