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Oil-Mineral Aggregate Formation on Oiled Beaches: Natural Attenuation and Sediment Relocation
Authors:Kenneth Lee  Patricia Stoffyn-Egli  Edward H Owens  Gary A Sergy  Chantal C Guénette  Roger C Prince
Institution:a Centre for Offshore Oil and Gas Environmental Research, Bedford Institute of Oceanography, Fisheries and Oceans Canada, P.O. Box 1006, 1 Challenger Drive, Dartmouth, NS, Canada B2Y 4A2
b BDR Research Limited, P.O. Box 652, Halifax, NS, Canada B3J 2T3
c Polaris Applied Sciences, Inc., #302, 755 Winslow Way East, Bainbridge Island, WA 98110, USA
d Environment Canada, #200, 4999, 98th Ave., Edmonton, AB, Canada T6B 2X3
e SINTEF Applied Chemistry, Environmental Engineering, 7034 Trondheim, Norway
f ExxonMobil Research and Engineering Co., Annandale, NJ 08801, USA
h Regional Oceans and Environmental Branch, Maurice Lamontagne Institute, Fisheries and Oceans Canada, P.O. Box 1000, Mont Joli, QC, Canada G5H 3Z4
Abstract:The significance of oil-mineral aggregate (OMA) formation on the effectiveness of the in situ shoreline treatment options of natural attenuation (natural recovery) and sediment relocation (surf washing) was examined during field trials on two mixed-sediment (sand and pebble) beaches experimentally oiled with IF-30 oil. At both sites, the amount of oil remaining in the experimental plots was dramatically reduced within five days after sediment relocation treatments. Time-series microscopy and image analysis of breaker-zone water samples demonstrate that OMA formation occurred naturally on the oiled beaches at both sites and was accelerated by the sediment relocation procedure. Lower concentrations of OMA in the breaker zone at Site 3 are attributed to the higher wave-energy levels at this site that presumably facilitated more rapid OMA dispersion. The granulometry and mineralogy of beach sediment and of subtidal sediment trap samples indicate that the material settling in nearshore waters originated from the relocated sediment and that a portion of the finer sediment was probably transported out of the study region before settling. Gas chromatography/mass spectrometry analysis demonstrated that a significant fraction of the oil dispersed into nearshore waters and sediments by interaction with mineral fines was biodegraded. The fact that little or no residual oil was found stranded on the shore in areas adjacent to the experimental plots and that only small amounts of oil were found in nearshore subtidal sediments and sediment trap samples suggests that a large fraction of the oil lost from the experimental plots may have been dispersed in the form of relatively buoyant OMA.
Keywords:Oil spill remediation  oil dispersion  oil-mineral aggregation  fine sediment  biodegradation
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