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黄麻纤维活性炭对亚甲基蓝和甲基橙吸附动力学
引用本文:何丽芬,刘其霞,季涛,高强.黄麻纤维活性炭对亚甲基蓝和甲基橙吸附动力学[J].环境工程学报,2013,7(12):4735-4740.
作者姓名:何丽芬  刘其霞  季涛  高强
作者单位:南通大学炭纤维应用技术研究所, 南通 226019;南通大学炭纤维应用技术研究所, 南通 226019;南通大学炭纤维应用技术研究所, 南通 226019;南通大学炭纤维应用技术研究所, 南通 226019
基金项目:交通运输部科技项目(2011319813500);南通大学自然科学类科研基金产学研项目(11C003);江苏省2012年度普通高校研究生科研创新计划项目(CXLX12-0888);南通大学研究生科技创新计划项目(YKC12076)
摘    要:以黄麻纤维为原料,采用磷酸活化法制备活性炭。研究黄麻纤维活性炭对亚甲基蓝和甲基橙2种染料的吸附行为。结果表明,采用磷酸制备的活性炭,由于表面含有羧基和含磷官能团等酸性基团,能够促进活性炭对亚甲基蓝的吸附;黄麻纤维活性炭对2种染料的平衡吸附量、初始吸附速率均随着初始浓度的增加而升高;相同条件下,黄麻纤维活性炭对亚甲基蓝的平衡吸附量大于甲基橙;黄麻纤维活性炭对两种染料的吸附行为更符合准二级动力学模型。

关 键 词:黄麻纤维  活性炭  亚甲基蓝  甲基橙  吸附动力学

Adsorption kinetics of jute fiber-based activated carbon on methylene blue and methyl orange
He Lifen,Liu Qixi,Ji Tao and Gao Qiang.Adsorption kinetics of jute fiber-based activated carbon on methylene blue and methyl orange[J].Techniques and Equipment for Environmental Pollution Control,2013,7(12):4735-4740.
Authors:He Lifen  Liu Qixi  Ji Tao and Gao Qiang
Institution:Institute of Carbon Fiber Applied Technology, Nantong University, Nantong 226019, China;Institute of Carbon Fiber Applied Technology, Nantong University, Nantong 226019, China;Institute of Carbon Fiber Applied Technology, Nantong University, Nantong 226019, China;Institute of Carbon Fiber Applied Technology, Nantong University, Nantong 226019, China
Abstract:Jute fiber-based activated carbon (JFAC) were prepared by using jute fibers as raw materials and phosphoric acid as activating agent. The adsorption behaviors of JFAC on methylene blue (MB) and methyl orange (MO) dyes were investigated. Results showed that JFAC prepared by phosphoric acid activation had good adsorption capacity on MB due to the acidic groups such as carboxyl and phosphorus-containing functional groups on their surfaces. The equilibrium adsorption capacity and the initial adsorption rate of JFAC on MB or MO increased with increasing of initial concentration. Under the same condition, the adsorption capability of JFAC on MB was greater than that on MO. Besides, the adsorption behaviors of JFAC on both MB and MO fitted well with Pseudo-second-order kinetic model.
Keywords:jute fiber  activated carbon  methylene blue (MB)  methyl orange (MO)  adsorption kinetics
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