The Long Term Weathering of Water-in-Oil Emulsions

This paper summarizes studies to determine the long-term stability of water-in-oil emulsions in the laboratory and in large tanks. The long-term stability of emulsions was investigated in the laboratory for up to 9 years and by studying emulsion formation in a large test tank over a period of 2-10 days.Two stable emulsions, formed in the laboratory, had been preserved for 5 and 9 years and remained stable despite a small water loss. The long-term stability appears to be similar to that for the short-term stability. Stable emulsion breakdown processes remain poorly understood, because these emulsions do not generally breakdown, but the primary processes may be mechanical break-up and water evaporation.The water-in-oil states produced were found to have analogous properties between the laboratory and two sets of experiments at a large test tank. No fundamental differences in states or properties were observed over the time periods studied (up to 222 h). The state of the oil was found to correlate well with a stability index as defined by the complex modulus divided by the oil viscosity. It is shown that this stability index becomes more useful when the viscosity of the oil is taken at the same time as the complex modulus measurement.The studies show that meso-stable emulsions will break down within 3 days, generally within 1 day and that those emulsions classified as stable remain up to 9 years under laboratory conditions. These studies also show that meso-stable emulsions do not reform, once broken.