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TiO2光催化氧化的研究进展 总被引:5,自引:0,他引:5
概述了TiO2光催化氧化降解水中污染物的原理及TiO2光催化剂的制备,提出了增强其活性的途径。TiO2光催化氧化可应用于印染、农药、造纸等工业废水及饮用水处理中,研制高效的负栽型纳米TiO2光催化剂、解决太阳能利用问题、开发多功能光催化反应器是今后TiO2光催化氧化的发展趋势。 相似文献
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稀土掺杂纳米TiO2光催化的研究进展 总被引:1,自引:0,他引:1
综述了近年来稀土掺杂纳米TiO2的研究进展,对其掺杂机理以及掺杂对TiO2晶型、晶粒、光谱响应范围、光催化活性等方面的影响进行了论述,并对今后的研究方向作了展望。 相似文献
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纳米TiO2的特性及其在环保方面的应用 总被引:8,自引:0,他引:8
纳米TiO2颗粒是一种重要的高性能和高功能材料,具有独特的光催化性和表面超双亲性等功能,在水处理和空气净化等环保领域具有广阔的应用前景。本文着重阐述了纳米TiO2的特性及其在环境保护中的应用,并对目前存在的问题及今后的发展方向进行了讨论。 相似文献
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负载型TiO2薄膜光催化剂降解亚甲基蓝 总被引:2,自引:0,他引:2
采用溶胶-凝胶法制备了玻璃负载的TiO2薄膜光催化剂,研究了该催化剂对亚甲基蓝溶液的光催化降解,考察了反应时间、水样的初始浓度、溶液的pH等对光催化降解效果的影响。 相似文献
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按纳米TiO2在反应器中存在的形式,分类论述了各种光催化反应器的结构原理和主要特点,介绍了近几年有关纳米TiO2光催化反应器的设计,讨论了光催化反应器设计中存在的问题和在污水处理中的研究进展。 相似文献
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Removal of the hazardous dye rhodamine B through photocatalytic and adsorption treatments 总被引:1,自引:0,他引:1
This paper reports on photocatalytic and adsorptive treatment of a hazardous xanthene dye, Rohdamine B, in wastewater. The photocatalytic degradation was carried out in the presence of the catalyst TiO(2) and the effects of pH, concentration of the dye, amount of TiO(2), temperature and electron acceptor H(2)O(2) on the degradation process were observed. It was found that photocatalytic degradation by TiO(2) is an effective, economical and faster mode of removing Rohdamine B from aqueous solutions. Attempts were also made to utilize activated carbon and rice husk as potential adsorbents to remove Rhodamine B from wastewater. The adsorption studies were carried out at 40, 50 and 60 degrees C, and the effects of pH, temperature, amount of adsorbents, concentration of adsorbate, etc., on the adsorption were measured. On the basis of adsorption data the Langmuir and Freundlich adsorption isotherm models were also confirmed. The adsorption isotherm constants thus obtained were employed to calculate thermodynamic parameters like Gibb's free energy, change in enthalpy and entropy. In order to observe the quality of wastewater COD measurements were also carried out before and after the treatments. A significant decrease in the COD values was observed, which clearly indicates that both photocatalytic and adsorption methods offer good potential to remove Rhodamine B from industrial effluents. 相似文献
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简要介绍了二氧化钛光催化氧化的基本原理,对影响二氧化钛光催化氧化的因素及解决途径进行了分析,综合论述了光催化在环境保护中的应用效果。研究结果表明,光催化是一项具有广阔应用前景的新型水处理技术,它不仅具有低能耗、易操作、无二次污染等特点,而且对一些特殊污染物的去除具有更佳的效果,有较好的推广价值。 相似文献
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Photocatalytic degradation of organic wastes by electrochemically assisted TiO2 photocatalytic system 总被引:4,自引:0,他引:4
Photocatalytic degradation of organic wastes with nanosized titanium dioxide particles has been studied for a long time in order to offer an appropriate method for wastewater treatment, but its practical application is greatly limited by the slow process. In this work, an electrochemically assisted TiO2 photocatalytic system was set-up by combining a TiO2 photocatalytic cell with a three-electrode potentiostatic unit. The composite system revealed high photocatalytic activity towards organic wastes mineralization. After continuous treatment for 0.5 h, the maximum absorption of rhodamine 6G (R-6G) was reduced by more than 90%; chemical oxygen demand (COD) and biochemical oxygen demand (BOD5) of textile dye wastewater (TDW) were decreased by 93.9 and 88.7%, respectively. The biodegradability of TDW was also improved because the COD/BOD5 ratio decreased from 2.1 to 1.2. All these results indicated that the composite system could be used for effective organic wastes mineralization or as a feasible detoxification and color removal pretreatment stage for biological post treatment. 相似文献
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Influence of parameters on the heterogeneous photocatalytic degradation of pesticides and phenolic contaminants in wastewater: a short review 总被引:4,自引:0,他引:4
In recent years, the application of heterogeneous photocatalytic water purification processes has gained wide attention due to its effectiveness in degrading and mineralizing the recalcitrant organic compounds as well as the possibility of utilizing the solar UV and visible-light spectrum. This paper aims to review and summarize the recent works on the titanium dioxide (TiO(2)) photocatalytic oxidation of pesticides and phenolic compounds, predominant in storm and wastewater effluents. The effects of various operating parameters on the photocatalytic degradation of pesticides and phenols are discussed. Results reported here suggest that the photocatalytic degradation of organic compounds depends on the type and composition of the photocatalyst and, light intensity, initial substrate concentration, amount of catalyst, pH of the reaction medium, ionic components in water, solvent types, oxidizing agents/electron acceptors, catalyst application mode, and calcination temperature in the water environment. A substantial amount of research has focused on the enhancement of TiO(2) photocatalysis by modification with metal, non-metal and ion doping. Recent developments in TiO(2) photocatalysis for the degradation of various pesticides and phenols are also highlighted in this review. It is evident from the literature survey that photocatalysis has good potential to remove a variety of organic pollutants. However, there is still a need to determine the practical utility of this technique on a commercial scale. 相似文献
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文章介绍了新疆油田在稠油污水处理和回用方面的关键技术和成熟经验,采用强酸性树脂软化技术和化学清洗技术实现了稠油污水回用注汽锅炉。六九区污水处理站采用高效水质稳定技术,使处理后的污水达到了GB 8978—1996《污水综合排放标准》的二级标准,稠油污水在处理后符合GB 1576—2008《工业锅炉水质》的要求,大幅度降低了注汽锅炉的运行成本;将60℃以上的稠油污水替代清水回注稀油油藏,热水驱油,改善了驱油效果,同时根据污水温度较高的特点,对注水井井口的保温工艺进行改进,实现了稠油污水热能的综合利用,为油田污水治理和回用提供了借鉴。 相似文献