不同源类型农业非点源负荷特征研究——以新田小流域为例

以珠江三角洲北部新田小流域为研究对象,采用源类型法,在流域范围内建立林地、果园、旱地和水田四个全封闭的农业用地单元,并对四个单元出口处的径流量进行同步采样,分析COD、BOD、氨氮、总氮和总磷等污染物的负荷特征.结果表明:(1)流域地表水存在着明显非点源污染现象,不同源类型,地表径流的污染程度不同.(2)不同源类型农业非点源污染负荷强度不同,其中水田、旱地单位面积非点源负荷强度较大,果园、林地各项污染物的负荷强度相对最小.受地表扰动、施肥等人类活动影响,流域内水田、旱地是农业非点源污染发生的关键源区.(3)流域范围内,不同源类型农业非点源负荷总量不同,其中,果园各项污染物非点源负荷总量最大,其次是林地,水田、旱地非点源负荷输出总量较小,流域范围内,源面积成为影响非点源负荷总量的主要因素.(4)相应的非点源污染治理不仅是关键源区,同时应关注大面积流失区.     

Methane Production in River and Lake Sediments in Taiwan

To investigate the relationship between methane production in the sediments and pollution of the river and lake, biochemical oxygen demand (BOD) and chemical oxygen demand (COD) of the water sample, organic matter content and methane production of the sediment were measured. Experimental results indicated that BOD, COD and organic matter contents were low in Bei-tan Lake, the I-lan River and reservoirs; and methane production of these sediments ranged from 0.24 to 1.06 mg L- 1. However, BOD, COD and organic matter contents were high in the Hsin-dan River, Keelung River, drainage river of Taoyuan County, park pond and fishery pond. Methane production of these sediments was between 11.75 and 54.54 mg L-1. Sediments of drain river and fishery pond had high methane production, at 25.41 to 54.54 mg methane L. Methane production of sediments had a good correlation with BOD, COD and organic matter contents. Methane production was proportional to the increment in incubation temperature from 12 to 40C.     

基于着生硅藻指数的梧桐河水生态健康评价

在黑龙江省梧桐河,调查了13个点位的着生硅藻群落结构和水环境特征,应用8种硅藻指数对该河流水生生态系统进行健康评价,并在此基础上应用主成分分析、相关分析、冗余分析、箱型图分析等统计分析方法研究了影响梧桐河着生藻类群落的主要环境因子和8种硅藻指数在梧桐河的适用情况。结果显示:梧桐河存在一定程度的环境污染,优势种以小型异极藻(Gomphonema parvulum)等耐污种为主。8个硅藻指数中,硅藻属指数(Generic Index of Diatom,GI)、澳大利亚河流硅藻生物评价指数(Diatom Index for Australian Rivers,DIAR;Diatom Species Index for Bioassessment of Australian Rivers,DSIAR)评价结果偏差较大,在梧桐河不适用;相似度指数(Jaccard Index,JI)与富营养化硅藻指数(Trophic Diatom Index,TDI)评价结果较为严格,评分明显偏低;硅藻污染耐受指数(Pollution Tolerance Index,PTI)、硅藻生物评价指数(Diatom Bioassessment Index,DBI)和生物硅藻指数(Biological Diatom Index,BDI)在梧桐河流域适用性最好。根据冗余分析(RDA),将梧桐河流域点位分为3组,第一组点位为中-重度污染,主要影响因子为流速和总磷;第二组点位为轻-中度污染,主要影响因子为磷酸盐、氨氮和溶解氧;第三组点位为轻污染-清洁,主要影响因子为p H和电导率。     

QUAL2E模型在大沽河干流青岛段水质模拟中的应用

采用QUAL2E模型对大沽河干流青岛段的水质进行了模拟和预测。针对大沽河的具体情况,选用BOD5、COD和氮作为模拟预测指标,用实验模拟方法、模型率定法并参考相关文献确定了BOD耗氧系数k1、BOD复氧系数k2、BOD沉降系数k3、COD耗氧系数和弥散系数等水质参数,并对模拟结果进行了验证,表明预测值和实测值的相关性较好;对BOD5、k1、k2和Q(流量)进行了灵敏度分析,结果表明对大沽河DO浓度影响敏感的参数依次是:Q、k2、BOD、k1,即流量Q是模型最敏感的参数,说明河流的水力学参数对DO影响较大。     

Multivariate statistical techniques for the evaluation of spatial and temporal variations in water quality of the Mahanadi river–estuarine system (India) – a case study

Spatial and temporal distributions of water quality using multivariate statistical techniques for the evaluation of nutrients (NO₂-N, NO₃-N, NH₄-N, PO₄-P, SiO₄-Si, total N, total P) in relation to some physico-chemical features (DO, BOD, TSS, TDS, SO₄²⁻, Cl⁻) were studied for 31 different stations of the Mahanadi river–estuarine system in the eastern part of India. The seasonal nutrient variations (except SiO₄-Si) exhibit higher values during monsoon season in unpolluted stations and the reverse trends for polluted stations, which are related to agricultural run-off and regional anthropogenic activities respectively. Silicate shows a well defined pattern of distribution with a higher concentration during the monsoon, which is slightly removed from the estuarine water of Mahanadi during the pre-monsoon season. The results of R-mode factor analyses revealed that anthropogenic contributions are responsible for the increase in nutrients and the decrease in DO and pH levels of the water. The magnitude of BOD with respect to total N and P demonstrates the intensity of organic pollution in the system. The removal of silicate in the saline system is clearly visible through factor analysis and the different mode of association of TSS is reflected seasonally. The relationships among the stations are highlighted by cluster analysis, represented in dendograms to categorize different levels of contamination.     

Transport of pollutants in two estuarine systems on the coast of Georgia

The aim of the present study was to examine the distribution of pollutants in two coastal systems in Georgia: (1) Kubitskali river which flows into the Black sea through the city of Batumi and is polluted mainly from the effluents of an oil refinery; (2) Paliastomi lake, which is a shallow water body at the south-east of the city of Poti. During 2000-2001, two samplings took place in each system, one in the low-flow period and one in the high-flow period. During these samplings, pH, temperature, dissolved oxygen, and salinity were measured in situ, whereas water samples were collected for the analysis of trace metals, nutrients, and organic pollutants with standard methods. The results of the measurements indicate the significant pollution of both systems by ammonia and in the case of Kubitskali River also by oil products. The need for a sustainable management plan of the activities taking place in the river basin is urgent.     

Transport of pollutants in two estuarine systems on the coast of Georgia

The aim of the present study was to examine the distribution of pollutants in two coastal systems in Georgia: (1) Kubitskali river which flows into the Black sea through the city of Batumi and is polluted mainly from the effluents of an oil refinery; (2) Paliastomi lake, which is a shallow water body at the south-east of the city of Poti. During 2000–2001, two samplings took place in each system, one in the low-flow period and one in the high-flow period. During these samplings, pH, temperature, dissolved oxygen, and salinity were measured in situ, whereas water samples were collected for the analysis of trace metals, nutrients, and organic pollutants with standard methods. The results of the measurements indicate the significant pollution of both systems by ammonia and in the case of Kubitskali River also by oil products. The need for a sustainable management plan of the activities taking place in the river basin is urgent.     

Seasonal variations in physicochemical characteristics and cyanobacterial diversity of a lake in Northern India

Physicochemical analyses and cyanobacterial diversity of Ramgarh Lake water were performed at five sampling sites during winter, summer, and monsoon seasons. Higher load of solids, carbon, and nutrients were persistent throughout the analysis that indicates the conversion of lake from oligotrophic to eutrophic nature. High nutrients load enhanced cyanobacterial biomass, while low nutrients load produced relatively less biomass. The physicochemical parameters of water samples revealed minimum 2.9 mg L^?1 dissolved oxygen (DO) at site-1 during summer, while maximum (5.6 mg L^?1) at site-4 in monsoon season. Maximum biochemical oxygen demand (BOD) (40 mg L^?1) and chemical oxygen demand (COD) (126 mg L^?1) were recorded at site-1 during summer, whereas minimum BOD (18 mg L^?1) and COD (52 mg L^?1) were evident at site-3 in monsoon season. Minimum concentration of nitrate (0.72 mg L^?1) was recorded at site-3 in summer, whereas maximum 2.7 mg L^?1 was present at site-5 in winter season. The phosphate concentration was maximum (0.52 mg L^?1) at site-5 in summer, and minimum (0.18 mg L^?1) was observed at site-4 in monsoon season. Cyanobacterial diversity was higher during all the seasons, and dominated by the species of Microcystis at all the five sampling sites.     

The Water Quality of Kingston Harbour: Evaluating the Use of the Planktonic Community and Traditional Water Quality Indices

Abstract

Kingston Harbour has been experiencing increased levels of organic pollution since initial ecological assessments in 1971. to develop a new baseline of eutrophication in the Harbour 20 years later, and determine the most appropriate indices to be used in the continued monitoring the area, the water quality of Kingston Harbour was reassessed between December 1992 and 1993, by contemporaneous sampling of traditional water column parameters and planktonic communities at 28 stations within the Harbour. Indices used for water quality assessment were temperature, salinity, light penetration, dissolved oxygen, BOD and nutrients (nitrates-N, phosphate-P and ammonia-N). Results indicated that the planktonic community provided the most reliable index of increased eutrophication and changes in water quality. While physical variables indicated little change in Harbour waters and chemical variables indicated significant but erratic changes, the planktonic community displayed the classic characteristics of eutrophication. Phytoplankton biomass (a maximum of 148 mg m^?3 chlorophyll a) was 5 to 10 times greater than in 1971 while zooplankton abundances (maximum of 80,000 animals m^?3) were 4 times greater. in both cases the community composition had altered and there were fewer taxa than previously found.     

白洋淀芦苇型水陆交错带水化学动态及其净化功能研究

于2007年3月-11月对富营养化湖泊一白洋淀进行了现场调查,分析了温度、溶解氧（DO）、叶绿素、总磷（TP）及其他水化学指标的动态变化规律,并讨论了它们之间的相互关系。结果表明：白洋淀芦苇（Phragmites australis var．baiyangdiansis）型水陆交错带对营养物质具有强烈的截留作用,可以达到净化白洋淀水体的效果。从水质指标的空间分布看,污染较重的府河河口区域其水体TP、化学需氧量（CODc,）含量明显高于污染较轻的湖泊中心区域,空间梯度上呈逐步递减趋势。根据水体盐度、总溶解性固体、TP及DO含量进行聚类分析,可以将采样点分为3类：Ⅰ区、污染较重河口区域;Ⅱ区、中间过渡缓冲区域;Ⅲ区、污染较轻中心区域。Ⅰ区其水体DO含量明显低于Ⅲ区,而水体盐度则明显高于Ⅲ区。通过调查发现：在8月份,白洋淀水体DO含量突然增加;相关分析表明：叶绿素含量与DO（P=0．046）及温度（P〈0．01）之间呈显著正相关关系。结合叶绿素等指标的动态变化规律,8月份左右可能是白洋淀藻类爆发的危险时期。     

潜流人工湿地理化性质及不同形态氮素的空间分布

对潜流人工湿地系统的可溶解氧、pH、氧化还原电位以及水温等理化因子和不同形态氮素的空间分布进行了较全面研究。结果表明,潜流人工湿地上部溶解氧高于下部;湿地下部pH较小,主要在6.9～7.2之间;氧化还原电位表现为上部前端氧化,下部后端还原;湿地装置内下部温度总体比上部要高,前端表现得尤其明显;湿地前端上部是COD和氨氮降解的主要场所,在前端下部区域硝氮的浓度低而亚硝氮、氨氮的浓度相对较高;湿地系统中亚硝氮含量较低,仅在前端中下部有所积累;总氮浓度在湿地前端较高而后端较低,其去除率在根本上依赖于反硝化作用的强度。     

Evaluating the seasonal changes of water quality of the Değirmendere and Galyan Rivers (Trabzon, Turkey)

The De?irmendere and Galyan (De?irmendere tributary) Rivers that discharge their water into the Black Sea are important watersheds in the northeastern part of Turkey. Water quality parameters were sampled from 1997 through 2001 for each year at five sites (three for Galyan, two for Degirmendere) along 29 and 42 km gradients, respectively covering all seasons. Surface water was collected from the sites and analyzed for temperature, total alkaline (MAAL), total dissolved solids (TDS), dissolved oxygen (DO), pH, conductivity (EC), nitrate (NO3), nitrite (NO2), total hardness (TH), phenolphthalein alkalinities (PAL) and organic matter (PV). Seasonal changes of water quality were analyzed statistically for both Rivers and evaluated according to the TS 266, EU and WHO standards. The analysis of variance results showed that Ca, Mg, MAL, NO3, pH, TDS and TH parameters of the De?irmendere River and Ca, DO, EC, MAL, NO3, pH and TH parameters of the Galyan River showed seasonal differences (p<0.05). The maximum values of the water pollution parameters for the two Rivers were below the threshold values throughout the study period. When both Rivers were compared, the mean values of the pollution parameters of the Degirmendere River were higher than those of the Galyan River and very close the limits. The results indicate that both Rivers can be used for the production of potable water during all seasons but only with an advanced treatment in the De?irmendere and a moderate treatment in the Galyan River, and for indirect and non-contact recreational activities.     

Assessment of physico-chemical properties and metal contents of water and sediments of Bodo Creek,Niger Delta,Nigeria

Some physico-chemical properties and the concentrations of the metals Fe, Mn, Ni, Cd, Cr, Co, Cu, Pb, and Zn in water and sediments were examined from September 2011 to January 2012 in Bodo Creek, where oil spills have been recurrent. Temperature, pH, total dissolved solid, conductivity, salinity, dissolved oxygen, biological oxygen demand (BOD), chemical oxygen demand (COD), total hardness, sulfate, nitrate, and phosphate were determined in surface water. Particle size, total organic matter (TOM), and pH were also determined in the sediments. The parameters were within permissible limits except the mean values of BOD, COD, total hardness, and sulfate that exceeded levels permissible for domestic use. The sediments consisted mainly of sand, with TOM ranging from 0.2% to 5.5%. With the exception of cadmium that was below detection limit, metal levels (mg kg^?1) in the sediments were 12 (Mn), 1070 (Fe), 10 (Cu), 10 (Zn), 5.3 (Cr), 1.1 (Pb), 1.0 (Ni), and 0.5 (Co) while in water they were 24, 98, 21, 6.9, 4.0, 0.6, 0.18, and 0.16, respectively. The latter were higher than World Health Organization recommended permissible levels for both surface and drinking water.     

广东省跨市河流边界水质状况研究

对1994--2001年问广东省25个边界水质控制断面的氨氮、生化需氧量和高锰酸钾指数等监测资料进行统计分析，结果显示，全省跨市河流边界水质状况总体上趋于好转，但部分断面有恶化趋势。2001年污染较为严重的边界断面主要有西湖村、企坪、上垟、石碧、青洋大桥及雁田等6个。氨氮污染最为严重。     

Biological treatments of textile industrial effluents in Lagos metropolis, Nigeria

The assessment of the effluents from two textile industries in Ilupeju in Lagos metropolis, Nigeria showed that they were high in conductivity, biochemical oxygen demand (BOD), chemical oxygen demand (COD), total dissolved solids (TDS) and contained traces of heavy metals like Ca, Zn but high concentrations of Cr and Pb. These wastewaters are normally discharged into neighbouring water bodies. Five bacterial groups, namely Micrococcus sp., Enterobacter sp., Alcaligens sp., Bacillus sp. and Acinetobacter sp. were isolated from these effluents. They were used individually for biotreatment and found to be able to utilize the components of the wastewaters for growth, Bacillus sp. and Acinetobacter sp. being the most efficient utilizers as they were able to reduce BOD to zero. The total viable count (TVC) increased significantly depicting growth of the bacterial population. The pH was regulated from 3.4-6.80 for NSF effluent and 12.2-10.29 for STI effluent. The work emphasises the level of industrial pollution in our environment as wastes are indiscrimately dumped into surrounding water bodies in urban areas, the textile industry being a case study. The treatment of any form of waste before disposal into the environment is important and ensures safety of the populace.     

Elemental Analysis of Water and Sediments by External Beam Pixe Part 3: Axios (Vardar) River, Greece

The Axios (Vardar) River originates from the south west part of Yugoslavia, transverses Greece, and discharges into the Thermaikos bay in the north Aegean Sea.

The proton induced X-ray emission (PIXE) method with external beam was used for the elemental analysis of water and sediment samples, while measurements of water temperature, dissolved oxygen content, conductivity, pH, and the water flow were made in situ. Water samples were also analysed for total phosphates, nitrates, chlorophyll, and BOD. The data collected for a 16-month period indicate that the Axios River is polluted as far as the metal content is concerned; its primary productivity is low and it is slightly enriched during its course into the Greek territory.     

袁河水系溶解态痕量金属元素分布特征及来源分析

为研究袁河水系水体溶解态痕量金属元素污染来源与水质状况,分别于2018年7月和2019年1月在袁河干流和支流采集38个表层水样,检测了痕量金属元素Cr、Fe、Mn、As、Al、Cd、Ni和Tl的浓度.采用单因素方差分析分析袁河水系痕量金属元素的时空特征,基于痕量金属元素水质指数评价袁河痕量金属元素污染程度,采用相关分析、主成分分析探讨痕量金属元素污染的主要来源.结果表明,袁河部分金属元素时间或空间差异显著,Cr、Cd、As浓度在丰、枯水期之间差异显著,Fe、Cd、Tl浓度在干、支流之间差异显著.袁河丰、枯水期污染程度相似,主要污染河段位于宜春河段和新余河段,重度污染采样点基本上位于支流.痕量金属元素中Cr、Fe、As主要来源于城市废水,工业活动和采矿活动;Ni、Cd、Tl主要来源于生活污水和工业废水;Mn、Al主要来源于自然活动和采矿活动.本研究可以为袁河流域的痕量金属元素污染治理提供科学依据.     

Seasonal variation assessment of impact of industrial effluents on physicochemical parameters of surface water of River Challawa,Kano, Nigeria

The physicochemical characteristics of the River Challawa in the Kumbotso Local Government Area of Kano State were studied across four seasons (warm and dry, cold and dry, hot and dry, and warm and wet seasons) between October 2006 and August 2008. Physicochemical parameters like pH, electrical conductivity (EC), total dissolved solids (TDSs), total suspended solids (TSS), alkalinity, turbidity, hardness, dissolved oxygen (DO), biological oxygen demand (BOD), chemical oxygen demand (COD), ammonia, chloride, nitrate, sulfate, and phosphate were analyzed and compared with standard permissible limits. The mean range of parameters determined across the seasons revealed: 8.36–8.59 for pH; 209.57–335.27 µS cm^?1 for EC; 134.05–208.5 mg L^?1 for TDS; 182.4–273.45 mg L^?1 for TSS; 125.3–276.07 mg L^?1 for hardness; 16.11–40 mg L^?1 of CaCO₃ for alkalinity; 2.76–3.78 mg L^?1 for DO; 1.9–43.33 mg L^?1 for BOD; 231.67–310.06 mg L^?1 for COD; 221.67–441.67 mg L^?1 for turbidity; 17.98–35.89 mg L^?1 for chloride; 5.12–8.89 mg L^?1 for nitrate; 37–558.83 mg L^?1 for sulfate; and 0.47–0.81 mg L^?1 for phosphate. Data showed that all parameters determined were significantly different among the various sampled sites across seasons. With the exception of COD, EC, and phosphate, all other parameters determined were within the WHO and USPH standard limits.     

Uncertainty analysis on aquatic environmental impacts of urban land use change

Uncertainties hamper the implementation of strategic environmental assessment (SEA). In order to quantitatively characterize the uncertainties of environmental impacts, this paper develops an integrated methodology through uncertainty analysis on land use change, which combines the scenario analysis approach, stochastic simulation technique, and statistics. Dalian city in China was taken as a case study in the present work. The results predict that the Fuzhou River poses the highest environmental pollution risk with a probability of 89.63% for COD in 2020. Furthermore, the Biliu River, Fuzhou River, Zhuang River, and Dasha River have 100% probabilities for NH₃-N. NH₃-N is a more critical pollutant than COD for all rivers. For COD, industry is the critical pollution source for all rivers except the Zhuang River. For NH₃-N, agriculture is the critical pollution source for the Biliu River, Yingna River, and Dasha River, sewage for the Fuzhou River and Zhuang River, and industry for the Dengsha River. This methodology can provide useful information, such as environmental risk, environmental pressure, and extremely environmental impact, especially under considerations of uncertainties. It can also help to ascertain the significance of each pollution source and its priority for control in urban planning.     

人工湿地对有机污染物的去除效果与动态特征

通过对荣成人工湿地污水处理系统1999年1月至2004年12月间监测数据进行分析,确定系统的处理效果及有机污染物去除效果的动态特征。结果表明,人工湿地对SS、COD、BOD5均有很好的去除效果,出水质量浓度分别为27.6±6.6、90.0±12.5和22.7±4.3 mg.L-1,去除率分别为73.9%、63.8%和72.5%。大肠菌群、粪大肠菌群去除率分别为99.7%和99.6%。对NH4 -N和TP去除效果较差,出水质量浓度分别为11.2±2.7和2.03±0.29 mg.L-1,去除率分别为45.1%和30.2%。BOD5、COD的去除效果和季节变化有一定关系,每年的4—7月BOD5去除效果最佳,1月和12月去除效果最差。COD的去除效果每年6月和7月最高,1月和12月最低。分析BOD5、COD和SS去除效果的年际变化发现,BOD5和COD年平均去除率从1999年到2004年有增加的趋势。