城市生态保护红线划定方法与实践

基于近10年来我国城市(群)地区生态保护红线划分的实践经验,结合环境总体规划的探索,提出了一套城市生态保护红线体系与划分方法。首先,按照"识-评-落-合"的技术流程,划定城市生态功能红线。其次,通过识别大气环境和水环境的重要性,敏感性和脆弱性,划定环境质量红线。第三,基于合理的模型方法计算大气环境、水环境和自然资源承载力,分析测算环境资源开发上限。最后,借助GIS软件实现这三条红线的空间叠加,综合划分出生态保护红线。上述生态保护红线体系,与现有的各部门空间和资源管理制度能进行充分有序的衔接,可以作为促进新型城镇化健康发展的资源环境管理基础平台。     

省级生态保护红线划定实践研究 ——以青岛市为例

在省级及以上禁止开发区、重点生态功能保护区等进行调查分析的基础上,以青岛市为实践区域,与多类规划衔接,划定青岛市省级生态保护红线.青岛市最终划定59处省级生态保护红线区,面积合计1120.65 km2,占国土面积的9.9%.划定的生态保护红线符合确立"三生"空间和落实"多规合一"的要求,有利于改善生态系统服务功能,保障人居环境安全,增强经济社会可持续发展能力,对于青岛市市级生态保护红线的划定和生态安全格局的构建具有非常重要的意义.     

推进生态保护红线落地 保障生态文明制度建设

划定生态保护红线是规范和约束各类开发利用活动,保障国家和区域生态安全的必然举措,是全面深化改革,加快推进生态文明制度建设与创新的重要任务。在总结我国生态保护红线划定理论与实践基础上,揭示了生态保护红线划定与管理过程中面临的问题与挑战,据此提出建立完善生态保护红线制度体系的对策建议,为推动生态保护红线战略的实施提供借鉴。     

基于禀赋与压力的城市环境综合分区理论与方法研究

环境综合分区是城市环境总体规划的主要任务和落实资源合理利用与生态环境保护空间约束的重要手段.基于资源环境禀赋和压力的环境综合分区理论与方法,在生态功能分区和大气环境、水环境、水资源、土地资源分区基础上,提出城市环境综合分区二级区划方案,以大连市为例进行实证研究.根据综合分区方案,针对资源环境问题和发展现状,细化生态保护红线及产业空间准入线,引导城市资源利用与环境保护,更好地指导城市建设与产业发展.     

新政

正《关于划定并严守生态保护红线的实施方案》审议通过按照中央部署要求,为落实统筹经济发展与生态保护,科学划定全省生态保护红线,严格落实各级党委和政府主体责任,强化生态保护红线刚性约束,努力实现一条红线管控重要生态空间,3月22日,广东省政府常务会议审议并原则通过《关于划定并严守生态保护红线的实施方案》,决定经修改后提交省委全面深化改革领导小组会议审议。     

山东省生态保护红线划定实践与管理策略

生态保护红线的划定是山东省推进生态文明建设的重要举措。文中介绍了山东省生态保护红线划定的背景、组织形式、划定原则、划定范围和方法以及划定结果,分析了生态保护红线划定之后的管理策略,总结了生态保护红线划定经验,提出了生态保护红线制度体系构建建议,为其他省市生态保护红线划定提供参考和借鉴。     

城市生态保护红线划定技术研究——以宜昌市为例

划定生态保护红线,是生态文明建设的一项重要任务,对维护国家和区域生态安全及经济社会可持续发展具有重要的战略意义。目前,城市化发展中面临着突出生态环境问题,在城市层面开展生态保护红线的划定工作显得更加紧迫。但现阶段生态保护红线的划分技术上仍处于不断探索与完善阶段。基于此,文章以湖北省宜昌市为例,利用RS和GIS技术,采用"识-评-落-融-分"的技术流程,提出了一套城市生态保护红线体系与划分方法。结果表明:宜昌市生态保护红线体系划分为3个层级:生态保护红线区、生态保护黄线区和生态保护绿线区;生态保护红线区、黄线区和绿线区分别占全市面积的48.83%、31.50%和19.67%。     

云南省生态保护红线划定与管理思考

划定生态保护红线写入《环境保护法》,标志着中国将以强制性法律手段实施国土空间管控体系建设。本文介绍了云南省生态保护红线划定的原则、划定类型和方法,分析了划定实际推动过程中存在的和可能出现的问题,提出了构建生态红线体系的思考。生态保护红线划定从已有法定保护区域入手,将现有法定空间管控范围进行梳理和归纳,以维护云南生态系统完整性为目标,按分区分类的原则进行划定,完成云南省生态保护红线"一张图",再将工作向纵深推进,在县市开展"多规合一"工作阶段落地。同时,生态保护红线作为生态环境保护的一项制度创新,应建立一套综合管理体系,以划定范围为管控基础,建立红线区切实可行管控办法,建立健全生态补偿渠道和补偿机制。通过生态红线政绩考核体制和责任追究制度的建立和完善,实现"绿水青山就是金山银山",最终推动国土空间管控体系的制度创新。     

面向空间管控的环境总体规划研究与实践

以ARCGIS为技术平台,基于空间数据,利用空间分析、统计学、遥感等多种方法,通过对区域生态系统服务功能的评价,采用主导因素法对区域环境功能进行识别,综合考虑评价单元具有重要影响的主导因子及相关的政策、规划,对区域环境空间管控格局进行解析。以瑞丽市为例进行研究,系统划定城市环境资源上线、生态保护红线、环境质量底线,构建城市发展的环境约束的底线框架。     

基于生态约束的城市开发边界模拟研究——以南京为例

城市开发边界划定是国土空间规划的重要内容,也是实施国土空间管治、城乡建设管理和生态安全管控的关键抓手,对于推动城市空间高质量发展具有基础性和约束性作用。综合利用回归分析模型、InVEST模型和CA模型,探索构建基于生态约束的城市开发边界划定方法,并以南京市中心城区为例,在评价城市生态用地重要性和建设用地空间扩展潜力基础上,开展不同目标年份的城市用地扩张模拟,据此划定城市开发边界。研究表明：城市建设用地扩张具有动态性、复杂性、系统性特征,受到多因子相互作用,基于生态约束的城市开发边界模拟能够兼顾城市空间发展需求和居民高品质生态环境诉求,促进城市发展与生态保护相统一、人口经济和资源环境相协调,有助于丰富城市开发边界划定方法研究,为国土空间规划编制提供科学参考。     

Effects of two sludge application on fractionation and phytotoxicity of zinc and copper in the soil

The potential harm of heavy metals is a primary concern in application of sludge to the agricultural land. A pot experiment was conducted to evaluate the effect of two sludges on fractionation of Zn and Cu in soil and their phytotoxicity to pakchoi. The loamy soil was mixed with 0%, 20%, 40%, 60% and 80% (by weight) of digested sewage sludge (SS) and composted sludge (SC). The additions of both sludges caused a significant raise in all fractions, resulting in that exchangeable (EXCH) and organic bound (OM) became predominance of Zn and organic bound Cu occupied the largest portion. There was more available amount of Zn and Cu in SS treatments than SC treatments. During the pot experiment, the concentration of Zn in EXCH, carbonate (CAR) and OM and Cu in EXCH and OM fractions decreased in all treatments, so their bioavailability reduced. Germination rate and plant biomass decreased when the addition rate was high and the best yield appeared in 20% mixtures at the harvest of pakchoi. The two sludges increased tissue contents of Zn and Cu especially in the SS treatments. Zn in pakchoi was not only in relationship to ΔEXCH and ΔCAR forms but also in ΔOM forms in the sludge-soil mixtures. Tissue content of Cu in pakchoi grown on SC-soils could not be predicted by ΔEXCH. These correlation rates between Zn and Cu accumulation in pakchoi and variation of different fractions increased with time, which might indicate that sludges represented stronger impacts on the plant in long-term land application.     

Intraspecific differences in effects of co-contamination of cadmium and

A hydroponic experiment was carried out to study intraspecific differences in the effects of different concentrations of cadmium (Cd)(0-10 mg/L) and arsenate (As(V)) (0-8 mg/L) on the growth parameters and accumulation of Cd and As in six wheat varieties Jing-9428, Duokang-1, Jingdong-11, Jing-411, Jingdong-8 and Zhongmai-8. The endpoints of wheat seedlings, including seed germination,biomass, root length and shoot height, decreased with increasing the Cd and As concentrations. Significant differences in seed germination, biomass, root length, shoot height and the accumulation of Cd and As were observed between the treatments and among the varieties (p ＜ 0.05). The lethal dosage 50% were about 20, 80, 60, 60, 80 and 20 mg As/L for Jing-9428, Duokang-1, Jingdong-11,Jing-411, Jingdong-8 and Zhongmai-8, respectively, and the corresponding values for Cd were about 30, 80, 20, 40, 60 and 10 mg Cd/L, respectively. Among the six varieties, Duokang-1 was found to be the most resistant to Cd and As toxicity, and Zhongmai-8 was the most sensitive to Cd and As co-contamination. The resistance of the six varieties was found dependant on the seedling uptake of Cd and As. Duokang-1 was the most suitable for cultivation in Cd and As co-contaminated soils.     

Toxic effects of acetochlor, methamidophos and their combination on nifH gene in soil

Toxic effects of two agrochemicals on nifH gene in agricultural black soil were investigated using denaturing gradient gel electrophoresis （DGGE） and sequencing approaches in a microcosm experiment. Changes of soil nifH gene diversity and composition were examined following the application of acetochlor, methamidophos and their combination. Acetochlor reduced the nifH gene diversity （both in gene richness and diversity index values） and caused changes in the nifH gene composition. The effects of acetochlor on nifH gene were strengthened as the concentration of acetochlor increased. Cluster analysis of DGGE banding patterns showed that nifH gene composition which had been affected by low concentration of acetochlor （50 mg/kg） recovered firstly. Methamidophos reduced nifH gene richness that except at 4 weeks. The medium concentration of methamidophos （150 mg/kg） caused the most apparent changes in nifH gene diversity at the first week while the high concentration of methamidophos （250 mg/kg） produced prominent effects on nifH gene diversity in the following weeks. Cluster analysis showed that minimal changes of nifH gene composition were found at 1 week and maximal changes at 4 weeks. Toxic effects of acetochlor and methamidophos combination on nifH gene were also apparent. Different nifH genes （bands） responded differently to the impact of agrochemicals： four individual bands were eliminated by the application of the agrochemicals, five bands became predominant by the stimulation of the agrochemicals, and four bands showed strong resistance to the influence of the agrochemicals. Fifteen prominent bands were partially sequenced, yielding 15 different nifH sequences, which were used for phylogenetic reconstructions. All sequences were affiliated with the alpha- and beta-proteobacteria, showing higher similarity to eight different diazotrophic genera.     

EDTA-enhanced phytoremediation of lead contaminated soil by Bidens maximowicziana

Phytoremediation is a potential cleanup technology for the removal of heavy metals from contaminated soils.Bidens maximowicziana is a new Pb hyperaccumulator,which not only has remarkable tolerance to Pb but also extraordinary accumulation capacity for Pb.The maximum Pb concentration was 1509.3 mg/kg in roots and 2164.7 mg/kg in overground tissues.The Pb distribution order in the B. maximowicziana was:leaf>stem>root.The effect of amendments on phytoremediation was also studied.The mobility of soil Pb and the Pb concentrations in plants were both increased by EDTA application.Compared with CK(control check),EDTA application promoted translocation of Pb to overground parts of the plant.The Pb concentrations in overground parts of plants was increased from 24.23-680.56 mg/kg to 29.07-1905.57 mg/kg.This research demonstrated that B.maximowicziana appeared to be suitable for phytoremediation of Pb contaminated soil,especially,combination with EDTA.     

Distribution and ecological effect of mercury in Laogang landfill, Shanghai, China

Laogang landfill near Shanghai is the largest landfill in China, and receives about 10000 t of daily garbage per day, Samples of topsoil and plants were analyzed to evaluate mercury pollution from the landfill. For topsoil samples, there were significant correlations among total mercury （HgT）, combinative mercury （Hgc） and gaseous mercury （HgG）, and content of total organic carbon （TOC）, but, no significantly relationship was found between Hg content and filling time. Hg content changes in vertical profiles with time showed that the average Hgv of profiles 1992, 1996, and 2000 was similar, but their average HgG was quite different. HgT was significantly correlated with Hgc in profile 1992 and 2000, and Hgv was significantly correlated with Hg6 in profile 1996. HgG/Hgv ratio in profile samples decreased in the order of （HgG,/HgT）1992〉（HgG/HgT）1996〉〉（HgG/HgT）2000. A simple outline of Hg release in landfill could be drawn： with increasing of filling time, degradation undergoes different biodegradation, accordingly, gaseous mercury goes through small, more, and small proportion to total mercury. Distribution of Hg in plants was inhomogeneous, following the order of leaf〉root〉stem. The highest value of leaf may be associated with higher atmospheric Hg from landfill. Ligneous plants （e.g. Phyllostachys glanca, Prunus salicina and Ligustrum lucidum） are capable of enriching more Hg than herbaceous plants.     

Arsenic uptake by arbuscular mycorrhizal maize （Zea mays L.） grown in an arsenic-contaminated soil with added phosphorus

The effects of arbuscular mycorrhizal (AM) fungus (Glomus mosseae) and phosphorus (P) addition (100 mg/kg soil) on arsenic (As) uptake by maize plants (Zea mays L.) from an As-contaminated soil were examined in a glasshouse experiment.Non-mycorrhizal and zero-P addition controls were included.Plant biomass and concentrations and uptake of As,P,and other nutrients,AM colonization,root lengths,and hyphal length densities were determined.The results indicated that addition of P significantly inhibited root colonization and development of extraradical mycelium.Root length and dry weight both increased markedly with mycorrhizal colonization under the zero-P treatments,but shoot and root biomass of AM plants was depressed by P application.AM fungal inoculation decreased shoot As concentrations when no P was added,and shoot and root As concentrations of AM plants increased 2.6 and 1.4 times with P addition,respectively.Shoot and root uptake of P,Mn,Cu,and Zn increased,but shoot Fe uptake decreased by 44.6%,with inoculation, when P was added.P addition reduced shoot P,Fe,Mn,Cu,and Zn uptake of AM plants,but increased root Fe and Mn uptake of the nonmycorrhizal ones.AM colonization therefore appeared to enhance plant tolerance to As in low P soil,and have some potential for the phytostabilization of As-contaminated soil,however,P application may introduce additional environmental risk by increasing soil As mobility.     

Enzymatic oxidation of aqueous pentachlorophenol

The influence of the nonionic surfactant Tween 80 on pentachlorophenol （PCP） oxidation catalyzed by horseradish peroxidase was studied. The surfactant was tested at concentrations below and above its critical micelle concentration （CMC）. Enhancement of PCP removal was observed at sub-CMCs. The presence of Tween 80 in the reaction mixture reduced enzyme inactivation which occurred through a combination of free radical attack and sorption by precipitated products. A simple first-order model was able to simulate time profiles for enzyme inactivation in the presence or absence of Tween 80. At supra-CMCs, the surfactant caused noticeable reductions in PCP removal, presumably through micelle partitioning of PCP which precluded the hydrophobic PCP molecule from interacting with the enzyme.     

Decomposition of alachlor by ozonation and its mechanism

Decomposition and corresponding mechanism of alachlor, an endocrine disruptor in water by ozonation were investigated. Results showed that alachlor could not be completely mineralized by ozone alone. Many intermediates and final products were formed during the process, including aromatic compounds, aliphatic carboxylic acids, and inorganic ions. In evoluting these products, some of them with weak polarity were qualitatively identified by GC-MS. The information of inorganic ions suggested that the dechlorination was the first and the fastest step in the ozonation of alachlor.     

Degradation of metabolites accumulated of benzo[a]pyrene by coupling Penicillium Chrysogenum with KMnO4

Several main metabolites of benzo[a]pyrene （BaP） formed by Penicillium chrysogenum, Benzo[a]pyrene-1,6-quinone （BP 1,6- quinone）, trans-7,8-dihydroxy-7,8-dihydrobenzo[a]pyrene （BP 7,8-diol）, 3-hydroxybenzo[a]pyrene （3-OHBP）, were identified by high-performance liquid chromatography （HPLC）. The three metabolites were liable to be accumulated and were hardly further metabolized because of their toxicity to microorganisms. However, their further degradation was essential for the complete degradation of BaP. To enhance their degradation, two methods, degradation by coupling Penicillium chrysogenum with KMnO4 and degradation only by Penicillium chrysogenum, were compared; Meanwhile, the parameters of degradation in the superior method were optimized. The results showed that （1） the method of coupling Penicillium chrysogenum with KMnO4 was better and was the first method to be used in the degradation of BaP and its metabolites; （2） the metabolite, BP 1,6-quinone was the most liable to be accumulated in pure cultures; （3） the effect of degradation was the best when the concentration of KMnO4 in the cultures was 0.01% （w/v）, concentration of the three compounds was 5 mg/L and pH was 6.2. Based on the experimental results, a novel concept with regard to the bioremediation of BaP-contaminated environment was discussed, considering the influence on environmental toxicity of the accumulated metabolites.     

Impact of atrazine and nitrogen fertilizers on the sorption of chlorotoluron in soil and model sorbents

Sorption of chlorotoluron in ammonium sulfate, urea and atrazine multi-solutes system was investigated by batch experiments. The results showed application of nitrogen fertilizers to the soil could affect the behavior of chlorotoluron. At the same concentration of N, sorption of chlorotoluron decreased as the concentration of atrazine increased on the day 0 and 6 in soil, respectively. The sorption of chlorotoluron increased from 0 to 6 d when soils were preincubated with deionized water, ammonium sulfate and urea solution for 6 d. That indicated incubation time was one of the most important factors for the sorption of chlorotoluron in nitrogen fertilizers treatments. The individual sorption isotherms of chlorotoluron in rubbery polymer and silica were strictly linear in single solute system, but there were competition sorption between pesticides or between pesticides and nitrogen fertilizers. That indicated the sorption taken place by concurrent solid-phase dissolution mechanism and sorption on the interface of water-organic matter or water-mineral matter.