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电极构型对空气阴极生物燃料电池发电性能的影响
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中文关键词  空气阴极生物燃料电池(ACMFC)  设计模式  功率密度  电子回收率
英文关键词  Air-cathode microbial fuel cell (ACMFC)  Electrode configuration  Power density  Electron recovery efficiency
作者单位
尤世界 哈尔滨工业大学市政环境工程学院哈尔滨150090 
赵庆良 哈尔滨工业大学市政环境工程学院哈尔滨150090 
姜珺秋 哈尔滨工业大学市政环境工程学院哈尔滨150090 
中文摘要
      在空气阴极生物燃料电池(ACMFC)中,从阴极扩散进入阳极的氧气能够被兼性微生物作为电子受体还原,进而导致电子损失严重;此外,有关电极构型对功率输出的影响还需进行深入的研究。本文利用葡萄糖作底物,对两种不同电极构型的空气阴极生物燃料电池ACMFC1和ACMFC2的功率输出和电子回收进行了比较研究,结果表明,ACMFC1的内阻为302.14Ω,阳极电位为-323mV,最大功率密度为3070 mW/m3;ACMFC2的内阻为107.79Ω,阳极电位为-442mV,最大功率密度达到9800 mW/m3。在间歇条件下,ACMFC2可以连续运行220h,电子回收率为30.1%;而ACMFC1只能运行不到50h,电子回收率为9.78%。因此,合理的设计空气阴极生物燃料电池电极构型可以减小内阻,增大电池电动势进而增大功率输出,提高电子回收率。
英文摘要
      In air-cathode microbial fuel cell (ACMFC), oxygen diffused into the reactor from cathode without PEM can be reduced as electron acceptor via aerobic respiration by facultative microorganisms, resulting in either a decreasing of power generation or electron loss. Meanwhile, how electrode configuration as a factor influences power generation from ACMFC requires to be further explored in detail. In this study, ACMFC1 and ACMFC2 with different electrode configuration were compared to examine power density and electron recovery from glucose. The results showed that ACMFC1 generated a maximum power density of 3070mW/m3 with internal resistance of 302.14Ω and anode potential of -323mV; while maximum power density of 9800mW/m3 for ACMFC2 was obtained with internal resistance of 107.79Ω and anode potential of -442mV. ACMFC2 could sustain generating electricity for nearly 220 h (ERE of 30.1%), comparing with ACMFC1 of less than 50 h (ERE of 9.78%) under batch operation. Therefore, an improved design for electrode configuration of ACMFC can be performed to generate higher power with low internal resistance, meanwhile, achieve increasing electron recovery simultaneously.

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