不同微波能量输入条件下污泥中碳、氮、磷的释放特性

考察了城市污水处理厂污泥在54kJ和108kJ的微波能量输入条件下碳、氮、磷的释放情况,处理后混合液终温约为56℃、90℃.结果表明,相同污泥浓度条件下,增加微波输入能量后污泥上清液的总碳、有机碳、总氮及总磷浓度明显升高,污泥中总碳、总氮、总磷的释放率提高近1倍,最高分别可达5.26%、22.06%和33.15%,但无机碳、氨氮、正磷酸盐浓度均有不同程度下降.统计分析表明,污泥浓度对总有机碳、总碳、氨氮、总氮、正磷酸盐及总磷的释放具有显著影响,而微波功率仅与污泥中无机碳的释放关联显著.污泥中碳、氮、磷释放的归一化分析结果表明,总磷释放对微波输入能量的利用效率最高,无机碳释放对能量利用率最低.在微波输入能量提高后,污泥浓度相同的样品的无机碳、氨氮及正磷酸盐的归一化指标P(X)平均降低了约67%、73%和56%.

Releases of Carbon, Nitrogen and Phosphorus from Sewage Sludge at Different Microwave Energy Inputs

In this study, the releases of carbon, nitrogen and phosphorus from sludge treated by microwave irradiation were investigated by batch experiments at two microwave energy inputs (MEIs), 54 kJ and 108 kJ. The final temperatures of the treated samples at these two MEIs were about 56℃ and 90℃, respectively. Results showed that the higher MEI was more helpful to release TC, TOC, TN and TP from sludge treated by microwave. The release rates of TC, TN and TP were doubled at the MEI of 108 kJ than that of 54 kJ, and their highest rates were 5.26%, 22.06% and 33.15%, respectively. The MLSS significantly affected releases of TOC, TC, TN, NH_4~+-N, TP and ortho-PO_4~(3-). However, the microwave power (MWP) had no significant effect on these releases except IC. The normalization of these parameters, representing the energy efficiencies of treating sludge, clearly showed that the P (TP) was the highest and the P(IC) was the lowest. However, the average values of P(IC), P(NH_4~+-N) and P(ortho-PO_4~(3-)) decreased at the same MLSS concentration, respectively, about 67%, 73% and 56% when the MEI doubled from 54 kJ to 108 kJ.