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聚氨酯缓冲材料在2种典型环境下的耐候性研究
引用本文:胡涛,李茜,孙茂钧,孙有美,张宸,王玲.聚氨酯缓冲材料在2种典型环境下的耐候性研究[J].装备环境工程,2023,20(1):119-126.
作者姓名:胡涛  李茜  孙茂钧  孙有美  张宸  王玲
作者单位:西南技术工程研究所,重庆400039;弹药贮存环境效应重点实验室,重庆400039;海南万宁大气环境材料腐蚀国家野外科学观测研究站,海南 万宁 571500
摘    要:目的 研究聚氨酯缓冲材料在湿热海洋和干热沙漠环境下的老化性能。方法 将3种不同表观密度的聚氨酯缓冲材料在万宁和敦煌试验站进行1 a的自然环境试验,探究聚氨酯缓冲材料外观、静态压缩性能、压缩永久变形性能和红外光谱的变化。结果 在1 a的自然环境试验中,材料压缩强度先增大后降低,压缩永久变形逐渐增大;在万宁试验站,样品表面出现发霉现象,密度为25、30、40 kg/m3的聚氨酯缓冲材料的压缩强度分别增大或衰减至106.4%、93.3%、87.5%,压缩永久变形分别增大109%、98%、138%;在敦煌试验站,密度为25、30、40 kg/m3的聚氨酯缓冲材料的压缩强度分别增大或衰减至106.4%、98.2%、97.8%,压缩永久变形分别增大55%、74%、93%。结论 聚氨酯缓冲材料在自然环境中会发生水解和热氧降解等老化反应,使材料性能出现下降。材料表观密度越大,性能衰减越快。材料对于湿热海洋环境更敏感,在万宁站的老化程度大于敦煌站。

关 键 词:聚氨酯(PU)  缓冲材料  自然环境老化  静态力学性能  压缩永久变形中图分类号:TB484.3  文献标识码:A  文章编号:1672-9242(2023)01-0119-08

Weather Resistance of Polyurethane Cushioning Materials in Two Typical Environments
HU Tao,LI Qian,SUN Mao-jun,SUN You-mei,ZHANG Chen,WANG Ling.Weather Resistance of Polyurethane Cushioning Materials in Two Typical Environments[J].Equipment Environmental Engineering,2023,20(1):119-126.
Authors:HU Tao  LI Qian  SUN Mao-jun  SUN You-mei  ZHANG Chen  WANG Ling
Institution:Southwest Institute of Technology and Engineering, Chongqing 400039, China;CSGC Key Laboratory of Ammunition Storage Environmental Effects, Chongqing 400039, China;Wanning Materids Corrosion National Observation and Research Station, Hainan Wanning 571500, China
Abstract:The work aims to study the aging performance of polyurethane cushioning material in hot humid ocean and hot dry desert environments. Through a one-year natural environment experiment of three different apparent densities of polyurethane cushioning materials at Wanning Test Station and Dunhuang Test Station, the appearance, static compression performance, compression set performance and infrared spectrum changes of polyurethane cushioning materials were explored. The results showed that the compressive strength of the material first increased and then decreased, and the compression set gradually increased; In Wanning Test Station, the surface of the sample showed mildew. The compressive strength of polyurethane cushioning materials with densities of 25, 30 and 40 kg/m3 attenuated to 106.4%, 93.3% and 87.5%, respectively, and the compression set increased by 109%, 98% and 138%, respectively; In Dunhuang Test Station, the compressive strength of polyurethane cushioning materials with densities of 25, 30 and 40 kg/m3 increased or attenuated to 106.4%, 98.2% and 97.8%, respectively, and the compression set increased by 55%, 74% and 93%, respectively. The performance of polyurethane cushioning materials will decrease due to aging reactions such as hydrolysis and thermal oxygen degradation in the natural environment. The greater the apparent density of the material, the faster the performance degradation. Thus, the aging degree of polyurethane cushioning material at Wanning Station is greater than that at Dunhuang station, and it is more sensitive to the hot and humid marine environment.
Keywords:polyurethane (PU)  cushioning material  aging in natural environment  static mechanical properties  compression set
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