PVC塑料型材老化试验与思考

本文针对PVC塑料型材老化现象,从引起PVC塑料型材老化的基本观点、人工老化试验、不同地区气候老化影响、老化导致变色的影响因素等方面进行了讨论,提出了解决PVC塑料型材老化现象意见.     

聚氯乙烯彩色型材耐候性能测试与评价

通过对彩色型材老化性能的全面评价,得出不同的着色工艺如共挤、覆膜、涂装、通体以及不同的色系对老化性能有很大的影响,通体着色以及PVC/PVC共挤彩色型材的耐候性比较差:附着力、剥离强度、色差、冲击强度保留率等指标能比较全面的表征彩色型材的耐候性能.     

我国典型气候环境下塑料老化严酷度表征模型研究

太阳辐照、温度、湿度是影响塑料老化的最主要的环境因素。基于以上的三种环境因素,分别建立模型进行量化分析,形成环境条件对塑料老化的严酷度表征模型。应用模型可以通过两个地点的环境条件推测塑料在两地老化的严酷度,并进行比较。通过开展高分子参考材料(聚苯乙烯和聚碳酸酯)在我国典型气候环境的自然老化试验,采用塑料老化过程的光学性能数据对严酷度模型进行验证,表明严酷度模型能够反应塑料在我国典型气候的老化严酷度。     

2011年塑料制品老化与防老化技术研讨会预备通知

塑料是一种比较容易老化的材料,塑料制品的质量和使用寿命与塑料的老化有着密切关系。因此,在塑料的科研生产和加工应用中,防老化是一项非常重要的技术。随着市场对塑料制品需求的扩大,特别是在建筑材料、汽车部件、电子电器等行业中,对塑料制品的要求也越来越高。为此,中国电器科学研究院工业产品环境适应性国家重点实验室与中国塑料加工工业协会塑料助剂专业委员决定     

光热老化对车用改性聚丙烯耐刮擦性的影响研究

改性聚丙烯被广泛的应用于汽车内外饰件上,是用量最大的车用塑料。但因其表面硬度相对较低,在使用中容易被划伤发白,影响外观。因此,配方中常需添加耐刮擦剂。本文对改性聚丙烯经氙灯光老化和高温热老化后的耐刮擦性进行了研究,发现老化后耐刮擦性出现不同程度的下降。从而对改性聚丙烯长期使用中耐刮擦性能的评估具有一定参考意义。     

影响塑料老化的因素及老化测试研究

塑料广泛用于国计民生的各个领域,但其气候老化导致的产品失效带来巨大的经济损失.导致气候老化的主要因素是日光辐射、温度和水.在日光光谱中,长波紫外具有相对更强的老化能力.在新材料、新工艺的开发中,耐候性的验证是必不可少的.相比自然老化测试,试验室加速老化具有周期短、重复性及再现性好的优点,但仍需不断提高测试的相关性.     

塑料在湿热和亚湿热气候大气暴露与人工加速试验相关性探讨

介绍塑料在海南湿热和广州亚湿热气候大气暴露试验与人工模拟加速试验结果,寻求塑料在不同条件下老化后性能的变化规律,并探讨塑料大气暴露试验与人工模拟加速试验之间性能变化的相关性。     

老化测试为什么您更加需要它

塑料部件的老化测试逐渐成为防止潜在的产品失效的决定性步骤.随着越来越多的原始设备制造商开始向加工商征求设计及材料选择方案,使用过程中的老化失效责任也渐渐地进入了供应链.     

应用于高盐高辐照环境下的钢结构涂层防护行为研究

为研究在严酷环境下涂层对钢结构的防护性能,本文通过对应用于钢结构外表面、内表面以及钢支架的涂层进行了1年的现场暴露试验以及2000h的模拟加速腐蚀试验,积累了涂层在钢结构的老化数据,获取了涂层的腐蚀等级评级。结果表明：现场暴露1年后,载荷尚未产生明显的影响,所有涂层均未出现失光、变色、粉化、开裂、起泡等老化现象;经过2000h盐雾试验后,涂层表面形貌未发生明显变化,涂层未出现起泡、开裂和出锈等现象,表明涂层具有良好抗盐雾和水汽的渗透能力;经过2000h紫外老化试验后,涂层均未出现严重的老化现象,但都出现了不同程度的变色和粉化现象。     

耐候ABS材料研究

通过自然气候老化和紫外老化试验UV-B,研究了ABS塑料外观颜色、力学性能在老化实验过程中的变化.试验结果表明:光稳定剂的加入,ABS耐候性能提高,相较未加光稳定剂ABS体系,AE值下降,冲击保持率提高,受阻胺光稳定剂A和紫外光吸收剂B、C并用有协同作用,光屏蔽剂的使用可以提高耐候性,从而降低成本.此外我们讨论了自然气...     

PVC-based composite material containing recycled non-metallic printed circuit board (PCB) powders

The study is directed to the use of non-metallic powders obtained from comminuted recycled paper-based printed circuit boards (PCBs) as an additive to polyvinyl chloride (PVC) substrate. The physical properties of the non-metallic PCB (NMPCB) powders were measured, and the morphological, mechanical and thermal properties of the NMPCB/PVC composite material were investigated. The results show that recycled NMPCB powders, when added below a threshold, tended to increase the tensile strength and bending strength of PVC. When 20 wt% NMPCB powders (relative to the substrate PVC) of an average diameter of 0.08 mm were added, the composite tensile strength and bending strength reached 22.6 MPa and 39.83 MPa, respectively, representing 107.2% and 123.1% improvement over pure PVC. The elongation at break of the composite material reached 151.94% of that of pure PVC, while the Vicat softening temperature of the composite material did not increase significantly compared to the pure PVC. The above results suggest that paper-based NMPCB powders, when used at appropriate amounts, can be effective for toughening PVC. Thus, this study suggests a new route for reusing paper-based NMPCB, which may have a significant beneficial environmental impact.     

Polyvinyl chloride used as a chlorinating and a reducing agent

Polyvinyl chloride (PVC) or vinyl is a recyclable material. It can be used as a chlorinating and a reducing agent. Two tests of chlorination and reduction of two different samples of jarosite and hematite were realized using PVC, results are presented in this paper. The chlorination test shows that the HCl gas produced from PVC and heated at ≈250°C can be used as a chlorine source to recover as chlorinated compounds the valuable metals such as Zn, Pb contained in jarosite. The XRD reveals the presence of lead and zinc chlorides in the condensates obtained. The second test of reduction was conducted using a mixture of PVC and hematite treated in a nitrogen atmosphere between 200 and 1000°C. The results show that at low temperature, PVC produces HCl and with kinetic consideration, no reactions can be observed with hematite. However, at high temperature, the weight of the hematite sample decreases by ≈15%, due to the reduction of hematite to iron metal.     

新疆化工企业清洁生产潜力分析——以新疆中泰化学华泰重化工有限责任公司为例

在对清洁生产潜力分析方法简要介绍的基础上,引入Umberto（R）物流管理软件,对华泰化工公司PVC生产线进行建模分析、评估,查找浪费环节,提高企业资源能源利用水平,同时为其它企业进行类似分析提供思路。     

Gas-phase sorption-desorption of propargyl bromide and 1,3-dichloropropene on plastic materials

The goal of this research was to provide information for choosing appropriate materials for studying gas-phase concentrations of propargyl bromide (3BP) and 1,3-dichloropropene (1,3-D) in laboratory experiments. Several materials were tested and found to sorb both gas-phase chemicals in the following order: stainless steel (SS) < Teflon polytetrafluoroethylene (PTFE-FEP) approximately flexible polyvinyl chloride (PVC) approximately acrylic < low-density polyethylene (PE) < vinyl approximately silicone < polyurethane foam (PUF). Sorption of SS was insignificant and PUF sorbed all the fumigant that was applied. For the other materials, linear sorption coefficients (Kd) for 3BP ranged from 3.0 cm3 g(-1) for PVC to 215 cm3 g(-1) for silicone. Freundlich sorption coefficients for 1,3-D ranged from 11.5 to 371 cm3 g(-1). First-order desorption rate constants in an open system ranged from 0.05 to 1.38 h(-1) for 3BP and from 0.07 to 1.73 h(-1) for 1,3-D. In a closed system, less than 2% of sorbed fumigant desorbed from vinyl while up to 99% desorbed from PVC within 24 h when equilibrated at the highest headspace concentration. Sorption of both fumigants was linearly related to the square root of time except for vinyl and silicone. This may indicate non-fickian diffusion of fumigant into the polymer matrix. Vinyl, silicone, PE, and PUF should be avoided for quantitative study of organic gases, except possibly as a trapping medium. Use of PTFE, PVC, and acrylic may require correction for sorption-desorption and diffusion.     

Environmental life cycle assessment of different types of the municipal wastewater pipeline network

With the onset of social life, humans have considered waste disposal as essential, and they have been able to repel it through brick and clay channels. Checking sewage pipes for energy consumption and a longer lifetime than other sewage system components is important. Climate change and exploitation of industrial resources have made environmental impacts, which are important factors in decision making. The purpose of this study was to introduce the most suitable type of sewage pipe considering environmental protection. Therefore, we applied the environmental life cycle assessment (LCA) method, using Sima Pro 8.2.3 software for the one-kilometer length of concrete pipes (300 mm in diameter), Polyvinyl chloride (PVC), and polyethylene (PE) (315 mm in diameter). Also, the BEES method and sensitivity analysis were used to validate the results. The comparison between three types of municipal wastewater pipes indicated that PE pipes are a more environmentally friendly option than PVC, and concrete pipes in pipe recycling, reducing extraction from untapped resources, and inefficient extraction of resources. Electricity, diesel fuel, and sulfate resistance cement consumption for concrete production are the most pollution elements in the LCA of concrete pipes. Usage of PVC granular, sanitary landfill of PVC pipes, and using hydraulic drill in LCA of PVC pipes are the most elements of generating pollution. The usage of PE granules, PE pipes landfilling, hydraulic excavator, and electricity consumption in the LCA of the PE pipes are the greatest polluting parameters.     

Industrial metabolism of PVC in China: A dynamic material flow analysis

In China, the rapid development of the polyvinylchloride (PVC) industry will inevitably lead to various environmental problems. This paper studies the PVC metabolism further by (1) constructing dynamic models based on material flow analysis (MFA), (2) introducing calculation on detailed lifetime distribution of different types of products and recycling, and (3) obtaining the performances of waste emissions and accumulation as a function of raw material input and time. Based on system evolution theory and population development models, the developing trend of the PVC industry is studied, and annual consumptions in future years are predicted. The annual emission and accumulation after metabolism can be calculated by tracking the amount of raw material input, existing form and process flow for a single year (2003), as well as over a longer period (from 1958 to 2048) in China. Analysis indicates that over 0.6 billion tons of PVC waste will have accumulated in the environment by the end of 2050. In this scenario analysis, the effects of product structure, lifetime distribution, mechanical recycling, chemical recycling and incineration on waste output are all taken into consideration. The product metabolism process can be decelerated by changing these factors appropriately. However, mechanical recycling and chemical recycling are the most effective solutions.     

A Constructal Approach to the Optimal Design of Photovoltaic Cells

The constructal law is used for the minimization of the photovoltaic cells (PVC) electrical series resistance. In this paper we report a theoretical, step by step construction of optimal PVC, from the smallest, elemental cell to the largest assembly that relies on the minimisation of the maximum voltage drop subject to volume (material) constraints. This completely deterministic approach produces optimal geometric shape for each assembly level, the optimal number and orientation of constituents within each new, higher order assembly and the optimal size of each new collector (metallic) path.     

基于GIS的我国农村老年人口时空发展研究

以2000年、2003年、2006年和2009年4个时间点的农村老年人口数据为基础,从农村老年人口系数、老少比和养老负担3个指标对我国大陆31个地区的农村老年人口状况做了时间和空间上的对比分析。结果表明,农村老龄化发展迅速且从东部向中西部快速递进,农村老龄化的集中程度趋于降低。