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Structure and activity relationships for amine based CO2 absorbents—I
Institution:1. Faculty of Science and Technology, Twente University, P.O. Box 217, 7500 AE Enschede, The Netherlands;2. Procede Group BV, P.O. Box 328, 7500 AH Enschede, The Netherlands;3. Department of Chemical and Biochemical Engineering, Clarkson University, P.O. Box 5705, Potsdam, NY 13699-5705, USA;2. CSIRO Manufacturing, Clayton, Victoria, 3168, Australia;3. CSIRO Energy, Newcastle, NSW 2300, Australia;2. Clean Energy Technologies Research Institute (CETRI), University of Regina, Regina, Saskatchewan S4S 0A2, Canada;1. National Research Council, ICCOM Institute, via Madonna del Piano 10, 50019 Sesto F.no, Florence, Italy;2. University of Florence, Department of Chemistry, via della Lastruccia 3, 50019 Sesto F.no, Florence, Italy;3. National Research Council, DSCTM, piazzale Aldo Moro 7, 00185 Rome, Italy;2. CSIRO Manufacturing, Clayton, Victoria 3168, Australia;1. Research Institute of Innovative Technology for the Earth (RITE), 9-2 Kizugawadai, Kizugawa-shi, Kyoto 619-0292, Japan;2. Advanced Technology Research Laboratories, Nippon Steel & Sumitomo Metal Corporation, 20-1 Shintomi, Futtsu, Chiba 293-8511, Japan
Abstract:A study to determine the structure and activity relationships of various amine based CO2 absorbents was performed in which, the absorption of pure CO2 at atmospheric pressure was measured to assess the total absorption rate and capacities. Results showed that an increase in chain length between the amine and different functional groups in the absorbent structure, result in a decrease of absorption rate whereas, the absorption capacity was increased in most absorbents.
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