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掺Al-TiO2改性膨润土去除微污染水中COD和NH4-N
引用本文:吴光锋,聂锦旭,陈仕稳. 掺Al-TiO2改性膨润土去除微污染水中COD和NH4-N[J]. 环境工程学报, 2014, 8(9): 3761-3766
作者姓名:吴光锋  聂锦旭  陈仕稳
作者单位:广东工业大学土木与交通工程学院, 广州 510006;广东工业大学土木与交通工程学院, 广州 510006;广东工业大学土木与交通工程学院, 广州 510006
基金项目:广东省教育部产学研项目(2012B090400030)
摘    要:采用掺Al-TiO2作为改性剂制备改性膨润土,考察了微波辐射功率、辐射时间、TiO2改性剂用量、铝盐掺杂量、pH值对微污染水中COD和NH4-N去除效果的影响。实验表明,微波辐射功率为460 W,辐射时间为8 min,TiO2改性剂用量为1.3 mmol/g,铝盐掺杂量为0.2 mmol/g为最佳制备条件。pH值为6.0,改性膨润土投加量为40 mg/L,沉淀时间为30min时,对微污染水中初始浓度15 mg/L的COD和5 mg/L的NH4-N去除率分别达到92%和59%以上。

关 键 词:改性膨润土  TiO2  微污染水  COD  NH4+

Removal of COD and NH4-N from micro-polluted water by aluminum-doped TiO2 modified bentonite
Wu Guangfeng,Nie Jinxu and Chen Shiwen. Removal of COD and NH4-N from micro-polluted water by aluminum-doped TiO2 modified bentonite[J]. Techniques and Equipment for Environmental Pollution Control, 2014, 8(9): 3761-3766
Authors:Wu Guangfeng  Nie Jinxu  Chen Shiwen
Affiliation:School of Civil and Transportation Engineering, Guangdong University of Technology, Guangzhou 510006, China;School of Civil and Transportation Engineering, Guangdong University of Technology, Guangzhou 510006, China;School of Civil and Transportation Engineering, Guangdong University of Technology, Guangzhou 510006, China
Abstract:Modified bentonite was prepared by means of modifier from aluminum-doped TiO2. Effects of microwave power, microwave time, TiO2 modifier dosage, the amount of aluminous dope and pH value on COD and NH4-N removal efficiency in micro-polluted water were investigated. The experimental results showed that the best prepared conditions were microwave power of 460 W, microwave time of 8 min, TiO2 modifier dosage of 1.3 mmol/g and aluminous-doped dosage of 0.2 mmol/g. Under the following conditions, pH value of 6.0, modified bentonite dosage of 40 mg/L, precipitation time of 30 min, the removal rate of COD and NH4-N will be up to 92% and 59%, respectively at COD concentration of 15 mg/L and NH4-N concentration of 5 mg/L in micro-polluted water.
Keywords:modified bentonite  TiO2  micro-polluted water  COD  NH4+
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