分段控制江水污染治理系数的最优解

本文根据（环境科学概论）的水质基本方程，对江水分段水质管理提出数学模型，用线性规划和最优化方法提出控制江水污染的决策措施，我们可以根据这些数据有计划地提出治理方案，使江水水质符合国家标准，同时使资金投入最省。     

分光光度法与容量法测定COD_(Cr)值的对比实验

本文将CODCr测定的重铬酸钾褪色法运用于本监测中心的日常样品测定中,并且与《GB11914—89水质化学需氧量》方法进行了同时测定,结果相同,另外还推算出了消除硫酸铬干扰产生的曲线校值系数,应用此系数的倒数乘褪色方程的斜率得出新方程,将双波长测定改为单波长测定,两种方程计算结果一致。     

梯级开发河流污染物的积累性和缓冲性——兼论惰性物的积累模型

本文论述了梯级开发河流的“水库－河流”两重性，当该河流呈水库性质时，会发生对污染物的积累和缓冲；同时，论述了惰性物质氯离子（Ｃｌ＾－）的积累模型，提出了破坏此积累性和缓冲性的临界流量，以及如何用它来改善梯级开发河流的水质。     

西蒙得木对金沙江干热河谷生态保护的作用

金沙江干热河谷生态条件恶劣，水土流失严重，对长江流域中下游特别是三峡大坝存在着极大的负面影响。治理长江流域，保护三峡大坝的重要源头是金沙江干热河谷的生态环境建设。西蒙得木生长的生态环境与金沙江干热河谷的生态环境非常相似，并且西蒙得木具有极高的经济价值，因此在金沙江干热河谷种植西蒙得木，既能改良生态环境，又能发展当地经济。     

改性玉米秸秆吸附去除废水中四环素的研究

应用平衡吸附法，研究了不同投加量（改性玉米秸秆）、温度及pH条件下，改性玉米秸秆对水体中四环素的吸附作用，并利用等温曲线及吸附动力学方程对试验结果进行了拟合。结果表明：在吸附剂用量0．4g，温度30℃，振荡时间30min，pH值7的条件下，对水体中四环素浓度为50．136mg／L的吸附率可达93．4％。四环素废水吸附均符合Langmuir及Freundlich等温模式。但Langmuir方程拟合得较好，Elovich方程能更好地拟舍改性玉米秸秆对水体中四环素的吸附动力学曲线。     

酸雨pH预测的偏最小二乘回归模型

酸雨pH值受酸性离子[SO4^2-]、[NO3^-]和碱性离子[Ca^2 ]、[NH4^ ]等的影响。这些影响因素之间存在多重相关性。用一般最小二乘回归法建模预测pH值，估计参数存在着很大的误差且物理意义明显不足。应用偏最小二乘回归技术建立pH值预测模型，克服了自变量之间的多重相关性的问题，因而更具有先进性，计算结果更为可靠。以我国17个城市pH值预测为例，探讨偏最小二乘法的优势，并与最小二乘回归法进行了比较。     

酸催化氧化法处理含对苯二酚废水的方法

本文主要研究用硫酸作催化剂，30％过氧化氢作氧化剂，再经过pH值的调节和活性炭吸附，使对苯二酚化学需氧量值从3615mg／L降至260mg/L。化学需氧量的去除率高达93．3％。     

金沙江流域水土流失与人类活动影响分析

长江三峡水利枢纽工程能否正常发挥效益，泥沙是重要的制约因素之一，而水库的泥沙主要来自上游金沙江，其多年平均输沙量占入库寸滩站的５２７％。因此，本文对金沙江泥沙的地区组成、水土流失及人类活动影响等问题进行了深入的分析，并提出了防治对策。     

枫江流域水污染状况及防治对策

本文分析了广东省揭阳枫江水污染现状及原因,提出了整治枫江水污染的对策。     

简析锰矿中的杂质对软锰矿烟气脱硫的影响

简述了中国锰矿资源的特点,简析了锰矿中的杂质对软锰矿烟气脱硫体系的影响,并在矿石中杂质对体系pH缓冲能力分析的基础上,将软锰矿分为高碱性矿石、中碱性矿石和低碱性矿石。     

我国煤炭开采和燃烧过程中的硫污染对土壤环境的影响

我国煤炭在开采和燃烧过程中形成的硫污染物主要是酸性矿井水和二氧化硫,由煤炭燃烧造成的硫的干湿沉降以及煤炭开采过程中形成的酸性矿井水使土壤的物理化学性质发生变化,从而对土壤造成严重的破坏。主要表现在造成土壤中可溶性硫酸盐的大幅度升高;引起土壤的pH值下降;植物营养元素特别是K、Na、Ca、Mg等产生淋失;活性铝溶出量增加;有毒重金属活化;抑制土壤酶的活性等方面。可以通过脱硫除尘、加强绿化、建立合理的工业布局、加入土壤改良剂等措施来减少硫污染物的排放量和改善其对土壤环境的影响,但总量控制是关键,是最根本的途径。     

Removal of Se(IV) from aqueous solution using sulphuric acid-treated peanut shell

A carbonaceous sorbent was prepared from peanut shell via sulphuric acid treatment. Se(IV) removal from aqueous solution on the sorbent was studied varying time, pH, Se(IV) concentration, temperature and sorbent status (wet and dry). Se(IV) removal was faster using the wet sorbent than the dry sorbent following a pseudo-first-order model. Se(IV) removal increases at low pH values, and decreases as pH increases until pH 7. Sorption was found to fit the Langmuir equation and sorption capacity for the wet sorbent was higher than that for the dry one. Both sorbents showed an increased selenium sorption by rising the temperature. Redox processes between Se(IV) and the carbon sorbent are involved. Analysis by scanning electron microscope and X-ray powder diffraction for the sorbent after the reaction with acidified Se(IV) confirmed the availability of elemental selenium as particles on the sorbent surface as a result of Se(IV) reduction. Physicochemical tests showed an increase in sorbent acidity, cation exchange capacity (CEC) and surface functionality after the reaction with acidified Se(IV), indicating the oxidation processes occurring on the sorbent surface. Due to its reduction properties, the sorbent seems efficient for Se(IV) removal from aqueous solution.     

Chemical and isotopic compositions of the Minjiang River, a headwater tributary of the Yangtze River

We describe the anthropogenic impacts on the major dissolved elements (Cl(-), NO(3)(-)-N, SO(4)(2-), and Na(+)) in the water from the Minjiang River (a headwater tributary of the Yangtze River) and upper Yangtze River in relation to increasing human activity. The major element chemistry and hydrogen, oxygen, and sulfur isotopic compositions were investigated. When the Minjiang River flows through the populated Sichuan Basin, the concentrations of Cl(-), NO(3)(-)-N, SO(4)(2-), and Na(+) gradually increase. The increasing SO(4)(2-) in the highly polluted Minjiang River had high delta(34)S values (+6.3 to approximately +13.6 per thousand), implicating the anthropogenic sources of sulfur from air pollutants, domestic wastewater, industrial effluents, and agricultural fertilizers. The water quality of the upper Yangtze River does not worsen after receiving the Minjiang River because the water from the lightly polluted Jinshajiang River contributes most of the total flux in the Yangtze River. However, these rivers deserve attention and further research because the Yangtze River is the most important river in China in terms of water quality.     

中国南方酸雨的分布特征及其成因分析

本文阐述了酸雨的危害、近几年中国南方地区酸雨的污染的时空分布状况、酸雨的成因等3方面的内容。研究表明：我国南方酸雨区的酸雨污染状况基本上处在一个稳定的时期。降水pH〈5的区域有从长江中上游向长江中下游发展的趋势;在时间分布上,秋季冬季降水pH低,酸雨发生的频率高;春季夏季降水pH高,酸雨发生的频率低。在酸雨的成因上,着重讨论了大气性质、污染物的迁移和扩散、气候条件、大气中颗粒物浓度以及土壤性质对酸雨形成的影响。     

Dissolution kinetics of heavy metals in Dutch carbonate- and sulfide-rich freshwater sediments

In two sulfide-rich freshwater sediments from the Biesbosch and Kromme Rijn River in the Netherlands differing in carbonate content and acid volatile sulfide (AVS) content, metal and sulfide dissolution kinetics were studied at different acid concentrations by varying both the procedure of acid addition and the extraction time. The establishment of equilibrium was monitored by measuring the pH in time, which reached a near constant value. The equilibrium pH was reached quickly when large amounts of acid were added and slowly when small amounts of acid were added. This observation was confirmed by the yield of extracted metals after either a 45-min or 24-h extraction over a pH range from 0 to 5. The pH factor seemed to be of more influence than time for the dissolution of metals. The amount of extracted metals was highly dependent on the metal itself due to its physico-chemical behavior. Although the sediments studied varied in carbonate content, acid volatile sulfide (AVS), and total metal content, the extracted fraction of metals compared with their total content in the sediment was similar for most metals. Finally, the AVS content as well as the ratio of simultaneously extracted metals (SEM; sum of Cd, Cu, Ni, Pb, and Zn) to AVS decreased with increasing pH. Because the SEM to AVS ratio may be used to set environmental quality criteria for the sediment compartment, this observation is of significance.     

活性炭烟气脱硫技术研究新进展

研制了新型活性炭脱硫剂－脱硫活性碳纤维。研究表明，脱硫活性碳纤维由于含碳量高、比表面积大、微孔丰富、孔径分布窄、有较多适于吸附ＳＯ２的表面官能团，因而吸附能力及吸附、脱附速度显著大于普通活性炭。在相同工艺条件下，脱硫活性碳纤维吸附容量为粒状疾性炭的４－５倍，空速粒达活性炭的１０倍。采用活性碳纤维脱硫可比普通活性碳脱硫剂用量成倍减少。另外，由于活性碳纤维阻力小，系统能耗可显著降低。活性碳烟气脱硫采用     

DECLINING INTENSITY OF ACID MINE DRAINAGE IN THE NORTHERN APPALACHIAN BITUMINOUS COAL FIELDS: MAJOR ALLEGHENY RIVER TRIBUTARIES1

ABSTRACT: For more than 30 years, a program of continuous monitoring of pH, acidity, alkalinity, and other parameters has been maintained on a network of large streams degraded by acid mine drainage in the northern Appalachian high sulfur coal region. Continuous records since 1952 are available at a number of stations, and at several stations, acidity records date back to 1930. Comparable analysis techniques were maintained over the period of record, assuring the long term continuity of the database. This monitoring program has captured integrated long term trends within large and complex watersheds with numerous and varied types of mine discharges. The focus of this paper is a historical trend analysis of lightly to severely acid degraded major tributaries of the Allegheny River. Over the past three decades, all of the Allegheny River drainage basin stations have demonstrated steady and substantial declines in acidity and associated increases in pH and alkalinity. The average recorded decline in total acidity at four stations monitored since the 1950s was 94 percent. Since the 1970s, acidity declined by an average of 63 percent at 10 stations. Oxidative exhaustion of pyritic minerals exposed by mining is proposed as a major factor influencing these trends.     

Evaluation of water treatment sludge for ameliorating acid mine waste

This study investigated the liming effect of water treatment sludge on acid mine spoils. The study was conducted with sludge from a water purification plant along the Vaal River catchments in South Africa. The optimum application rate for liming acid spoils and the speed and depth with which the sludge reacted with the mine waste were investigated. Chemical analysis indicated that the sludge is suitable as a liming agent because of its alkaline pH (8.08), high bicarbonate concentration (183.03 mg L(-1)), and low salinity (electrical conductivity = 76 mS m(-1)). The high cation exchange capacity of 15.47 cmol(c) kg(-1) and elevated nitrate concentration (73.16 mg L(-1)) also increase its value as an ameliorative material. The soluble concentrations for manganese, aluminum, lead, and selenium were high at a pH of 5 although only selenium (0.83 mg L(-1)) warranted some concern. According to experimental results, the application of 10 Mg ha(-1) of sludge to acid gold tailings increased the leach water pH from 4.5 to more than 7.5 and also increased the medium pH from 2.4 to 7.5. The addition of sludge further reduced the solubility of iron, manganese, copper, and zinc in the ameliorated gold tailings, but increased the electrical conductivity. The liming tempo was highest in the coal discard profile that had a coarse particle size distribution and took the longest to move through the gold tailings that had a fine particle size distribution. Results from this study indicate that the water treatment sludge investigated is suitable as a liming agent for rehabilitation of acid mine waste.