燃烧假人实验室安全监控及应急处理系统设计

针对燃烧假人实验室的安全监控和应急处理要求,根据相关国家标准,设计了感温、感烟、可燃气体探测器、声光报警器,摄像装置、通排风系统、灭火处理系统和水喷淋降温装置,并采取防雷击和防静电措施,实现了对高温、烟雾和燃气泄露等安全隐患的全面监控和处理。     

炼厂液化石油气(高含烯烃LPG)作为车用燃料的试验研究

炼厂液化石油气成分复杂,主体成分包含大量的烯烃,且含有硫、水及其他杂质.将其直接作为汽车燃料,对车辆以及燃料供给系统均存在不同程度的危害.通过试验研究除杂等精制工艺过程,得到了高含烯烃精制液化石油气,消除了杂质对燃料供给系统和发动机的影响.并研究了高含烯烃液化石油气在车辆上的使用性能.试验表明,高含烯烃液化石油气可使车辆的动力性有所提高,排放性能与标准车用液化石油气接近.由于炼厂液化石油气价格相对较低,因此车辆燃料费用大大降低,得到了包括出租车辆在内的广大用户的认可,具有良好的推广应用前景.     

冷冻堵漏法在危险化学品泄漏事故中的应用

为了研究液化气体泄漏冷冻堵漏的堵漏机制,运用流体力学、传热学等知识对液化石油气（LPG）储罐（槽罐）泄漏时泄漏口处产生局部低温的现象进行了研究,探讨了LPG液相泄漏和气相泄漏2种不同泄漏形式的低温效应。结果表明:液相泄漏时,泄漏口处温度下降程度与泄漏口面积成正比,且随着罐体内部压力的减小而减弱,推导出喷水冷冻堵漏的成冰时间公式;气相泄漏时,对罐内压力与温度的平衡关系进行模拟并建立了数学模型;发现由于LPG气、液相之间对流换热和汽化吸热效应的差异,导致液相与气相之间的温度差,此温度差是罐体外壁产生结霜分层现象的主要原因。     

多元可燃性混合气体临界氧浓度的测定

可燃性气体(蒸气)的临界氧浓度目前只限于对单元气体混合物的研究,且影响因素较少提及。通过实验测定了人工煤气、液化石油气的爆炸极限和临界氧浓度,对可燃性气体(蒸气)临界氧浓度的影响因素进行了研究,所测定的数据为煤气、液化石油气的安全防爆工作提供了依据。     

民用压缩气体或液化气体气瓶库与周围建(构)筑物安全间距探讨

民用压缩气体和液化气体一旦发生爆炸，会造成很大的破坏力。根据压缩气体和液化气体的特性，通过计算，由爆炸中心到能保证人身安全和建筑(构筑)物和设备免遭破坏的最小距离。     

CFD-based assessment and visualization of the failure consequences of LPG tankers

This paper presents a simulation analysis of the explosions following an LPG leak and visualizes the consequences of the accident to reduce the consequences of the LPG leak explosion. Firstly, this paper proposes a CFD numerical simulation-based method for visualizing the consequences of LPG tanker failure. The method combines satellite maps and CFD numerical simulation data to visualize the consequences of LPG leaks and explosions, taking into account the influence of obstacles on the danger range of leaks and explosions; Secondly, this paper applies the method to a liquefied petroleum gas accident that occurred in the Wenling section of the Shenhai Expressway and performs CFD numerical simulation on the accident process and visualizes the consequences of the accident. Therefore, this method can provide a theoretical reference for the prior prevention of LPG accidents and the analysis of the consequences of accidents, as well as certain practical guidance instructive.     

LPG船液货泄漏事故风险评估系统研究

通过对液化石油气(LPG)船舶液货舱泄漏事故危险度因素分析,建立液化气液体货物泄漏源强、蒸气释放源强和蒸气扩散计算模型,并制定泄漏事故风险评价流程,基于VB语言编写泄漏事故风险评估系统。利用该系统能够计算得出泄漏事故发生后蒸发气在不同时刻不同区域的蒸发气浓度、爆炸或火灾后对生命财产的伤害半径以及伤害程度等相关参数。对某航行状态下的LPG实船进行模拟分析,结果表明能够对LPG船舶泄漏事故进行有效风险评估,并能对船舶航行安全应急预案的制定和事故后海事鉴定提供一定的技术帮助。     

液化石油气罐车卸车作业事故——安全阀意外开启泄压原因调查

为了提高液化石油气罐车采用压缩机卸车法作业的安全性,通过对某液化石油气罐车卸车作业时其顶部安全阀意外开启泄压的事故原因进行调查,查明了导致罐车顶部安全阀意外开启泄压的直接原因是操作工人违章作业导致储罐与罐车罐体内气相液化石油气压差安全裕量严重不足所致。同时探讨了在夏季高温环境采用压缩机法对液化石油气罐车卸车作业时液化石油气罐车顶部安全阀整定值设定、液化石油气储罐与罐车罐体内气相液化石油气压差安全裕量的重要性。     

Application of CREAM human reliability model to cargo loading process of LPG tankers

The storage and handling processes of liquefied petroleum gas (LPG) constitutes a complex operational environment in the maritime mode of transportation. The LPG cargo is carried by specially designed ships called LPG tankers. The LPG cargo loading and discharging operations have always potential hazards. Thus, the crew on-board LPG tankers should be fully aware of operational risks during the cargo handling process, which includes various critical tasks such as drying, inerting, gassing-up, cooling, and reliquefaction. During these stages, human reliability (operation without failure) plays a crucial role in sustainable transportation of cargo. Human reliability analysis (HRA), related to various parameters such as the human factor, technology, and ergonomics, is always a critical consideration as regards maritime safety and environment. The main focus of the research is to systematically predict human error potentials for designated tasks and to determine the required safety control levels on-board LPG ships. The paper adopted CREAM (Cognitive reliability and error analysis method) basic and extended versions in order to assess human reliability along with the cargo loading process on-board LPG tanker ships. Specifically, the model is demonstrated with an operational case study. Consequently, the research provides should contribute to maritime safety at sea and prevention of human injury and loss of life on-board LPG ship.     

事故树分析法在LPG储罐火灾爆炸事故中的应用

LPG(液化石油气)属于危险化学品之一,LPG储罐发生火灾爆炸的机率大,造成的损失比较严重,故对其火灾爆炸事故进行研究具有重要意义。LPG储罐爆炸根据其发生机理分为化学爆炸(燃爆)和物理爆炸两种模式。本文通过对LPG储罐燃爆﹑物理爆炸两类事故进行系统分析,建立了以LPG储罐燃爆、物理爆炸为顶事件的事故树。通过对其事故树的定性分析,得到了影响顶事件的各个最小割(径)集。通过计算底事件的结构重要度,确定了影响LPG储罐火灾爆炸事故的主要因素,并提出了相应的改进措施,进而提高LPG储罐的安全性和运行可靠性。     

Computational fluid dynamics (CFD) study of heat radiation from large liquefied petroleum gas (LPG) pool fires

Liquefied petroleum gas (LPG) is flammable and has risks of pool fires during its transportation, storage, and applications. The heat radiation by LPG pool fires poses hazards to individuals nearby and can lead to potential failures of ambient facilities. Due to the high costs and invasive nature of experiments for investigating large-scale pool fires, computational fluid dynamics (CFD) is employed in this study as the cost-effective and noninvasive method to simulate the process and analyze the characteristics of large hydrocarbon pool fires. Specifically, an experimentally validated 3-D CFD model has been built to simulate surface emissive power (SEP) and incident radiation of large-scale LPG pool fires with three different diameters and wind speeds. Steady-state simulations with P1 radiation and probability density function (PDF) combustion models were employed to obtain reliable data after the optimizations based on the comparisons with experimental data and empirical models. The comparison with benchmark experimental data demonstrates that the CFD model employed in this study can accurately predict the incident radiation of large LPG pool fires. A new SEP correlation is also proposed, which is specifically for LPG pool fires with a diameter between 10 m and 20 m. Additionally, the safe separation distances between LPG facilities and surrounded objects have been estimated based on the CFD simulation results. The high-resolution CFD model for large LPG pool fires in this work provides noninvasive and direct quantitative evidence to enhance the fundamental understanding on the safety of large LPG pool fires and can assist regulatory agencies in refining the safety limits in the cost-effective and time-saving manners.     

大型LPG罐区火灾爆炸事故后果评估

针对大型LPG(液化石油气)储罐区潜在的火灾爆炸危险性，建立了喷射火、火球、UVCE爆炸和BLEVE爆炸的数学伤害模型，对其发生火灾、爆炸后人员和建筑(设备)所受到的伤害和损伤进行了定量后果评估。     

基于人工神经网络的LPG公路运输的风险评价模型及其应用

为使LPG公路运输的风险评价更加客观、合理,遵循区域性、动态性和可量化原则,建立了LPG公路运输的风险评价指标,并将个人风险和社会风险作为评价结果。利用人工神经网络的自组织、自学习和自适应功能,提出基于人工神经网络理论的LPG公路运输的风险评价方法,通过Matlab软件中的神经网络工具箱对评价模型进行训练,并通过实践验证该模型的可行性。结果表明,该方法能较好地克服评价深度、评价指标间复杂关系和评价指标作用模糊的限制,且评价结果直观的反映了评价对象的个人风险和社会风险的风险程度。     

An experimental investigation of fluid flow and combustion characteristics of dual-fuel in a cylindrical combustion chamber

Combustion and fluid flow characteristics of coflowing LPG and kerosene have been investigated experimentally. A cylindrical water cooled combustion chamber was used to investigate the effect of changing the injection location and percentage of liquid fuel during gaseous fuel combustion. It was found that the injection of liquid fuel leads to an increase in the absolute value of maximum positive axial velocity and reduces the absolute value of the maximum negative axial velocity compared to the case of LPG alone. Also, a stable temperature distribution is noticed at axial distance of X/D approximately equal to 2.15 (where X is the axial distance measured from the inlet of diffuser, and D is chamber diameter). This is less than that of gaseous fuel combustion (approximately equal to 2.91). The change of injection location leads to a reduction in values of gas temperatures at X_inj/D=0.15 then it increased to reach maximum values at X_inj/D=0.35 which is approximately the same value for combustion of LPG fuel only. Any further increase in the injection location leads to a reduction in gas temperature, especially at the upstream sections of the combustion chamber. Also, it was found that values of temperature along the combustion chamber were decreased with increasing the percentage of the injected liquid fuel due to incomplete combustion of liquid fuel. Values of combustion chamber efficiency (η) for all percentage of liquid fuel at X_inj/D=0.35 are higher than those for combustion of LPG alone.     

液化石油气球罐泄漏危险的预防和控制探讨

阐述了液化石油气球罐的特点。对液化石油气球罐的泄漏危险性进行了分析,主要存在的泄漏危险有泄漏物质易燃易爆、易发生泄漏、受热易膨胀导致泄漏、泄漏气体易积聚、泄漏事故具有隐蔽性、泄漏物质具有毒害性。根据液化气泄漏危险性分析,提出了预防和控制液化石油气球罐泄漏危害的安全措施:加强设备质量管理,杜绝泄漏现象;合理设置球罐,降低泄漏风险;规范安全操作,减少泄漏量;防止泄漏气体积聚;设置防泄漏安全装置;及时发现泄漏;设置消防给水及灭火设施;妥善处理泄漏事故。     

Fire and risk analysis during loading and unloading operation in liquefied petroleum gas (LPG) bottling plant

The article focuses on analyzing risks associated with the gas transfer operation in a liquified petroleum gas (LPG) bottling plant in India. The transfer operations involve transferring liquified gas from the transport tanker to the underground storage tank. Due to the rapid expansion of the cities, many LPG bottling plants in India got surrounded by residential areas and business centers. Moreover, to maintain the supply chain, the frequency of the transfer operations at the bottling plant also increased. In this scenario, an accidental release of LPG during the transfer operation may lead to various consequences such as a pool fire, a fireball, and even a catastrophic rupture of the tank with a successive explosion of its contents. In the study, the operations involved in bottling plants are classified into different hazard zones and analyzed. The probability of occurrence of events leading to an accident is modeled using modeling tools such as ALOHA and PHAST. The consequences of an accident following various events, such as jet fire, fireball, etc., are modeled, and the simulation results are compared. The thermal radiation has been estimated as 4–40 kW/m², which could adversely affect the nearby population and could result in damaging plant machinery and equipment.     

平板模型对液化石油气连续泄漏扩散模拟分析与探讨

对目前主要的气体泄漏扩散模拟计算模型进行比较分析,选择平板模型用于液化石油气连续泄漏扩散模拟计算,运用假设中型和大型泄漏的计算实例结果,通过与挪威船级社(DNV)开发的SAFETI风险评价软件的计算结果进行对比分析,可以得出:在静风条件下,平板模型对液化石油气连续泄漏扩散模拟的准确性高。随着云团扩散密度降低,平板模型计算偏差逐步加大,且计算偏差随风速的增大而变大,因而利用平板模型进行模拟计算的结果应予修正。     

火灾爆炸危险指数法的应用

介绍了运用火灾爆炸危险指数法对液化石油气储罐和加油站内埋地汽油罐进行安全评价的实例，主要是估算其发生爆炸可能影响的范围以及所造成的损失，并提出相应的安全对策。     

现行标准下某在用LPG卧式储罐的设计制造和检验分析

液化石油气卧式储罐是我国石油化工行业常用的储存设备,其设计检验和评估分析尤为重要.本文以公司某超期服役的在用LPG卧式储罐为例,结合TSG R21-2016《固定式压力容器安全技术监察规程》等现行国家标准和规定对其进行了设计制造和检验验收的再分析,最后根据最新的全面检验结果对该LPG储罐现阶段服役状况进行了分析总结,符...     

基于热-结构耦合分析的液化石油气储罐失效预警判定*

为研究火灾中球罐应力场分布情况,找到球罐失效破裂条件,以液化石油气为研究对象,基于球罐稳态热响应,通过ANSYS热-结构耦合有限元分析法进行研究。结果表明:充装率85%的液化石油气球罐最高温度部位出现在气相区,约619.66 ℃;最大应力值出现在气液交界处,约615.18 MPa;得到球罐破裂失效时温度值和应力值,并设置2次预警值。研究结果可为液化石油气储罐失效预警提供参考和判定依据。