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1.
Two studies were conducted to address the potential nonlinear relationship between emotional exhaustion and voice. Study 1 developed and tested a model rooted in conservation of resources theory in which responses to emotional exhaustion are determined by individual‐level and group‐level conditions that influence the perceived safety and efficacy of voice and drive prohibitive voice behaviors by giving rise to either resource‐conservation‐based or resource‐acquisition‐based motivation. Specifically, there was a curvilinear (U‐shaped) relationship between emotional exhaustion and prohibitive voice under conditions of (i) high job security and (ii) high interactional justice climate, but a linearly negative relationship when these resources were low. Study 2 replicated and extended these findings to include an empirical examination of these effects on promotive versus prohibitive voice. Results confirmed the findings of Study 1, provided evidence of differences in the nomological networks of promotive and prohibitive voice, and indicated that prohibitive voice is more salient to the experience of high emotional strain. Implications of the findings and areas for future research are discussed. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

2.
The safety issue of ethanol gasoline and the methods to control or weaken its explosion have attracted attention. To clarify the effect of C6F12O (perfluoro(2-methyl-3-pentanone)) on the explosion of ethanol gasoline-air mixtures and intrinsic mechanism, the explosion overpressure and flame propagation behavior under different equivalence ratios (φ = 0.6–0.8) and C6F12O concentrations (χinh = 0–4.0%) were experimentally obtained. The detailed inhibitor reaction process was also obtained by CHEMKIN based on a new assembly kinetic mechanism. The results show that the effects of C6F12O on the explosion characteristics of ethanol gasoline varied with χinh and φ. For rich flames, C6F12O is more effective than and heptafluoropropane (C₃HF₇) and nitrogen (N2) in suppressing explosions; for lean and equivalence ratio flames, the addition of C6F12O may result in more severe explosions. The decrease in chemical reactivity is mainly because the mole fractions of OH and H radicals and the proportion of paths H radicals involved decrease after adding C6F12O, and R1500: CF3COF + H = CF3CO + HF, R965: CF2:O + H = CF:O + HF, R863: CF3 + H = CF2 + HF are main suppressing reactions.  相似文献   

3.
BG Technology and the Major Hazard Assessment Unit (MHAU) of the Chemicals and Hazardous Installations Division (CHID) of the HSE have developed a novel approach for the management of the risk of harm to people in the vicinity of major hazards. Particular attention is given to such risk in the vicinity of high-pressure gas pipelines.The objective of the approach is to provide a means of allowing reasonable development of land whilst ensuring that a tolerable level of risk is maintained.One means of managing this type of risk is known as the F/N approach. The F/N approach expresses and manages the risk in terms of the frequency, F, of N or more casualties occurring. However, the F/N approach may lead to a perceived inconsistency as it may allow some initial development of a particular type of dwelling in a particular location, then preclude further development in adjacent locations.The approach derived herein provides some alleviation to this perceived inconsistency by discouraging localised regions of high population density, thereby promoting a more uniform distribution of development of land.The essence of the approach is to apply a weighting (≥1) to casualty density prior to the evaluation of casualty expectation. The resulting parameter, which has been aptly named weighted expectation (WE), is assessed according to a criterion based on true casualty expectation (E). The weighting on casualty density is derived directly from an appropriately constructed F/N criterion line (or envelope), thereby ensuring a close relationship between the outcomes of WE and F/N assessments.The Scaled Risk Integral (SRI), which has been developed previously, is shown to be a special case of WE.The practical application of WE and its relationship with F/N are demonstrated through simple high-pressure pipeline case studies.  相似文献   

4.
IntroductionNegative reinforcement from crash warnings may reduce the likelihood that drivers engage in distracted driving. Alternatively, drivers may compensate for the perceived safety benefit of crash warnings by engaging in distractions more frequently, especially at higher speeds. The purpose of this study was to examine whether warning feedback from an integrated vehicle-based safety system affected the likelihood that various secondary behaviors were present among drivers ages 16–17, 20–30, 40–50, and 60–70.MethodParticipants drove an instrumented sedan with various collision warning systems for an extended period. Ten 5-second video clips were randomly sampled from driving periods at speeds above 25 mph and below 5 mph each week for each driver and coded for the presence of 11 secondary behaviors.ResultsAt least one secondary behavior was present in 46% of video clips; conversing with a passenger (17%), personal grooming (9%), and cellphone conversation (6%) were the most common. The likelihood that at least one secondary behavior was present was not significantly different during periods when drivers received warnings relative to periods without warnings. At least one secondary behavior was 21% more likely to be present at speeds below 5 mph relative to speeds above 25 mph; however, the effect of vehicle speed was not significantly affected by warning presence. Separate models for each of the five most common secondary behaviors also indicated that warnings had no significant effect on the likelihood that each behavior was present.ConclusionsCollision warnings were not associated with significant increases or decreases in the overall likelihood that teen and adult drivers engaged in secondary behaviors or the likelihood of the behaviors at speeds above 25 mph or below 5 mph.Practical applicationsThere was no evidence that forward collision warning and other technologies like those in this study will increase or decrease distracted driving.  相似文献   

5.
The present study developed a nomological network that theoretically linked time urgency to related variables. To test the proposed relationships, time urgency, achievement strivings (AS), and impatience/irritability (II) were utilized as predictors of health and performance 18 months later. Multivariate canonical correlation analyses provided support for a complex nomological network among the predictors and the outcome measures. Redundancy coefficients and a rotated structure matrix were employed to identify two significant dimensions, labeled crammers and organizers, that linked the predictors with the outcome measures. The results also indicated that the time urgency subcomponents were differentially related to several health outcomes. These findings provide further validity evidence for the time urgency construct, and they suggest that time urgency variables should be considered as important predictors of both health and performance outcomes. Directions for future research on time urgency are discussed. © 1998 John Wiley & Sons, Ltd.  相似文献   

6.
7.
Perfluorocarbons (PFCs) are being used as etching/cleaning gases in microelectronic or semiconductor manufacturing processes. These compounds under industrial uses mainly include CF4 (tetrafluorocarbon), C2F6 (hexafluoroethane), C3F8 (octafluoropropane), and cyclo-C4F8 or c-C4F8 (octafluorocyclobutane). From the globally environmental issues and regulatory points of view, it is urgent to control the emissions of these significant greenhouse gases from the industrial processes. This article reviews these PFCs in terms of physiochemical properties, industrial uses, and environmental hazards (e.g. global warming, and toxicity and exposure hazards). Further, it addresses some available recovery/recycle technologies (i.e. cryogenic condensation/distillation, pressure swing adsorption, and membrane separation) of process exhaust gases containing PFCs from semiconductor manufacturing processes in this review paper.  相似文献   

8.
IntroductionCrash warning systems have been shown to provide safety benefits, but no studies have examined how teenagers respond. This study sought to find out whether young, inexperienced drivers change behavior in response to warnings.MethodsForty 16–17 year-olds drove an instrumented vehicle equipped with a system that warned for lane departures and potential rear-end and lane change/merge crashes. Participants were randomly assigned to experimental or control groups, and their driving was monitored for 14 weeks during 2011–12. For the experimental group, this included a treatment period, when crash alerts were received by drivers, and baseline and post-treatment periods, when warnings were recorded but not received. The control group never received warnings. Data were analyzed to determine whether warnings were associated with changes in driving behavior.ResultsA total of 15,039 trips were analyzed. Lane drifts accounted for 73% of warnings. Forward collision warning rates doubled for all drivers during the treatment period and continued at an increased rate post-treatment. This was likely a result of the fact that, as time went on, all drivers spent more time following vehicles at close distances. Receiving alerts was associated with effects on following and lane-changing behavior, including more time spent following at close distances (17%), fewer lateral drifts (37%) and fewer unsignaled lane changes (80%). Receiving warnings wasn't associated with an increased likelihood of engaging in secondary tasks.ConclusionsWarning systems may result in improved lane-keeping and turn-signal behaviors by novice drivers, but there is some indication they may result in more close-following behaviors.Practical applicationsThere is some evidence that lane departure warning may improve turn-signal use for young drivers. While there is no evidence of safety benefits from the other types of warnings, there is some evidence of an increase in close-following behavior but no increase in secondary tasks due to the presence of those capabilities.  相似文献   

9.
Objective: This study evaluated the effectiveness of a series of 1-year multifaceted school-based programs aimed at increasing booster seat use among urban children 4–7 years of age in economically disadvantaged areas.

Methods: During 4 consecutive school years, 2011–2015, the Give Kids a Boost (GKB) program was implemented in a total of 8 schools with similar demographics in Dallas County. Observational surveys were conducted at project schools before project implementation (P0), 1–4 weeks after the completion of project implementation (P1), and 4–5 months later (P2). Changes in booster seat use for the 3 time periods were compared for the 8 project and 14 comparison schools that received no intervention using a nonrandomized trial process.

The intervention included (1) train-the-trainer sessions with teachers and parents; (2) presentations about booster seat safety; (3) tailored communication to parents; (4) distribution of fact sheets/resources; (5) walk-around education; and (6) booster seat inspections.

The association between the GKB intervention and proper booster seat use was determined initially using univariate analysis. The association was also estimated using a generalized linear mixed model predicting a binomial outcome (booster seat use) for those aged 4 to 7 years, adjusted for child-level variables (age, sex, race/ethnicity) and car-level variables (vehicle type). The model incorporated the effects of clustering by site and by collection date to account for the possibility of repeated sampling.

Results: In the 8 project schools, booster seat use for children 4–7 years of age increased an average of 20.9 percentage points between P0 and P1 (P0 = 4.8%, P1 = 25.7%; odds ratio [OR] = 6.9; 95% confidence interval [CI], 5.5, 8.7; P < .001) and remained at that level in the P2 time period (P2 = 25.7%; P < .001, for P0 vs. P2) in the univariate analysis. The 14 comparison schools had minimal change in booster seat use. The multivariable model showed that children at the project schools were significantly more likely to be properly restrained in a booster seat after the intervention (OR = 2.7; 95% CI, 2.2, 3.3) compared to the P0 time period and compared to the comparison schools.

Conclusion: Despite study limitations, the GKB program was positively associated with an increase in proper booster seat use for children 4–7 years of age in school settings among diverse populations in economically disadvantaged areas. These increases persisted into the following school year in a majority of the project schools. The GKB model may be a replicable strategy to increase booster seat use among school-age children in similar urban settings.  相似文献   


10.
Aim. The purpose of this study was to examine the associations between various health and fitness measures and Functional Movement Screen? (FMS?) scores among 78 firefighter recruits. Methods. Relationships between FMS? scores and age, body mass index (BMI), sit and reach (S&R) distance, estimated maximal aerobic capacity (O2max), estimated one-repetition maximum squat (1RM-Squatmax), and plank endurance (%Plankmax) were examined. Results. Total FMS? scores were significantly correlated with BMI (r?=??0.231, p?=?0.042), estimated 1RM-Squatmax (r?=?0.302, p?=?0.007), and %Plankmax (r?=?0.320, p?=?0.004). Multiple regression analyses indicated that this combination of predictors significantly predicted (F(3, 74)?=?5.043, p?=?0.003) Total FMS? score outcomes and accounted for 17% of the total variance (R2?=?0.170). In addition, logistic regression analyses indicated that estimated 1RM-Squatmax also significantly predicted (χ2?=?6.662, df?=?1, p?=?0.010) FMS? group membership (≤14 or ≥15). Conclusion. These results suggest that the health and fitness measures of obesity (BMI), bilateral lower extremity strength (estimated 1RM-Squatmax), and core muscular endurance (%Plankmax) are significantly associated with functional movement patterns among firefighter recruits. Consequently, injury prevention programs implemented among firefighter recruits should target these aspects of health and fitness.  相似文献   

11.
The purpose of this study was to develop a model for an integrated estimation of the functional state of the human organism (FSHO) and an integral estimation of physical factors (PF) for hygienic rating. Tests were performed twice with 3 men in 0.7-clo clothing during 4-hr mental work with 9 combinations of 4 PF: wideband noise (55–83 dB(A)), whole-body vibration (6 Hz, az = 0.2–1.8 ms?2), air temperature (18–30 °C), and illumination (1, 3, 5 lx). Thermoregulatory, cardiovascular, and psychophysiological reactions and temporary threshold of hearing (TTS2) shifts were studied. For the integral estimation of PF influence on FSHO the model F(y1, y2, ... ym) = f(x1, x2, ... xn) was used, relating both FSHO and PF sets. The most important physiological parameters in creating FSHO are defined and the contribution of individual parameters of FSHO and PF is found.  相似文献   

12.
Purpose. The aim of this article was to check whether mindfulness-based stress reduction (MBSR) is an effective intervention in reducing work-related stress in the case of workers in a copper mine. Methods. Sixty six employees were randomized to the experimental group (32 participants) or to the control group (34 participants). Work-related stress was measured using the job content questionnaire (JCQ) and mental health was measured using the general health questionnaire (GHQ-28) Experimental manipulation was 40-h MBSR training. Results. Multivariate repeated-measures analysis of variance revealed a significant increase of JCQ decision latitude (F?=?17.36, p?<?0.001) and social support (supervisor F?=?9.00, p?<?0.004; coworker F?=?5.61, p?<?0.020), and a significant decrease in GHQ-28 anxiety (F?=?5.28, p?<?0.079) and depression (F?=?3.95, p?<?0.048) due to the intervention. Conclusions. The study confirms that MBSR can be effective in reducing stress resulting from the external risk (and/or imagined fear) of losing one’s health or life. The use of MBSR could be recommended in health and safety activities in difficult and dangerous work conditions, such as mining, to promote workers’ well-being.  相似文献   

13.
In this study perceived mental stress during occupational work was compared to heart rate variability (HRV) using a traditional questionnaire and a novel wristop heart rate monitor with related software. The aim was to find HRV parameters useful for mental stress detection. We found the highest correlation between perceived mental stress with the differences between the values of triangular interpolation of rythm-to-rythm (RR) interval histogram (TINN) and the root mean square of differences of successive RR intervals (RMSSD) obtained in the morning and during the workday(r = -.73 andr = -.60, respectively). The analysis shows that as the RMSSD and TINN value differences increase from night to morning, the stress decreases.  相似文献   

14.
Analytical and numerical solutions are used to determine the critical conditions for thermal explosion of autocatalytic reaction. The solutions covers both the reaction governed by the Arrhenius kinetics equation and the Frank-Kamenetskii approximation for that equation. The definition of criticality as the point at which d2θ/2=0, d3θ/3=0 and /〉0 is used here. The study is dealt with low and high exothermicity (B) of the reaction and their effects on the critical parameters. The numerical solutions cover the whole reaction from start at β = 0 up to the end at β = 1.0. All trajectories from subcritical, critical to supercritical are offered. The effects of different parameters such as B, ψ and θa (ambient temperature) on the critical conditions are presented. The results showed that the lower the autocatalytic factor (β0) is, the pronounced autocatalytic reaction explosion. The analytical solution offered analytical expressions for the critical condition and the different limits of the solutions are clarified. It was found that the numerical results confirm the analytical solution.  相似文献   

15.
Purpose. The relationship between enterprise size and psychosocial working conditions has received little attention so far but some findings suggest that conditions are more favorable in small enterprises. This could have a positive impact on workers’ mental health. The objective of this study was to test the mediating effect of perceived working conditions in the relationship between enterprise size and anxious or depressive episodes. Methods. Data from the 2010 SUMER – Surveillance Médicale des Expositions aux Risques professionnels (French periodical cross-sectional survey) were analyzed; N?=?31,420 for the present study. Anxious or depressive episodes were measured with the hospital anxiety and depression scale and the perceived working conditions were psychological demand, decision latitude and social support as assessed with Karasek's job content questionnaire. The indirect effect was tested according to the method proposed by Preacher and Hayes. Results. In a multivariate logistic regression, the risk of anxious or depressive episodes was found to be lower in micro enterprises (2–9 employees). Formal tests pointed to a significant indirect effect of enterprise size on mental health through perceived working conditions, with a larger effect for psychological demand. Conclusion. This study highlights perceived working conditions as an explanation of the effects of enterprise size.  相似文献   

16.
Thriving at work refers to a positive psychological state characterized by a joint sense of vitality and learning. On the basis of Spreitzer and colleagues' model, we present a comprehensive meta‐analysis of antecedents and outcomes of thriving at work (K = 73 independent samples, N = 21,739 employees). Results showed that thriving at work is associated with individual characteristics, such as psychological capital (rc = .47), proactive personality (rc = .58), positive affect (rc = .52), and work engagement (rc = .64). Positive associations were also found between thriving at work and relational characteristics, including supportive coworker behavior (rc = .42), supportive leadership behavior (rc = .44), and perceived organizational support (rc = .63). Moreover, thriving at work is related to important employee outcomes, including health‐related outcomes such as burnout (rc = ?.53), attitudinal outcomes such as commitment (rc = .65), and performance‐related outcomes such as task performance (rc = .35). The results of relative weights analyses suggest that thriving exhibits small, albeit incremental predictive validity above and beyond positive affect and work engagement, for task performance, job satisfaction, subjective health, and burnout. Overall, the findings of this meta‐analysis support Spreitzer and colleagues' model and underscore the importance of thriving in the work context.  相似文献   

17.
Purpose. To study whether perceptual identification should be included as a measure to evaluate physiological stress. Methods. Physiological variables oxygen uptake (VO2), ventilation, heart rate, blood lactate concentration, rectal temperature (Trec) and mean skin temperature, and perceptual variables rate of perceived exertion, thermal sensation and time to exhaustion, were measured at submaximal and maximal intensities during graded exercise on a treadmill to exhaustion in 12 firefighters wearing protective clothing and extra mass at 40 and 10 °C. Physiological strain index (PhSI) and perceptual strain index (PeSI) were calculated. Results. Apart from Trec, all physiological and perceptual variables were higher at submaximal intensities of 40 °C. Time to exhaustion was 16% shorter and the corresponding VO2 was reduced by 7% in the heat. A high correlation (r?=?89) between PhSI and PeSI was found at both temperatures. PeSI scores were equal to PhSI at both ambient temperatures, except at the two highest intensities in the heat, where PeSI was higher. Conclusions. These findings support use of perceptual identification to evaluate physiological stress. However, at very high intensities under hot conditions the perceptual strain was estimated higher than the physiological strain. More precise indexes are needed to include perceptual measures in safety standard.  相似文献   

18.
IntroductionThe present study examines the self-reported frequency of non-lost work time workplace injuries (“microaccidents”) and the frequency of three types of work-related safety behaviors (i.e., safety voice, safety compliance, and safety neglect) recalled over a four-week period.MethodWe analyzed data on microaccidents and safety behaviors from 19,547 young workers (aged 15–25 years, Mdn = 18 years; 55% male) from multiple Canadian provinces.ResultsApproximately one-third of all young workers recalled experiencing at least one microaccident at work in the last four weeks. Comparisons across three age groups revealed that younger workers, particularly between the ages of 15–18, reported more frequent microaccidents, less safety voice, less safety compliance, and more safety neglect than workers aged 19–22. This pattern of results also held for comparisons between workers in 19–22 and 23–25 age groups, except for safety voice which did not differ between these two older age groups. In terms of gender, males and females reported the same frequency of microaccidents, but males reported more safety voice, more safety compliance, and more safety neglect than females did. The results and limitations of the present study are discussed.ConclusionFrequency of microaccidents and safety behavior vary among young worker age sub-groups.  相似文献   

19.
Cascade-based attack vulnerability on the US power grid   总被引:5,自引:0,他引:5  
The vulnerability of real-life networks subject to intentional attacks has been one of the outstanding challenges in the study of the network safety. Applying the real data of the US power grid, we compare the effects of two different attacks for the network robustness against cascading failures, i.e., removal by either the descending or ascending orders of the loads. Adopting the initial load of a node j to be Lj=[kjmΓjkm)]α with kj and Γj being the degree of the node j and the set of its neighboring nodes, respectively, where α is a tunable parameter and governs the strength of the initial load of a node, we investigate the response of the US power grid under two attacks during the cascading propagation. In the case of α<0.7, our investigation by the numerical simulations leads to a counterintuitive finding on the US power grid that the attack on the nodes with the lowest loads is more harmful than the attack on the ones with the highest loads. In addition, the almost same effect of two attacks in the case of α=0.7 may be useful in furthering studies on the control and defense of cascading failures in the US power grid.  相似文献   

20.
1,1-Di (tert-butylperoxy) cyclohexane (DTBPH) has been widely employed in the chemical industry. Unfortunately, organic peroxides have been involved in many serious fires and explosions in manufacturing processes, storage, and transportation. This study investigated the thermokinetic parameters by isothermal kinetic and non-isothermal-kinetic simulation, using differential scanning calorimetry (DSC) tests. DSC was applied to assess the kinetic parameters, such as kinetic model, frequency factor (ln k0), activation energy (Ea), reaction order, and heat of reaction (ΔHd). Comparisons of non-isothermal and isothermal-kinetic model simulation led to a beneficial kinetic model of thermal decomposition to predict the thermal hazard of DTBPH. Simulations of a 0.5 L Dewar vessel and 25 kg barrel commercial package in liquid thermal explosion models were performed and compared to the results in the literature. From the results, the optimal conditions for use of DTBPH to avoid violent runaway reactions during the storage and transportation were determined. This study established the features of thermal decomposition that could be executed as a reduction of energy potential and storage conditions in view of loss prevention.  相似文献   

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