共查询到20条相似文献,搜索用时 203 毫秒
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Nick D. Hutson 《Water, Air, & Soil Pollution: Focus》2008,8(3-4):323-331
The US fleet of coal-fired power plants, with generating capacity of just over 300 GW, is known to be a major source of domestic mercury (Hg) emissions. To address this, in March 2005, the Environmental Protection Agency (EPA) promulgated the Clean Air Mercury Rule (CAMR) to reduce emissions of mercury from these plants. It is generally believed that most of the initial (Phase I) mercury reductions will come as a co-benefit of existing controls used to remove particulate matter (PM), SO2, and NO X . Deeper reductions in emissions (as required in Phase II of CAMR) may require the installation of mercury-specific control technology. Duct injection of activated carbon sorbents is the mercury-specific control technology that has been most widely studied and has been demonstrated over a wide range of coal types and combustion conditions. The effectiveness of the mercury control options (both “co-benefit control” and “mercury-specific control”) is significantly impacted by site-specific characteristics such as the combustion conditions, the configuration of existing air pollution controls, and the type of coal burned. This paper identifies the role of coal properties and combustion conditions in the capture of mercury by fly ash and injected sorbents. 相似文献
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An entrained-flow system has been designed and constructed to simulate in-flight mercury capture by sorbents in ducts of coal-fired
utility plants. The test conditions of 1.5 s residence time, 140°C temperature, 4.5 ppbv inlet Hg0 concentration, and 0–20 lb/MMacf sorbent injection rates were chosen to simulate conditions in the ducts. Novel oxidants
developed in previous fixed-bed tests and novel sorbents derived from the novel oxidants were tested for their Hg0 capture in the entrained-flow system to examine the possibility of using those sorbents in a full-scale system. Darco-FGD
and Darco Hg-LH served as benchmark sorbents with which mercury control capability of the novel oxidants and novel sorbents
could be compared. The test results showed that the novel oxidants have remarkable Hg0 oxidation capability, and the novel sorbents showed a better performance in Hg0 removal than Darco Hg-LH. 相似文献
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介绍了燃煤电站汞的排放状况,并指出了汞危害性以及我国面临的脱汞压力,论述了烟气中汞存在形式以及影响其存在形式的因素.探讨了当前燃煤电站利用现有污染控制设备进行协同脱汞的研究进展,包括:燃烧器/反应器、选择性催化还原脱硝(SCR)、电除尘器(布袋除尘)(ESP/FF)、湿法烟气脱硫系统(WFGD)等设备.提出了脱汞吸附剂处理问题,并对今后烟气脱汞技术的研究趋势进行了展望. 相似文献
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汞是煤中最易挥发的重金属元素之一,燃烧产物中汞的排放为火电厂锅炉汞污染的主流。烟气中的汞主要采用活性炭或者其他吸附剂、飞灰再循环、湿法烟气脱硫装置等手段来去除,但普遍存在吸附剂价格昂贵、经济效应不高,具体脱除效应不明显、仅适用中小型火电厂锅炉等实际问题。为配合脱汞市场,需要在完善测试手段和控制手段的基础上,着重解决多组分污染物联合脱除汞反应的竞争机制和活性/选择性调控规律、吸收剂固体表面物理化学、大容积/大流量反应器内超低浓度污染物的富集/反应机理等关键技术问题。在火电厂烟气零价汞形态转化机理、汞迁移转化动力学模型的研究以及高效价廉吸附剂的开发等方面取得突破,开发具有自主知识产权的新型燃煤电厂烟气中汞排放控制方法。 相似文献
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Agarwalla Hridesh Das Tarit Baran Senapati Rabinarayan Gangopadhyay Monalisa Masto Reginald E. Kumar Manish Singh Vikram 《Journal of Material Cycles and Waste Management》2023,25(5):2632-2641
Journal of Material Cycles and Waste Management - India is considered as one of the major mercury emitters of the world. Coal combustion in power plants is the foremost source of mercury emissions.... 相似文献
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欧盟国家燃煤电厂环保政策及技术路线分析 总被引:1,自引:0,他引:1
温室气体的排放控制作为全球性的环境问题受到了广泛关注。中国是火力发电的大国,其燃煤机组的温室气体排放总量巨大。《火电厂大气污染物排放标准》(GB 13223-2011)提高了我国燃煤电厂的烟气污染物排放的要求,对火电厂烟气处理的技术选择和投资都会产生重大影响。针对中国燃煤电厂环保面临的新形势,阐述了欧盟国家的环保政策重点,并对欧盟国家燃煤电厂污染物控制的相关标准进行了分析,同时简要介绍了欧盟国家燃煤电厂环保的主要技术路线,在一定程度上可作为中国燃煤电厂污染物控制的借鉴和参考。 相似文献
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Masaki Takaoka Shingo Domoto Kazuyuki Oshita Nobuo Takeda Shinsuke Morisawa 《Journal of Material Cycles and Waste Management》2012,14(2):113-119
Sewage sludge contains trace amounts of mercury, and sewage sludge incineration is a major source of mercury emissions. However, relatively few studies have reported on mercury emissions from sewage sludge incineration. Consequently, data on emissions from sewage sludge incinerators must be updated to estimate current emissions of mercury. In this study, we examined mercury emissions and speciation using continuous mercury analyzers in two incinerators. The mercury concentrations in stack gas from facilities A and B were 36.6 and 21.1???g/Nm3, respectively. As a result, the emission rate was calculated to be 0.282?C0.750?g/ton-dry sludge. Considering the total amount of sewage sludge incinerated in Japan, the mercury emissions from sewage sludge incinerators were estimated to be 0.49?C1.31?tons/year. 相似文献
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电厂燃煤过程中汞控制技术研究 总被引:3,自引:0,他引:3
燃煤电厂汞控制技术分燃烧前、燃烧中和燃烧后脱汞,燃烧后脱汞技术为主要汞控制排放工艺,其中吸附剂吸附方法的研究较为广泛。基于国内外近几年燃煤电厂烟气脱汞技术的研究,综述了汞控制技术的最新进展。 相似文献
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简述了石灰石—石膏湿法烟气脱硫废水的主要来源、成分、特性及废水处理机理,经物理和化学方法处理后的脱硫废水,主要污染物去除效果明显,pH、CODCr、悬浮物及重金属等均已达到排放要求。 相似文献
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Examining Source-Receptor Relationships for Mercury in Scandinavia Modelled and Empirical Evidence 总被引:1,自引:0,他引:1
Munthe John Kindbom Karin Kruger Olaf Petersen Gerhard Pacyna Jozef Iverfeldt Åke 《Water, Air, & Soil Pollution: Focus》2001,1(3-4):299-310
The atmosphere remains the major source of mercuryin Swedish ecosystems. Since the late eighties,atmospheric emissions of mercury have drasticallydecreased in Europe. Wet deposition of mercury hasdecreased over the last decade but still exhibitsa clear south-to-north gradient, greatlyinfluenced by source areas in northern and centralEurope. The decreases in emissions can beattributed to both direct measures to close knownpoint sources and a declining economy and energyconsumption in many East European countries.Further reductions of mercury emissions willrequire that other source categories such asindirect emissions from mercury-containingproducts and crematories are be considered. 相似文献
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顺应国家政策走向,积极脱硝促进燃煤火电和谐发展——电力集团脱硝战略浅析 总被引:3,自引:0,他引:3
控制NOx排放是电力企业在建设资源节约型和环境友好型社会中的一项重要工作.分析了我国NOx排放状况以及控制政策的发展趋势,并对新的电力工业体制下,建立以电力集团为责任主体和组织核心的NOx控制战略和规划提出了一些建议. 相似文献
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A new approach to vapor phase elemental mercury capture has been explored; this approach exploits an ionic liquid coating
layer to oxidize elemental mercury for subsequent immobilization by chelating ligands. The room temperature ionic liquid 1-butyl-1-methyl
pyrrolidinium bis(trifluoromethane sulfonyl)imide (P14) was selected for study based on its oxidation potential window, thermal stability, and low vapor pressure. Tests were also
completed in which KMnO4 was added to P14 to form a new ionic liquid, P14–KMnO4, with a higher oxidation potential. In room-temperature bulk liquid phase capture experiments, 59% of the elemental mercury
in the inlet gas was captured using P14 alone; mercury capture using P14–KMnO4 was quantitative. P14 and P14–KMnO4 coatings were successfully applied to mesoporous silica substrates and to silica substrates functionalized with mercury chelating
ligands. The coating layers were found to be thermally stable up to 300°C. Fixed-bed tests of nonfunctionalized silica coated
with P14 showed an elemental mercury uptake of 2.7 mg/g adsorbent at 160°C; at the same temperature, functionalized silica coated
with P14–KMnO4 showed an elemental mercury capacity of at least 7.2 mg/g adsorbent, several times higher than that of activated carbon.
The empty bed gas residence time in these tests was 0.04 s. A chelating adsorbent incorporating P14 in the coating layer, may be capable of simultaneous removal of elemental and oxidized mercury from coal combustion flue
gases. 相似文献
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David Chung Hyo-Hyun Choi Hye-Young Yoo Ji-Young Lee Sun-Kyoung Shin Jung Min Park Junbeum Kim 《Journal of Material Cycles and Waste Management》2017,19(1):46-54
To prepare for the international mercury convention, the characteristics of mercury emissions from a zinc smelting facility in South Korea have been reviewed and a material flow analysis (MFA) has been conducted in this research. As inputs into the mercury MFA study, zinc ores and sulfuric acid were examined, whereas wastewater sludge, effluence water, spent catalyst, and emissions from the casting and roasting processes were examined as outputs. Mercury concentrations extracted from end products like zinc ingots, cadmium ingots, and sulfuric acid were then analyzed. Our results showed that the wastewater sludge discharged from the zinc smelting process had a relatively higher concentration of mercury, indicating that the concentration of mercury was further enriched in the wastewater sludge. The wastes discharged through the zinc smelting process should be thoroughly controlled, as results of the MFA showed that approximately 89 % of the mercury contained in the original input was later found in the waste. According to this study, the higher the concentration of mercury within zinc ores at the input stage, the higher is the mercury concentration found in the wastewater sludge at the output stage. 相似文献
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泡沫玻璃砖在烟囱防腐中的应用 总被引:1,自引:0,他引:1
火电厂燃煤烟气中存在一定量的SO3,会显著降低烟气的酸露点。由于湿法脱硫后烟温低于酸露点,烟气中的SO3与水蒸汽形成的硫酸蒸汽会凝结下来,造成混凝土烟囱的低温腐蚀。以2×135MW机组烟气脱硫技改工程湿烟囱防腐为例,详细介绍了烟囱内衬泡沫玻璃砖防腐的施工工序、技术要求及注意事项。 相似文献