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Partitioning and mobility behavior of metals in road dusts from national-scale industrial areas in Korea
Authors:Trang TT Duong  Byeong-Kyu Lee
Institution:1. Department of Chemistry, Payame Noor University, P.O. BOX 19395-3697, Tehran, Iran;2. Department of Medicinal Chemistry and Radiopharmacy, Faculty of Pharmacy, Tehran University of Medical Sciences, Tehran, Iran;3. Drug Design and Development Research Center, Tehran University of Medical Sciences, Tehran, Iran;1. College of Chemical Engineering, Huaqiao University, Xiamen, 361021, China;2. Analytical Laboratory of Beijing Research Institute of Uranium Geology, Beijing, 100029, China;3. Key Lab of Environmental Monitoring of University in Fujian Province, Xiamen, 361024, China;1. Department of Earth Sciences, College of Sciences, Shiraz University, Shiraz 71454, Iran;2. School of Environmental Sciences, University of Guelph, Guelph, ON, Canada N1G 2W1;1. Faculty of Geology and Geoenvironment, National and Kapodistrian University of Athens, Panepistimiopolis, Zographou, 157 84, Athens, Greece;2. Department of Environmental Geosciences, Faculty of Environmental Sciences, Czech University of Life Sciences Prague, Kamýcká 129, 165 21, Prague 6, Czech Republic
Abstract:In this study, we investigated the characteristics of heavy metal contamination in road dusts collected from industrial areas in Korea. A total of 12 sampling sites, including nine sites in three different industrial complexes (ICs), two IC vicinity areas and one background area, were selected for this study. The collected road dusts were divided into four categories. The heavy metals (Cd, Cu, Pb, Zn, and Ni) were extracted from the road dust by an aqua regia extraction method and analyzed by atomic absorption spectrometry. The highest concentrations of Cd, Cu, and Pb were identified in road dusts from areas near the non-ferrous metal IC, followed by those from the petrochemical IC. The petrochemical IC and the mechanical/shipbuilding IC showed the highest concentrations of Ni and Zn in their road dusts, respectively. The concentration of heavy metals in the road dusts collected from the IC vicinity areas, even those located in a rural environment, were very high. The concentration of heavy metals increased with decreasing particle size of the road dusts. This study also analyzed the mobility of the heavy metals in the road dusts using partial sequential extraction with the Tessier procedure. The order of mobility identified, based on exchangeable and carbonate fractions of the heavy metals, was Cd > Zn > Pb > Cu > Ni.
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