Possibility of converting indigenous Salvadora persica L. seed oil into biodiesel in Pakistan

In this research study, biodiesel has been successfully produced from vegetable seed oil of an indigenous plant Salvadora persica L. that meets the international biodiesel standard (ASTM D6751). The biodiesel yield was 1.57 g/5 g (31.4% by weight) and the in-situ transesterification ester content conversion was 97.7%. The produced biodiesel density was 0.894 g/mL, its kinematic viscosity 5.51 mm²/s, HHV 35.26 MJ/kg, flash point 210°C, cetane no. 61, and sulfur content 0.0844%. Thermal analysis of the biodiesel showed that 97% weight loss was achieved at 595°C with total oxidation of the biodiesel. The production energy efficiency was 0.46% with a lab scale setup, assuming the volume fraction ratio (volume of the sample/total volume of the equipment used). The results revealed that single-step in-situ transesterification method is suitable for the production of biodiesel from S. persica seed oil.     

Scleropyrum pentandrum (Dennst.) mabb—oil as a feedstock for biodiesel production—engine performance and emission studies

A feasibility study on utilization of non edible oil of Scleropyrum pentandrum was carried out to see its potential as a new source for biodiesel production. Nonedible oil seeds of Scleropyrum pentandrum have oil content of 55–60%. Transesterification of freshly extracted oil in the presence of anhydrous sodium hydroxide at a concentration 1% (w/v oil) and methanol-oil ratio of 40% (v/v oil) yields 90.8% methyl esters under conventional heating. Month old oil requires sulfuric acid pretreatment (esterification) before transesterification. The transesterified oil has a density 889–893 kg/m³; kinematic viscosity of 4.21–5.7 mm²/s; cetane index 46.03; pour point of ?15°C and gross calorific value of 40.135 MJ/kg and oxidative stability of 2.35 hours. The properties are well within the Indian, European and American standard limits recommended for biodiesel except the oxidation stability, which can be improved by adding antioxidant additives. The engine performance studies of B10 and B20 blends of Scleropyrum pentandrum biodiesel (SP biodiesel) with statistical inference confirmed that it can be used as a fuel in CI engines without any engine modifications. The engine exhaust emission analysis showed that the emission of hydrocarbons can be minimized by at least 15–20%, CO emission by 15%, smoke opacity by 10–12% and moderately lesser CO₂ and NOx emissions.     

Homogeneous catalysed biodiesel synthesis from Alexandrian Laurel (Calophyllum inophyllum L.) kernel oil using ortho-phosphoric acid as a pretreatment catalyst

In this study, a non-edible seed oil of Alexandrian Laurel (Calophyllum inophyllum L.) with higher free fatty acid content has been harnessed to produce biodiesel by transesterification process. The 20.2% free fatty acid (FFA) content was first reduced to 12.9% by using TOP degumming process. Ortho-phosphoric acid was used to esterify the refined kernel oil. Transesterification reaction was performed with NaOH as an alkaline catalyst and methanol as an analytical solvent. The effects of methanol to oil molar ratio (MR), catalyst concentration (CC), reaction temperature (TP), reaction time (TM), and stirrer speed (SS) on biodiesel conversion were studied to optimize the transesterification conditions using DOE- approach. The experimental study revealed that 9:1 MR, 0.8 wt.% CC, 60°C TP, 75 min TM and 1000 rpm SS were the optimal process control variables. The study indicated that CC was the most important control parameter in optimal methyl ester production. The optimal treatment combination yielded 97.14% of biodiesel. The profile of biodiesel was determined using gas chromatography-mass spectrometry. ¹H NMR spectrum of Calophyllum inophyllum methyl ester (CIME) has been reported. The properties of the biodiesel have been found within specifications of the ASTM D6751 and EN 14214 standards and hence could be considered as a suitable alternative to diesel fuel for sustainable circulation of carbon.     

Application of response surface methodology for the optimization of biodiesel production from yellow mustard (Sinapis alba L.) seed oil

In the present study, response surface methodology (RSM) involving central composite design (CCD) was applied to optimize the reaction parameters of biodiesel production from yellow mustard (Sinapis alba L.) seed oil during the single-step transesterification process. A total of 30 experiments were designed and performed to determine under the effects of variables on the biodiesel yield such as methanol to oil molar ratio (2:1–10:1), catalyst concentration (0.2–1.0 wt.% NaOH), reaction temperature (50–70°C), and reaction time (30–90 min). The second order polynomial model was used to predict the biodiesel yield and coefficient of determination (R²) was found to be at 0.9818. The optimum biodiesel yield was calculated as 96.695% from the model with the following reaction conditions: 7.41:1 of methanol to oil molar ratio, 0.63 wt. % NaOH of catalyst concentration, 61.84°C of reaction temperature, and 62.12 min of reaction time. It is seen that the regression model results were in agreement with the experimental data. The results showed that RSM is a suitable statistical technique for optimizing the reaction parameters in the transesterification process in order to maximize the biodiesel yield.     

Biodiesel synthesis and characterization using welted thistle plant (Carduus acanthoides) as source of new non-edible seed oil

In this work we applied base catalyzed transesterification to convert non-edible welted thistle oil (Carduus acanthoides) as new non-edible feedstock into biodiesel (Fatty acid methyl esters). The highest biodiesel yield of 88% was obtained using optimized reaction conditions of 70°C and 5:1 molar ratio (methanol:oil). The synthesized esters were characterize and confirmed by the application of NMR and FT-IR techniques. Gas chromatography and mass spectroscopy identified different fatty acids as palmatic acid (C16:0), oleic acid (C18:1), linoleic acid (18:2), arachidic acid (C20:0), eicosanic acid (C20:1), and erucic acid (C22:1) in the oil of welted thistle. Six corresponding methyl esters reported in welted thistle oil biodiesel includes 9-hexadecenoic acid, hexadecanoic acid, 9-octadecadienoic acid, 11-eicosanoic acid, eicosanoic acid and 13-docosenoicacid. Fuel properties, such as density @40°C Kg/L (0.8470), kinematic viscosity @ 40°C c St (4.37), flash point (95°C), cloud point (+4°C), pour point (?5°C), and sulfur contents (0.0112% wt) of the biodiesel produced were compatible with American Society for Testing and Materials D 6751 specifications.     

Production and characterization of biodiesel from Eriobotrya Japonica seed oil: an optimization study

Biodiesel is now-a-days recognized as a real potential alternative to petroleum-derived diesel fuel due to its number of desirable characteristics. However, its higher production cost resulting mainly due to use of costly food-grade vegetable oils as raw materials is the major barrier to its economic viability. Present work is an attempt to explore the potential of Eriobotrya japonica seed oil for the synthesis of biodiesel using alkali-catalyzed transesterification. Optimization of production parameters, namely molar ratio of alcohol to oil, amount of catalyst, reaction time and temperature, was carried out using Taguchi method. Fatty acid composition of both oil and biodiesel was determined using GC and H¹ NMR. Alcohol to oil molar ratio of 6:1, catalyst amount of 1% wt/wt, 2 h reaction time and 50 ^°C reaction temperature were found to be the optimum conditions for obtaining 94.52% biodiesel. Highest % contribution was shown by the ‘amount of catalyst’ (67.32%) followed by molar ratio of alcohol to oil (25.51%). Major fuel properties of E. japonica methyl esters produced under optimum conditions were found within the specified limits of ASTM D6751 for biodiesel, hence it may be considered a prospective substitute of petro-diesel.     

Application of treated wastewater and digested sewage sludge to obtain biodiesel from Helianthus annuus L. seeds oil

Waste from wastewater treatment plants (WWTP) for Helianthus annuus L. production may be a viable solution to obtain biodiesel. This study achieved two objectives: assess the agronomical viability of waste (wastewater and sludge) from the Alcázar de San Juan WWTP in central Spain for H. annuus L. production; use H. annuus L. seeds grown in this way to obtain biodiesel. Five study plots, each measuring 6 m × 6 m (36 m²), were set up on the agricultural land near the Alcázar de San Juan WWTP. Five fertilizer treatment types were considered: drinking water, as the control; treated wastewater; 10 t ha^?1 of air-dried sewage sludge; 20 t ha^?1 of air-dried sewage sludge; 0.6 t ha^?1 of commercial inorganic fertilizer. Soil, irrigation water, sewage sludge, crop development and fatty acid composition in achenes oil were monitored. The 20 t ha^–1 dose of sewage sludge proved effective to grow H. annuus L. with similar results to those grown with a commercial fertilizer. However, precautions should be taken when irrigating with wastewater because of high salinity and nutrient deficiency. Sunflower oil was composed mostly of linoleic and oleic acid. The remaining fatty acids were linolenic, estearic, nervonic, palmitoleic, and palmitic.     

The convective hot air drying of Lactuca sativa slices

The storage of fresh agricultural products is not easy because of its high moisture. Dehydration is an efficient preservation method. The investigation of drying modeling and transfer characteristics are important for selecting operating conditions and equipment design. The drying behavior of Lactuca sativa slices, with the thickness of 2 mm, was investigated at 60.0–80.0°C and 0.60–1.04 m sec^?1 velocity in a convective hot air drier. The mass transfer during the drying process was described using six thin drying models. The convective heat transfer coefficient α and mass transfer coefficient k_H were finally calculated. The results showed that the drying process could be separated into three stages including accelerating rate, constant rate, and falling rate period, which was influenced by hot air temperature and velocity, and the Modi?ed Page model agreed well with the experimental data. When the operating temperature was increased from 60.0°C to 80.0°C, α was found increased from 88.07 to 107.93 W·m^?2·K^?1, and k_H increased from 46.32 × 10^–3 to 68.04 × 10^–3 kg·m^?2·sec^?1·ΔH^?1. With the increase of air velocity from 0.60 to 1.04 m·sec^?1, α was increased from 78.85 to 101.35 W·m^?2·K^?1, and k_H was enhanced from 51.78 × 10^–3 to 65.85 × 10^–3 kg·m^?2·sec^?1·ΔH^?1.     

Transesterification of Caesalpinia eriostachys seed oil using heterogeneous and homogeneous basic catalysts

Caesalpinea eriostachys seed oil, as a source of triglycerides with potential application for biodiesel production in Mexico is introduced. Its lipid profile obtained by Gas Chromatography-Mass Spectrometry (GC-MS) revealed saturated and unsaturated glycerol esters as the constituents. Therefore, heterogeneous and homogeneous catalyzed transesterification reactions were assayed employing ZnAl hydrotalcites and KOH, as the catalysts, respectively. The transesterification reactions yielded 59% for Zn/Al(2), 79% for Zn/Al(4), and 90% for KOH, depicting typical behavior, as in biodiesel production data from literature, where Zn-Al hydrotalcites or KOH were assayed. The caloric, density, viscosity values, and fatty acid methyl esters profile from reaction products were concordant to EN 14214, suggesting C. eriostachys as a promising feedstock for biodiesel production.     

Net Carbon Sequestration Potential and Emissions in Home Lawn Turfgrasses of the United States

Soil analyses were conducted on home lawns across diverse ecoregions of the U.S. to determine the soil organic carbon (SOC) sink capacity of turfgrass soils. Establishment of lawns sequestered SOC over time. Due to variations in ecoregions, sequestration rates varied among sites from 0.9 Mg carbon (C) ha^?1 year^?1 to 5.4 Mg C ha^?1 year^?1. Potential SOC sink capacity also varied among sites ranging from 20.8 ± 1.0–96.3 ± 6.0 Mg C ha^?1. Average sequestration rate and sink capacity for all sites sampled were 2.8 ± 0.3 Mg C ha^?1 year^?1 and 45.8 ± 3.5 Mg C ha^?1, respectively. Additionally, the hidden carbon costs (HCC) due to lawn mowing (189.7 kg Ce (carbon equivalent) ha^?1 year^?1) and fertilizer use (63.6 kg Ce ha^?1 year^?1) for all sites totaled 254.3 kg Ce ha^?1 year^?1. Considering home lawn SOC sink capacity and HCC, mean home lawn sequestration was completely negated 184 years post establishment. The potential SOC sink capacity of home lawns in the U.S. was estimated at 496.3 Tg C, with HCC of between 2,504.1 Gg Ce year^?1 under low management regimes and 7551.4 Gg Ce year^?1 under high management. This leads to a carbon-positive system for between 66 and 199 years in U.S. home lawns. More efficient and reduction of C-intensive maintenance practices could increase the overall sequestration longevity of home lawns and improve their climate change mitigation potential.     

Garcinia gummi-gutta (L.) Robs.: A promising feedstock for biodiesel production

In the present study crude Garcinia gummi-gutta seed oil was evaluated as a potential feedstock for biodiesel production. Due to the high acid value (29.73 mg KOH/g) the oil was converted to biodiesel by using acid catalyzed esterification process. Further, biodiesel properties of the sample were evaluated, which fulfilled the biodiesel specifications laid by ASTM D6751, EN 14214 and IS 15607. The biodiesel possessed excellent cetane number (66.09) and a high flash point (158°C). In addition, the calorific value (41.03 MJ/kg) was very close to diesel fuel. The results suggest that the G. gummi-gutta can be an alternative source for diesel and can be used as a potential feedstock for biodiesel in India.     

An effective approach to improve ethanol productivity by simultaneous saccharification and fermentation of rice straw

Fuel ethanol was produced using rice straw with the simultaneous saccharification and fermentation (SSF) method. The influence of cellulose liquefaction pretreatment and Fe²⁺ quantity on ethanol productivity was investigated in detail. At the same time, the optimized conditions including fermentation temperature, Fe²⁺ amount, yeast inoculation quantity, and the inoculated cellulose enzyme dosage in the SSF process were systematically investigated by analyzing fuel ethanol yield. The result indicated that fuel ethanol yield was 0.319 g per gram rice straw by SSF approach when appropriate amount of Fe²⁺ was added into the reaction system. The optimal technology parameters were: fermenting temperature of 36°C, Fe²⁺ amount of 4 mg · g^?1, inoculating proportion of 20%, cellulose enzyme of 20 IU · g^?1, and Pachysolen tannophilu/saecharomyces cerevisiae of 1:2 ratio. The ethanol yield under the best conditions was larger than that of the control group. We hope that this research can facilitate to achieve large-scale comprehensive utilization for rice straw.     

Synthesis and use of a catalyst in the production of biodiesel from Pongamia pinnata seed oil with dimethyl carbonate

The preparation of sodium methoxide-treated algae catalysts and their activity in the transesterification of Pongamia pinnata seed oil by dimethyl carbonate were investigated. We also investigated the effect of the sodium methoxide-treated algae catalyst on the biodiesel yield. The development of sodium methoxide-treated algae catalysts can overcome most problems associated with dissolution in dimethyl carbonate. The products were analyzed using gas chromatography-mass spectroscopy to identify the fatty acid methyl esters in the biodiesel produced. The molar ratio of Pongamia pinnata seed oil to dimethyl carbonate in transesterification in the presence of the sodium methoxide-treated algae catalyst was observed to play a substantial role in this study, wherein the Pongamia pinnata seed oil conversion increased with increasing catalyst concentration. The highest percent conversion rate was 97%. With intense research focus and development, an ideal catalyst can indeed be developed for optimal biodiesel production that is both economically feasible and environmentally benign.     

Ferric-manganese doped sulphated zirconia nanoparticles catalyst for single-step biodiesel production from waste cooking oil: Characterization and optimization

Biodiesel of waste cooking oil origin is gaining attention as a replacement for current fossil fuels, as its low-priced, recycled feedstock shall prevent food source competition, which is estimated to happen with current biodiesel production processes. As a result, waste cooking oil has been claimed to be a highly potential feedstock for biodiesel production. In the present research work, Fe-Mn doped sulphated zirconia catalyst was synthesized and used in simultaneous esterification and transesterification of waste cooking oil to biodiesel synthesis. The catalyst was prepared through the impregnation method and characterized by using XRD, TPD-NH_3, FT-IR, BET, and TEM. Response surface methodology (RSM) in conjunction with the central composite design (CCD) was applied to statistically evaluate and optimize the biodiesel preparation process. It was found that the synthesis of biodiesel achieved an optimum level of 97.2% waste cooking oil methyl ester’s (WCOME’s) yield at the following reaction conditions: methanol/oil molar ratio: 10:1, catalyst concentration: 3.0 wt %, and reaction temperature: 160 °C. The extremely high WCOME’s yield of 97.2% was proved to be due to high acidity, surface area, and large pore diameter; reactants can easily diffuse into the interior pore of the catalyst and allow them to be in contact with active sites that enhance catalytic activity.     

Simulation and validation of a suitable model for thin layer drying of ginger rhizomes in an induced draft dryer

Variation in drying material and their biological differences, coupled with heat supply method in different dryers, makes mathematical modeling of drying complicated. Attempt was made to simulate a drying process and to identify best suitable model out of six selected drying models, for drying of ginger slices in a solar-biomass integrated drying system designed and developed for spice drying. Moisture content data were converted into the moisture ratio (MR) expressions and curve fitting with drying time for the selected drying models was analyzed. Sigma Plot software was used for nonlinear regression to the data obtained during drying and for modeling of drying curves. The suitability of the models was evaluated in terms of statistical parameters such as coefficient of determination (R²), mean percentage error (P), and standard error estimate. Drying air temperature was in the range of 47–55°C and air velocity was between 1.0 and 1.3 m s^?1. Ginger slices were dried from 88.13% to 7.65 ± 0.65% (wb) in 16 h. Trays were interchanged in a predetermined matrix sequence from 4 h onwards when moisture content was reduced to 60–70% (wb), for uniformity in drying. Highest value of R² (0.997), lowest value of SEE (0.020), and P value < 0.0001 established Page model as the best suitable model for the developed drying system. The predicted MRs were in good agreement with the experimental values and the effective moisture diffusivity for ginger was found to be 2.97 × 10^–7 m² s^?1.     

A comprehensive review on biodiesel production using Moringa oleifera oil

Biodiesel has emerged as one of the most promising renewable energy to substitute existing petroleum-derived diesel fuel being used in transportation sectors. Among the various feedstocks reported for biodiesel production, Moringa oleifera oil is becoming a promising replacement for conventional diesel fuel. Therefore, this work provides a comprehensive overview of the recent progress in biodiesel production from Moringa oleifera oil. The physicochemical properties, fatty acid composition of oil and methyl esters, oil extraction methods, esterification, and transesterification process, and purification methods employed in the biodiesel production have been discussed.     

The effect of cerium oxide additive on the performance and emission characteristics of a CI engine operated with rice bran biodiesel and its blends

In this study, the rice bran oil (RBO) has been converted into methyl ester with an aid of transesterification reaction. Chemically, transesterification means conversion of triglyceride molecule or a complex fatty acid into alcohol and ester by removing the glycerin and neutralizing the free fatty acids. The B20 blend samples [80% diesel + 20% biodiesel] were prepared for each methyl ester obtained from RBO and then the cerium oxide (CeO₂) nanoparticles were added to the each B20 blend samples at a dosage of 50 ppm and 100 ppm with an aid of ultrasonicator. Moreover, in the absence of any engine modifications, the performance and emission characteristics of those blend samples have been investigated from the experimentally measured values such as density, viscosity, cloud point, pour point, and calorific value while the engine performance was also analyzed through the parameters like exhaust gas temperature (EGT), brake specific fuel consumption (BSFC), brake thermal efficiency (BTE), exhaust emission of carbon monoxide (CO), hydrocarbon (HC), and nitrogen oxide (NOx). The experimental results reveal that the use of CeO₂ blended biodiesel in diesel engine has exhibited good improvement in performance characteristic and reduction in exhaust emissions.     

Effect of calcination temperature on the application of sodium zirconate solid base catalyst for biodiesel production from Jatropha curcas oil

Influence of catalyst calcination temperature on the catalyst characteristics and catalytic transesterification of Jatropha curcas oil for biodiesel production was studied by using sodium zirconate (Na₂ZrO₃) solid base catalyst. Na₂ZrO₃ catalysts were prepared by impregnation method followed by calcination at temperatures of 700, 800, and 900°C. The prepared catalysts were characterized by X-ray diffraction analysis, Fourier transform infrared spectroscopy, and field emission scanning electron microscopy. Important parameters influencing the catalytic activity and fatty acid methyl ester yield were investigated. It was found that the increase in calcination temperature showed marked increase in activity due to the increased porosity and presence of tetragonal zirconia. Investigation of the reusability of the catalysts showed that the catalytic activity was retained even after five cycles of reaction.     

Field-Level Financial Assessment of Contour Prairie Strips for Enhancement of Environmental Quality

The impacts of strategically located contour prairie strips on sediment and nutrient runoff export from watersheds maintained under an annual row crop production system have been studied at a long-term research site in central Iowa. Data from 2007 to 2011 indicate that the contour prairie strips utilized within row crop-dominated landscapes have greater than proportionate and positive effects on the functioning of biophysical systems. Crop producers and land management agencies require comprehensive information about the Best Management Practices with regard to performance efficacy, operational/management parameters, and the full range of financial parameters. Here, a farm-level financial model assesses the establishment, management, and opportunity costs of contour prairie strips within cropped fields. Annualized, depending on variable opportunity costs the 15-year present value cost of utilizing contour prairie strips ranges from $590 to $865 ha^?1 year^?1 ($240–$350 ac^?1 year^?1). Expressed in the context of “treatment area” (e.g., in this study 1 ha of prairie treats 10 ha of crops), the costs of contour prairie strips can also be viewed as $59 to about $87 per treated hectare ($24–$35 ac^?1). If prairie strips were under a 15-year CRP contract, total per acre cost to farmers would be reduced by over 85 %. Based on sediment, phosphorus, and nitrogen export data from the related field studies and across low, medium, and high land rent scenarios, a megagram (Mg) of soil retained within the watershed costs between $7.79 and $11.46 mg^?1, phosphorus retained costs between $6.97 and $10.25 kg^?1, and nitrogen retained costs between $1.59 and $2.34 kg^?1. Based on overall project results, contour prairie strips may well become one of the key conservation practices used to sustain US Corn Belt agriculture in the decades to come.     

Promotional effect of transition metal doping on the properties of KF/CaO catalyst for biodiesel synthesis

A series of heterogeneous KF/CaO catalysts modified with transition metals (lanthanum, cerium, and zirconium) were prepared via wet impregnation method and applied to the trsansesterification process of waste cooking oil (WCO) as feedstock with methanol to biodiesel production. The structure, performance of the solid catalysts was characterized by X-ray diffraction (XRD), temperature programmed desorption of CO₂ (CO₂-TPD), scanning electron microscopy (SEM), and energy-dispersive spectroscopy (EDS). The effect of methanol/oil molar ratio, ¹reaction time, reaction temperature, catalyst amount, and stability was investigated. The results showed that 10 wt% of lanthanum, cerium, and zirconium improved the catalytic activity of KF/CaO catalyst. The maximum catalytic activity using the lanthanum doping of 10wt% on KF/CaO catalyst was reached 98.7% under the optimal reaction condition of methanol/oil molar ratio of 12:1, reaction for 1 h at reaction temperature of 65°C, and 4% (wt/wt oil) catalyst amount. In addition, the FAME yield of KF/CaO/La catalyst remained higher than 95% after 10 cycles. The promotional effect of lanthanum doping could be attributed to the enhancement of the basicity strength of KF/CaO catalyst and block the leach of Ca²⁺ in the transesterification reaction.