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1.
We determined the contamination status and accumulation profiles of polychlorinated biphenyls (PCBs), hydroxylated PCB congeners (OH-PCBs), polybrominated diphenyl ethers (PBDEs), hydroxylated PBDEs (OH-PBDEs), methoxylated PBDEs (MeO-PBDEs), and bromophenols (BPhs) in serum from e-waste recycling workers and residents near a coastal area in India. Residue levels of penta- to octa-chlorinated PCBs, penta- to octa-chlorinated OH-PCBs, 6MeO-BDE47, 6OH-BDE47, and 2,4,6-tri-BPh in serum from residents living near the coastal area were significantly higher than those in serum from e-waste recycling workers. Residue levels of tri- to tetra-chlorinated PCBs, tri- to tetra-chlorinated OH-PCBs, PBDEs, octa-brominated OH-PBDEs, and tetra-BPhs in serum from e-waste recycling workers were higher than those in serum from residents living near the coastal area. Principal component analysis revealed that residents living near the coastal area and e-waste recycling workers had different serum profiles of chlorinated and brominated compounds.  相似文献   

2.
With the rapid growth of electronic waste (e-waste), policies that aim to effectively manage this waste stream have been introduced globally in recent years. Seattle, Washington, has been on the forefront of introducing policies to divert e-waste from the landfills and maximize recycling. With the introduction of the Take-it-Back-Network, a solid recycling infrastructure has existed in the Greater Seattle region since 2003. In 2009, the E-Cycle Washington program took into effect and now allows recyclers to offer free recycling of certain e-waste to households and small entities. Although policies to divert e-waste from the landfill to reuse and recycling is effective, there is also a need to analyze the current regional recycling infrastructure’s capacity to handle changing equipment and material quantities. This study aims to characterize the Seattle regional e-waste management capacity, with a focus on retired monitors as an example of a changing e-waste technology. We investigated waste computer monitor recycling in the Greater Seattle region, which includes the counties of King, Pierce, Snohomish, and Kitsap. Interviews were conducted on 20 collectors, 1 handler, and 2 processors to collect information on their business models, computer monitor management processes, and collection/processing quantities. Using this information, we summarize the material flows of end-of-life (EOL) cathode ray tube (CRT) and liquid crystal display (LCD) monitors in the region, both from the qualitative and quantitative perspective.  相似文献   

3.
The crude recycling of electronic and electric waste (e-waste) is now creating a new set of environmental problems especially in developing countries such as China. The present study aimed to characterize the dioxin-like compounds in Taizhou area, one of the largest e-waste recycling centers in China, using both chemical analysis and in vitro bioassay. Agricultural soil samples were screened for aryl hydrocarbon receptor (AhR) activity with EROD bioassay in H4IIE cells, and the concentrations of the target AhR agonists including polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs), polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs) were determined by instruments. The bioassay-derived TCDD equivalents (TEQ(bio)) and the chemical-calculated TCDD equivalents (TEQ(cal)) were then compared, and mass balance analysis was conducted to identify the contributors of the observed response. Raw soil extracts from all locations induced significant AhR activities, where the TEQ(bio) ranged from 5.3 to 210 pg/g dry weight soil (pg/g dw). The total concentrations of 17 PCDD/Fs, 36 PCBs and 16 PAHs varied from 210 to 850 pg/g dw, 11 to 100 ng/g dw, and 330 to 20,000 ng/g dw, respectively. Profile characterization of the target analytes revealed that there were similar sources originating from the crude dismantling of electric power equipments and the open burning of e-waste. There was a significant relationship between TEQ(cal) and TEQ(bio) (r=0.99, p<0.05). Based on the mass balance analysis, PCDD/Fs, PCBs and PAHs could account for the observed AhR responses in vitro elicited by soil extracts, though their respective contributions varied depending on sample location. In this study, the combination of chemical analysis and bioanalytical measurements proved valuable for screening, identifying and prioritizing the causative agents within complex environmental matrices.  相似文献   

4.
PCB levels in fish (collected from local rivers), atmosphere and human milk samples have been studied to determine the exposure levels of PCBs for local residents and e-waste workers in Guiyu, a major electronic waste scrapping center in China. The source appointment and correlation analyses showed that homologue composition of PCBs in 7 species of fish were consistent and similar to commercial PCBs Aroclor 1248. PCB levels in air surrounding the open burning site were significantly higher than those in residential area. Inhalation exposure contributed 27% and 93% to the total body loadings (the sum of dietary and inhalation exposure) of the local residents, and e-waste workers engaged in open burning respectively. Total PCB concentrations in human milk ranged from N.D. to 57.6 ng/g lipid, with an average of 9.50 ng/g lipid. The present results indicated that commercial PCBs derived from e-waste recycling are major sources of PCBs accumulating in different environmental media, leading to the accumulation of high chlorinated biphenyls in human beings.  相似文献   

5.
Reverse logistics play a significantly increased role in supply chains. Producers are incorporating reverse logistics into their supply chain design because of governmental legislation, economic benefits from product recovery, and customers' demands for better environmental practices. Motivated producers face two main challenges in reverse logistics network design: (1) how do you build product recovery activities into traditional forward logistics networks? and (2) how do you manage the impact of uncertainty in the reverse logistics supply chain? Moreover, producers need to consider many tradeoffs leading to efficient network design. Published case studies have discussed these tradeoffs, and we describe a framework to evaluate these tradeoff considerations. We then apply the framework to three new case studies: medical device refurbishing, municipal e‐waste recycling, and carpet fibre recycling.  相似文献   

6.
国外废旧家用电子电器回收再利用研究   总被引:7,自引:0,他引:7  
随着废旧家用电子电器数量和种类的增加及其产生的环境污染问题,废旧家用电子电器的处理处置、回收再利用引起世界各国的广泛关注。本文阐述了一些工业发达国家在废旧家用电子电器回收再利用方面所采取的措施、取得的成功经验和未来发展趋势。  相似文献   

7.
Water and several wild aquatic species including Chinese mysterysnail, prawn, fish, and water snake were collected from a reservoir surrounded by several e-waste recycling workshops in South China. The samples were examined to investigate the levels and bioaccumulation extent of polybrominated diphenyl ethers (PBDEs) and polychlorinated biphenyls (PCBs) released from electronic waste (e-waste) which was processed by crude recycling method. Elevated levels of PBDEs [52.7 to 1702 ng/g wet weight (ww)] and PCBs (20.2-25958 ng/g ww) were found in the collected biota species compared to that in the reference samples (13.0-20.5 ng/g ww for PBDEs and 75.4-82.8 ng/g ww for PCBs). log BAF (bioaccumulation factor) ranged from 2.9 to 5.3 for PBDEs and from 1.2 to 8.4 for PCBs, depending on congeners and species. The relationship between log BAFs and log K(OW) (octanol-water partition coefficient) can be adequately described by species-specific parabolic models wherein log BAFs generally increased at log K(OW)<7 then decreased with further increasing log K(OW) both for PBDEs and PCBs. The exceptions were for Chinese mysterysnail and prawn, in which the log BAFs showed a positive linear correlation with log K(OW) for PBDEs. Some PBDE and PCB congeners showed BAF values declining from the general trend predicted by K(OW), largely attributing to metabolism of these congeners in species sampled.  相似文献   

8.
Technological innovation and shorter product life cycles of electrical and electronic equipment coupled with their rapidly growing applications have resulted in the generation of an enormous amount of waste from electrical and electronic equipment (WEEE). To address the potential environmental problems that could stem from improper end‐of‐life management of WEEE, many countries have drafted national legislation to improve the reuse, remanufacture and material recycling from WEEE, and to reduce the amount of such waste going to landfills. With the introduction of such legislation comes an increased need for the recovery operators to evaluate the recycling costs and environmental benefits of reclaimed products and materials in order to select the most appropriate end‐of‐life options for individual products in WEEE. This paper presents a systematic methodology for ecological and economical assessment to provide a holistic understanding of the impacts associated with different end‐of‐life options for such waste. This assessment, in addition to providing decision‐support for the selection of the best possible end‐of‐life option for a particular product in WEEE, could also generate vital information to support the design and material selection processes during the initial product development activities. The assertion made is that the detailed considerations of the ecological and economical impacts associated with different end‐of‐life options will significantly improve the recovery and recycling of WEEE.  相似文献   

9.
The East China Seas (ECSs) are the receptors of the land-based persistent organic pollutants (POPs), such as polybrominated diphenyl ethers (PBDEs) mainly from China through atmospheric deposition driven by the East Asian winter monsoon and fluvial discharge (e.g., Yangtze River and Yellow River), making the offshore sediments to be a good proxy to reconstruct history of those pollutants in China. In this work, four well-placed sediment cores were extracted from the mud areas in the ECSs, and the 210Pb-dated cores were analyzed to yield historical concentration profiles of PBDEs in the area. The results showed that there was a persistent increase from 1970s and almost no clear sign in the decline of PBDEs until recently in China. More importantly, there was a faster increase of PBDEs from 1990s in China; while this period was just shown as gradually leveling off or even declining trends in developed countries. The persistently increasing trend of PBDEs in China since 1990s could be largely due to the booming of the manufacturing industry and unexpectedly transfer of PBDE pollution from developed countries to China. Besides, the relative high concentrations and fluxes of PBDEs in the core from coastal ECS located near a well-known electrical/electronic waste (e-waste) recycling area suggests an important contribution of PBDE emissions from recycling centers of e-waste in China. Although efforts in environmental monitoring of PBDE contamination have been substantially increased over the last decade, China is still lagging behind in terms of nationwide regulation of PBDE usage and treatment of disposal PBDE-containing products.  相似文献   

10.
Environment, Development and Sustainability - The issue of e-waste recycling is imminent. With the continuous enhancement of Internet technology and people's awareness of sustainable...  相似文献   

11.
This article analyzes how electronic waste (e-waste) gets represented in television news stories. The main objective is to present a perspective on how a “low-frequency” emergency (i.e. a lengthy and ongoing state of environmental emergency) is presented as a newsworthy issue. Drawing on literature on televised “distant suffering,” the article engages in a multimodal text analysis of four news stories about e-waste. The findings show how on-location reports from e-waste dumping sites make use of sublime imagery in the visual representations; how e-waste dumping sites are presented as strange spaces, with no clear and comprehensible history; and finally, that the representations suggest an ambivalence and uncertainty when it comes to agency (who is responsible and what can be done?). The article ends with a discussion of the implications of this mode of representation and its effectiveness in eliciting an appropriate response to the harms caused by e-waste.  相似文献   

12.
The formation and environmental release of highly toxic organohalogen compounds associated with informal recycling of waste electric and electronic equipment (e-waste) is a growing problem at e-waste dumps/recycling sites (EWRSs) in many developing countries worldwide. We chose a cross-sectional study design to measure the internal exposure to polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) as well as polychlorinated biphenyls (PCBs) of individuals working on one of the largest EWRSs of Africa, located at Agbogbloshie, Accra, Ghana, and in controls from a suburb of Accra without direct exposure to EWRS activities. In whole blood samples of 21 age matched male exposed individuals (mean age: 24.7 years, SD 6.0) and 21 male controls (mean age: 24.4 years, SD 5.7) 17 PCDD/F congeners were determined. Moreover three indicator PCB congeners (#138, #153 and #180) were measured in blood of 39 exposed (mean age: 27.5 years, SD 11.7) and 19 non-exposed (mean age: 26.8 years, SD 9.7) patients. Besides a health examination, biometric and demographic data, residential and occupational history, occupational exposures and working conditions were recorded using a standardized questionnaire. In the exposed group, median PCDD/F-concentrations were 6.18 pg/g lipid base WHO2005-TEq (range: 2.1–42.7) and significantly higher compared to the control group with 4.60 pg/g lipid base WHO2005-TEq (range: 1.6–11.6). Concentrations were different for 2,3,7,8-TetraCDD, three HexaCDD and all 10 PCDF congeners, indicating a combustion pattern. Using a multivariate regression analysis exposure to EWRS activities was the most important determinant for PCDD/F exposure. Median PCB levels for the indicator congeners #138, #153 and #180 were 0.011, 0.019 and 0.008 μg/l whole blood (ranges: 0.002–0.18, 0.003–0.16, 0.002–0.078) in the exposed group and, surprisingly, significantly higher in the controls (0.037, 0.062 and 0.022; ranges: 0.005–0.46, 0.010–0.46, 0.004–0.21). In a multivariate regression approach e-waste related activities had no positive influence on internal PCB exposure, but rather the time living in Accra. The internal PCB exposure is in particular notable for a country where PCBs have historically never been produced or used. The impact of EWRS activities on organohalogen compound exposure of individuals working at and living in the surroundings of the Agbogbloshie EWRS, and the surprisingly high PCB exposure of people living in Accra not involved in e-waste activities require further investigation.  相似文献   

13.
This study reports concentrations and human dietary intake of hexabromocyclododecanes (HBCDs), polychlorinated biphenyls (PCBs) as well as selected “novel” brominated flame retardants (NBFRs) and organochlorine pesticides, in ten staple food categories. Samples were sourced from areas in Taizhou City, eastern China, where rudimentary recycling and disposal of e-waste is commonplace, as well as from nearby non-e-waste impacted control areas. In most instances, concentrations in foods from e-waste recycling areas exceeded those from control locations. Concentrations of 2-ethylhexyl-2,3,4,5-tetrabromobenzoate (EH-TBB) and bis-(2-ethylhexyl)-3,4,5,6-tetrabromophthalate (BEH-TBP) in samples from e-waste sites were 3.09–62.2 ng/g and 0.81–16.3 ng/g lipid weight (lw), respectively; exceeding consistently those in foods acquired from control sites by an order of magnitude in many cases. In contrast, while concentrations of HBCD in some foods from e-waste impacted areas exceed those from control locations; concentrations in pork, shrimp, and duck liver are higher in control samples. This highlights the potential significance of non-e-waste sources of HBCD (e.g. building insulation foam) in our study areas. While concentrations of DDT in all foods examined except pork were higher in e-waste impacted samples than controls; our exposure estimates were well below the provisional tolerable daily intake of 0.01 mg/kg bw/day derived by the Joint FAO/WHO Meeting on Pesticide Residues. Concentrations of ΣPCBs resulted in exposures (650 and 2340 ng/kg bw/day for adults and children respectively) that exceed substantially the Minimal Risk Levels (MRLs) for ΣPCBs of 20 ng/kg bw/day derived by the Agency for Toxic Substances & Disease Registry. Moreover, when expressed in terms of dioxin-like toxicity equivalency based on the four dioxin-like PCBs monitored in this study (DL-PCBs) (PCB-105, 118, 156, and 167); concentrations in e-waste impacted foods exceed limits set by the European Union in 6 of the 8 food groups studied and result in dietary exposures for children (10.2 pg TEQ/kg bw/day) that exceed the WHO tolerable daily intake of 1–4 pg TEQ/kg bw/day.  相似文献   

14.
Emission of polycyclic aromatic hydrocarbons (PAHs) from e-waste recycling activities in China is known. However, little is known on the association between PAH exposure and oxidative damage to DNA and lipid content in people living near e-waste dismantling sites. In this study, ten hydroxylated polycyclic aromatic hydrocarbons (OH-PAHs) and two biomarkers [8-hydroxy-2′-deoxyguanosine (8-OHdG) and malondialdehyde (MDA)] of oxidative stress were investigated in urine samples collected from people living in and around e-waste dismantling facilities, and in reference population from rural and urban areas in China. The urinary levels of ∑10OH-PAHs determined in e-waste recycling area (GM: 25.4 μg/g Cre) were significantly higher (p < 0.05) than those found in both rural (11.7 μg/g Cre) and urban (10.9 μg/g Cre) reference areas. The occupationally exposed e-waste workers (36.6 μg/g Cre) showed significantly higher (p < 0.01) urinary Σ10OH-PAHs concentrations than non-occupationally exposed people (23.2 μg/g Cre) living in the e-waste recycling site. The differences in urinary Σ10OH-PAHs levels between smokers (23.4 μg/g Cre) and non-smokers (24.7 μg/g Cre) were not significant (p > 0.05) in e-waste dismantling sites, while these differences were significant (p < 0.05) in rural and urban reference areas; this indicated that smoking is not associated with elevated levels of PAH exposure in e-waste dismantling site. Furthermore, we found that urinary concentrations of Σ10OH-PAHs and individual OH-PAHs were significantly associated with elevated 8-OHdG, in samples collected from e-waste dismantling site; the levels of urinary 1-hydroxypyrene (1-PYR) (r = 0.284, p < 0.01) was significantly positively associated with MDA. Our results indicate that the exposure to PAHs at the e-waste dismantling site may have an effect on oxidative damage to DNA among selected participants, but this needs to be validated in large studies.  相似文献   

15.
BackgroundE-waste includes electrical and electronic equipment discarded as waste without intent of reuse. Informal e-waste recycling, typically done in smaller, unorganized businesses, can expose workers and communities to serious chemical health hazards. It is unclear if formalization into larger, better-controlled electronics recycling (e-recycling) facilities solves environmental and occupational health problems.ObjectivesTo systematically review the literature on occupational and environmental health hazards of formal e-recycling facilities and discuss challenges and opportunities to strengthen research in this area.MethodsWe identified 37 publications from 4 electronic databases (PubMed, Web of Science, Environmental Index, NIOSHTIC-2) specific to chemical exposures in formal e-recycling facilities.DiscussionEnvironmental and occupational exposures depend on the degree of formalization of the facilities but further reduction is needed. Reported worker exposures to metals were often higher than recommended occupational guidelines. Levels of brominated flame-retardants in worker's inhaled air and biological samples were higher than those from reference groups. Air, dust, and soil concentrations of metals, brominated flame-retardants, dioxins, furans, polycyclic-aromatic hydrocarbons, or polychlorinated biphenyls found inside or near the facilities were generally higher than reference locations, suggesting transport into the environment. Children of a recycler had blood lead levels higher than public health recommended guidelines.ConclusionsWith mounting e-waste, more workers, their family members, and communities could experience unhealthful exposures to metals and other chemicals. We identified research needs to further assess exposures, health, and improve controls. The long-term solution is manufacturing of electronics without harmful substances and easy-to-disassemble components.  相似文献   

16.
近年来,随着电子商务的迅速崛起,快递废弃物激增所带来的环境污染、资源浪费程度日趋严重,营建快递废弃物回收产业链,促进快递废弃物循环使用的呼声日益急促。快递废弃物的循环使用涉及到多方利益相关者,本文基于利益主体协同演化视角,分别构建未引入政府约束机制和引入政府约束机制的"快递企业-消费者"演化博弈模型,借以探索政府、消费者及快递企业在快递废弃物回收产业链营建过程中所扮演的角色,借助复制动态方程得到利益相关方的演化稳定策略和规律,并进一步应用MATLAB仿真工具进行仿真模拟,研究结果表明:未引入政府约束机制下,博弈系统难以依靠市场调节快速演化到理想状态,快递企业和消费者会反复权衡参与营建快递废弃物回收产业链的收益和成本,根据净收益进行策略选择,当二者净收益大于0时,博弈系统会逐渐演化为理想状态,反之,博弈系统则会逐渐演化为不良状态。引入政府约束机制可以快速的引导快递企业和消费者向理想状态演化,加大对快递企业营建回收产业链的补贴力度以及对营建回收产业链怠工的罚款程度能够促进快递废弃物回收产业链营建的快速高效执行。本文的研究对快递废弃物回收产业链的营建起到一定的启示作用:1从政府的角度出发,快递废弃物回收产业链的成功营建能够带来社会环境资源福利的增加,所以不应仅仅依靠市场行为,政府应当充分发挥其在营建过程中的引导作用;2从快递企业的角度出发,快递企业是回收产业链的实施方,应将环境保护作为企业发展的责任,积极主动参与回收产业链的营建;3从消费者的角度出发,作为回收产业链运行的初始点,消费者应该从自身做起,提高环保意识,责任意识,积极推动回收产业链的营建。  相似文献   

17.
As biodegradable material represents approximately 70% of household waste in Brazil, any strategy to divert appreciable waste quantities from landfills of necessity has to include valorization and recycling of this material. A societal change of attitude is required to perceive this challenge. Experiments in an urban apartment building are described that produced this change of attitude with a success factor of 80%. Divided waste collection was implemented that separated at the source biodegradable from inert material. Correct collection, handling and display procedures were established. Composting of biodegradable material was carried out under the rooftop of the building as an alternative to using it as animal feed. Half of the inert material entered the reverse logistics chain and was also diverted from the landfill. Waste related material flow through the building is completely quantified, food intake and waste production are related, diversion of both biodegradable and inert waste components from the landfill is measured and the composting process is described. The landfill diversion stands at 61%, mass reduction through the composting process is 80% and matured compost is returned to residents for use in flower cages. The system has been operational for two years and stands out as a precedent in successful decentralized household waste management supported by material flow analysis. Readers should send their comments on this paper to: BhaskarNath@aol.com within 3 months of publication of this issue.  相似文献   

18.
This review represents an assessment of the pollution status of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) in China (the mainland, Hong Kong and Taiwan). During the past decades, seven PCDD/Fs pollution hotspots have been found: (a). Ya-er Lake, Hubei Province, with 'total PCDD/Fs' level reaching 177,427 pg g(-1) (dry weight) in lake sediments; (b). Chinese Schistosomiasis affected areas of Jiangxi Province with 33,660 pg g(-1) in soil; (c). e-waste recycling area of Yangtze River Delta, with 2726 pg g(-1) in paddy soil; (d). e-waste recycling area of Guiyu (eastern part of Guangdong Province), with 967,500 pg g(-1) in mixture of burnt residue and soil (the highest level among all hotspots); (e). Pearl River Delta with 2630 pg g(-1) in coastal sediment. (f). Kwun Tong, Victoria Harbour, Hong Kong with 10,999 pg g(-1) in coastal sediment; and (g). southern Taiwan with 606,000 pg g(-1) in soil near the vicinity of a pentachlorophenol manufacturing factory. The main sources of PCDD/Fs in China were formed from impurities during the production of polychlorophenol, hexachlorobenzene, polychlorinated biphenyls, organic chlorinated pesticide and triclosan. In addition, sources of PCDD/Fs included municipal waste incineration, mineral fuel usage, open burning of electronic waste and crop residues, industrial waste discharge and vehicle exhaust emission. Due to potential human health risks from long-term exposure to PCDD/Fs at these hotspots, body loadings of these contaminants should be monitored.  相似文献   

19.
The rise of electronic commerce and the stricter government regulations on the recovery of end-of-life products increased the number of products returned by customers. A company may deal with increasing product returns by developing its own reverse logistic system. However, high fixed costs associated with dedicated reverse logistics equipment and infrastructure force many companies to outsource their reverse logistics operations to third-party reverse logistics providers. One of the important problems faced by third-party reverse logistics providers is the selection of the types of used products to be collected. In this study, a four-phase used product selection methodology is proposed. First, the quantitative and qualitative selection criteria are determined. Then the weights of the criteria are calculated using fuzzy analytic hierarchy process. Next, simulation models are employed to determine the values of quantitative criteria. Finally, technique for order preference by similarity to ideal solution ranks alternative used product types. A numerical example is also provided in order to present the applicability of the proposed methodology.  相似文献   

20.
Alternative production approaches are required because of conventional manufacturing's adverse environmental impacts. Remanufacturing returns used products to at least original performance specification from customers' perspectives and gives the resultant products warranties at least equal to that of new equivalents. Remanufacturing is relatively novel in research terms compared to conventional manufacture and recycling but often is more profitable than both. It would help manufacturers address competitive, environmental and legislative pressures by enabling them to meet pressing waste legislation while producing high-quality, lower cost products with less environmentally damaging end-of-life (EoL) and manufacturing modes. Remanufacturing is highly profitable in large, complex mechanical and electromechanical products but with conventional manufacturing and design modes not so in smaller products; particularly fast moving ones. However, effective waste management is urgently required for such products because waste electrical and electronic equipment constitutes the fastest growing EU waste stream and a large percentage of products being produced by major developing economies such as China are of this type. Active disassembly (AD) enables product non-destructive, self-disassembly at EoL and was invented to facilitate a step-change improvement in recycling. This research investigated the use of AD to extend profitable remanufacturing into small EoL electrical and electronic products.  相似文献   

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