| 亚甲基蓝在有机酸膨润土上的吸附行为 |
| |
| 引用本文： | 周娟, 张寒冰, 童张法, 覃岳隆, 陈光浩, 宋振宇, 陶靖鹏. 亚甲基蓝在有机酸膨润土上的吸附行为[J]. 环境工程学报, 2015, 9(3): 1057-1061. doi: 10.12030/j.cjee.20150311 |
| |
| 作者姓名： | 周娟 张寒冰 童张法 覃岳隆 陈光浩 宋振宇 陶靖鹏 |
| |
| 作者单位： | 1. 广西大学化学化工学院, 广西石化资源加工及工程强化技术重点实验室, 南宁 530004; 2. 广西大学环境学院, 南宁 530004 |
| |
| 基金项目： | 国家自然科学基金资助项目(21166004);广西大学科研基金(XBZ120056);广西石化资源加工及过程强化技术重点实验室主任课题基金(2013Z004) |
| |
| 摘 要： | 为了解决染料废水带来的污染问题,采用柠檬酸对天然膨润土(RB)直接改性,制备柠檬酸膨润土(CAB),并探讨了溶液pH值、表面活性剂对CAB去除亚甲基蓝(MB)的影响。研究结果表明,CAB在去除MB方面有很宽的pH适宜范围,溶液pH值对CAB去除MB的影响不大;MB溶液中加入十二烷基苯磺酸钠(SDBS)以后,CAB对MB的去除率基本保持不变,而十六烷基三甲基溴化铵(CTAB)的加入则明显抑制CAB对MB的去除;MB在CAB上的吸附同时符合Langmuir和Redlich-Peterson模型,CAB对MB的Langmuir吸附容量为252 mg/g;CAB表面的羧基和羟基是吸附MB的主要吸附位点。研究表明,CAB是一种在染料的去除方面非常有应用前景的吸附剂。
|
| 关 键 词： | 天然膨润土 柠檬酸膨润土 亚甲基蓝 吸附行为 |
| 收稿时间： | 2014-03-14 |
Adsorption behavior of methylene blue on citric acid bentonite |
| |
| Zhou Juan, Zhang Hanbing, Tong Zhangfa, Qin Yuelong, Chen Guanghao, Song Zhenyu, Tao Jingpeng. Adsorption behavior of methylene blue on citric acid bentonite[J]. Chinese Journal of Environmental Engineering, 2015, 9(3): 1057-1061. doi: 10.12030/j.cjee.20150311 |
| |
| Authors: | Zhou Juan Zhang Hanbing Tong Zhangfa Qin Yuelong Chen Guanghao Song Zhenyu Tao Jingpeng |
| |
| Affiliation: | 1. Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China; 2. School of Environment, Guangxi University, Nanning 530004, China |
| |
| Abstract: | To solve the serious water pollution by dye wastewater, citric acid bentonite (CAB) was obtained by modifying raw bentonite (RB) with citric acid directly and its adsorption performance of methylene blue (MB) was studied as a function of pH and surfactants. It was found that pH had little effect on MB adsorption so CAB had a broad pH range for MB removal. The removal efficiencies of MB on CAB in the presence of sodium dodecylbenzenesulfonate (SDBS) were kept constant while those in the presence of cetyltrimethylammoniun bromide (CTAB) were obviously restrained. MB adsorption on CAB could be described by the Langmuir and Redlich-Peterson models and the respective Langmuir adsorption capacity was 252 mg/g. The groups of carboxyl and hydroxyl were the major adsorption sites for MB removal. In summary, the study suggests that CAB is a promising adsorbent in dyes removal from aqueous solution. |
| |
| Keywords: | raw bentonite citric acid bentonite methylene blue adsorption behavior |
| 本文献已被 CNKI 等数据库收录！ |
| 点击此处可从《环境工程学报》浏览原始摘要信息 |
|
点击此处可从《环境工程学报》下载全文 |
|
