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A simple formula for calculating the ionization potential of two-electron ions
Authors:Hannu Elo
Institution:(1) Faculty of Pharmacy, University of Helsinki, P.O. Box 56 (Biocenter 2), 00014 Helsinki, Finland
Abstract:The ionization potential of one-electron ions can be calculated from a well-known simple equation, but no such equation has been available for calculating the ionization potential of multi-electron ions. I report here an equation that accurately gives the ionization potential of helium-like (i.e., two-electron) ions as a function of the atomic number, the relative difference from experimental values being below 1% for all ions for which reliable experimental data were found (Z = 3–29). The equation also predicts the stability of the negative hydrogen ion (the hydride ion), H, although with twice too large a value for the ionization potential.
Keywords:Ionization energy  Helium isoelectronic series  Dependence of effective nuclear charge on atomic number  Helium-like ions
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