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典型化工行业有害VOCs排放清单及长三角地区应用
引用本文:鲁君,黄奕玮,黄成.典型化工行业有害VOCs排放清单及长三角地区应用[J].环境科学,2019,40(11):4856-4861.
作者姓名:鲁君  黄奕玮  黄成
作者单位:上海市环境科学研究院,国家环境保护城市大气复合污染成因与防治重点实验室,上海200233;上海市环境科学研究院,国家环境保护城市大气复合污染成因与防治重点实验室,上海200233;上海市环境科学研究院,国家环境保护城市大气复合污染成因与防治重点实验室,上海200233
基金项目:上海市重大环保科研项目(2017-02);国家自然科学基金项目(21777101);国家重点研发计划项目(2018YFC0213800)
摘    要:以美国加州和中国台湾有害挥发性有机物(HVOCs)排污收费物种为依据,筛选8种HVOCs物种,分别为苯、甲苯、二甲苯、乙苯、苯乙烯、二氯甲烷、1,1-二氯乙烯和三氯乙烯,通过排放因子法,建立了2014年的长三角地区典型化工行业总VOCs排放清单,VOCs排放量为13. 55万t,结合工艺源项HVOCs物种排放占比,建立了长三角地区典型化工行业的HVOCs排放清单,2014年排放量HVOCs约为5. 24万t,其中占比最高的HVOCs物种为二氯甲烷和苯,HVOCs占VOCs排放较大的工艺源项为聚氨酯类树脂、烷基苯、乙苯、丙烯酸树脂、氯苯、乙苯、环己酮、乙烯及聚苯乙烯等的生产.

关 键 词:毒害  挥发性有机物(VOCs)  排放清单  化工  长三角地区
收稿时间:2019/1/25 0:00:00
修稿时间:2019/6/11 0:00:00

Hazardous Volatile Organic Compound Emission Inventory Study and Its Application in a Typical Chemical Industry in the Yangtze River Delta
LU Jun,HUANG Yi-wei and HUANG Cheng.Hazardous Volatile Organic Compound Emission Inventory Study and Its Application in a Typical Chemical Industry in the Yangtze River Delta[J].Chinese Journal of Environmental Science,2019,40(11):4856-4861.
Authors:LU Jun  HUANG Yi-wei and HUANG Cheng
Institution:State Environmental Protection Key Laboratory of the Cause and Protection of Urban Air Pollution Complex, Shanghai Academy of Environment Sciences, Shanghai 200233, China,State Environmental Protection Key Laboratory of the Cause and Protection of Urban Air Pollution Complex, Shanghai Academy of Environment Sciences, Shanghai 200233, China and State Environmental Protection Key Laboratory of the Cause and Protection of Urban Air Pollution Complex, Shanghai Academy of Environment Sciences, Shanghai 200233, China
Abstract:Based on hazardous volatile organic compound (HVOCs) species recommended by the California Air Resources Board and Taiwan Environmental Agency(China), eight HVOCs species were focused on, namely benzene, toluene, xylene, ethylbenzene, styrene, dichloromethane, 1,1-dichloroethylene, and trichloroethylene. A top-down method was used to establish a VOCs emission inventory for typical chemical industries in the Yangtze River Delta (YRD). The total VOCs emission in 2014 was 135500 tons. The HVOCs emission inventory of a typical chemical industry in the YRD was also established from different chemical processes and approximately 52400 tons of HVOCs was emitted in 2014. The most abundant HVOCs species were dichloromethane and benzene. The major chemical processes of HVOCs emissions were for producing polyurethane resin, alkylbenzene, ethylbenzene, acrylic resin, chlorobenzene, ethylbenzene, cyclohexanone, ethylene, and polystyrene.
Keywords:hazardous  volatile organic compounds (VOCs)  emission inventory  chemical industry  Yangtze River Delta
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