厦门市区环境天然放射性水平监测

参照国家环保局颁发的<环境天然放射性水平调查规定>,在厦门城市建城区开展了原野、道路和建筑物室内γ辐射剂量率监测,查明了市区环境的天然放射性水平现状,为厦门市放射性环境管理提供了重要的资料.     

建材用工业废渣及其产品的放射性和放射性检测

建材用工业废渣及其产品的放射性和放射性检测刘鄂（新疆辐射环境监理站８３００１１）《家庭》杂志１９９３年７期刊登了一篇题为《一家三口死于肺癌》的文章，认为其“罪魁祸首是煤渣砖”，相继一些报刊转载了类似文章。一时间弄得十分紧张，造成一些施工中的楼房停工，...     

新疆城市放射性废物库环境放射性调查

本文分析了新疆城市放射性废物库2012—2016年的γ剂量率、中子剂量率、表面沾污、氡浓度、土壤中放射性核素比活度以及地表水核素含量变化情况。监测结果表明:新疆城市放射性废物库库区内新库、老暂存库以及库外周围γ辐射剂量率和中子剂量率均处于乌鲁木齐市正常本底水平,表面沾污和氡浓度均未见异常,库区周围环境地表水白鸟湖总α、总β放射性浓度均低于《生活饮用水卫生标准》,土壤中γ核素均在乌鲁木齐市环境土壤天然放射性水平范围中。通过废物库的监测,对掌握新疆城市放射性废物库周边放射性水平,开展环境辐射评价提供了科学依据。     

新疆乌鲁木齐市放射性水平调查

为建立公众相关的放射性本底数据库,掌握环境介质的放射性水平和变化趋势,科学评价放射性水平及对人群健康效应的影响,新疆辐射环境监督站持续开展了对乌鲁木齐市周围环境介质放射性监测工作。本文给出了2013—2017年乌鲁木齐市气溶胶、沉降灰、土壤和地表水、饮用水中放射性核素水平以及γ瞬时剂量率和γ累计剂量的调查测量结果。调查结果表明乌鲁木齐市天然放射性水平处于本底范围内,这对掌握乌鲁木齐市放射性水平提供了科学依据。     

正交设计在废水吸附试验研究中的应用

本文应用正交设计的基本理论，试验研究了粉煤灰，工业煤渣和泥炭在不同状况下对纺织印染废水的吸附处理效果，确定了最佳吸附工况，取得了较为满意的结果，为正交设计理论于环境污染治理技术的研究进行了有益的尝试，具有一定的实际意义。     

2016—2020年四川省地级市(州)饮用水源地总α、总β放射性水平及健康风险评估

为了解四川省各地级市(州)饮用水源地的放射性水平,评价其水源地辐射水平的安全性,于2016—2020年对全省各地级市(州)饮用水源地进行布点、采样,分析水中总α、总β的放射性水平,利用健康风险模型对居民的健康风险进行评估。结果显示:各地级市(州)饮用水源地的总α、总β放射性浓度范围分别为0.008~0.094、0.011~0.190 Bq/L,不同年度、不同水源地、不同水源地类型的总α和总β放射性水平间比较,差异均无统计学意义(P>0.05);不同水期的总α、总β放射性水平的差异有统计学意义(P<0.05),总α和总β放射性对各年龄段居民的总致癌风险均低于WHO和ICRP发布的最严格控制限值。该次调查显示,四川省21个地级市(州)饮用水源地的总α和总β放射性处于安全水平,各年龄组的健康风险都是处于可接受的范围内。     

宜春钽铌矿周围放射性调查与评价

对宜春钽铌矿周围陆地γ辐射和水体放射性环境现状进行了调查与评价，结果表明，宜春钽铌矿排放废水放射性水平远低于《污水综合排放标准》（GB8978—1996）规定的限值，陆地和环境水体均未受到放射性污染。     

云南水环境放射性水平监测结果分析

根据2013—2020年云南省河流、湖泊、饮用水和地下水省控点、国控点的水中放射性水平监测结果,分析了水中总α、总β、U、Th、²²⁶Ra、⁴⁰K、¹³⁷Cs、⁹⁰Sr的监测浓度。结果表明:六大水系监测断面水中总α、总β均小于0.5、1.0 Bq/L;九大高原湖泊水中放射性水平相对较高的是Ⅴ类水体杞麓湖、异龙湖,放射性水平相对较低的是Ⅰ类水体抚仙湖、泸沽湖,滇池内海水中U、Th浓度优于滇池外海;饮用水源地水中放射性总α、总β均显著低于《生活饮用水卫生标准》(GB 5749—2022)规定限值。     

新疆建筑材料用工业废渣及其建材产品的辐射水平

报道了分布在新疆１３个地州市８０多个厂家的建材用工业废渣及其建材产品的放射性检测结果。多数废渣及其产品的放射性水平低于国家规定的限制（控制）标准，可以用作建筑材料，少数地区的部分工业废渣明显高于限制标准，不能用作建筑材料．必须健全放射性检测和管理制度．     

2007—2015年长江流域四川段主要江河放射性水平分析

对2007—2015年长江流域四川段主要12条江河水体放射性核素活度浓度的监测结果进行了分析。结果表明，四川段主要江河放射性核素水平远低于我国规定的露天水源的限制浓度。与1995年中国环境天然放射性（四川省部分）、1988年长江水系天然放射性活度浓度参考范围相比，U、Th、²²⁶Ra、⁴⁰K、¹³⁷C_s均有上升趋势，其他核素活度浓度涨落不明显均在本底范围内。总 α、总 β放射性活度浓度测值均符合《生活饮用水卫生标准》（GB 5749—2006）的限值要求。     

Seasonal variation for the ratio of BaP to BeP at different sites in Great Xiamen Bay

From March 2008 to February 2009, PM(10) samples were collected and analyzed for polycyclic aromatic hydrocarbons (PAHs) at eight sampling sites in Great Xiamen Bay, China. Analyses of the seasonal and spatial variations of these compounds revealed the following results. Significantly high levels of PAHs were found in the winter compared to the summer, sometimes exceeding 100 ng m(-3), and the spatial variations were influenced most by the sampling site surroundings. Composition profiles of PAHs of an urban and a rural site were shown to be very similar with a positive correlation coefficient larger than 0.9 at the 0.01 level of significance for the same season. Diagnostic ratios, together with principal component and multiple linear regression analysis, showed that more PAHs were from grass/wood/coal combustion in winter than in other seasons. The ratios of benzo[a]pyrene to benzo[e]pyrene (BaP-BeP) in winter and fall were 0.6-1.7 times higher than those in spring and summer, suggesting the importance of local emissions of PAHs. The BaP-BeP ratios in Kinmen were generally lower than those in Xiamen, indicating that the aging degree of PAHs was higher in Kinmen than in Xiamen. The external input of PAHs from upwind urban and industrial areas was one of the key factors causing high levels of PAHs in PM(10) in Great Xiamen Bay in winter.     

Study of heavy metals in some environmental samples

Fuels like coal and rubber are frequently used for brick burning. However, both coal and rubber contain heavy metals. These heavy metals may elutriate in the wake of fly ash or may adsorb or absorb in the product. The present work deals with the analysis of heavy metals in some samples collected from brick burning industries located in the vicinity of a metropolitan city, Peshawar, Pakistan. Samples from raw clay, product, chimney scale and fossil fuel & rubber were collected and leached with acid mixture. The leachates were concentrated and analyzed by atomic absorption spectrophotometer for the determination of chromium (Cr), lead (Pb), cadmium (Cd) and antimony (Sb). It was observed that heavy metals are present in clay, brick and chimney scale. However, significant amount of these metals was observed in chimney scale. It is inferred that such emanations laden with heavy metals are accompanying the stack gases which are being dumped in to the environment. In order to avoid environmental problems, strict environmental regulations shall be enforced and a constant check on these emanations to the environment must be made to ensure clean air act.     

燃油和燃煤电厂排放可吸入颗粒物的物理化学特性

分别对燃烧重油与烟煤两个电厂排放可吸入颗粒物的显微结构、颗粒类型及重金属在可吸入颗粒物中分布特征进行研究.研究表明,燃煤电厂排放可吸入颗粒物的形态都以球形颗粒为主,而燃油电厂排放可吸入颗粒物由一些絮状物和类似于燃煤飞灰中球形颗粒组成.根据可吸入颗粒物的化学组成,发现燃油电厂排放可吸入颗粒物的颗粒类型有硅铝质和钙-硅铝质...     

煤矿矿井废水综合治理探讨

对煤矿矿井废水进行机械作用,实现清、污分离,清水回用,煤泥渣统一处理,使煤矿矿井废水实现零排放.     

Ozone Destruction on Solid Particles

Ozone (O3) is an important constituent of the Earth atmosphere, either stratosphere, where it has a beneficial role to protect Earth's surface from harmful UV-B radiation, or troposphere where it is considered an air pollutant. We investigated the ozone destruction on solid particles of natural or anthropogenic origin as: silica-gel, pollen, coal fly ash, titanium dioxide with different specific surface (s) and sodium halides (NaCl, NaBr and NaI). The experiments were conducted in a fluidized bed reactor with elevated ambient concentrations of O3 (100 ppb) employed. The results indicate that the destruction of O3 depends upon: sample quantity (silica-gel with equal s), sample surface (TiO2 with different s) and chemical composition (coal fly ash comparative to wood ash). Interesting results were obtained with sodium halides: no effect on O3 concentrations was detected with NaCl, NaBr shows a certain destruction, while NaI removes completely O3 from the air stream. In the experiments with NaI doped NaCl, the destruction of O3 was dependent on NaI quantity.     

Methodology of CO2 emission evaluation in the life cycle of office building façades

The construction industry is one of the greatest sources of pollution because of the high level of energy consumption during its life cycle. In addition to using energy while constructing a building, several systems also use power while the building is operating, especially the air-conditioning system. Energy consumption for this system is related, among other issues, to external air temperature and the required internal temperature of the building. The façades are elements which present the highest level of ambient heat transfer from the outside to the inside of tall buildings. Thus, the type of façade has an influence on energy consumption during the building life cycle and, consequently, contributes to buildings' CO₂ emissions, because these emissions are directly connected to energy consumption. Therefore, the aim is to help develop a methodology for evaluating CO₂ emissions generated during the life cycle of office building façades. The results, based on the parameters used in this study, show that façades using structural glazing and uncolored glass emit the most CO₂ throughout their life cycle, followed by brick façades covered with compound aluminum panels or ACM (Aluminum Composite Material), façades using structural glazing and reflective glass and brick façades with plaster coating. On the other hand, the typology of façade that emits less CO₂ is brickwork and mortar because its thermal barrier is better than structural glazing façade and materials used to produce this façade are better than brickwork and ACM. Finally, an uncertainty analysis was conducted to verify the accuracy of the results attained.     

Monitoring the species of arsenic, chromium and nickel in milled coal, bottom ash and fly ash from a pulverized coal-fired power plant in western Canada

The concentration of As, Cr and Ni and their speciation (As3+;5+, Cr3+;6+ and Ni0;2+) in milled coal, bottom ash and ash collected by electrostatic precipitator (ESP) from a coal fired-power plant in western Canada were determined using HGAAS, ICP-AES and XANES. The chemical fractionation of these elements was also determined by a sequential leaching procedure, using deionized water, NH4OAC and HCI as extracting agents. The leachate was analyzed by ICP-AES. Arsenic in the milled coal is mostly associated with organic matter, and 67% of this arsenic is removed by ammonium acetate. This element is totally removed from milled coal after extraction with HCI. Arsenic occurs in both the As3+ and the As5+ oxidation states in the milled coal, while virtually all (>90%) of the arsenic in bottom ash and fly ash appears to be in the less toxic arsenate (As5+) form. Both Ni and Cr in the milled coal are extracted by HCI, indicating that water can mobilize Ni and Cr in an acidic environment. The chromium is leached by water from fly ash as a result of the high pH of the water, which is induced during the leaching. Ammonium acetate removes Ni from bottom ash through an ion exchange process. Chromium in milled coal is present entirely as Cr3+, which is an essential human trace nutrient. The Cr speciation in bottom ash is a more accentuated version of the milled coal and consists mostly of the Cr3+ species. Chromium in fly ash is mostly Cr3+, with significant contamination by stainless-steel from the installation itself.     

Comparative on Causes and Accumulation of Selenium in the Tree-rings Ambient High-selenium Coal Combustion Area from Yutangba, Hubei, China

Toxic trace elements emitted during coal combustion are the main sources of air pollution. They are released into the atmosphere mainly in the forms of fine ash, smoke and flue, and thus adversely affect plant, animal and human health. Selenium is one of toxic and the most volatile in coal. Large amount of atmospheric emission of selenium, as well as selenium present and scrubber stockpiles in ash may create serious environmental problems. In the paper, on the basis of investigating the abundance and distribution of selenium in plant-rings during recent 20 years, the bioaccumulation of selenium is explained that selenium in plant, which were collected from the village of selenium-rich coal combustion, is much higher than that in plants collected away from the village of selenium-rich coal combustion. The main origins of selenium are selenium-rich coal combustion and high-selenium rock weathered. The selenium recycle by food chain and selenium will accumulate and redistribute in environments.     

南京某燃煤电厂汞的排放特点及分布特征

选择南京某燃煤电厂330 MW机组，对煤、炉渣、粉煤灰、烟尘、石灰石、石膏和烟气中的汞取样测量，探讨煤中汞在燃烧过程中的变化情况，并进一步分析汞的排放特点及分布特征。指出，煤经燃煤锅炉炉内高温燃烧后，炉渣中的汞对环境影响不明显；粉煤灰、烟尘中的汞存在富集现象，且随着粒径变细，富集程度加剧；燃煤锅炉燃烧后，随石膏排放的汞占比较大，应采取相应的防治措施。     

Speciation of nickel in Canadian subbituminous and bituminous feed coals, and their ash by-products

The nickel species in the feed coals and ash by-products from seven Canadian power plants (including one with a fluidized bed combuster) burning local subbituminous and bituminous coals with sulfur contents ranging from 0.22 to 3.6% have been examined using nickel XANES spectroscopy. XANES spectroscopy of Ni in coal and coal derived ash is complicated by a poor signal : noise ratio due to fluorescence of the much more abundant iron in the coal. Nevertheless, it has proved possible to show that the Ni environment in coals varies from largely oxidic species to mixtures of Ni-containing oxide and sulfide species. The nickel in one oxidized coal appears to be present as nickel sulfate. Nickel in all bottom and fly ash samples examined appears also to be present largely in oxygen anion environments. With the exception of one fly ash sample, for which the Ni exhibited spectral features similar to those for Ni(2+) in spinel or oxide phases, the nickel in the bottom and fly ash samples appears to exist largely as Ni(2+) in environments similar to those reported for Ni in silicate glasses. The data obtained indicate that the presence of potentially carcinogenic nickel sulfides in ash by-products from combustion of these coals is unlikely.