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1.
A study of the enhancement of the collection efficiency of granular bed filters by electrical means is reported. By applying electric fields of a few kV/cm (DC or AC) across a bed of insulating granules, the efficiency for submicron charged aerosol is greatly increased, to the point where the efficiency minimum normally observed with such filters in the size range 0.1–1 μm is removed. The performance of such filters is explored as a function of granule size, applied field, face velocity and charge state of the entering aerosol with both a bench-scale flow system (to 40 ft3/min; 1.1 m3/min) and a wind tunnel (to 600 ft3/min; 17 m3/min). Some theoretical estimates are made to identify the most likely physical mechanism of electrical enhancement, and a number of potential application possibilities are discussed.  相似文献   

2.
Fine particle filtration efficiencies of electrically enhanced granular beds are computed and compared with available experimental data. Collection efficiencies of a single bed sphere in a gaseous flow are first calculated by numerically solving the equations of particle motion. The collection mechanisms incorporated here are inertial impaction, interception, and charged fine particle-imposed electric field interaction. The approach is based upon a “unit cell” model which enables one to include the effects of surrounding bed particles on the collection process. Stokes' flow and potential flow are used to model the gas flow around the bed particle. Total efficiency is computed by integrating the single-sphere collection efficiency over the bed volume. These calculated total bed efficiencies compare satisfactorily with data obtained from an existing granular bed facility over a range of parameter values. Both theory and experimental data show that the electrical force significantly enhances particulate collection in granular beds.  相似文献   

3.
The authors investigate the effect of filtration and aerosol loading of the air on the level of short-lived air-borne daughter products of radon. By the use of a combination of filtration and aerosol loading, it is possible to shift the partitioning of the radon daughters in the room between the states: airborne, plated-out on the walls, and trapped by filters; the airborne fraction will shift between being attached to aerosol particles and existing as molecular-sized clusters. When the air filtered the equilibrium factor decreases with increasing filtration rate. At high aerosol concentrations the decrease can be explained solely as an effect of the filter removing the daughter products from the air passing through it. As the aerosol production and concentration is lowered, the decrease in equilibrium factor becomes larger. This is caused by an increase in the unattached fraction of the airborne activity and hence in the wall-deposited fraction of the total activity. At a given radon concentration, the dose delivered to a certain portion of the respiratory tract depends not only upon the equilibrium factor but also upon the fraction of, especially, 84218Po in the unattached state. It is further demonstrated that, according to the dose model of Harley and Pasternak, the dose to the basal cells of the epithelium of the bronchii will in general decrease with increasing filtration rate and increase with decreasing aerosol concentration.  相似文献   

4.
The statistical mechanics of particles at the surface of a dust deposit are presented as a step towards a microscopic theory of electrostatic precipitation. The paper consists of three major divisions: (1) field induced entrainment, (2) particle condensation at the surface, and (3) hydrodynamic limits on precipitation.In the first part of this paper, the entrainment of dust from surfaces by electrostatic forces was considered as a simple Markov process. A choice of x−1 for the dependence of the adhesive potential (van der Waals particle attraction) led to an exponential emission rate in the Kramers-Chandrasekhar approximation. This result suggested a simple experimental procedure for determining the adhesive properties of the dust. In addition it was found that both thermal Brownian and particle-deposit collisions contribute to the entrainment.In the second part, the precipitation problem was discussed in terms of a two-dimensional Ising model. The Markovian assumption demanded that the efficiency of the electrostatic precipitator be divided into a product of factors depending on particle migration and condensation in the two-dimensional surface. From this perspective a new collection criterion was established and the importance of particle collisions at the surface of the deposit was demonstrated.Finally, in the third part the role of bulk fluid flows in particle condensation and migration was addressed. The superficial gas flow and secondary flow were found to introduce anisotropy into the Ising lattice and also to enhance the mean particle energy at the surface. The Navier Stokes Equation was numerically integrated for the case of a wire-plate type corona. Plots of the stream function and gas velocity profile were presented and these suggested the existence of a lower limit on the shear stress that acts on surface particles.  相似文献   

5.
昆明市街道灰尘粒度特征及其环境意义   总被引:4,自引:0,他引:4  
对昆明市2008年1、3、4、5、7和9月份6次采集的街道灰尘样品进行了粒度分析。结果表明:昆明市街道灰尘粒度主要呈三峰特征,第一众数为65~125 μm,第二众数为3~15 μm,第三众数为0.15~0.3 μm,平均粒径范围在39.91~255.85 μm,平均值为87.1 μm,旱季(90.6 μm)大于雨季(83.7 μm);粒度分布以正偏度为主,峰态为中等到偏窄且不对称,分选很差;与现代粉尘源区尘暴降尘的粒度分布模式高度相似,街道灰尘沉积是大气环流对远近不同距离粗细颗粒物的混合搬运的结果,应是风积作用的继续;灰尘细粒含量较高,≤100 μm的颗粒平均为635%,在适当的大气动力条件下,昆明市街道灰尘颗粒有60%~90%可以进入大气;灰尘主要来源于土壤风沙尘、建筑尘、工业烟尘和汽车尾气排放,灰尘中可吸入颗粒平均占25.2%,潜在危害性大。  相似文献   

6.
Fine particle (aerodynamic diameter <2.5 microm) samples were collected during six intensive measurement periods from November 2001 to August 2003 at Gosan, Jeju Island, Korea, which is one of the representative background sites in East Asia. Chemical composition of these aerosol samples including major ion components, trace elements, organic and elemental carbon (OC and EC), and particulate polycyclic aromatic hydrocarbons (PAHs) were analyzed to study the impact of long-range transport of anthropogenic aerosol. Aerosol chemical composition data were then analyzed using the positive matrix factorization (PMF) technique in order to identify the possible sources and estimate their contribution to particulate matter mass. Fourteen sources were then resolved including soil dust, fresh sea salt, transformed natural source, ammonium sulfate, ammonium nitrate, secondary organic carbon, diesel vehicle, gasoline vehicle, fuel oil combustion, biomass burning, coal combustion, municipal incineration, metallurgical emission source, and volcanic emission. The PMF analysis results of source contributions showed that the natural sources including soil dust, fresh and aged sea salt, and volcanic emission contributed to about 20% of the measured PM(2.5) mass. Other primary anthropogenic sources such as diesel and gasoline vehicle, coal and fuel oil combustion, biomass burning, municipal incineration, metallurgical source contributed about 34% of PM(2.5) mass. Especially, the secondary aerosol mainly involved with sulfate, nitrate, ammonium, and organic carbon contributed to about 39% of the PM(2.5) mass.  相似文献   

7.
Since the deposition of particulate in the respiratory system is strongly influenced by particle size, a correct assessment of this parameter is important for any inhalation experiment studying the potential health effects of air pollutants. Measuring the distribution of particles according to their aerodynamic diameter and mechanical mobility diameter is crucial in analyzing the deposition of submicron particles in the lower respiratory system. Cascade impactor measurements of diluted diesel exhaust in 12.6 m3 animal exposure chambers in the GMR Biomedical Science Department showed that the mass median aerodynamic diameter of the aerosol was 0.2 μm with 88% of the mass in particles smaller than 1 μm. Diffusion battery measurements showed that the mass median mechanical mobility diameter was about 0.11 μm. Transmission electron micrographs of particles deposited on chamber surfaces revealed both agglomerates and nearly spherical particles. The particles in these chambers are similar in size and shape to diesel particles described elsewhere. The flux of diesel particles to food surfaces was measured. Calculations of the expected daily dose by inhalation and by feeding showed that the “worst case” dose by feeding was only about one-tenth the dose by breathing.  相似文献   

8.
As a consequence of the nuclear accident that took place in Palomares (Almería, Spain) more than 40 years ago, actinides contamination is present in the area nowadays. Previous investigations performed with soil samples collected in different locations of Palomares indicate that the contamination in the area is highly inhomogeneous, suggesting the existence of radioactive particles, thus hindering the evaluation of the radiological situation. This work presents the methodology used for the location of the radioactive particles in the field and their isolation in the laboratory for further speciation and characterization studies. Colour pictures, electron microscopy images and EDX analyses show that most of the studied particles present a granular appearance with a variable grain size and a high fragmentation tendency, being plutonium and uranium the most abundant nuclear elements. Radiochemical determinations and activity isotopic ratios prove that the nuclear material is aged weapon grade plutonium arising from the Palomares accident.  相似文献   

9.
BackgroundStudies measuring health effects of Saharan dust based on large particulate matter (PM) fraction groups may be masking some effects. Long distant transport reduces the amount of heavier and larger particles in the Saharan air masses increasing the relative contribution of smaller particles that may be more innocuous. This study investigates the association between different PM fractions and daily mortality during Saharan and non-Saharan days in Barcelona, Spain.MethodsWe collected daily PM1, PM2.5–1 and PM10–2.5 fractions, and cause-specific mortality (cardiovascular, respiratory and cerebrovascular) between March 2003 and December 2007. Changes of effects between Saharan and non-Saharan dust days were assessed using a time-stratified case–crossover design.ResultsDuring non-Saharan dust days we found statistically significant (p < 0.05) effects of PM10–2.5 for cardiovascular (odds ratio for increase of an interquartile range, OR = 1.033, 95% confidence interval: 1.006–1.060) and respiratory mortality (OR = 1.044, 95% CI: 1.001–1.089). During Saharan dust days strongest cardiovascular effects were found for the same fraction (OR = 1.085, 95% CI: 1.017–1.158) with an indication of effect modification (p = 0.111). Effects of PM2.5–1 during Saharan dust days were about the double than in non-dust days for cardiovascular and respiratory mortality, but these differences were not statistically significant.ConclusionOur results using independent fractions of PMs provide further evidence that the effects of short-term exposure to PM during Saharan dust days are associated with both cardiovascular and respiratory mortality. A better understanding of which of the different PM size fractions brought by Saharan dust is more likely to accelerate adverse effects may help better understand mechanisms of toxicity.  相似文献   

10.
Production of radioactive particles for use in environmental studies   总被引:1,自引:0,他引:1  
This paper presents an aerosol generation technique developed to produce dry aerosol particles of various sizes from aqueous solutions of salt. The technique was tested with sodium chloride, lithium carbonate and uranyl acetate at various aqueous concentrations which produced particles in the size range of 0.13-1.37 microm Mass Median Diameter (MMD). The generated aerosols were acceptably monodisperse with a geometric standard deviation of 1.4-2. Both MMD and Mass Median Aerodynamic Diameter (MMAD) increased significantly (p<0.001) with increased concentration of the salt in solution. The technique can also be used to generate aerosols of different chemical species. The results obtained indicate that the system is convenient for use with various aerosol-forming materials, with a stable particle size distribution being maintained for a long period of steady operation. The technique was successfully applied in wind tunnel studies to simulate the release of submicron radioactive particles and their interception by crops, grass and tree canopies. The relevance and application of the technique in other areas of environmental assessment studies is discussed.  相似文献   

11.
Primary Biologic Atmospheric Particles (PBAPs) constitute an interesting and poorly investigated component of the atmospheric aerosol. We have developed and validated a method for evaluating the contribution of overall PBAPs to the mass concentration of atmospheric particulate matter (PM). The method is based on PM sampling on polycarbonate filters, staining of the collected particles with propidium iodide, observation at epifluorescence microscope and calculation of the bioaerosol mass using a digital image analysis software. The method has been also adapted to the observation and quantification of size-segregated aerosol samples collected by multi-stage impactors.Each step of the procedure has been individually validated. The relative repeatability of the method, calculated on 10 pairs of atmospheric PM samples collected side-by-side, was 16%.The method has been applied to real atmospheric samples collected in the vicinity of Rome, Italy. Size distribution measurements revealed that PBAPs was mainly in the coarse fraction of PM, with maxima in the range 5.6–10 μm. 24-h samples collected during different period of the year have shown that the concentration of bioaerosol was in the range 0.18–5.3 μg m 3 (N = 20), with a contribution to the organic matter in PM10 in the range 0.5–31% and to the total mass concentration of PM10 in the range 0.3–18%.The possibility to determine the concentration of total PBAPs in PM opens up interesting perspectives in terms of studying the health effects of these components and of increasing our knowledge about the composition of the organic fraction of the atmospheric aerosol.  相似文献   

12.
Components and quantity of street dust are environmental pollution indicators especially in big cities. Street dust is generally composed of car exhaust gas originated particles and wind-transported particles. Heavy metals, which are found in street dust, such as Pb, Cu, Mn, Zn, Cd and Ni are significant for environmental pollution. According to the kind of vehicle in traffic, quantity and type of heavy metals vary in street dust. The use of leaded gasoline gives a boost to the importance of lead level especially in street dust even at the start of 21st century. These metals possess bioaccumulation property, and the possibility of the amount of these metals reaching a critical value and threatening human health increases the importance of this issue. In this study, street dusts have been collected from E-5 Highway from Topkapi to Avcilar regions that spans about 18 km in Istanbul, Turkey, and Pb, Cu, Mn, Zn, Cd and Ni concentrations have been detected in street dust. Twenty-two street dust samples were taken from a total of 22 different points at previously decided 14 main areas. Analyses were conducted using Leeds Public Analyst method. According to the results of this study, Pb, Cu and Zn concentrations in E-5 Highway between Topkapi and Avcilar region in Istanbul were higher than maximum concentration levels of these heavy metals in normal soil. This situation indicates that there is heavy metal pollution in the inspected area in E-5 Highway in Istanbul.  相似文献   

13.
The adverse consequences of particulate matter (PM) on human health have been well documented. Recently, special attention has been given to mineral dust particles, which may be a serious health threat. The main global source of atmospheric mineral dust is the Sahara desert, which produces about half of the annual mineral dust. Sahara dust transport can lead to PM levels that substantially exceed the established limit values. A review was undertaken using the ISI web of knowledge database with the objective to identify all studies presenting results on the potential health impact from Sahara dust particles. The review of the literature shows that the association of fine particles, PM2.5, with total or cause‐specific daily mortality is not significant during Saharan dust intrusions. However, regarding coarser fractions PM10 and PM2.5–10 an explicit answer cannot be given. Some of the published studies state that they increase mortality during Sahara dust days while other studies find no association between mortality and PM10 or PM2.5–10. The main conclusion of this review is that health impact of Saharan dust outbreaks needs to be further explored. Considering the diverse outcomes for PM10 and PM2.5–10, future studies should focus on the chemical characterization and potential toxicity of coarse particles transported from Sahara desert mixed or not with anthropogenic pollutants. The results of this review may be considered to establish the objectives and strategies of a new European directive on ambient air quality. An implication for public policy in Europe is that to protect public health, anthropogenic sources of particulate pollution need to be more rigorously controlled in areas highly impacted by the Sahara dust.  相似文献   

14.
Granules of high density polyethylene (PEHD) and low density polyethylene (PELD) were used in preparation of the mortar matrices in the immobilization process of radioactive waste materials containing 137Cs. The diameter of granulate forms varied from 0.2 to 2.0 mm. Four types of PEHD and PELD, forming four types of matrix materials, were used instead of ordinarily used stone granules of 2 mm average diameter, to decrease the porosity and density of the mortar matrix and avoid the segregation of stone particles on the bottom of the immobilized radioactive waste cylindric form. The physico-chemical characteristics of the radioactive waste mortar mixture form were improved, especially the radionuclide leach-rate. It decreased from 4% for the material prepared with stone granules to 2.5% to 3% for the materials prepared with PEHD and PELD. Mechanical strengths of the mortar-radioactive waste mixture samples prepared with PELD and PEHD were notably higher, 14 to 18 MPa, than the monoliths prepared with the ordinary stone granules, 11 MPa. Using PEHD and PELD as granules in the radioactive waste mortar mixture, the weight of the final, full-sized immobilized monolith was up to 25% lower than material with stone granules.  相似文献   

15.
A new automated version of the piezoelectric microbalance measures the mass concentration of airborne particles smaller than a preselected aerodynamic cutoff diameter. It is designed for near-real-time, unattended, round-the-clock measurements of nearly any aerosol environment inhabited by humans. The instrument uses an electrostatic precipitator to deposit particles with greater than 95% efficiency onto a piezoelectric quartz crystal sensor which is able to detect a deposit of 0.005 μg. The precipitator and sensor are nearly identical to those in the portable instrument reported previously. Measurements comparing within ± 15% with gravimetrically measured filter samples are documented for a wide variety of aerosols in the 50 μg/m3 to 5.5 mg/m3 range. The instrument measures particles from 10 μm down to 0.01 μm in diameter, including submicron combustion smokes and metallic fumes. The piezoelectric microbalance technique senses the mass concentration of the aerosol, rather than light scattering properties as is done by photometers and nephelometers. The piezobalance, with 1 L/min sample flow, is more sensitive than any other mass-sensing instrument, making it especially suited for low concentration indoor measurements, even below 50 μg/m3. An automatic piezobalance recently measured respirable aerosol mass concentrations in several offices. Each measurement was the average concentration during a 30-min period. The 24-h/day measurements continued for several days. Especially interesting is the diurnal pattern, both for offices with and without smokers. The effect of a single nearby smoker was clearly illustrated when the smoker was absent one day in the middle of a week. Normal daytime peak concentrations in that office reached 80–110 μg/m3 with a smoker present, but only 50–60 μg/m3 when the smoker was absent. Curious smokers who briefly stopped byt o see the instrument caused single half-hour averages to triple, to values as high as 294 μg/m3 in one office.  相似文献   

16.
We characterized flame retardant (FR) morphologies and spatial distributions in 7 consumer products and 7 environmental dusts to determine their implications for transfer mechanisms, human exposure, and the reproducibility of gas chromatography–mass spectrometry (GC–MS) dust measurements. We characterized individual particles using scanning electron microscopy/energy dispersive x-ray spectroscopy (SEM/EDS) and Raman micro-spectroscopy (RMS). Samples were screened for the presence of 3 FR constituents (bromine, phosphorous, non-salt chlorine) and 2 metal synergists (antimony and bismuth). Subsequent analyses of select samples by RMS enabled molecular identification of the FR compounds and matrix materials. The consumer products and dust samples possessed FR elemental weight percents of up to 36% and 31%, respectively. We identified 24 FR-containing particles in the dust samples and classified them into 9 types based on morphology and composition. We observed a broad range of morphologies for these FR-containing particles, suggesting FR transfer to dust via multiple mechanisms. We developed an equation to describe the heterogeneity of FR-containing particles in environmental dust samples. The number of individual FR-containing particles expected in a 1-mg dust sample with a FR concentration of 100 ppm ranged from < 1 to > 1000 particles. The presence of rare, high-concentration bromine particles was correlated with decabromodiphenyl ether concentrations obtained via GC–MS. When FRs are distributed heterogeneously in highly concentrated dust particles, human exposure to FRs may be characterized by high transient exposures interspersed by periods of low exposure, and GC–MS FR concentrations may exhibit large variability in replicate subsamples. Current limitations of this SEM/EDS technique include potential false negatives for volatile and chlorinated FRs and greater quantitation uncertainty for brominated FR in aluminum-rich matrices.  相似文献   

17.
The oxidation states of uranium in depleted uranium (DU) particles were determined by synchrotron radiation based mu-XANES, applied to individual particles isolated from selected samples collected at different sites in Kuwait. Based on scanning electron microscopy with X-ray microanalysis prior to mu-XANES, DU particles ranging from submicrons to several hundred micrometers were observed. The median particle size depended on sources and sampling sites; small-sized particles (median 13 microm) were identified in swipes taken from the inside of DU penetrators holes in tanks and in sandy soil collected below DU penetrators, while larger particles (median 44 microm) were associated with fire in a DU ammunition storage facility. Furthermore, the (236)U/(235)U ratios obtained from accelerator mass spectrometry demonstrated that uranium in the DU particles originated from reprocessed fuel (about 10(-2) in DU from the ammunition facility, about 10(-3) for DU in swipes). Compared to well-defined standards, all investigated DU particles were oxidized. Uranium particles collected from swipes were characterized as UO(2), U(3)O(8) or a mixture of these oxidized forms, similar to that observed in DU affected areas in Kosovo. Uranium particles formed during fire in the DU ammunition facility were, however, present as oxidation state +5 and +6, with XANES spectra similar to solid uranyl standards. Environmental or health impact assessments for areas affected by DU munitions should therefore take into account the presence of respiratory UO(2), U(3)O(8) and even UO(3) particles, their corresponding weathering rates and the subsequent mobilisation of U from oxidized DU particles.  相似文献   

18.
It is known that in soils and sediments moisture adsorbed on particle surfaces and in the pore system significantly affects the behaviour of recoiling radon (222Rn) atoms after decay of parent 226Ra, leading to increased 222Rn emanation. As a first step in an effort to characterize the 222Rn source term in mineralised sediments in the present study, complementing previous studies in the area, granitic esker sand samples were collected in order to test how moisture content affects 222Rn emanation at different grain size fractions. Emanation fractions measured for natural samples were compared with theoretical calculations. Six different grain size fractions were studied at 0%, 5% and 10% moisture contents relative to the mass of solids. In a further study necessary complementary information on the chemical and structural distribution of 226Ra was gained by selective leaching experiments. The results showed that 226Ra concentration increases from 50 Bq/kg at grain size 1-2 mm to 200 Bq/kg at grain size <0.063 mm. Respectively, the emanation factor increased from 0.12 to 0.30 at 5% moisture content. Both emanation factor and radium concentration increased significantly when grain size was below 0.125-0.250 mm. Above this fraction, the emanation fraction was approximately constant, 0.13 at 5% moisture content. In most of the grain size fractions, emanation reaches its maximum at 5% moisture content, being twice as high as in a dry sample. For the small particles (<0.063 mm) the 226Ra distribution is rather complex and depends on the mineral composition compared to larger particles wherein emanation from the internal pore system and the adjacent matrix is dominating over the contribution from external surface.  相似文献   

19.
船舶航行时螺旋桨产生的射流会对河道水流产生扰动,这种扰动是否能引起河床底泥的再悬浮需要更深入的论证分析。通过对比分析螺旋桨射流发展规律的研究成果,以湘江典型河段为研究对象,结合实船测量结果和此段河流地质资料,探讨了螺旋桨射流对湘江长株潭段河床底泥扰动的影响,并对此段河床底泥起动和悬浮条件进行了理论分析。结果表明:在周围环境流速较低的条件下,螺旋桨射流初始速度、河床水深及泥沙粒径是决定泥沙是否运动的主要因素。湘江长株潭河段已基本库区化,大部分河道平均水深远大于航道的标准水深2.8 m,河床泥沙平均粒径大于0.87 mm,其中细颗粒泥沙很少,由于螺旋桨射流断面平均流速小于泥沙起动流速,悬浮指标计算值远大于4,因此可以判断船舶正常航行在该段河流时底泥难以起动和再悬浮。  相似文献   

20.
Radon gas was allowed to accumulate in its radium source and then injected into a 36 m(3) test room, resulting in an initial radon concentration of 15 kBq m(-3). Filter papers were used to collect the short-lived radon progeny and thus to measure the Potential Alpha Energy Concentration (PAEC) in-situ in the year 1984 at different times and conditions according to the experimental design. The radon progeny collected on the filter papers were studied as a function of aerosol particle concentration ranging from 10(2)-10(5) particles cm(-3) in three different experiments. The highest aerosol particle concentration was generated by indoor cigarette smoking. Those filters were stored after the experiment, and were used after 16 years to study the activity of the radon long-lived alpha emitter progeny, (210)Po (T(1/2)=138 days). This isotope is separated from the short-lived progeny by (210)Pb beta emitter with 22.3 years half-life. After 16 years' storage of these filters, each filter paper was sandwiched and wrapped between two CR-39 nuclear track detectors, to put the detectors in contact with the surfaces of different filters, for 337 days. Correlation between the PAEC measured using filter papers in the year 1984 and the activity of long-lived alpha emitter (210)Po on the same filter papers measured in the year 2000 were studied. The results of the (210)Po activity showed a very good correlation of 0.92 with the PAEC 16 years ago. The results also depict that the PAEC and (210)Po activity in indoor air increased with the increase of aerosol particle concentration, which shows the attachment of short-lived radon progeny with the aerosol particles. The experiment proves that indoor cigarette smoking is a major source of aerosol particles carrying radon progeny and, thus, indoor cigarette smoking is an additional source of internal radiation hazard to the occupants whether smoker or non-smoker.  相似文献   

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