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城市污水再生氯消毒过程中HAAs生成及迁移转化
引用本文:成嘉蕾,韩芸,王冬梅,赵凯.城市污水再生氯消毒过程中HAAs生成及迁移转化[J].环境工程学报,2014,8(9):3731-3736.
作者姓名:成嘉蕾  韩芸  王冬梅  赵凯
作者单位:1. 西安建筑科技大学环境与市政工程学院, 西安 710055;1. 西安建筑科技大学环境与市政工程学院, 西安 710055;1. 西安建筑科技大学环境与市政工程学院, 西安 710055;2. 西安科建环保科技有限公司, 西安 710075;3. 西安创业水务集团有限公司, 西安 710086
基金项目:陕西省自然科学基金资助项目(2012JQ7021);陕西省科技统筹创新(2011KTZB-03-03-03);陕西省教育厅项目(12JS050)
摘    要:针对城市污水再生处理工艺中卤乙酸类(HAAs)消毒副产物和卤乙酸生成潜能(HAAFP),结合三维荧光光谱,分析HAAs及其前体物的变化规律。结果表明,二级出水经2次加氯过程后,再生出水中的总卤乙酸浓度增加了90%,其中溴代乙酸的增幅最大,占增加量的82%。卤乙酸生成潜能较大的为氯代乙酸类物质,说明水中存在大量的氯代乙酸前体物。从工艺过程来看,总卤乙酸生成潜能与总有机物荧光强度分别下降了32%和28%,表明该再生处理工艺对HAAs前体物有一定的去除作用。

关 键 词:城市污水再生  卤乙酸  卤乙酸生成潜能  三维荧光光谱
收稿时间:8/8/2013 12:00:00 AM
修稿时间:9/8/2013 12:00:00 AM

HAAs transformation in municipal wastewater reclaimation process during chlorine disinfection
Cheng Jialei,Han Yun,Wang Dongmei and Zhao Kai.HAAs transformation in municipal wastewater reclaimation process during chlorine disinfection[J].Techniques and Equipment for Environmental Pollution Control,2014,8(9):3731-3736.
Authors:Cheng Jialei  Han Yun  Wang Dongmei and Zhao Kai
Institution:1. School of Environmental and Municipal Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China;1. School of Environmental and Municipal Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China;1. School of Environmental and Municipal Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China;2. Xi'an Kejian Environmental Protection Technology Co. Ltd., Xi'an 710075, China;3. Xi'an Capital Water Co. Ltd., Xi'an 710086, China
Abstract:In municipal wastewater reclaimation process, the variation of HAAs and HAAFP was investigated, and the concentration of HAAs precursors was analyzed with 3DEEM. The results showed that the concentration of total HAAs increased by 90% after twice chlorination, while the biggest increasing was bromated HAAs, accounting for 82%. Chlorinated HAAFP was the largest, indicating that there were a lot of chlorinated HAAs precursors. From the process, the total HAAFP and organic matter fluorescence intensity decreased by 32% and 28%, respectively, indicating that the reclaimed treatment had a certain effect on HAAs precursors removal.
Keywords:municipal wastewater reclaimation  HAAs  HAAFP  3DEEM
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