Natural vs. plantation forests: A case study of land reclamation strategies for the humid tropics

Biomass and productivity were compared in two plantations and in one stand of natural regeneration on similar sites in a premontane moist forest region of Puerto Rico. While initial growth rates of plantation species were higher, after four decades productivity of the natural regeneration plots was equal to or greater than productivity of the plantations. For the first 44 years, aboveground biomass of natural regeneration increased at an average annual rate of 3.8t·ha^–1·yr^–1, but the last year of the study it was 14.7t·ha^–1. Biomass increment of a pine plantation averaged between 8 and 10.5t·ha^–1·yr^–1 except for one year when the rate was much lower, possibly because of hurricane damage. A tropical hardwood plantation averaged close to 4t·ha^–1·yr^–1 for 41 years. It is suggested that in countries where funds for land reclamation are limited, intensive plantations may not always be the best strategy. Natural regeneration or shelterbelt plantations may be suitable alternatives.     

Effect of selected and non-selected urban waste compost on the initial growth of corn

Brazil produces approximately 242,000 t of waste per day, 76% of it being dumped outdoors and only 0.9% recycled, including composting, which is an alternative still little known in Brazil. In search of a better destination for residues produced by domestic activities, composting stands as a feasible alternative. Organic compost from waste may be used for various purposes, among which are soil recovery, commercial production, pastures, lawns and reforestry and agriculture. However, the quality of the compost determines the growth and the development of plants. The effect of compost made from urban waste on corn plant (Zea mays L.) growth was investigated. Two types of compost were used: the selected compost (SC), produced from organic waste selectively collected; and the non-selected compost (NSC), taken from a 15-year-old cell from the Canabrava land-fill, located in Salvador, Bahia, Brazil (altitude 51 m, 12°22′–13°08′S, 38°08′–38°47′W). Corn was seeded in polyethylene pots, with soil-compost mixing substrate in the proportion of 0, 15, 30, 45 and 60 t ha⁻¹ equivalent doses. Chemical analyses of the compost and growth properties of the plant like chlorophyll content; height and stem diameter; aerial and radicular dry biomasses, were used to evaluate compost quality. Plants cultivated with SC presented a superior gain, being of 52.5% in stem diameter, 71.1 and 81.2% in root and stem biomasses, respectively. Chlorophyl content alterations were observed in plants from treatments using 30 t compost ha⁻¹ dose onwards. Conventional and multivariate statistical methods were used to evaluate these results. The beneficial action of organic compost in plant growth was confirmed with this research.     

Screening analysis of volatile organic contaminants in commercial inorganic coagulants used for drinking water treatment

A method for quality screening is suggested to detect volatile impurities in inorganic coagulants that are used for drinking water treatment. Static headspace gas chromatography with mass spectrometry detection (HS–GCMS) is sensitive and selective to detect volatiles in low concentrations. This study has discovered that volatile organic impurities are detectable in ferric and aluminium-based coagulants which are used for drinking water treatment. For ferric chloride, 2-propanol was detected at a level of 17–24 μg ml⁻¹, acetone at 0.7–1.7 μg ml⁻¹, 1,1,1-trichloroacetone at 0.02–0.04 μg ml⁻¹, trichloromethane at 0.01–0.02 μg ml⁻¹ and toluene at 0.01–0.12 μg ml⁻¹. For ferric chloride sulfate, acetone was detected at a level of 0.12 μg ml⁻¹, 1,1,1-trichloroacetone at 0.06–0.08 μg ml⁻¹, trichloromethane at 0.13–0.23 μg ml⁻¹, bromodichloromethane at 0.04–0.06 μg ml⁻¹ and dibromochloromethane at 0.04–0.05 μg ml⁻¹. For aluminium hydroxide chloride, only trichloromethane was detectable, but below the method detection limits (MDL). Although the concentrations of these impurities in commercial coagulants are low, this observation is important and should have impact on water industries for them to pay attention to the chemicals they are using for drinking water production.     

Utilization of waste product (tamarind seeds) for the removal of Cr(VI) from aqueous solutions: Equilibrium, kinetics, and regeneration studies

In the present study, an adsorbent was prepared from tamarind seeds and used after activation for the removal of Cr(VI) from aqueous solutions. The tamarind seeds were activated by treating them with concentrated sulfuric acid (98% w/w) at a temperature of 150 °C. The adsorption of Cr(VI) was found to be maximum at low values of initial pH in the range of 1–3. The adsorption process of Cr(VI) was tested with Langmuir, Freundlich, Redlich–Peterson, Koble–Corrigan, Tempkin, Dubinin–Radushkevich and Generalized isotherm models. Application of the Langmuir isotherm to the system yielded a maximum adsorption capacity of 29.7 mg/g at an equilibrium pH value ranging from 1.12 to 1.46. The adsorption process followed second-order kinetics and the corresponding rate constants obtained were 2.605 × 10⁻³, 0.818 × 10⁻³, 0.557 × 10⁻³ and 0.811 × 10⁻³ g/mg min⁻¹ for 50, 200, 300 and 400 mg/L of initial Cr(VI) concentration, respectively. The regenerated activated tamarind seeds showed more than 95% Cr(VI) removal of that obtained using the fresh activated tamarind seeds. A feasible solution is proposed for the disposal of the contaminants (acid and base solutions) containing high concentrations of Cr(VI) obtained during the regeneration (desorption) process.     

Biomass and nutrient removals from commercial thinning and whole-tree clearcutting of central hardwoods

The objective of this research was to evaluate the impacts of increasing product removal on biomass and nutrient content of a central hardwood forest ecosystem. Commercial thinning, currently the most common harvesting practice in southern New England, was compared with whole-tree clearcutting or maximum aboveground utilization. Using a paired-watershed approach, we studied three adjacent, first-order streams in Connecticut. During the winter of 1981–82, one was whole-tree clearcut, one was commercially thinned, and one was designated as the untreated reference. Before treatment, living and dead biomass and soil on the whole-tree clearcut site contained 578 Mg ha^–1 organic matter, 5 Mg ha^–1 nitrogen, 1 Mg ha^–1 phosphorus, 5 Mg ha^–1 potassium, 4 Mg ha^–1 calcium, and 13 Mg ha^–1 magnesium. An estimated 158 Mg ha^–1 (27% of total organic matter) were removed during the whole-tree harvest. Calcium appeared to be the nutrient most susceptible to depletion with 13% of total site Ca removed in whole-tree clearcut products. In contrast, only 4% (16 Mg ha^–1) of the total organic matter and 2% of the total nutrients were removed from the thinned site. Partial cuts appear to be a reliable management option, in general, for minimizing nutrient depletion and maximizing long-term productivity of central hardwood sites. Additional data are needed to evaluate the long-term impacts of more intensive harvests.     

Recycling of banana pseudostem waste for economical production of quality banana

Banana pseudostem biomass, traditionally incinerated and wasted, has been conserved and recycled by solid state fermentation (SSF) into plant growth stimulating soil conditioner (SC). This SC alone or combined with biofertilizers showed reduced mortality (10 and 12%) of planted suckers, enhanced chlorophyll contents (593 and 661 μg g⁻¹), gave biomass (35.0 and 36.6 kg) at par and improved yield (54.2 and 55.0 MT ha⁻¹), with that of the control (23%, 312 μg g⁻¹, 36.3 kg and 49.4 MT ha⁻¹, respectively). This has afforded (i) saving of chemical fertilizers by 50%, (ii) reduction in quantum (40%) and frequency (15%) of irrigation and (iii) reduction in cost of electricity and labor without sacrificing quality and quantity of banana. Thus, a voluminous agro-waste is converted into an eco-friendly agro-input for sustainable productivity.     

Acid-forming emissions in Alberta,Canada

The sulphur dioxide and nitrogen oxides emissions from all sources in Alberta, Canada, during 1982 amounted to 488,297 and 353,511 tonnes, respectively. During this year deposition of wet sulphate from all stations in the province, 8 kg ha^–1 yr^–1, compares well with the five-year average (1978–1982) value of 10 kg ha^–1 yr^–1. These measurements are about one-half of the wet sulphate deposition criteria of 20 kg ha^–1 yr^–1 established for protecting the moderately sensitive aquatic ecosystem in eastern Canada. Due to dry, cold, continental climate conditions of Alberta, dry sulphate or sulphur deposition is equally or more important than wet deposition. No effects of the long-range transport of atmospheric pollutants (LRTAP) on the ecosystems in Alberta have been observed to date. Atmospheric deposition target loadings of SO₄ ^–2, NO₃ ^–, and H⁺ for Alberta and western Canadian environmental conditions should be developed to protect the highly sensitive ecosystems. Some future research and monitoring priorities for Alberta and western Canada are outlined.     

Sewage sludge as organic ameliorant for revegetation of fine bauxite refining residue

The rise in aluminium demand in the world has significantly increased the generation of bauxite residue which occupies huge areas of land worldwide. Direct revegetation of residue storage areas has been unsuccessful because of the high alkalinity and salinity, and poor nutrient contents of the fine residue (red mud). This paper describes glasshouse and field experiments evaluating the potential use of sewage sludge as an organic ameliorant for gypsum amended red mud. The growth of Agropyron elongatum in red mud receiving gypsum (0 and 38.5 t ha⁻¹) and sewage sludge (0, 38.5 and 77 t ha⁻¹) amendment was assessed in a glasshouse study. Leachate and soil analyses revealed that gypsum was effective in reducing the pH, EC and ESP of red mud, while sewage sludge gave additional reductions in EC, Na and ESP. No evidence of any significant increases in heavy metal contents were observed in the leachates following sewage sludge amendment. However, soil Al contents were more available in red mud receiving only sewage sludge treatment. Sewage sludge amendment significantly increased dry weight yield and provided sufficient nutrients for plant growth except K which was marginal. No heavy metal accumulation was observed in Agropyron. Following that, a field experiment was performed having red mud amended with sewage sludge (38.5, 77 and 154 t ha⁻¹) and gypsum (38.5 and 77 t ha⁻¹) to evaluate their effects on soil physical properties of red mud. Sewage sludge significantly reduced soil bulk density (25%) and particle density (9%) and increased the total porosity of red mud (8%). Hydraulic conductivity also increased from 1.5 to 23 × 10⁻⁵ m s⁻¹. Plant cover percentage and dry weight yield of Agropyron increased with an increase in gypsum and sewage sludge amendment. The results confirm that sewage sludge is effective in improving both soil structure and nutrient status of gypsum amended red mud. The use of sewage sludge for red mud revegetation provides not just an option for sludge disposal, but also a cost effective revegetation strategy for bauxite refining industry.     

Growth and macronutrient removal of water hyacinth in a small secondary sewage treatment plant

Studies have been made of the growth characteristics of water hyacinth, Eichhornia crassipes (Mart.) Solms, and its ability to remove N, P and K, in a secondary settling pond of a small secondary sewage treatment plant serving both the academic and residential blocks of the Swire Marine Laboratory, University of Hong Kong. The treatment plant consists of, in series, a primary settling tank, a trickling filter compartment and a secondary settling pond from which part of the treated wastewater is recycled to the primary settling tank while the remaining effluent (1 to 2 m³ daily) mixes with and hence is diluted by the outflowing seawater from the aquarium system of the Swire Marine Laboratory before discharge to the sea. Samples of wastewater have been taken regularly from the primary sedimentation pond, the outflow of the trickling filter, the secondary settling pond and the effluent of the treatment plant (before mixing with aquarium outflow) since January, 1992. Physical, chemical and biological characteristics of the samples have been determined and are typical of secondary effluents, with a mean pH of about 7.5, total solids 1200 mg L⁻¹, suspended solids 45 mg L⁻¹, conductivity 2000 μS cm⁻¹, salinity 1 ppt, dissolved oxygen 2 mg L⁻¹, BOD₅ 45 mg L⁻¹, Kjeldahl-N 30 mg L⁻¹, NH₄,-N 25 mg L⁻¹, NO₃-N 4 mg L⁻¹, total P 10 mg L⁻¹, K 35 mg L⁻¹ and total coliforms of less than 10⁵ colonies 100 ml⁻¹.Water hyacinth plants have been stocked in the secondary settling pond as an integral part of the treatment plant so as to improve the quality of, as well as to retrieving and recycling nutrient elements from, the wastewater. The plants are periodically harvested to maintain an active growing crop. The growth rate, standing crop biomass, tissue nutrient composition, nutrient storage and accumulation rate of two growth cycles, one from February 25 to March 18 (mean temperature 17.6°C) and the other from 22 April to 12 May (24.8°C) are reported. The water hyacinth assumed a relatively high standing crop biomass of 10 kg m⁻² (5 to 6 t DM ha⁻¹), and growth rates of 48 and 225 g m⁻² day⁻¹, respectively, for the first and second growth period. Nutrient storage capacities were relatively high, at about 20, 7.5 and 16.5 g m⁻² for N, P and K, respectively. The nutrient composition was very high, reaching 5.42% for N, 1.97 for P, and 4.57 for K. Both the stem and lamina accumulated high levels of N, while the petiole had the highest level of P and K. Apart from nutrient removal, the water hyacinth also helped to decrease the suspended solids, BOD₅ value and total coliforms of the wastewater.It is concluded that water hyacinth improves the quality of wastewater in such small-scale sewage treatment plants and it is recommended that frequent harvests of water hyacinth would increase the treatment efficiency, especially during the active growing season with high temperatures coupled with intense solar radiation.     

Response of Organic and Inorganic Carbon and Nitrogen to Long-Term Grazing of the Shortgrass Steppe

We investigated the influence of long-term (56 years) grazing on organic and inorganic carbon (C) and nitrogen (N) contents of the plant–soil system (to 90 cm depth) in shortgrass steppe of northeastern Colorado. Grazing treatments included continuous season-long (May–October) grazing by yearling heifers at heavy (60–75% utilization) and light (20–35% utilization) stocking rates, and nongrazed exclosures. The heavy stocking rate resulted in a plant community that was dominated (75% of biomass production) by the C₄ grass blue grama (Bouteloua gracilis), whereas excluding livestock grazing increased the production of C₃ grasses and prickly pear cactus (Opuntia polycantha). Soil organic C (SOC) and organic N were not significantly different between the light grazing and nongrazed treatments, whereas the heavy grazing treatment was 7.5 Mg ha^–1 higher in SOC than the nongrazed treatment. Lower ratios of net mineralized N to total organic N in both grazed compared to nongrazed treatments suggest that long-term grazing decreased the readily mineralizable fraction of soil organic matter. Heavy grazing affected soil inorganic C (SIC) more than the SOC. The heavy grazing treatment was 23.8 Mg ha^–1 higher in total soil C (0–90 cm) than the nongrazed treatment, with 68% (16.3 Mg ha^–1) attributable to higher SIC, and 32% (7.5 Mg ha^–1) to higher SOC. These results emphasize the importance in semiarid and arid ecosystems of including inorganic C in assessments of the mass and distribution of plant–soil C and in evaluations of the impacts of grazing management on C sequestration.     

Mobility of oil and other sludge constituents during oily sludge treatment by landfarming

Five levels of oily sludge application were made to the surface layer of a desert sandy soil in Kuwait. The migration of the constituents of the sludge to subsurface soil layers was investigated at intervals over a period of 29 months. The data show very limited mobility to subsurface soil layer (40–70 cm depth) but not to 70–90 cm depth. The environmental impact of the added sludge is related to soil pH and to the Zn equivalent value of the sludge. Zn equivalent for the soil treated with oily sludge was 612 mg kg⁻¹, which is much lower than permissible limits. This soil can accept more than 1000 t ha⁻¹ from this type of sludge. However, due to the heterogeneous composition of sludge the Zn equivalent value should be calculated for each batch. Addition of oily sludge to the desert soil susceptible to wind erosion had a significant effect on minimizing soil loss under wind tunnel conditions. This effect is attributed to aggregation of the soil particles in the surface soil layers.     

160 h of chemical-looping combustion in a 10 kW reactor system with a NiO-based oxygen carrier

Chemical-looping combustion, CLC, is a technology with inherent separation of the greenhouse gas CO₂. The technique uses an oxygen carrier made up of particulate metal oxide to transfer oxygen from combustion air to fuel. In this work, an oxygen carrier consisting of 60% NiO and 40% NiAl₂O₄ was used in a 10 kW CLC reactor system for 160 h of operation with fuel. The first 3 h of fuel operation excepted, the test series was accomplished with the same batch of oxygen carrier particles. The fuel used in the experiments was natural gas, and a fuel conversion to CO₂ of approximately 99% was accomplished. Combustion conditions were very stable during the test period, except for the operation at sub-stoichiometric conditions. It was shown that the methane fraction in the fuel reactor exit gas was dependent upon the rate of solids circulation, with higher circulation leading to more unconverted methane. The carbon monoxide fraction was found to follow the thermodynamical equilibrium for all investigated fuel reactor temperatures, 660–950 °C. Thermal analysis of the fuel reactor at stable conditions enabled calculation of the particle circulation which was found to be approximately 4 kg/s, MW. The loss of fines, i.e. the amount of elutriated oxygen carrier particles with diameter <45 μm, decreased during the entire test period. After 160 h of operation the fractional loss of fines was 0.00022 h⁻¹, corresponding to a particle life time of 4500 h.     

Unexpected difference in phenol sorption on PTMA- and BTMA-bentonite

The comparison of phenol sorption on phenyltrimethylammonium (PTMA)- and benzyltrimethylammonium (BTMA)-bentonite shows a clear difference as far as phenol sorption isotherms are concerned. For PTMA-bentonite the sorption isotherm is of a straight-line character which results from simple partitioning of phenol between the aqueous and organic phases sorbed on the bentonite surface. For BTMA-bentonite the isotherm has a convex shape, characteristic of physicochemical sorption.For the first time a three-parametric model, including the dissociation constant of phenol pK_a, distribution constant of phenol Kd_phen and phenolate anion Kd_phen⁻ between the aqueous phase and the bentonite phases is used for the evaluation of phenol sorption on organoclays with pH change. The model shows that the values of Kd_phen are higher than those of Kd_phen⁻ for all investigated initial phenol concentrations.The inspection of the FTIR spectrum of BTMA-bentonite loaded with phenol in the regions 1300–1600 and 1620–1680 cm⁻¹ shows the features of π–π electron interaction between the benzene rings of phenol and the BTMA cation together with the phenol–water hydrogen bond strengthened by this interaction.     

Antibacterial behavior of silver-modified clinoptilolite-heulandite rich tuff on coliform microorganisms from wastewater in a column system

The water disinfecting behavior of silver-modified clinoptilolite–heulandite rich tuff (ZSAg) as an antibacterial agent against coliform microorganisms from water in a continuous mode was investigated. Silver recovery from the disinfected effluents by the sodium-modified clinoptilolite–heulandite rich tuff (ZSNa) was also considered. Escherichia coli (ATCC 8739) and total coliform microorganisms, as indicators of microbiological contamination of water, were chosen to achieve the disinfection of synthetic wastewater or municipal wastewater. Ammonium (NH₄⁺) and chloride (Cl⁻) ions were added to the synthetic wastewater as an interfering chemical species on the disinfection processes. The antibacterial activity of the ZSAg as a bactericide was measured by the coliform concentration as evaluated by the APHA method. The amount of silver in the disinfected effluents was determined using atomic absorption spectroscopy. The inactivation of the ZSAg was calculated from the breakthrough curves based on the model reported by Gupta et al. It was found that when the silver concentration in the effluent is less than 0.6 μg/mL, the bacterial survival percentage increased and the volume of disinfected water diminished. The total silver amounts found in the effluent at the end of the disinfection processes varied depending on the water treated (synthetic or municipal wastewater). The presence of NH₄⁺ ions in synthetic wastewater influent notably improved the disinfected water volume (zero NVC/100 mL), in comparison to the disinfection of the same influent without NH₄⁺ ions. A contrary water disinfection behavior was observed in the presence of Cl⁻ ions. The silver recovery does not depend on the mass of the sodium zeolitic bed according with the wastewater to be treated (synthetic or municipal wastewater) and the presence of NH₄⁺ or Cl⁻ ions in the influent also influenced the silver recovery from wastewater. The ZSNa did not have antibacterial activity. Therefore the amount of bactericide agent (silver-modified natural zeolite), coliform microorganisms from water (E. coli or consort of coliform microorganisms) as well as the water quality (synthetic wastewater or municipal wastewater) influenced both the disinfection process and the silver recovery in a column system.     

Soil erosion under different vegetation covers in the Venezuelan Andes

This comparative study of soil erosion considered different environments in an ecological unit of the Venezuelan Andes. The soils belong to an association of typic palehumults and humic dystrudepts. Soil losses were quantified by using erosion plots in areas covered by four types of vegetation, including both natural and cultivated environments. The highest soil erosion rate evaluated corresponded to horticultural crops in rotation: reaching a value of 22 Mg ha^–1 per year. For apple tree (Malus sylvestris Miller) plots, soil losses reached values of 1.96 Mg ha^–1 per year. Losses from pasture (Pennisetum clandestinum Hochst. ex Chiov.) plots, without livestock grazing, were as high as 1.11 Mg ha^–1 during the second year of the experiment. The highest soil losses generated from plots under natural forest were equal to 0.54 Mg ha^–1 per year. Environmental factors such as total and effective rainfall, runoff, and some soil characteristics as those related to soil losses by water erosion were evaluated. The type of management applied to each site under different land use type and the absence of conservation practices explain, to a large extent, the erosive processes and mechanisms.     

Factors affecting nitrate distribution in shallow groundwater under a beef farm in South Eastern Ireland

Groundwater contamination was characterised using a methodology which combines shallow groundwater geochemistry data from 17 piezometers over a 2 yr period in a statistical framework and hydrogeological techniques. Nitrate–N (NO₃-N) contaminant mass flux was calculated across three control planes (rows of piezometers) in six isolated plots. Results showed natural attenuation occurs on site although the method does not directly differentiate between dilution and denitrification. It was further investigated whether NO₃-N concentration in shallow groundwater (<5 m below ground level) generated from an agricultural point source on a 4.2 ha site on a beef farm in SE Ireland could be predicted from saturated hydraulic conductivity (K_sat) measurements, ground elevation (m Above Ordnance Datum), elevation of groundwater sampling (screen opening interval) (m AOD) and distance from a dirty water point pollution source. Tobit regression, using a background concentration threshold of 2.6 mg NO₃-N L⁻¹ showed, when assessed individually in a step wise procedure, K_sat was significantly related to groundwater NO₃-N concentration. Distance of the point dirty water pollution source becomes significant when included with K_sat in the model. The model relationships show areas with higher K_sat values have less time for denitrification to occur, whereas lower K_sat values allow denitrification to occur. Areas with higher permeability transport greater NO₃-N fluxes to ground and surface waters. When the distribution of Cl⁻ was examined by the model, K_sat and ground elevation had the most explanatory power but K_sat was not significant pointing to dilution having an effect. Areas with low NO₃ concentration and unaffected Cl⁻ concentration points to denitrification, low NO₃ concentration and low Cl⁻ chloride concentration points to dilution and combining these findings allows areas of denitrification and dilution to be inferred. The effect of denitrification is further supported as mean groundwater NO₃-N was significantly (P < 0.05) related to groundwater N₂/Ar ratio, redox potential (Eh), dissolved O₂ and N₂ and was close to being significant with N₂O (P = 0.08). Calculating contaminant mass flux across more than one control plane is a useful tool to monitor natural attenuation. This tool allows the identification of hot spot areas where intervention other than natural attenuation may be needed to protect receptors.     

Organic carbon diminution and estimates of carbon dioxide release from plantation soil

Summary This paper evaluates the rates of organic carbon diminution in the soil under monospecific tree plantations of teak, gmelina, rubber, oil palm, cashew and coffee. The differences between the organic carbon status of their soils and soil under nearby natural rain forest vegetation are compared. Annual rates of organic carbon decrease for the 0–10 cm soil layer, varied from 82.1 kg ha^–1 for cashew to 316.7 kg ha^–1 for oil palm. The tree plantations appear to release more carbon dioxide from the soil into the atmosphere than the natural forest. They therefore, appear to have the potential of contributing towards global warming — a threat they are supposed to mitigate.     

Comparison of biosorbents with inorganic sorbents for removing copper(II) from aqueous solutions

In comparison with several other reported inorganic sorbents, Camellia tree leaf and primary sludge obtained from a settling tank as a pretreatment to the activated sludge system in a Hong Kong sewage treatment plant were evaluated for removing Cu(II) from aqueous solutions. Experimental data were modeled by the Langmuir isotherm equation to estimate the maximum sorption capacity (q_max). Results show that, at pH 5.6, biosorbents, Camellia tree leaf and primary sludge in particular, exert higher sorption capacities (q_max > 40 mg g⁻¹) than inorganic sorbents, Na-montmorillonite (q_max = 33.3 mg g⁻¹), fly ash (q_max = 18.8 mg g⁻¹), and goethite powder (10.3 mg g⁻¹). Furthermore, a pseudo second-order kinetic model was found to properly describe the experimental data for both bio- and inorganic sorbents. Sorption of Cu(II) on the Camellia tree leaf and primary sludge were much faster than that on the inorganic sorbents. In addition, desorption tests revealed that the desorption capacities of the two biomaterials are higher than the other selected materials; and much more Cu(II) can be retrieved from the Cu(II)-loaded biosorbents. Finally, increasing solution pH was found to greatly increase q_max and accelerate sorption processes.     

Methane fermentation of dung from litter-free reared domestic animals — an optimisation study

Data on the quantity (27 453 tons from litter-free reared animals in Bulgaria, only) and the chemical and energy characteristics of dung produced in intensive management farms for domestic animals suggests that technologies combining biogenic elements recycling with energy utilistation and dung decontamination are expedient to be applied on these types of farms. To this effect a fermenter was designed and a mathematical model (a Chen-Hashimoto model based computer programme) was applied, as a result of which the optimum methane fermentation parameters were determined. The technological methane output (Y_v) — indicator of biogas production efficiency (output/dm³ fermentor volume) showed an optimum at temperature 55°C and period of exchange 6 days. The methane output per unit mineralised organic matter in the substrate (B) — assumed as an indicator of ecological efficiency (maximum organic matter degradation) exhibited an optimum at 33°C for 15 days period of exchange.     

Batch and continuous biosorption of Cu by immobilized biomass of Arthrobacter sp.

The ability of free and polysulphone immobilized biomass of Arthrobacter sp. to remove Cu²⁺ ions from aqueous solution was studied in batch and continuous systems. The Langmuir and Freundlich isotherm models were applied to the data. The Langmuir isotherm model was found to fit the sorption data indicating that sorption was monolayer and uptake capacity (Q^o) was 175.87 and 158.7 mg/g for free and immobilized biomass respectively at pH 5.0 and 30 °C temperature, which was also confirmed by a high correlation coefficient, a low RMSE and a low Chi-square value. A kinetic study was carried out with pseudo-first-order reaction and pseudo-second-order reaction equations and it was found that the Cu²⁺ uptake process followed the pseudo-second-order rate expression. The diffusivity of Cu²⁺ on immobilized beads increased (0.402 × 10⁻⁴ to 0.435 × 10⁻⁴ cm²/s) with increasing concentration from 50 to 150 mg/L. The maximum percentage Cu²⁺ removal (89.56%) and uptake (32.64 mg/g) were found at 3.5 mL/min and 20 cm bed height. In addition to this the Bed Depth Service Time (BDST) model was in good agreement with the experimental data with a high correlation coefficient (>0.995). Furthermore, sorption and desorption studies were also carried out which showed that polysulphone immobilized biomass could be reused for up to six sorption–desorption cycles.