| 基于线性溶解能关系预测污染物在被动采样材料与环境介质之间的分配系数 |
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| 引用本文： | 迟平,李雪花,陈景文,陈明明,王亚南,张金多,张翼飞. 基于线性溶解能关系预测污染物在被动采样材料与环境介质之间的分配系数[J]. 环境化学, 2011, 30(1): 366-373 |
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| 作者姓名： | 迟平 李雪花 陈景文 陈明明 王亚南 张金多 张翼飞 |
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| 作者单位： | 工业生态与环境工程教育部重点实验室,大连理工大学环境学院,大连,116024 |
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| 基金项目： | 中央高校基本科研业务费专项资金资助 |
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| 摘 要： | 半透膜采样装置(SPMD)作为一种重要的被动采样器,被用于监测有机污染物的环境水平.SPMD的采样材料是置于低密度聚乙烯"口袋"中的三油酸甘油酯.根据有机污染物在被动采样材料与环境介质之间的平衡分配系数(包括被动采样材料/空气分配系数K(sA).和被动采样材料/水分配系数K(sw))值,可估算SPMD的采样速率,也可计...
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| 关 键 词： | 线性溶解能关系(LSER) 有机污染物 半透膜采样装置(SPMD) 分配系数 |
PREDICTION OF THE PARTITION COEFFICIENTS BETWEEN SEMIPERMEABLE MEMBRANE DEVICES AND ENVIRONMENTAL MEDIA BY LINEAR SOLVATION ENERGY RELATIONSHIPS |
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| CHI Ping,LI Xuehua,CHEN Jingwen,CHEN Mingming,WANG Yanan,ZHANG Jinduo,ZHANG Yifei. PREDICTION OF THE PARTITION COEFFICIENTS BETWEEN SEMIPERMEABLE MEMBRANE DEVICES AND ENVIRONMENTAL MEDIA BY LINEAR SOLVATION ENERGY RELATIONSHIPS[J]. Environmental Chemistry, 2011, 30(1): 366-373 |
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| Authors: | CHI Ping LI Xuehua CHEN Jingwen CHEN Mingming WANG Yanan ZHANG Jinduo ZHANG Yifei |
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| Affiliation: | CHI Ping LI Xuehua CHEN Jingwen CHEN Mingming WANG YananZHANG Jinduo ZHANG Yifei(Key Laboratory of Industrial Ecology and Environmental Engineering,School of Environmental Science and Technology,Dalian University of Technology,Dalian,116024,China) |
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| Abstract: | emi-permeable membrane devices(SPMD) are employed as a passive sampler to determine environmental levels of organic contaminants.The sampling material is triolein contained in the tube,made of low-density polyethylene.The equilibrium partition coefficients between the sampling material and the environmental media(SPMD/air partition coefficient KSA and SPMD/water partition coefficient KSW) are required to determine the sampling rates and estimate the concentrations of the pollutants.However,the deployment of... |
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| Keywords: | linear solvation energy relationships(LSER) organic contaminants semipermeable membrane devices(SPMD) partition coefficients |
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