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纳米TiO2光催化氧化微量丙酮气的研究
引用本文:许红娟,刘建周,江晶亮,陆富生,吴杰,陈娟,庄盈,刘涛,徐正新,戴新联,童敏明. 纳米TiO2光催化氧化微量丙酮气的研究[J]. 环境科技, 2008, 21(6): 17-19
作者姓名:许红娟  刘建周  江晶亮  陆富生  吴杰  陈娟  庄盈  刘涛  徐正新  戴新联  童敏明
作者单位:1. 中国矿业大学化工学院,江苏,徐州,221008
2. 中国矿业大学信电学院,江苏,徐州,221008
基金项目:国家自然科学基金  
摘    要:
采用溶胶-凝胶法制备了纳米TiO2膜。测试了TiO2光催化剂对微量丙酮气的催化氧化反应性能的测试。结合TG,XRD及TEM等对催化剂的表征,研究了纳米TiO2膜的制备条件对其结构和反应性能的影响,探索了纳米TiO2膜光催化氧化的机理。结果表明:制得的TiO2膜平均粒径为20nm,TiO2膜经550℃焙烧后呈现锐钛型和少量金红石型晶体的混晶。当金红石型的质量分数为13.6%时,TiO2光催化剂表现出较好的催化活性,丙酮的转化率最高达到45.26%。

关 键 词:纳米TIO2  光催化氧化  丙酮

Study on Photocatalytic Oxidation of Micro Acetone by Nano-TiO2
XU Hong-juan,LIU Jian-zhou,JIANG Jing-liang,LU Fu-sheng,WU Jie,CHEN Juan,ZHUANG Ying,LIU Tao,XU Zheng-xin,DAI Xin-lian,TONG Min-ming. Study on Photocatalytic Oxidation of Micro Acetone by Nano-TiO2[J]. Jiangsu Environmental Science and Technology, 2008, 21(6): 17-19
Authors:XU Hong-juan  LIU Jian-zhou  JIANG Jing-liang  LU Fu-sheng  WU Jie  CHEN Juan  ZHUANG Ying  LIU Tao  XU Zheng-xin  DAI Xin-lian  TONG Min-ming
Affiliation:XU Hong-juan, LIU Jian-zhou, JIANG Jing-liang, LU Fu-sheng, WU Jie, CHEN Juan, ZHUANG Ying, LIU Tao, XU Zheng-xin, DAI Xin-lian, TONG Min-ming
Abstract:
The nano-TiO2 films were prepared with sol-gel method. The photocatalytic oxidation reaction performances of these photocatalysts in the micro acetone mixed with air were tested. The catalyst samples were characterized by TG, XRD and TEM etc, and the effect of preparation conditions on their structure and reaction activities were studied, and the photocatalytic oxidation mechanism were explored. The results showed that the average particle diameter of these photocatalysts was 20 nm. The nano-TiO2 films calcined at 550 ℃ had two crystal phases, anatase and rutile. When the content of the rutile was 13.6 %, the nano--TiO2 photocatalysts had better activity, and the conversion of acetone was 45.26 %.
Keywords:Nano-TiO2  Photocatalytic oxidation  Acetone
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