陕西渭北旱塬区生境质量及碳储量时空演变分析与模拟

探析生境质量与碳储量的时空格局演化规律,对建立陕西渭北旱塬区生态安全屏障、优化国土空间格局具有积极反馈作用.以渭北旱塬区为研究案例,基于PLUS模型模拟2035年不同发展情景下土地利用空间格局,并采用InVEST模型分析研究区1980~2020年及未来多情景下生境质量和碳储量分布特征.结果表明:①近40年间,研究区内生境质量低等级区面积扩大462.55 km²,碳储量共减少7.85×10⁶t,二者总体呈逐年下降趋势; ②研究期间,生境质量降级区域集中在研究区东北部延安市域内,质量提升区域呈条状分布在靠近水源或海拔较高的地区.碳储量高值区集中分布在研究区内地势复杂、人口稀疏的区域,碳储量减少区域呈点状零散分布在研究区全域,未出现明显聚集现象; ③2035年碳储量除自然发展情景外,其他状态碳储量均有不同程度减少.经济优先发展情景中生境质量低等级区面积20787.41 km²,是较模拟初期低等级区增速最快和高等级区减幅最大的模拟情景.研究结果可为研究区低碳绿色发展、生态修复提供决策参考和数据支撑.     

基于InVEST模型的伏牛山地区生态系统碳储量时空变化模拟

在生态文明建设高质量的发展环境下,探究国土空间规划视角下土地利用合理规划与碳减排关系有重大现实意义.山地生态系统作为自然、社会和经济的综合生态系统,对区域生态环境质量提高和可持续发展具有重要影响.以河南省伏牛山区为研究对象,采用InVEST与CA-Markov模型预测2000～2030年多情景下伏牛山生态系统碳储量的时空分布差异.结果表明：(1) 2000～2020年,伏牛山地耕地和林地大面积减少,水域和建设用地增加.自然增长情景下耕地持续减少;耕地保护情境下耕地面积减少速度得到有效缓解;生态保护情景下,林地草地面积得到了有效保护.(2) 2000～2020年,伏牛山地生态系统碳储量减少2.62×106 t;自然增长情景下,生态系统碳储量持续减少;耕地保护情景稍有缓解;生态保护措施有效缓解了碳损失.(3)碳储量随海拔升高呈驼峰状变化,随着坡度升高而呈现增加的趋势.因此,在未来伏牛山地区国土空间规划中,可综合考虑生态保护与耕地保护情景,在增加碳储量的同时也保证了粮食生产.     

基于InVEST模型和PLUS模型的环杭州湾生态系统碳储量

研究土地利用方式与生态系统服务碳储量的关系,对于区域碳排放管理具有重要意义.利用InVEST模型碳储量模块和PLUS模型,探究并预测研究区2000～2018年和2018～2030年生态系统碳储量时空变化特征及其与土地利用方式之间的关系.结果表明,研究区2000、 2010和2018年碳储量分别为7.250×10⁸、 7.227×10⁸和7.241×10⁸ t,呈先减后增趋势.土地利用类型变化是导致生态系统碳储量变化的主要因素,建设用地的快速扩张导致碳储量降低.与土地利用类型相对应,研究区碳储量空间分异显著,并以碳储量分界线为界,呈现“东北低西南高”特征.预测结果显示,至2030年碳储量为7.344×10⁸ t,较2018年增加1.42%,林地面积的增长是主要原因.     

广州森林碳储量时空演变及异质性分析

利用1990年、1997年和2004年3个时相的Landsat TM数据,基于CART分析算法,提取广州森林分类信息.利用样方调查与同期TM数据的光谱响应数据,分别建立了阔叶林、针叶林、园地的逐步回归模型,计算了广州森林碳储量,绘制了碳密度分布图.结果表明,广州森林覆盖率1997年比1990年显著增加,而2004年比1997年略有减少.3个时期广州森林碳储量、碳密度分别为5.93×106t、7.07×106t、7.64×106t与22.1t·hm-2、22.7t·hm-2、24.7t·hm-2,均呈上升趋势.3个时期均有40%以上的森林碳密度低于25 t·hm-2,80%以上森林碳密度低于50t·hm-2;但总体趋势是低碳密度森林比重减少,高碳密度森林比重增加,森林碳密度结构朝良性发展.在广州碳储量估算的基础上,计算Moran I系数与Geary C系数,表明研究区森林碳密度3个时期都存在正的自相关性,且分布格局由随机离散分布趋向于聚集分布.进一步利用半变异函数,对碳密度分布格局异质性进行分析,表明3个时期森林碳密度的空间分布格局异质性差异不大,1997年略强于其它时期;空间结构上均属于高度相关;空间自相关因素是森林碳密度空间异质性的主要因素;从1990～2004年,相关尺度增加,引起空间异质性的随机因素所占比重减少,自相关因素所占比重增加.     

三江平原湿地不同土地利用方式下土壤有机碳储量研究

选取东北三江平原沼泽湿地5种土地利用方式,共16个土壤剖面,对土壤有机碳储量分布特征进行了研究.结果表明,不同土地利用方式下,土壤剖面有机碳含量与有机碳密度均呈自上而下降低的趋势,且随着深度的增加,垂直差异变小.开垦降低了土壤有机碳含量和有机碳密度,并改变了其在表层的分布结构特征.初步估算5种土地利用方式下土壤有机碳储量分别为:沼泽湿地1.58×104t/km2、退耕还湿地1.23×104t/km2、林地1.01×104t/km2、水田0.85×104t/km2、旱田0.99×104t/km2.开垦降低了湿地土壤有机碳储量,且对耕地的影响大于林地,而退耕还湿有利于土壤有机碳的固定及储量的增加.     

贵州森林碳汇现状及增汇潜力分析

区域层面的森林碳收支估算研究有利于为整体层面持续固碳增汇的森林经营提供科学参考,评估森林碳汇对减少区域内碳排放的贡献。采用温室气体清单估算法,对2000、2005和2010年贵州省森林碳汇进行估算,结果表明:贵州省森林碳汇从15.380×106增长到22.447×106、24.314×106 t CO2,呈稳定增长趋势,占全省碳排放量的6.73%～10.35%。贵州省尚有161.70×104 hm2宜林地,如果能用于发展碳汇林业,每年可吸收CO2达2.379×106 t,30年内将吸收CO2达71.370×106 t。贵州省正处于碳排放增长阶段,相对于森林碳汇而言,全区域碳减排工作任重道远,森林碳汇能力有很大的提升空间。     

林线树种太白红杉碳储量估算

林线对气候变化十分敏感,有关环境如何影响林线植被碳储量分布的研究鲜见报道.采用野外调查、遥感影像解译和生物量模型计算相结合的方法,对秦岭主峰太白山林线树种——太白红杉(Larix chinensis)碳储量、碳密度及其分布进行了估算.结果表明:太白红杉林总碳储量为5.290×105 t,其中南坡碳储量为1.765×105 t,北坡碳储量为3.525×105 t,南北坡碳储量分布不均与太白红杉分布面积和海拔有很大的关系;太白红杉林碳密度为0～17.40 kg/m2,平均值为(7.65±4.15)kg/m2,与年均温度呈正相关,与海拔和年降水量呈负相关,温度是影响太白红杉林碳密度的关键因素.     

山西南部中条山生态系统碳储量时空分布及驱动因素

为探究陆地生态系统碳储量特征对促进区域低碳建设、实现区域“碳达峰、碳中和”的作用.本文运用InVEST模型的碳储量模块估算了2000～2020年中条山生态系统碳储量,并通过净生态系统生产力(NEP)对其结果进行修正,最后利用地理探测器分析碳储量空间分异的驱动因素.结果表明:2000～2020年中条山修正后碳储量总体呈增加趋势,累计增加了2.296×10⁶t,碳储量高值区主要分布于东部、中部和西北部,低值区分布于西南部及中部小部分区域.2000～2020年中条山陆地生态系统碳汇总量呈增加趋势,区域年均单位NEP为0.060kgC/(m²·a),碳汇区主要分布在东部,碳源区分布在中部及西北部.碳储量空间分异主要受年均NDVI、人类活动强度和年均潜在蒸散发的影响,其次是年均气温、年均人口和高程.不同因子的交互作用对碳储量的影响呈双因子增强和非线性增强,表明碳储量空间分异是由自然因素和人为因素共同作用的结果.中条山在生态环境保护和区域低碳建设中,应综合考虑不同影响因素的特点,采取差异化的生态调控模式和策略,提高生态系统的稳定性,增强碳储存能力.     

成渝经济区陆地植被碳储量动态及碳汇战略研究

利用卫星遥感数据,对2000年-2007年间成渝经济区耕地、森林和草地等陆地植被的碳储量进行了估算.结果表明:(1)7年间耕地和草地分别减少了2 388.89 km2和1 231.05 km2,林地增加了2 908.70 km2,其中耕地主要转出为林地和建设用地,草地转出主要为林地和耕地;(2)7年间成渝经济区碳储量呈逐渐增加的趋势,共增加了625.16万tC/a,年增长率为0.21%.其中耕地、草地碳储量分别减少了165.79万tC/a和933.87万tC/a,林地碳储量增加了1 724.81万tC/a.(3)结合碳储量变化的趋势,提出了以打造低碳城市为目标的成渝经济区碳汇战略.     

黑龙江大兴安岭森林绿色核算研究

在对国内外森林绿色核算研究综述的基础上,对黑龙江大兴安岭1997-2003年森林资源的实物量、价值量和森林绿色GDP等进行了核算。核算结果表明:黑龙江大兴安岭森林的eaGDP(environmentallyadjustedGDP)1997年为38.19×108元,2003年为57.34×108元,年均增长7.01%;森林的eaNDP(environmentallyadjustedNDP)1997年为25.70×108元,2003年为43.96×108元,年均增长9.36%。在森林绿色GDP核算的基础上,进行了资产负债和财富核算。结果表明,1997-2003年,黑龙江大兴安岭林地、林木存量价值呈减少的趋势;森林环境效益呈增加的趋势,反映在社会经济发展中对林地、林木存量的过度开发和利用。森林绿色GDP占GDP的比重和森林资源占国民财富的比重也呈下降的趋势,说明黑龙江大兴安岭虽然在天然林保护工程后,全面禁止天然林采伐,森林的生长量大于消耗量,表现为流量价值有所增加,反映森林是可持续的经营,但从存量上看对国民经济发展的支撑力是下降的。最后,研究指出,应加强生态补偿政策的研究,积极落实森林可持续经营对策和建议加强绿色财富政策的制定,以保证黑龙江大兴安岭森林的可持续发展和绿色财富的增长。     

Effects of two sludge application on fractionation and phytotoxicity of zinc and copper in the soil

The potential harm of heavy metals is a primary concern in application of sludge to the agricultural land. A pot experiment was conducted to evaluate the effect of two sludges on fractionation of Zn and Cu in soil and their phytotoxicity to pakchoi. The loamy soil was mixed with 0%, 20%, 40%, 60% and 80% (by weight) of digested sewage sludge (SS) and composted sludge (SC). The additions of both sludges caused a significant raise in all fractions, resulting in that exchangeable (EXCH) and organic bound (OM) became predominance of Zn and organic bound Cu occupied the largest portion. There was more available amount of Zn and Cu in SS treatments than SC treatments. During the pot experiment, the concentration of Zn in EXCH, carbonate (CAR) and OM and Cu in EXCH and OM fractions decreased in all treatments, so their bioavailability reduced. Germination rate and plant biomass decreased when the addition rate was high and the best yield appeared in 20% mixtures at the harvest of pakchoi. The two sludges increased tissue contents of Zn and Cu especially in the SS treatments. Zn in pakchoi was not only in relationship to ΔEXCH and ΔCAR forms but also in ΔOM forms in the sludge-soil mixtures. Tissue content of Cu in pakchoi grown on SC-soils could not be predicted by ΔEXCH. These correlation rates between Zn and Cu accumulation in pakchoi and variation of different fractions increased with time, which might indicate that sludges represented stronger impacts on the plant in long-term land application.     

Intraspecific differences in effects of co-contamination of cadmium and

A hydroponic experiment was carried out to study intraspecific differences in the effects of different concentrations of cadmium (Cd)(0-10 mg/L) and arsenate (As(V)) (0-8 mg/L) on the growth parameters and accumulation of Cd and As in six wheat varieties Jing-9428, Duokang-1, Jingdong-11, Jing-411, Jingdong-8 and Zhongmai-8. The endpoints of wheat seedlings, including seed germination,biomass, root length and shoot height, decreased with increasing the Cd and As concentrations. Significant differences in seed germination, biomass, root length, shoot height and the accumulation of Cd and As were observed between the treatments and among the varieties (p ＜ 0.05). The lethal dosage 50% were about 20, 80, 60, 60, 80 and 20 mg As/L for Jing-9428, Duokang-1, Jingdong-11,Jing-411, Jingdong-8 and Zhongmai-8, respectively, and the corresponding values for Cd were about 30, 80, 20, 40, 60 and 10 mg Cd/L, respectively. Among the six varieties, Duokang-1 was found to be the most resistant to Cd and As toxicity, and Zhongmai-8 was the most sensitive to Cd and As co-contamination. The resistance of the six varieties was found dependant on the seedling uptake of Cd and As. Duokang-1 was the most suitable for cultivation in Cd and As co-contaminated soils.     

EDTA-enhanced phytoremediation of lead contaminated soil by Bidens maximowicziana

Phytoremediation is a potential cleanup technology for the removal of heavy metals from contaminated soils.Bidens maximowicziana is a new Pb hyperaccumulator,which not only has remarkable tolerance to Pb but also extraordinary accumulation capacity for Pb.The maximum Pb concentration was 1509.3 mg/kg in roots and 2164.7 mg/kg in overground tissues.The Pb distribution order in the B. maximowicziana was:leaf>stem>root.The effect of amendments on phytoremediation was also studied.The mobility of soil Pb and the Pb concentrations in plants were both increased by EDTA application.Compared with CK(control check),EDTA application promoted translocation of Pb to overground parts of the plant.The Pb concentrations in overground parts of plants was increased from 24.23-680.56 mg/kg to 29.07-1905.57 mg/kg.This research demonstrated that B.maximowicziana appeared to be suitable for phytoremediation of Pb contaminated soil,especially,combination with EDTA.     

Distribution and ecological effect of mercury in Laogang landfill, Shanghai, China

Laogang landfill near Shanghai is the largest landfill in China, and receives about 10000 t of daily garbage per day, Samples of topsoil and plants were analyzed to evaluate mercury pollution from the landfill. For topsoil samples, there were significant correlations among total mercury （HgT）, combinative mercury （Hgc） and gaseous mercury （HgG）, and content of total organic carbon （TOC）, but, no significantly relationship was found between Hg content and filling time. Hg content changes in vertical profiles with time showed that the average Hgv of profiles 1992, 1996, and 2000 was similar, but their average HgG was quite different. HgT was significantly correlated with Hgc in profile 1992 and 2000, and Hgv was significantly correlated with Hg6 in profile 1996. HgG/Hgv ratio in profile samples decreased in the order of （HgG,/HgT）1992〉（HgG/HgT）1996〉〉（HgG/HgT）2000. A simple outline of Hg release in landfill could be drawn： with increasing of filling time, degradation undergoes different biodegradation, accordingly, gaseous mercury goes through small, more, and small proportion to total mercury. Distribution of Hg in plants was inhomogeneous, following the order of leaf〉root〉stem. The highest value of leaf may be associated with higher atmospheric Hg from landfill. Ligneous plants （e.g. Phyllostachys glanca, Prunus salicina and Ligustrum lucidum） are capable of enriching more Hg than herbaceous plants.     

Toxic effects of acetochlor, methamidophos and their combination on nifH gene in soil

Toxic effects of two agrochemicals on nifH gene in agricultural black soil were investigated using denaturing gradient gel electrophoresis （DGGE） and sequencing approaches in a microcosm experiment. Changes of soil nifH gene diversity and composition were examined following the application of acetochlor, methamidophos and their combination. Acetochlor reduced the nifH gene diversity （both in gene richness and diversity index values） and caused changes in the nifH gene composition. The effects of acetochlor on nifH gene were strengthened as the concentration of acetochlor increased. Cluster analysis of DGGE banding patterns showed that nifH gene composition which had been affected by low concentration of acetochlor （50 mg/kg） recovered firstly. Methamidophos reduced nifH gene richness that except at 4 weeks. The medium concentration of methamidophos （150 mg/kg） caused the most apparent changes in nifH gene diversity at the first week while the high concentration of methamidophos （250 mg/kg） produced prominent effects on nifH gene diversity in the following weeks. Cluster analysis showed that minimal changes of nifH gene composition were found at 1 week and maximal changes at 4 weeks. Toxic effects of acetochlor and methamidophos combination on nifH gene were also apparent. Different nifH genes （bands） responded differently to the impact of agrochemicals： four individual bands were eliminated by the application of the agrochemicals, five bands became predominant by the stimulation of the agrochemicals, and four bands showed strong resistance to the influence of the agrochemicals. Fifteen prominent bands were partially sequenced, yielding 15 different nifH sequences, which were used for phylogenetic reconstructions. All sequences were affiliated with the alpha- and beta-proteobacteria, showing higher similarity to eight different diazotrophic genera.     

Enzymatic oxidation of aqueous pentachlorophenol

The influence of the nonionic surfactant Tween 80 on pentachlorophenol （PCP） oxidation catalyzed by horseradish peroxidase was studied. The surfactant was tested at concentrations below and above its critical micelle concentration （CMC）. Enhancement of PCP removal was observed at sub-CMCs. The presence of Tween 80 in the reaction mixture reduced enzyme inactivation which occurred through a combination of free radical attack and sorption by precipitated products. A simple first-order model was able to simulate time profiles for enzyme inactivation in the presence or absence of Tween 80. At supra-CMCs, the surfactant caused noticeable reductions in PCP removal, presumably through micelle partitioning of PCP which precluded the hydrophobic PCP molecule from interacting with the enzyme.     

Decomposition of alachlor by ozonation and its mechanism

Decomposition and corresponding mechanism of alachlor, an endocrine disruptor in water by ozonation were investigated. Results showed that alachlor could not be completely mineralized by ozone alone. Many intermediates and final products were formed during the process, including aromatic compounds, aliphatic carboxylic acids, and inorganic ions. In evoluting these products, some of them with weak polarity were qualitatively identified by GC-MS. The information of inorganic ions suggested that the dechlorination was the first and the fastest step in the ozonation of alachlor.     

Arsenic uptake by arbuscular mycorrhizal maize （Zea mays L.） grown in an arsenic-contaminated soil with added phosphorus

The effects of arbuscular mycorrhizal (AM) fungus (Glomus mosseae) and phosphorus (P) addition (100 mg/kg soil) on arsenic (As) uptake by maize plants (Zea mays L.) from an As-contaminated soil were examined in a glasshouse experiment.Non-mycorrhizal and zero-P addition controls were included.Plant biomass and concentrations and uptake of As,P,and other nutrients,AM colonization,root lengths,and hyphal length densities were determined.The results indicated that addition of P significantly inhibited root colonization and development of extraradical mycelium.Root length and dry weight both increased markedly with mycorrhizal colonization under the zero-P treatments,but shoot and root biomass of AM plants was depressed by P application.AM fungal inoculation decreased shoot As concentrations when no P was added,and shoot and root As concentrations of AM plants increased 2.6 and 1.4 times with P addition,respectively.Shoot and root uptake of P,Mn,Cu,and Zn increased,but shoot Fe uptake decreased by 44.6%,with inoculation, when P was added.P addition reduced shoot P,Fe,Mn,Cu,and Zn uptake of AM plants,but increased root Fe and Mn uptake of the nonmycorrhizal ones.AM colonization therefore appeared to enhance plant tolerance to As in low P soil,and have some potential for the phytostabilization of As-contaminated soil,however,P application may introduce additional environmental risk by increasing soil As mobility.     

Degradation of metabolites accumulated of benzo[a]pyrene by coupling Penicillium Chrysogenum with KMnO4

Several main metabolites of benzo[a]pyrene （BaP） formed by Penicillium chrysogenum, Benzo[a]pyrene-1,6-quinone （BP 1,6- quinone）, trans-7,8-dihydroxy-7,8-dihydrobenzo[a]pyrene （BP 7,8-diol）, 3-hydroxybenzo[a]pyrene （3-OHBP）, were identified by high-performance liquid chromatography （HPLC）. The three metabolites were liable to be accumulated and were hardly further metabolized because of their toxicity to microorganisms. However, their further degradation was essential for the complete degradation of BaP. To enhance their degradation, two methods, degradation by coupling Penicillium chrysogenum with KMnO4 and degradation only by Penicillium chrysogenum, were compared; Meanwhile, the parameters of degradation in the superior method were optimized. The results showed that （1） the method of coupling Penicillium chrysogenum with KMnO4 was better and was the first method to be used in the degradation of BaP and its metabolites; （2） the metabolite, BP 1,6-quinone was the most liable to be accumulated in pure cultures; （3） the effect of degradation was the best when the concentration of KMnO4 in the cultures was 0.01% （w/v）, concentration of the three compounds was 5 mg/L and pH was 6.2. Based on the experimental results, a novel concept with regard to the bioremediation of BaP-contaminated environment was discussed, considering the influence on environmental toxicity of the accumulated metabolites.     

Impact of atrazine and nitrogen fertilizers on the sorption of chlorotoluron in soil and model sorbents

Sorption of chlorotoluron in ammonium sulfate, urea and atrazine multi-solutes system was investigated by batch experiments. The results showed application of nitrogen fertilizers to the soil could affect the behavior of chlorotoluron. At the same concentration of N, sorption of chlorotoluron decreased as the concentration of atrazine increased on the day 0 and 6 in soil, respectively. The sorption of chlorotoluron increased from 0 to 6 d when soils were preincubated with deionized water, ammonium sulfate and urea solution for 6 d. That indicated incubation time was one of the most important factors for the sorption of chlorotoluron in nitrogen fertilizers treatments. The individual sorption isotherms of chlorotoluron in rubbery polymer and silica were strictly linear in single solute system, but there were competition sorption between pesticides or between pesticides and nitrogen fertilizers. That indicated the sorption taken place by concurrent solid-phase dissolution mechanism and sorption on the interface of water-organic matter or water-mineral matter.