南通市近岸海域主要海产品重金属残留监测与评价

对南通市近岸海域捕捞的多获性鱼类6种,甲壳类2种,养殖的贝类7种,藻类2种共17种海产品158份样品重金属残留进行调查分析。采用样品超标率、内梅罗综合污染指数等指标对海产品重金属残留状况进行综合评价,结果表明,南通市近岸海域海产品中人工养殖的贝类、藻类重金属污染大于捕捞的鱼类、甲壳类,重金属及As在海产品中的残留为:Cd、As污染>Pb、Hg、Cu、Cr。     

近岸海域水质自动监测系统站位的布设

水质自动监测将是近岸海域环境监测的一个发展趋势。通过分析现有近岸海域自动监测站在站点布设过程中的经验,对近岸海域自动监测系统站位的设置原则、技术要求、基本条件及注意事项等进行阐述,为后续近岸海域自动监测系统的建设提供参考依据。     

近岸海域水质自动监测规范化研究

为规范近岸海域水质自动监测,基于近岸海域水质监测要求和质控要求、近岸海域水质自动监测系统特点和近岸海域水质自动监测运行的经验,开展了近岸海域水质自动监测规范化研究,编制了《近岸海域水质自动监测技术规范》(HJ 731—2014),规范了近岸海域水质自动监测系统建设、设备选择、系统验收、日常管理、维护和校准、质量保证和质量控制、数据有效性和上报、监测报告等方面的工作。有利于在标准方法基础上,使中国近岸海域水质自动监测系统的监测数据准确、可靠、可比,有利于近岸海域水质自动监测系统在日常监测中更好地发挥作用。     

中国近岸海域环境监测技术路线研究

针对中国\"十二五\"期间近岸海域环境形势和管理需求,在分析国内外监测技术发展趋势的基础上,提出现阶段近岸海域环境监测技术路线应以优化布点、现场采样、实验室分析、浮标自动监测和卫星遥感为基本手段,重点针对河口、海湾区域富营养化和生态效应问题,依托国家、省/分站、地(市)和县(区)四级监测运行模式,完善近岸海域质量、海岸带环境、陆源输入通量、监控预警和事故应急监测方法,构建基于生态目标的近岸海域环境综合监测和评价体系,并对各类监测点位、监测指标和监测频次进行了优化筛选。     

近岸海域水质自动监测质量保证和质量控制

根据实际工作经验,阐述了近岸海域水质自动监测系统运行过程中的质量保证与质量控制措施,包括建立规章制度、实验室条件、设备维护和校准、数据检查和审核、记录等方面的要求,通过实例介绍了设备维护和校准周期的确定、设备维护效果的影响和数据有效性的判别等,为近岸海域连续自动监测系统的有效管理提供依据。     

建设近岸海域水质自动监测系统应考虑的几个问题

在近岸海域自动监测系统建设前,需要明确建设自动监测系统的目的性;从人员、经费、技术性能等方面综合分析开展自动监测系统建设和运行的可行性分析;同时考虑监测子站建成后仪器设备的安全问题,以保证自动监测系统能够发挥应有的作用。     

浙江近岸海域表层沉积物重金属分布特征与生态风险评价

通过对浙江近岸海域477个表层沉积物样品粒度,以及样品中6种元素（Cu、Pb、Zn、Cr、Cd和As）和总有机碳（TOC）的分析,探讨重金属的空间分布特征及其生态风险。结果表明,研究区表层沉积物中重金属元素含量的空间分布较为相似,总体上表现为近岸高、远岸低;6种元素具有相似来源,与沉积物平均粒径和TOC均呈正相关性,且细颗粒泥质沉积物和TOC分别是导致其富集累积的主要和次要影响因素;6种元素的地累积指数较低,重金属污染总体上处于轻度水平;6种元素潜在生态风险系数由大到小依次为Cd＞As＞Pb＞Cu＞Cr＞Zn,总体上潜在生态风险程度轻微;地累积指数和综合潜在生态风险指数均表现为向岸海域的重金属污染程度远大于离岸海域。     

如东滩涂近岸海域沉积物重金属分布特征及风险评价

基于2017和2019年如东滩涂近岸海域沉积物重金属调查数据,探讨该海域沉积物重金属的分布特征,通过重金属与环境因子的相关性分析,研究影响重金属分布的控制因素.采用地累积指数法和潜在生态风险指数法评估其污染程度和潜在生态风险.结果表明,铜(Cu)、锌(Zn)、铅(Pb)、铬(Cr)、镉(Cd)、汞(Hg)、砷(As)平...     

江苏南通近岸海域伪虎鲸的出现与观测

于2022和2023年6月份,在江苏南通海门东灶港码头附近均发现约60头伪虎鲸（Pseudorca crassidens）活动,现场发现至少8对母子鲸,伪虎鲸在此活动时间约4个月,此地是中国近岸海域少有的大型鲸豚类重要栖息地,具有非常重要的保护价值。现通过连续2年（2022—2023年）的监测记录,初步发现伪虎鲸群集几十头的大群活动,可能是追随洄游产卵的鱼类而来。伪虎鲸频现南通近岸海域的原因包括：海门东灶港航道足够的水深、周边海域生态环境优良、人为干扰较小、水生生物资源较丰富等。目前该伪虎鲸种群也面临一定风险,2023年已发现有2头搁浅死亡的伪虎鲸,建议对该区域伪虎鲸种群及其栖息地进行更深入的监测研究,采取更加有效的保护措施。     

天津近岸海域水污染评价

为了认识天津近岸海域水质主要污染指标及污染物随年份的演变规律,根据1996年—2007年天津近岸海域水质监测数据,对天津近岸海域水污染状况进行了时空分析。结果表明,天津近岸海域水质总体呈恶化趋势,劣Ⅳ类海域面积比例呈增加趋势,主要污染因子为无机氮。提出,应确立治海先治陆的思想理念,建立陆源污染排放总量控制制度;加强对海上作业的管理,加强保护开发海域的生态环境。     

洪泽湖溧河洼水生植物体内重金属调查

对洪泽湖溧河洼区域的水生植物进行了Cu、Zn、Pb、Cr和Cd等重金属元素的污染调查与监测分析,结果表明:水生植物对重金属元素的吸收与积累反映了环境中的重金属污染水平,不同水生植物对各种重金属元素的吸收富集状况具有相对一致性,即Zn>Cu>Cr>Pb>Cd。水生植物对各种重金属元素的平均富集系数大小顺序为:Cd>Cu>Zn>Cr>Pb,这与各元素迁移性强弱的顺序也是相一致的,Cd、Cu、Zn等各元素较易为植物所吸收,而Pb的移动性较差。大部分水生植物根部的重金属含量比茎叶部分高。研究表明:可以从中筛选出具有高富集作用的植物,作为修复水体或土壤重金属污染的实验植物,为植物修复作用的研究提供参考。     

交通干道沿线土壤重金属监测与评估综述

公路运营所带来的铅、镉、锌等重金属污染物对人体健康安全存在着潜在和长期的影响。近年来,开展交通干道沿线重金属污染监测与评估工作已经成为环境监测工作的重要内容。从监测技术、评估方法、可能影响因素等几个方面对该领域的研究进展及成果进行了综述。采样段面的选取、点位的布设与样品的收集应该同时遵循全面性和代表性的原则。在同一交通干道内,均匀布置采样段面的同时可以尽量包含高车流量、中车流量与低车流量3种类型。考虑到重金属在横向距离上的分布规律,可以在0~100 m处设置密集采样点位,在100~300 m处设置适量采样点位。评估方法一般同时采用Kriging空间插值分析、污染指数分析、多元统计分析,生态风险评价与健康风险评价等多种分析方法。     

吐鲁番盆地葡萄园土壤重金属污染状况及其潜在生态风险

为探讨中国葡萄主产区土壤重金属污染状况及生态风险,从吐鲁番盆地葡萄园采集了101个土壤样品,测定As、Cd、Cr、Ni、Pb和Hg等6种元素的浓度。利用地质累积指数(I_geo)、潜在生态风险指数(RI)和生态风险预警指数(I_ER),对葡萄园土壤重金属污染状况及其潜在生态风险进行了评估。结果表明:吐鲁番盆地葡萄园土壤中6种元素的平均含量均小于《土壤环境质量农用地土壤污染风险管控标准(试行)》(GB 15618—2018)中的筛选值,但As、Cd、Cr、Hg的平均含量分别为新疆灌耕土背景值的1.05、1.58、1.49、1.15倍。各元素I_geo平均值排序为Cd(0.0)>Cr(-0.02)>As(-0.53)>Hg(-0.62)=Pb(-0.62)>Ni(-0.88),均表现为无污染;单项生态风险指数排序为Cd>As>Ni>Hg>Cr>Pb,均呈现轻微生态风险;RI平均值为17.33,属于轻微生态风险;I_ER平均值为-4.87,属于无警态势。Cd是...     

Canadian Environmental Effects Monitoring: Experiences with Pulp and Paper and Metal Mining Regulatory Programs

In Canada, Environmental Effects Monitoring (EEM) programs exist within two regulations: the Pulp and Paper Effluent Regulations and the newMetal Mining Effluent Regulations under the Canadian Fisheries Act. EEM provides a biological, effects-based feedback loop to assess the effectiveness of technology-based regulations in protecting receiving environments. The promulgation of the Pulp and Paper Effluent Regulations, in 1992, represented a significant step forward in the Canadian regulatory approach by incorporating directly into a regulation a requirement to assess the effects of effluent discharges on receiving environments using proven scientific monitoring methodologies. Similarly, an assessment of the aquatic impacts of mines resulted in recommendations to amend the Metal Mining Effluent Regulations, recently promulgated in 2002, and includes an EEM program as a science-based feedback loop. As such, these regulations recognize the possibility that national, technology-based standards may not necessarily protect all receiving environments because of the diversity and variability of both discharges and receiving sites across the country. Since that time, EEM has improved its flexibility by considering both advances in science and the uniqueness of monitoring sites across Canada to allow the most appropriate and cost-effective monitoring approaches at each site while maintaining national consistency. This paper discusses the use of monitoring under two Canadian regulations to assess effects on aquatic ecosystems. As well, the National EEM approach to maintaining up-to-date scientific practices in a national regulatory program is discussed using examples.     

Environmental Quality Of Urban Parks And Open Spaces In Hong Kong

It is widely purported that urban parks and open spaces can improve the urban environment by cleansing the air and reducing the noise. However, such environmental functions can be constrained by the size and the location of urban parks in very dense cities. This study examines the air and acoustic environment and heavy metal contamination in Hong Kong urban parks and open spaces. Using a hybrid field measurement and computer simulation approach, the study has found that while the air quality in urban parks is better than that of the roadside, it is not significantly different from that of the ambient conditions. Noise levels in the urban parks are not significantly lower than those at the typical home environment in Hong Kong. Heavy metals in urban park dust are slightly lower than that found at the roadside and are broadly comparable to those found at typical homes and nursery schools. These findings lend support to the postulation that the capability of urban parks and open spaces in dense cities to improve the urban environment is rather limited and call for a re-examination of the role of urban parks in enhancing urban livability. The findings also have implications on how urban parks in dense cities should be designed and managed.     

白银矿区土壤重金属及可培养细菌重金属耐受性研究

对白银矿区土壤重金属进行分析研究,分离、筛选和鉴定了受污染土壤中的可培养细菌,并考察其对土壤中重金属胁迫的耐受性。结果表明：白银矿区王岘镇尾渣堆和东大沟河沟土壤重金属污染Pb＞Zn＞Cu;从污染最严重的土壤中分离、筛选出砖红色微杆菌（Microbacterium testaceum）、特基拉芽孢杆菌（Bacillus tequilensis）和解单端孢菌素微杆菌（Microbacterium trichothecenolyticum）3种细菌,其中菌株M1（Microbacterium testaceum）对Pb、Zn、Cu、Cd的胁迫具有明显的耐受性。     

Competitive Retention of Lead and Cadmium on an Agricultural Soil

Lead and cadmium contamination of an agricultural soil has been studied using batch and column experiments. Thermodynamics of theretention phenomena may be represented by a Langmuir isotherm foran aqueous metal concentration up to 100 mg L^-1. First order kinetics with respect to the solid phase yield good predictabilityfor both batch and column experiments. Kinetics and thermodynamics of lead retention predominate over those ofcadmium. As a consequence, lead is preferentially retainedand can even displace sorbed cadmium. In the event of anspill involving both metals, cadmium would move further inthe soil and its aqueous concentration downstream could beeven higher than that of the influent solution, increasingpotential risks. A two-region model has been used to fit all the experimental results. Satisfactory predictions for column experiments are obtained with parameters which are consistent with those obtained for the batch experiments, for which sorption is described by a Langmuir isotherm including competitive retention.     

包头某铝厂周边土壤重金属污染及健康风险评价

以包头市某铝业周边500 m内土壤为研究对象,测定其东北、东南、西北、西南4个方向不同水平距离及深度处土样中Cu、Cd、Pb、Zn、Ni和Cr的含量,并采用地累积指数法和健康风险评价法对重金属污染状况进行评价。结果表明,该区域表层土壤中6种重金属普遍高于内蒙古土壤背景值,且在西南方向50 m处含量最高,人类活动对该区域重金属干扰强烈,而风向对重金属分布影响不大;铝厂周围土壤中Cd、Pb处于中污染-重污染,Cu和Ni处于无污染-中污染,Zn和Cr为无污染,各金属污染程度随土壤深度的增加而减轻;健康风险评价表明,研究区域内Cu、Pb、Ni和Cd均不存在非致癌健康风险,而Cd的致癌危害虽在可接受范围内,但已存在潜在致癌风险,Ni的致癌健康风险指数已超过预警值,应予以高度重视和防治。     

Levels and speciation of heavy metals in soils of industrial Southern Nigeria

A knowledge of the total content of trace metals is not enoughto fully assess the environmental impact of polluted soils. Forthis reason, the determination of metal species in solution isimportant to evaluate their behaviour in the environment andtheir mobilization capacity. Sequential extraction procedure wasused to speciate five heavy metals (Cd, Pb, Cu, Ni and Zn) fromfour contaminated soils of Southern Nigeria into sixoperationally defined geochemical species: water soluble,enchangeable, carbonates, Fe-Mn oxide, organic and residual.Metal recoveries were within ± 10% of the independentlydetermined total Cd, Pb, Cu, Ni and Zn concentrations. The highest amount of Cd (avg. 30%) in the nonresidual fractionswas found in the exchangeable fraction, while Cu and Zn weresignificantly associated with the organic fraction. Thecarbonate fraction contained on average 14, 18.6, 12.6, 13 and11% and the residual fraction contained on average 47, 18, 33,50 and 25% of Cd, Pb, Cu, Ni and Zn respectively. Assuming thatmobility and bioavailability of these metals are related to thesolubility of the geochemical form of the metals, and that theydecrease in the order of extraction sequence, the apparentmobility and potential bioavailability for these five metals inthe soil were: Pb > Zn > Cu > Ni > Cd. The mobility indexes ofcopper and nickel correlated positively and significantly withthe total content of metals, while mobility indexes of cadmiumand zinc correlated negatively and significantly with the totalcontent of metals.     

中国辐射环境监测法规标准问题分析

随着辐射环境复杂程度的不断提升,国内外良好实践和先进技术的出现,以及中国持续改善环境质量总目标的确立,中国的辐射环境监测法规标准体系面临新的挑战。通过对中国辐射环境监测法规标准进行梳理和研究,指出现有法规标准中存在的问题,提出解决问题的对策,建议加快制修订《中华人民共和国放射性污染防治法》、《环境监测管理条例》、《环境监测管理办法》以及辐射环境监测工作系列导则和相关行业标准,以保证辐射安全工作规范开展,全方位保证中国辐射环境质量提升。