Toxic effects of brominated flame retardants in man and in wildlife

Brominated flame retardants (BFRs) are ubiquitous industrial chemicals, and many of them are produced in large volumes. Due to this fact, several BFRs are found in quantifiable levels in wildlife, as well as in humans. However, we are still lacking information on the effects of BFR in wildlife and, especially, in man. This review summarises the biological effects of polybrominated diphenyl ethers (PBDEs), tetrabromobisphenol A (TBBPA) and derivates, hexabromocyclododecane (HBCD) and polybrominated biphenyls (PBBs), however excluding other aspects such as environmental levels. These BFR groups were selected because of a large volume production (PBDEs, TBBPA and derivates), and availability of some toxicity data in spite of much lower production volumes (HBCD and PBBs). In addition, the increase in levels of PBDEs in human (breast milk) and wildlife samples during later time made it especially interesting to include this BFR group. PBDES: The commercial PBDE products predominantly consist of so-called penta-, octa- and decabromodiphenyl ether products. Each product consists of a rather narrow range of congeners and is named after the dominating congener as regards the bromination pattern. Generally, the PentaBDEs seem to cause adverse effects at the comparably lowest dose, whereas much higher doses were needed for effects of the DecaBDEs. The critical effects of PentaBDEs are those on neurobehavioural development (from 0.6 mg/kg body weight) and, at somewhat higher dose, thyroid hormone levels in rats and mice, of OctaBDEs on fetal toxicity/teratogenicity in rats and rabbits (from 2 mg/kg body weight), and of DecaBDEs on thyroid, liver and kidney morphology in adult animals (from 80 mg/kg body weight). Carcinogenicity studies, only performed for DecaBDEs, show some effects at very high levels, and IARC (1990) evaluates DecaBDEs not classifiable as to its carcinogenicity to humans. TBBPA: The toxicity of TBBPA in the experimental in vivo studies is suggested to be low. In most reported studies, only doses in g/kg body weight were effective, but at least one study suggested renal effects at around 250 mg/kg body weight. Although difficult to include and interpret in a quantitative risk assessment, the in vitro effects on immunological and thyroid hormones, as well as binding to erythrocytes should be noted. Before a solid standpoint could be reached on TBBPA toxicity additional studies must be performed. This statement is even more valid regarding the TBBPA derivates, where there is an almost complete lack of toxicity data. HBCD: Also in the case of HBCD, relevant toxicity studies are lacking. Based on the present animal studies, a critical effect is seen in the liver and on thyroid hormones (LOAEL 100 mg/kg body weight/day). However, in a recent short paper behavioural effects in mice pups were observed already at 0.9 mg/kg body weight, and behavioural effects may be a sensitive endpoint for HBCD, as well as for other BFRs. PBBS: Due to the Michigan accident in 1973-1974, many toxicity studies on PBBs are available. The critical experimental effects are those on reproduction and carcinogenicity, and a NOAEL of 0.15 mg/kg body weight/day could be suggested based on the cancer effects. In man no unequivocal effects have been observed, although in some studies neurological and musculoskeletal symptoms were suggested. Based on the carcinogenic effects in animals, a human TDI of 0.15 microg/kg body weight has been presented.To conclude, the toxicity data are almost entirely based on experimental models. There are differences among the BFR groups, as well as within these groups, both regarding type of toxic effect and at what dose it appears. As BFRs will continue to appear both in industrial applications and, even if the production has ceased, in our environment, there is a continued need for effects studies on BFRs.     

Participatory approach in vision setting: emerging initiatives in local municipalities in Japan

In this paper, we present the emerging practices in Japanese local municipalities, in which participatory methods are applied to envision sustainable future and relevant target settings. We selected three local cases: Higashiomi city, Kizugawa city and Nagakute city as emerging initiatives. A comparative analysis was carried out to identify commonalities and differences, and to derive lessons for appropriate governance and systems for participatory deliberation in future visioning. We argue that the deliberation processes served as a platform for effective communication, and that installing a mechanism that allows reflexive deliberation processes is the key to make participatory methods fully functional.     

Polychlorinated biphenyls in ambient air of NW Greece and in particulate emissions

Polychlorinated biphenyls (PCBs) bound to total suspended particles (TSP) were determined in the area of Eordea basin, NW Greece, where intensive coal burning for electricity production takes place. The concentrations of PCBs exhibited high variability although within the range reported for urban industrialized areas. The presence of PCBs in fly ash generated from coal burning as well as in particulate emissions from vehicles, domestic heating, burning of refuses and biomass was also examined. The particles emitted from vehicles and central heating exhibited the higher content of PCBs, whereas fly ash the lower. The pattern of PCBs in TSP as well as in particulate emissions was discussed.     

Chromium toxicity in plants

Due to its wide industrial use, chromium is considered a serious environmental pollutant. Contamination of soil and water by chromium (Cr) is of recent concern. Toxicity of Cr to plants depends on its valence state: Cr(VI) is highly toxic and mobile whereas Cr(III) is less toxic. Since plants lack a specific transport system for Cr, it is taken up by carriers of essential ions such as sulfate or iron. Toxic effects of Cr on plant growth and development include alterations in the germination process as well as in the growth of roots, stems and leaves, which may affect total dry matter production and yield. Cr also causes deleterious effects on plant physiological processes such as photosynthesis, water relations and mineral nutrition. Metabolic alterations by Cr exposure have also been described in plants either by a direct effect on enzymes or other metabolites or by its ability to generate reactive oxygen species which may cause oxidative stress. The potential of plants with the capacity to accumulate or to stabilize Cr compounds for bioremediation of Cr contamination has gained interest in recent years.     

Multi-criteria decision analysis in adaptation decision-making: a flood case study in Finland

Decision-making for the purpose of adaptation to climate change typically involves multiple stakeholders, regions and sectors as well as multiple objectives related to the use of resources and perceived benefits. Standard cost–benefit analysis can be argued to take into account easily monetised effects only. Multi-criteria decision analysis (MCDA) embedded in participatory processes can therefore play an important role in defining the decision context and exploring stakeholders’ preferences. In this paper, a case study on flood protection of the Kokemäki river running through the city of Pori in West Finland was conducted. The study was realised as a MCDA workshop involving the key stakeholders of the region. The analysis produced a robust ranking of the considered flood protection alternatives. According to the stakeholders, the approach was useful as an exploratory way of gaining a deeper and shared understanding of the flood protection. It was shown that MCDA is well suited for decision-making in adaptation to climate change–enhanced extreme events.     

Theorizing stakeholders of sustainability in the digital age

Stakeholder theory, originally introduced in 1984 by philosopher Edward Freeman, is among the most influential theories today addressing the complex interplay of societal actors. It underwent several transformations and expansions, but the original Freeman model as well as the latest approaches places the corporation at the center positioning the theory as management driven. In this article—from a sustainability science perspective—we argue that sustainability could also be considered as the center, around which societal actors are grouped, because everyone, individuals as well as stakeholders, have a stake in a ‘common future’ that is built on the transformative concept of sustainability. Next to this shift of perspective from corporation to sustainability at the center, we advance the concept of sustainability stakeholders with the new paradigm of the digital age we (are about to) live in: the proposed sustainability-centered stakeholder theory is developed to incorporate novel parameters as brought about by digitalization (such as big data, real-time transparency, algorithmic correlations, predictive analytics, or changing privacy standards). Hence, we classify the stakeholders of sustainability according to their roles as “big data stakeholders:” collectors, generators, and utilizers of big data. This digital sustainability stakeholder model operationalizes the complex interplay between stakeholders focused on their ‘stake’ in sustainability and a common future and illustrates their roles in the digital age. Thus, it offers a normative framework to analyze stakeholders’ responsibility to contribute to, advance, promote, and achieve sustainability.     

Levels of 137Cs and 40K in edible parts of some vegetables consumed in Egypt

The concentrations of (137)Cs and (40)K in some Egyptian foodstuffs have been measured. The results of this study can be considered as a first step towards calculating the baseline levels of radioactivity in foodstuffs in Egypt. Furthermore, the data presented herein can be used as a reference level for future food radioactivity monitoring after the possible operation of the planned nuclear power plants, as well as to screen imported foodstuffs that are suspected of being contaminated. The overall intake of (137)Cs is quite low and no significant radionuclide contamination was found. The highest contents of (137)Cs and (40)K among the tested foodstuffs were in Jew's mallow and roquette. Calculations were also made to determine the potential dose to an individual consuming vegetables.     

Increased catecholamine levels in urine in subjects exposed to road traffic noise: the role of stress hormones in noise research

The nocturnal excretion of catecholamines in urine was studied in 30-45-year-old women whose bedroom and/or living room were facing streets of varying traffic volume. The traffic volume of the streets was used as an indicator of noise exposure; adrenaline and noradrenaline concentrations were assessed as indicators of the outcome of the physiological stress. Significant associations between traffic volume and noradrenaline concentrations in urine were found with regard to the exposure of the bedroom (not the living room), indicating a higher chronic physiological arousal in noise-exposed subjects as compared to less exposed. Subjective measures of disturbance due to traffic noise were positively correlated with the noradrenaline level. However, this was only found in subjects where closing the window could not reduce the perceived disturbance, which points to the effectiveness of individual coping mechanisms. Stress hormones are useful indicators to study associations, mechanisms, and interactions between noise, health outcomes, and effect modifiers in epidemiological noise research.     

The Economic Effect of Mineral Resources Exploitation in Bijie Prefecture in Guizhou

The exploitation of mineral resources plays an important role in promoting national economic development. Mining is an essential component of China＇s industrial economy. Using grey correlation method to analyze the correlative effect of mineral resources exploitation to relevant industries, using national income method to calculate the pulling effect of mineral resources exploitation to economic growth and using graphs as well as tables to analyze the income distribution effect, the article obtains active economic effect of mineral resources development in Bijie, Guizhou. Moreover, from the view of resources-cored effect, the article analyzes negative effects such as single industrial structure brought by mineral resource development. Through analysis, we find that mineral resources exploitation to some extent brings active effects including gross domestic product growth, local financial revenue growth and relevant industries development; however, its negative effects should not be ignored. The negative effect can be lightened by diversifying industrial structure and prolonging industrial chain.     

Climate Change Governance in China: A Case Study

Climate change is treated in China as an issue related closely to the national strategy for sustainable development as well as an issue in international collaboration in environment. The duality of the issue makes the climate change policy often waver between domestic and international emphases. In the past one and a half decades, the central government emphasized mostly on responding to international pressure by participating in negotiations in international treaties. However, the nation, as well as the world, will probably benefit more by taking a more proactive attitude towards mitigation and adaptation to climate change. This paper described the current governance structure for climate change management in China and made concrete recommendations for its improvement. The most urgent recommendation is to improve the cooperation of current National Coordination Committee on Climate Change with authority for policy-making and to oversee climate change.     

Inequality in water supply in India: an assessment using the Gini and Theil indices

Provision of drinking water is considered to be an essential public service. Ensuring adequate water supply remains a challenge in Indian cities that are experiencing rapid growth and often exhibit a mismatch between increasing demands and inadequate supply infrastructure. This study quantifies the existing inequality in water supply within Indian cities through Lorenz curve, Gini coefficient as well as Theil indices. Two types of Theil indices are estimated to gain different perspectives: water supply and population-weighted. Both the Theil indices are disaggregated, according to economic and regional categorisation of the cities, to explore the within- and between-group inequality. The water supply and population-weighted Theil indices provide different outlook of the inequality amongst the cities. But the population-weighted index is often better and pragmatic. Further, the inequality in access to tap water in India is studied by estimating modified Lorenz curves and Theil indices. Again, the Theil indices are decomposed into within and between components according to economic and regional grouping of states. The results suggest that there is disparity in supply of water in India, and infrastructure has to be boosted to meet the growing demand. This study is a step towards quantification of water supply inequality. The approach used in the study can contribute to monitoring of water supply equity as well as in formulating sustainable and equitable water policies.     

The Economic Effect of Mineral Resources Exploitation in Bijie Prefecture in Guizhou

Abstract

The exploitation of mineral resources plays an important role in promoting national economic development. Mining is an essential component of China’s industrial economy. Using grey correlation method to analyze the correlative effect of mineral resources exploitation to relevant industries, using national income method to calculate the pulling effect of mineral resources exploitation to economic growth and using graphs as well as tables to analyze the income distribution effect, the article obtains active economic effect of mineral resources development in Bijie, Guizhou. Moreover, from the view of resources-cored effect, the article analyzes negative effects such as single industrial structure brought by mineral resource development. Through analysis, we find that mineral resources exploitation to some extent brings active effects including gross domestic product growth, local financial revenue growth and relevant industries development; however, its negative effects should not be ignored. The negative effect can be lightened by diversifying industrial structure and prolonging industrial chain.     

Nonylphenol in the environment: a critical review on occurrence, fate, toxicity and treatment in wastewaters

Nonylphenol is a toxic xenobiotic compound classified as an endocrine disrupter capable of interfering with the hormonal system of numerous organisms. It originates principally from the degradation of nonylphenol ethoxylates which are widely used as industrial surfactants. Nonylphenol ethoxylates reach sewage treatment works in substantial quantities where they biodegrade into several by-products including nonylphenol. Due to its physical-chemical characteristics, such as low solubility and high hydrophobicity, nonylphenol accumulates in environmental compartments that are characterised by high organic content, typically sewage sludge and river sediments, where it persists. The occurrence of nonylphenol in the environment is clearly correlated with anthropogenic activities such as wastewater treatment, landfilling and sewage sludge recycling. Nonylphenol is found often in matrices such as sewage sludge, effluents from sewage treatment works, river water and sediments, soil and groundwater. The impacts of nonylphenol in the environment include feminization of aquatic organisms, decrease in male fertility and the survival of juveniles at concentrations as low as 8.2 mug/l. Due to the harmful effects of the degradation products of nonylphenol ethoxylates in the environment, the use and production of such compounds have been banned in EU countries and strictly monitored in many other countries such as Canada and Japan. Although it has been shown that the concentration of nonylphenol in the environment is decreasing, it is still found at concentrations of 4.1 mug/l in river waters and 1 mg/kg in sediments. Nonylphenol has been referred to in the list of priority substances in the Water Frame Directive and in the 3rd draft Working Document on Sludge of the EU. Consequently there is currently a concern within some industries about the possibility of future regulations that may impose the removal of trace contaminants from contaminated effluents. The significance of upgrading sewage treatment works with advanced treatment technologies for removal of trace contaminants is discussed.     

Sustainable Development and Wildlife Conservation in Tanzanian Maasailand

Many current wildlife conservation efforts in Africa focus on providing local communities with economic incentives to utilize wildlife as a form of land use in order to achieve the twin goals of ecological preservation as well as sustainable human economic development. Tanzanian Maasailand is home to some of the greatest concentrations of large mammals remaining outside National Parks and reserves, as well as a uniquely traditional human culture in the form of the Maasai themselves. Both are increasingly threatened by a variety of factors; poaching and habitat loss for wildlife, and the increasing marginalization of their pastoralist economy with regards to the Maasai. The fundamental cause of declining wildlife populations and biodiversity loss is that the Maasai have little economic or social interest in wildlife due to centralized management and financial benefits which are directed primarily to the Tanzanian state. Maasai pastoralism is highly compatible with wildlife, and the potential for the local communities to sustainably manage and benefit from this resource is promising. However, implementation of effective community-based natural resource management in the area faces political, cultural, and economic obstacles which will be critical in determining the outcomes of both conservation and community development efforts in Maasailand.     

Possible role of organic matter in radiocaesium adsorption in soils

The aim of this review is to examine the hypothesis that organic matter decreases the adsorption of radiocaesium on clay minerals. The factors that determine radiocaesium mobility and bioavailability in soil are briefly outlined to show why a relationship between soil organic matter content and enhanced Cs bioavailability is paradoxical. In all the investigations reviewed the ionic compositions of both the solid and the solution phases have been strictly controlled. We show that the addition of organic matter to reference clay minerals causes decreases of up to an order of magnitude in the distribution coefficient of radiocaesium. Similarly, the chemical removal of organic matter from the clay-sized fraction of soil usually leads to an increase in Cs adsorption. We suggest that the nature of the organic matter and its interaction with mineral surfaces are as important as the amount present.     

Urbanization in Western China

China has experienced considerable urbanization in the past 60 years,especially since the implementation of the Economic Reform and Opening-up Policy in 1978.In 1949,there were only 132 cities with an urban population of 27.4 million,while in 2008 China had 652 cities with a total urban population of 606 million.Such urbanization is attributed to the boost in the number of cities and the urban population.Urban expansion enhanced geographic inequality between the three major regions in China.Compared with the eastern and central regions,western China only has 19%of the total cities and 18%of the urban population.The urbanization rate was 37.2%for the western region in 2008,while it reached 53.3%for the eastern regions and 45.3%for central China.Using a geographic information system(GIS)and statistical analyses,this study aims at explaining the structure and spatial development of urbanization,and highlighting the current issues of urban inequality in western China during the past two decades.The paper drew following conclusions:(1)Urbanization disparities between eastern and western China have become increasingly obvious,but seem to be evolving slowly since the establishment of the government’s Western Development Priority Policy in 2000.(2)Cities of various sizes were expanded in western China,and the main factors affecting the urbanization are population numbers and density,government investment and geographic conditions.(3)Current patterns of urbanization in the western region are distributed unevenly between provinces.     

Environmental movement in Lebanon

The paper reviews and assesses the evolution of the environmental movement in both the public and the private sector in Lebanon. It studies the public sector involvement in the environmental movement by reviewing the commitments made by the government to the local, regional and international communities. The paper presents a summary of all the decisions, decrees, and laws pertaining to environmental protection that the Lebanese government has instituted over time, as well as all the conventions and agreements that the country has ratified and/or signed. Compared to the Arab world in the Middle East and North Africa, Lebanon is relatively more active and integrated in the world community. Using the total number of established environmental organizations and the level of reported activities aimed at spreading environmental awareness and educating people as indicators of private sector involvement in the environmental movement, the paper concludes that the post war era is characterized by a significant increase in the number of established organizations. It also concludes that there is a co-movement between economic and environmental variables. Readers should send their comments on this paper to: BhaskarNath@aol.com within 3 months of publication of this issue.     

Environmental impact assessment application in infrastructural projects in Malawi

The current increase in the number of development projects in Malawi is leading to loss of natural resources and the general degradation of the environment. Both the Malawi Environmental Management Act of 1996 and the Guidelines for Environmental Impact Assessment of 1997, prescribe a list of infrastructural projects that must undergo environmental impact assessment (EIA) before their implementation. This study identifies the key limitations of EIA application to infrastructural projects in Malawi. A desktop study used to gather information in this study involved a review of several documents such as EIA reports, policies and laws, books, journals and internet articles. Primary data was obtained from policymakers, contractors, EIA practitioners and the general public using both structured and unstructured interviews, as well as through questionnaires. Focus group discussions and direct observations were employed wherever necessary in the study. Major limitations to successful EIA in infrastructural projects in Malawi include: (1) limited experience and practice of EIA practitioners; (2) cost of EIA process; (3) limited links between EIA and urban planning procedures; (4) lack of political will; (5) project delays; (6) lack of effective monitoring and auditing, (7) lack of data, especially those to be used in predictive models. This violates the principles of sustainability science and the international best practices for EIA that were developed by the International Association for Impact Assessment. It is recommended that active environmental management should actively involve the interests of all stakeholders, and that follow up of predicted environmental impacts resulting from any project should entail monitoring, auditing and reporting.     

Recent advances in photocatalytic treatment of pollutants in aqueous media

Photocatalysis can be an excellent solution for resolving the world's energy and environmental problems. It has a wide range of applications for the decontamination of diverse hazardous pollutants in aqueous media. Technological progress in this research field has been achieved toward the improvement of the solar sensitivity to enhance the efficiency of pollutant decontamination. As a result, various strategies have been introduced to upgrade photocatalytic performance with the modification of prototypical photocatalyst such as doping, dye sensitization, semiconductor coupling, mesoporous supports, single site, and nano-based catalysts. In this review, a brief survey is presented to describe those strategies based on the evaluation made against various pollutants (such as pharmaceuticals, pesticides, heavy metals, detergents, and dyes) in aqueous media.     

A survey of radon level in underground buildings in China

From 2003-2004, using solid state nuclear detectors, a survey of the air radon level in 234 underground buildings in 23 cities of China was carried out during spring as well as summer and winter. The annual radon concentrations in these underground buildings range from 14.9 to 2482 Bq m(-3), with an overall mean value of 247 Bqm(-3). When radon concentrations are averaged according to cities, Fuzhou and Baotou have the relatively higher radon levels, which are 714 and 705 Bqm(-3), respectively. Guangzhou and Shanghai have the relatively lower radon levels with 71.1 and 72.6 Bqm(-3). The annual effective dose by exposure to radon received by people working in these cities is concluded to be 1.6 mSv. The geological formation, coating level, decorating materials and ventilation situation all affect the radon concentration in underground buildings. The radon level in underground buildings has the lowest value in winter and the highest value in summer.