THE RELATIONSHIP OF WATER QUALITY AND FISH OCCURRENCE TO SOILS AND GEOLOGY IN AN AREA OF HIGH HYDROGEN AND SULFATE ION DEPOSITION1

ABSTRACT: A survey of 61 headwater streams and their watersheds on Pennsylvania's Laurel Hill, an area of high hydrogen ion and sulfate deposition, was conducted in May and June 1983. Trout were absent from 12 or 20 percent of the streams. No fish were present in 10 streams. Thirty-three streams appeared to contain viable trout populations, 10 streams had other interferring cultural impacts and 6 streams had nonviable trout populations. Significant differences in water quality were noted among streams with and without fish. The streams having no fish as a group had significantly lower pH and alkalinity and higher dissolved aluminum than those with fish. Attempts were made to correlate soil type and geology with the presence or absence of trout. Watersheds with a major percentage of very stony land soil classifications always contained no trout or were culturally impacted. On the other hand, watersheds with a major percentage of Upshur (limestone derived) soils always supported trout. Watersheds with more than 30 percent Pocono Group bedrock supported trout in every case but two, while in every case but one, watersheds with more than 30 percent Pottsville Group bedrock did not support trout. Acid runoff episode data indicate severe transient acidification attributable to atmospheric deposition. It appears that a combination of very stony land, 30 percent Pottsville Group bedrock and high deposition of hydrogen ions and sulfate may result in transient acidification and absence of fish populations from headwater streams on Pennsylvania's Laurel Hill.     

Response of Fish and Macroinvertebrate Bioassessment Indices to Water Chemistry in a Mined Appalachian Watershed

Multimetric indices based on fish and benthic macroinvertebrate assemblages are commonly used to assess the biological integrity of aquatic ecosystems. However, their response to specific stressors is rarely known. We quantified the response of a fish-based index (Mid-Atlantic Highlands Index of Biotic Integrity, MAH-IBI) and a benthic invertebrate-based index (West Virginia Stream Condition Index, WV-SCI) to acid mine drainage (AMD)-related stressors in 46 stream sites within the Cheat River watershed, West Virginia. We also identified specific stressor concentrations at which biological impairment was always or never observed. Water chemistry was extremely variable among tributaries of the Cheat River, and the WV-SCI was highly responsive across a range of AMD stressor levels. Furthermore, impairment to macroinvertebrate communities was observed at relatively low stressor concentrations, especially when compared to state water quality standards. In contrast to the WV-SCI, we found that the MAH-IBI was significantly less responsive to local water quality conditions. Low fish diversity was observed in several streams that possessed relatively good water quality. This pattern was especially pronounced in highly degraded subwatersheds, suggesting that regional conditions may have a strong influence on fish assemblages in this system. Our results indicate that biomonitoring programs in mined watersheds should include both benthic invertebrates, which are consistent indicators of local conditions, and fishes, which may be indicators of regional conditions. In addition, remediation programs must address the full suite of chemical constituents in AMD and focus on improving linkages among streams within drainage networks to ensure recovery of invertebrate and fish assemblages. Future research should identify the precise chemical conditions necessary to maintain biological integrity in mined Appalachian watersheds.     

Use of man-made impoundment in mitigating acid mine drainage in the North Branch Potomac River

The US Department of the Army, Baltimore District Corps of Engineers, oversees a long-term monitoring study to assess and evaluate effects of the Jennings-Randolph reservoir on biota in the North Branch Potomac River. The reservoir was intended, in part, to mitigate effects of acid mine drainage originating in upstream and headwater areas. The present study assessed recovery of benthos and fish in this system, six years after completion of the reservoir. Higher pH and lower iron and sulfate concentrations were observed upstream of the reservoir compared to preimpoundment conditions, suggesting better overall water quality in the upper North Branch. Water quality improved slightly directly downstream of the reservoir. However, the reservoir itself was poorly colonized by macrophytes and benthic organisms, and plankton composition suggested either metal toxicity and/or nutrient limitation. One large tributary to the North Branch and the reservoir (Stony River) was shown to have high (and possibly toxic) levels of manganese, iron, zinc, and aluminum due to subsurface coal mine drainage. Macroinvertebrate diversity and number of taxa were higher in sites downstream of the reservoir in the present study. Compared with previous years, the present study suggested relatively rapid recovery in the lower North Branch due to colonization from two major unimpacted tributaries in this system: Savage River and South Branch Potomac. Abundance of certain mayfly species across sites provided the most clear evidence of longitudinal gradients in water quality parameters and geomorphology. Fish data were consistent with macroinvertebrate results, but site-to-site variation in species composition was greater. Data collected between 1982 and 1987 suggested that certain fish species have unsuccessfully attempted to colonize sites directly downstream of the reservoir despite the more neutral pH water there. Our results show that recovery of biota in the North Branch Potomac was attributed to decreased acid inputs from mining operations and dilution from the Savage River, which contributed better water quality. Continued improvement of North Branch Potomac biota may not be expected unless additional mitigation attempts, either within the reservoir or upstream, are undertaken.     

Watershed factors affecting stream acidification in the White Mountains of New Hampshire,USA

The streams tributary to acidic Cone Pond, pH 4.5–4.8, and circumneutral Black Pond, pH 5.3–6.4, in the White Mountains of New Hampshire, USA, were monitored for a year. The watersheds of these two ponds were characterized in terms of geology and stream hydrology. Chemical gradients and patterns in rock weathering and groundwater discharge explain many of the differences in mineral content and acidity of the streams. The rocks of Black watershed produced an average of ten times the equivalent of basic cations as rocks from Cone watershed. This is on the same order as the difference in acidity of the two streams. Down-stream changes in stream chemistry follow differing patterns, but reflect the same principle of residence time and water path length controlling chemical evolution of streamwater. Watershed and aquatic managers may use these parameters in an inexpensive and simple assessment of the susceptibility of individual streams and ponds to acidification. A method is recommended to determine quickly the potential influence of bedrock type to aquatic chemistry.     

MODELING ACID MINE DRAINAGE ON A WATERSHED SCALE FOR TMDL CALCULATIONS1

ABSTRACT: The Cheat River of West Virginia is impaired by acid mine drainage (AMD). Fifty‐five of its river segments were placed on the 303(d) list, which required calculations of total maximum daily load (TMDL) to meet the water quality criteria for pH, total iron, aluminum, manganese, and zinc. An existing watershed model was enhanced to simulate AMD as nonpoint source load. The model divided a watershed into a network of catchments and river segments. Each catchment was divided into soil layers, which could contain pyrite, calcite and other minerals. A kinetic expression was used to simulate pyrite oxidation as a function of oxygen in the soil voids. Oxygen in the soil voids was consumed by pyrite oxidation and replenished by earth breathing. The by‐products of pyrite oxidation were calculated according to its mass action equations. Chemical equilibrium was used to account for the speciation of ferrous and ferric irons and precipitation of metal hydroxides. Simulated hydrology and water quality were compared to available data. The USEPA used the calibrated model to calculate the TMDLs in the Cheat River Watershed.     

SENSITIVITY OF HIGH-ELEVATION STREAMS IN THE SOUTHERN BLUE RIDGE PROVINCE TO ACIDIC DEPOSITION1

ABSTRACT: The Southern Blue Ridge Province, which encompasses parts of northern Georgia, eastern Tennessee, and western North Carolina, has been predicted to be sensitive to impacts from acidic deposition, owing to the chemical composition of the bedrock geology and soils. This study confirms the predicted potential sensitivity, quantifies the level of total alkalinity and describes the chemical characteristics of 30 headwater streams of this area. Water chemistry was measured five times between April 1983 and June 1984 at first and third order reaches of each stream during baseflow conditions. Sensitivity based on total alkalinity and the Calcite Saturation Index indicates that the headwater streams of the Province are vulnerable to acidification. Total alkalinity and p11 were generally higher in third order reaches (mean, 72 μeq/θ and 6.7) than in first order reaches (64 μeq/θ and 6.4). Ionic concentrations were low, averaging 310 and 340 μeq/θ in first and third order reaches, respectively. A single sampling appears adequate for evaluating sensitivity based on total alkalinity, but large temporal variability requires multiple sampling for the detection of changes in pH and alkalinity over time. Monitoring of stream water should continue in order to detect any subtle effects of acidic deposition on these unique resource systems.     

PREDICTING BASEFLOW ALKALINITY AS AN INDEX TO EPISODIC STREAM ACIDIFICATION AND FISH PRESENCE1

ABSTRACT: Regression models to predict baseflow alkalinity from basin hydrogeology were developed and verified for headwater streams on the Laurel Hill anticline in southwestern Pennsylvania. Predicted baseflow alkalinities were then used to estimate sensitivity to acidification and presence of trout (Salvelinus fontinalis) populations for 61 headwater streams. Sensitivity classifications were verified by surveying trout populations. Geologic variables relating to the carbonate rock burial depth, extent of carbonate rock recharge areas, and length of stream channel flowing through effluent carbonate rock outcrops were much more useful in predicting baseflow alkalinity than areal extent of carbonate rocks. Baseflow alkalinity was not well related to status of trout populations on these anticlinal basins, especially on noneffluent basins where bedrock dip exceeded surface slope.     

A Spatially Explicit Model for Mapping Headwater Streams

Headwater streams are the primary sources of water in a drainage network and serve as a critical hydrologic link between the surrounding landscape and larger, downstream surface waters. Many states, including North Carolina, regulate activity in and near headwater streams for the protection of water quality and aquatic resources. A fundamental tool for regulatory management is an accurate representation of streams on a map. Limited resources preclude field mapping every headwater stream and its origin across a large region. It is more practical to develop a model for headwater streams based on a sample of field data that can then be extrapolated to a larger area of interest. The North Carolina Division of Water Quality has developed a cost‐effective method for modeling and mapping the location, length, and flow classification (intermittent and perennial) of headwater streams. We used a multiple logistic regression approach that combined field data and terrain derivatives for watersheds located in the Triassic Basins ecoregion. Field data were collected using a standard methodology for identifying headwater streams and origins. Terrain derivatives were generated from digital elevation models interpolated from bare‐earth Light Detection and Range data. Model accuracies greater than 80% were achieved in classifying stream presence and absence, stream length and perennial stream length, but were not as consistent in predicting intermittent stream length.     

The Role of Headwater Streams in Downstream Water Quality1

Abstract: Knowledge of headwater influences on the water‐quality and flow conditions of downstream waters is essential to water‐resource management at all governmental levels; this includes recent court decisions on the jurisdiction of the Federal Clean Water Act (CWA) over upland areas that contribute to larger downstream water bodies. We review current watershed research and use a water‐quality model to investigate headwater influences on downstream receiving waters. Our evaluations demonstrate the intrinsic connections of headwaters to landscape processes and downstream waters through their influence on the supply, transport, and fate of water and solutes in watersheds. Hydrological processes in headwater catchments control the recharge of subsurface water stores, flow paths, and residence times of water throughout landscapes. The dynamic coupling of hydrological and biogeochemical processes in upland streams further controls the chemical form, timing, and longitudinal distances of solute transport to downstream waters. We apply the spatially explicit, mass‐balance watershed model SPARROW to consider transport and transformations of water and nutrients throughout stream networks in the northeastern United States. We simulate fluxes of nitrogen, a primary nutrient that is a water‐quality concern for acidification of streams and lakes and eutrophication of coastal waters, and refine the model structure to include literature observations of nitrogen removal in streams and lakes. We quantify nitrogen transport from headwaters to downstream navigable waters, where headwaters are defined within the model as first‐order, perennial streams that include flow and nitrogen contributions from smaller, intermittent and ephemeral streams. We find that first‐order headwaters contribute approximately 70% of the mean‐annual water volume and 65% of the nitrogen flux in second‐order streams. Their contributions to mean water volume and nitrogen flux decline only marginally to about 55% and 40% in fourth‐ and higher‐order rivers that include navigable waters and their tributaries. These results underscore the profound influence that headwater areas have on shaping downstream water quantity and water quality. The results have relevance to water‐resource management and regulatory decisions and potentially broaden understanding of the spatial extent of Federal CWA jurisdiction in U.S. waters.     

Controls on Temperature in Salmonid‐Bearing Headwater Streams in Two Common Hydrogeologic Settings,Kenai Peninsula,Alaska

Headwater streams are the most numerous in terms of both number and length in the conterminous United States and play important roles as spawning and rearing grounds for numerous species of anadromous fish. Stream temperature is a controlling variable for many physical, chemical, and biological processes and plays a critical role in the overall health and integrity of a stream. We investigated the controls on stream temperature in salmon‐bearing headwater streams in two common hydrogeologic settings on the Kenai Peninsula, Alaska: (1) drainage‐ways, which are low‐gradient streams that flow through broad valleys; and (2) discharge‐slopes, which are high gradient streams that flow through narrow valleys. We hypothesize local geomorphology strongly influences surface‐water and groundwater interactions, which control streamflow at the network scale and stream temperatures at the reach scale. The results of this study showed significant differences in stream temperatures between the two hydrogeologic settings. Observed stream temperatures were higher in drainage‐way sites than in discharge‐slope sites, and showed strong correlations as a continuous function with the calculated topographic metric flow‐weighted slope. Additionally, modeling results indicated the potential for groundwater discharge to moderate stream temperature is not equal between the two hydrogeologic settings, with groundwater having a greater moderating effect on stream temperature at the drainage‐way sites.     

Assessing Ecological Integrity of Ozark Rivers to Determine Suitability for Protective Status

Preservation of extraordinary natural resources, protection of water quality, and restoration of impaired waters require a strategy to identify and protect least-disturbed streams and rivers. We applied two objective, quantitative methods to determine stream ecological integrity of headwater reaches of 10 Ozark rivers, 5 with Wild and Scenic River federal protective status. Thirty-four variables representing macroinvertebrate and fish assemblage characteristics, in-stream habitat, riparian vegetation, water quality, and watershed attributes were quantified for each river and analyzed using two multivariate approaches. The first approach, cluster and discriminant analyses, identified two groups of river with only one variable (% forested watershed) reliably distinguishing groups. Our second approach employed ordinal scaling to compare variables for each river to conceptually ideal conditions that were developed as a composite of optimal attributes among the 10 rivers. The composite distance of each river from ideal was then calculated using a unidimensional ranking technique. Two rivers without Wild and Scenic River designation ranked highest relative to ideal (highest ecological integrity), and two others, also without designation, ranked most distant from ideal (lowest ecological integrity). Fish density, number of intolerant fish species, and invertebrate density were influential biotic variables for scaling. Contributing physical variables included riparian forest cover, water nitrate concentration, water turbidity, percentage of forested watershed, percentage of private land ownership, and road density. These methods provide a framework for refinement and application in other regions to facilitate the process of establishing least-disturbed reference conditions and identifying rivers for protection and restoration.     

GEOMORPHOLOGY OF STEEPLAND HEADWATERS: THE TRANSITION FROM HILLSLOPES TO CHANNELS1

Headwater streams comprise 60 to 80 percent of the cumulative length of river networks. In hilly to mountainous terrain, they reflect a mix of hillslope and channel processes because of their close proximity to sediment source areas. Their morphology is an assemblage of residual soils, landslide deposits, wood, boulders, thin patches of poorly sorted alluvium, and stretches of bedrock. Longitudinal profiles of these channels are strongly influenced by steps created by sediment deposits, large wood, and boulders. Due to the combination of small drainage area, stepped shallow gradient, large roughness elements, and cohesive sediments, headwater streams typically transport little sediment or coarse wood debris by fluvial processes. Consequently, headwaters act as sediment reservoirs for periods spanning decades to centuries. The accumulated sediment and wood may be episodically evacuated by debris flows, debris floods, or gully erosion and transported to larger channels. In mountain environments, these processes deliver significant amounts of materials that form riverine habitats in larger channels. In managed steepland forests, accelerated rates of landslides and debris flows resulting from the harvest of headwater forests have the potential to seriously impact the morphology of headwater streams and downstream resources.     

What’s a Stream Without Water? Disproportionality in Headwater Regions Impacting Water Quality

Headwater streams are critical components of the stream network, yet landowner perceptions, attitudes, and property management behaviors surrounding these intermittent and ephemeral streams are not well understood. Our research uses the concept of watershed disproportionality, where coupled social-biophysical conditions bear a disproportionate responsibility for harmful water quality outcomes, to analyze the potential influence of riparian landowner perceptions and attitudes on water quality in headwater regions. We combine social science survey data, aerial imagery, and an analysis of spatial point processes to assess the relationship between riparian landowner perceptions and attitudes in relation to stream flow regularity. Stream flow regularity directly and positively shapes landowners’ water quality concerns, and also positively influences landowners’ attitudes of stream importance—a key determinant of water quality concern as identified in a path analysis. Similarly, riparian landowners who do not notice or perceive a stream on their property are likely located in headwater regions. Our findings indicate that landowners of headwater streams, which are critical areas for watershed-scale water quality, are less likely to manage for water quality than landowners with perennial streams in an obvious, natural channel. We discuss the relationships between streamflow and how landowners develop understandings of their stream, and relate this to the broader water quality implications of headwater stream mismanagement.     

Suspended-Sediment Concentration Regimes for Two Biological Reference Streams in Middle Tennessee1

Diehl, Timothy H. and William J. Wolfe, 2010. Suspended-Sediment Concentration Regimes for Two Biological Reference Streams in Middle Tennessee. Journal of the American Water Resources Association (JAWRA) 46(4): 824-837. DOI: 10.1111/j.1752-1688.2010.00460.x Abstract: Temporal patterns of suspended-sediment concentration (SSC) duration and frequency (SSC regimes) were characterized and compared with biological impairment thresholds for two headwater streams in the Western Highland Rim of Tennessee. The SSC regimes were plotted as curves showing concentrations and durations of the annual longest and tenth-longest SSC excursions above 18 concentrations for water years 2005-2008 in Copperas Branch and water years 2006 and 2008 in Kelley Creek. Both streams have fish communities remarkably diverse for their small drainage basin areas (420 and 565 ha, respectively), and represent biological reference conditions with respect to SSC. SSC-regime curves were similar for the two sites across water years. The measured SSC regimes reached or exceeded published experimentally based SSC impairment thresholds and plotted below a proposed long-term SSC reference regime for the Interior Plateau ecoregion (Ecoregion 71), suggesting that neither the experimentally based thresholds nor the proposed SSC reference regime adequately reflect the relation between SSC and biological impairment for Western Highland Rim headwater streams. The SSC regimes of the two study streams were similar to the estimated SSC regime of an unimpaired East Tennessee trout stream. Additional field studies are needed to describe SSC regimes in streams of varying basin scale, level of impairment, and region.     

Using GIS to Delineate Headwater Stream Origins in the Appalachian Coalfields of Kentucky

Headwater streams have a significant nexus or physical, chemical, and/or biological connection to downstream reaches. Generally, defined as 1st‐3rd order with ephemeral, intermittent, or perennial flow regimes, these streams account for a substantial portion of the total stream network particularly in mountainous terrain. Due to their often remote locations, small size, and large numbers, conducting field inventories of headwater streams is challenging. A means of estimating headwater stream location and extent according to flow regime type using publicly available spatial data is needed to simplify this complex process. Using field‐collected headwater point of origin data from three control watersheds, streams were characterized according to a set of spatial parameters related to topography, geology, and soils. These parameters were (1) compared to field‐collected point of origin data listed in three nearby Jurisdictional Determinations, (2) used to develop a geographic information system (GIS)‐based stream network for identifying ephemeral, intermittent, and perennial streams, and (3) applied to a larger watershed and compared to values obtained using the high‐resolution National Hydrography Dataset (NHD). The parameters drainage area and local valley slope were the most reliable predictors of flow regime type. Results showed the high‐resolution NHD identified no ephemeral streams and 9 and 65% fewer intermittent and perennial streams, respectively, than the GIS model.     

Hydrologic Connectivity and the Contribution of Stream Headwaters to Ecological Integrity at Regional Scales1

Abstract: Cumulatively, headwater streams contribute to maintaining hydrologic connectivity and ecosystem integrity at regional scales. Hydrologic connectivity is the water‐mediated transport of matter, energy and organisms within or between elements of the hydrologic cycle. Headwater streams compose over two‐thirds of total stream length in a typical river drainage and directly connect the upland and riparian landscape to the rest of the stream ecosystem. Altering headwater streams, e.g., by channelization, diversion through pipes, impoundment and burial, modifies fluxes between uplands and downstream river segments and eliminates distinctive habitats. The large‐scale ecological effects of altering headwaters are amplified by land uses that alter runoff and nutrient loads to streams, and by widespread dam construction on larger rivers (which frequently leaves free‐flowing upstream portions of river systems essential to sustaining aquatic biodiversity). We discuss three examples of large‐scale consequences of cumulative headwater alteration. Downstream eutrophication and coastal hypoxia result, in part, from agricultural practices that alter headwaters and wetlands while increasing nutrient runoff. Extensive headwater alteration is also expected to lower secondary productivity of river systems by reducing stream‐system length and trophic subsidies to downstream river segments, affecting aquatic communities and terrestrial wildlife that utilize aquatic resources. Reduced viability of freshwater biota may occur with cumulative headwater alteration, including for species that occupy a range of stream sizes but for which headwater streams diversify the network of interconnected populations or enhance survival for particular life stages. Developing a more predictive understanding of ecological patterns that may emerge on regional scales as a result of headwater alterations will require studies focused on components and pathways that connect headwaters to river, coastal and terrestrial ecosystems. Linkages between headwaters and downstream ecosystems cannot be discounted when addressing large‐scale issues such as hypoxia in the Gulf of Mexico and global losses of biodiversity.     

MINE DRAINAGE AND ROCK TYPE INFLUENCES ON EASTERN OHIO STREAM WATER QUALITY1

ABSTRACT: Stream water during fair weather (base flow) is largely ground water discharge, which has been in contact with minerals of the underlying aquifer. Base flow water quality should therefore reflect aquifer mineralogy as well as upstream land use. Three upstream mining categories (unmined lands, abandoned coal mines, and reclaimed coal mines) differed in pH, specific conductance, sulfate, iron, aluminum, and alkalinity for 122 streams in eastern Ohio. Aquifer rock type influenced pH, specific conductance, sulfate, iron, and alkalinity. Reclamation returned many components of acid mine drainage to near unmined levels, although sulfate and specific conductance were not improved. Acid mine drainage problems were less severe in watersheds underlain by the calcareous Monogahela Formation. These results should ayply to other Appalachian coal regions having similar rock units. The water quality data distributions were neither consistently normal nor lognormal. Statistical tests utilizing ranks of the water quality data, instead of the data themselves, proved useful in analyzing the influences of mining category and rock type.     

Comparing the Extent and Permanence of Headwater Streams From Two Field Surveys to Values From Hydrographic Databases and Maps

Supreme Court cases have questioned if jurisdiction under the Clean Water Act extends to water bodies such as streams without year‐round flow. Headwater streams are central to this issue because many periodically dry, and because little is known about their influence on navigable waters. An accurate account of the extent and flow permanence of headwater streams is critical to estimating downstream contributions. We compared the extent and permanence of headwater streams from two field surveys with values from databases and maps. The first used data from 29 headwater streams in nine U.S. forests, whereas the second had data from 178 headwater streams in Oregon. Synthetic networks developed from the nine‐forest survey indicated that 33 to 93% of the channel lacked year‐round flow. Seven of the nine forests were predicted to have >200% more channel length than portrayed in the high‐resolution National Hydrography Dataset (NHD). The NHD and topographic map classifications of permanence agreed with ~50% of the field determinations across ~300 headwater sites. Classification agreement with the field determinations generally increased with increasing resolution. However, the flow classification on soil maps only agreed with ~30% of the field determination despite depicting greater channel extent than other maps. Maps that include streams regardless of permanence and size will aid regulatory decisions and are fundamental to improving water quality monitoring and models.     

RED RIVER OF THE NORTH BASIN,MINNESOTA, NORTH DAKOTA,AND SOUTH DAKOTA1

ABSTRACT: The environmental setting of the Red River of the North basin within the United States is diverse in ways that could significantly control the areal distribution and flow of water and, therefore, the distribution and concentration of constituents that affect water quality. Continental glaciers shaped a landscape of very flat lake plains near the center of the basin, and gently rolling uplands, lakes, and wetlands along the basin margins. The fertile, black, fine-grained soils and landscape are conducive to agriculture. Productive cropland covers 66 percent of the land area. The principal crops are wheat, barley, soybeans, sunflowers, corn, and hay. Pasture, forests, open water, and wetlands comprise most of the remaining land area. About one-third of the 1990 population (511,000) lives in the cities of Fargo and Grand Forks, North Dakota and Moorhead, Minnesota. The climate of the Red River of the North basin is continental and ranges from dry subhumid in the western part of the basin to subhumid in the eastern part. From its origin, the Red River of the North meanders northward for 394 miles to the Canadian border, a path that is nearly double the straight-line distance. The Red River of the North normally receives over 75 percent of its annual flow from the eastern tributaries as a result of regional patterns of precipitation, evapotranspiration, soils, and topography. Most runoff occurs in spring and early summer as a result of rains falling on melting snow or heavy rains falling on saturated soils. Lakes, prairie potholes, and wetlands are abundant in most physiographic areas outside of the Red River Valley Lake Plain. Dams, drainage ditches, and wetlands alter the residence time of water, thereby affecting the amount of sediment, biota, and dissolved constituents carried by the water. Ground water available to wells, streams, and springs primarily comes from sand and gravel aquifers near land surface or buried within 100 to 300 feet of glacial drift that mantles the entire Red River of the North basin. Water moves through the system of bedrock and glacial-drift aquifers in a regional flow system generally toward the Red River of the North and in complex local flow systems controlled by local topography. Many of the bedrock and glacial-drift aquifers are hydraulically connected to streams in the region. The total water use in 1990, about 196 million gallons per day, was mostly for public supply and irrigation. Slightly more than one half of the water used comes from ground-water sources compared to surface-water sources. Most municipalities obtain their water from ground-water sources. However, the largest cities (Fargo, Grand Forks and Moorhead) obtain most of their water from the Red River of the North. The types and relative amounts of various habitats change among the five primary ecological regions within the Red River of the North basin. Headwater tributaries are more diverse and tend to be similar to middle-reach tributaries in character rather than the lower reaches of these tributaries for the Red River of the North. Concentrations of dissolved chemical constituents in surface waters are normally low during spring runoff and after thunderstorms. The Red River of the North generally has a dissolved-solids concentration less than 600 milligrams per liter with mean values ranging from 347 milligrams per liter near the headwaters to 406 milligrams per liter at the Canadian border near Emerson, Manitoba. Calcium and magnesium are the principal cations and bicarbonate is the principal anion along most of the reach of the Red River of the North. Dissolved-solids concentrations generally are lower in the eastern tributaries than in the tributaries draining the western part of the basin. At times of low flow, when water in streams is largely from ground-water seepage, the water quality more reflects the chemistry of the glacial-drift aquifer system. Ground water in the surficial aquifers commonly is a calcium bicarbonate type with dissolved-solids concentration generally between 300 and 700 milligrams per liter. As the ground water moves down gradient, dissolved-solids concentration increases, and magnesium and sulfate are predominant ions. Water in sedimentary bedrock aquifers is predominantly sodium and chloride and is characterized by dissolved-solids concentrations in excess of 1,000 milligrams per liter. Sediment erosion by wind and water can be increased by cultivation practices and by livestock that trample streambanks. Nitrate-nitrogen concentrations also can increase locally in surficial aquifers beneath cropland that is fertilized, particularly where irrigated. Nitrogen and phosphorous in surface runoff from cropland fertilizers and nitrogen from manure can contribute nutrients to lakes, reservoirs, and streams. Some of the more persistent pesticides, such as atrazine, have been detected in the Red River of the North. Few data are available to conclusively define the presence or absence of pesticides and their break-down products in Red River of the North basin aquifers or streams. Urban runoff and treated effluent from municipalities are discharged into streams. These point discharges contain some quantity of organic compounds from storm runoff, turf-applied pesticides, and trace metals. The largest releases of treated-municipal wastes are from the population centers along the Red River of the North and its larger tributaries. Sugar-beet refining, potato processing, poultry and meat packing, and milk, cheese, and cream processing are among the major food processes from which treated wastes are released to streams, mostly in or near the Red River of the North.