Monte Carlo based calibration of scintillation detectors for laboratory and in situ gamma ray measurements

The calibration of scintillation detectors for gamma radiation in a well characterized setup can be transferred to other geometries using Monte Carlo simulations to account for the differences between the calibration and the other geometry. In this study a calibration facility was used that is constructed from bricks of well-known activity concentrations of ⁴⁰K and of radionuclides from the ²³⁸U- and ²³²Th-series. Transfer of the calibration was attempted to a Marinelli beaker geometry with the detector inside a lead shield and to an in situ application with the detector positioned on a sand bed. In general this resulted in good correspondence (within 5-10%) between the activity concentrations derived using the transferred calibration and activities that were derived by independent measurements. Some discrepancies were identified that were attributed to coincident summing in the natural decay series and interference of radon.     

Characterization of phosphogypsum wastes associated with phosphoric acid and fertilizers production

The present work is directed to characterize the phosphogypsum (PG) wastes associated with phosphoric acid produced by the wet process in industrial facility for the production of fertilizers and chemicals in Egypt. The PG waste samples were characterized in terms of spectroscopic analysis (X-ray diffraction, X-ray fluorescence, IR spectra) and radiometric analysis (γ- and α-measurements). The γ-ray measurements showed that the average activity concentrations are 140 ± 12.6, 459 ± 36.7, 323 ± 28.4, 8.3 ± 0.76 and 64.3 ± 4.1 Bq/kg for U-238, Ra-226, Pb-210, Th-232 and K-40, respectively. The α-particle measurements of uranium isotopes showed that the average activity concentrations of U-238, U-235 and U-234 were 153 ± 9.8, 7 ± 0.38, 152 ± 10.4 Bq/kg, respectively. The average radiochemical recovery (%) of the destructive α-particle measurements is ∼70% with a resolution (FWHM) of ∼30 keV. Activity ratios of U-238/Ra-226 and U-238/Pb-210 were less than unity (i.e., <1) and equal to 0.31 ± 0.02 and 0.47 ± 0.16, respectively. The isotopic ratios of U-238/U-235 and U-238/U-234 (in PG and PR samples) were close to the normal values of ∼21.7 and ∼1, respectively and are not affected by the wet processing of phosphate rock (PR). The obtained results of PG waste samples were compared with phosphate rock (PR) samples. The radiation hazard indices are namely, radium activity index (Ra-Eq > 370 Bq/kg), total absorbed gamma dose rate (D_γr > 5 nGy/h) and radon emanation fraction (Rn-EF > 20%). Uncertainty of the sample counting was 95% confidence level of σ. The results indicated the necessity to find suitable routes to decrease and/or redistribute the radionuclide of environmental interest (i.e., Ra-226) in PG wastes, consequently to reduce its radiation impacts in the surrounding environment.     

西部地区促进农民工就业的产业选择

金融危机后,西部地区存在大量返乡农民工和就地转移的农村富余劳动力,农民工亟待"就业"与企业亟待"用工"凸显西部地区劳动力市场矛盾和产业结构偏差。西部地区调整产业偏差,进行慎密的产业选择,成为必然。通过构建农民工产业供求模型,对农民工产业流向进行理论分析,表明在区域工业化初期向工业化中期的过渡期以及在工业化中期,重化工业和高端技术产业对资本和技术的偏好,限制了劳动力从农业向非农产业的转移;通过运用比较分析法,考察西部产业选择的宏观与微观条件,透析出西部的资源特点、产业发展现状、城镇化水平、非农产业收入状况、非农产业就业吸纳能力。在理论模型推导和现实社会经济状况分析基础上,提出了产业选择思路和选择结果,即西部地区应重点发展技术—劳动密集型制造业、技术—劳动密集型农产品加工业、技术—劳动密集型服务业、旅游和旅游服务业和公益事业。     

Effect of soil texture on surfactant-based remediation of hydrophobic organic-contaminated soil

Surfactants may be used in remediation of subsoil and aquifer contaminated with hydrophobic compounds. The objectives of this study were to examine the effect of soil texture on hydrophobic organic contaminant (HOC; toluene, or 1,2,4-trichlorobenzene [TCB]) removal from six soils and to evaluate the optimal composition of soil texture for maximum HOC removal using aqueous surfactant solution. Selected surfactants were 4% (vol/vol) sodium diphenyl oxide disulfonate (DOSL) and 4% (wt/vol) sodium lauryl sulfate (LS). Toluene and TCB were selected as the lighter-than-water nonaqueous phase liquid (LNAPL) and denser-than-water nonaqueous phase liquid (DNAPL) model substances, respectively. Soil types used for this study were Ottawa sand and five Iowa soils (Fruitfield, Keomah, Crippin, Webster, and Galvar). The greatest recovery of toluene and TCB in batch tests was 73% and 84%, respectively, which was obtained with DOSL surfactant in Ottawa sand. The toluene removal of 95% in column tests has been achieved in the Ottawa sand and three Iowa soils (Fruitfield, Keomah, Crippin) with DOSL after effluent volume of 3750 ml (about 32 pore volume) passed. TCB removal of 98% in column tests has been achieved in Ottawa sand and three Iowa soils (Fruitfield, Keomah, Crippin) with DOSL after effluent volume of 2500 ml (about 21 pore volume) passed. These results were related with soil texture (clay content 30%), clay mineralogy (kaolinite and smectite), as a function of transported pore volume.     

238U series isotopes and 232Th in carbonates and black shales from the Lesser Himalaya: implications to dissolved uranium abundances in Ganga-Indus source waters

238U and (232)Th concentrations and the extent of (238)U-(234)U-(230)Th radioactive equilibrium have been measured in a suite of Precambrian carbonates and black shales from the Lesser Himalaya. These measurements were made to determine their abundances in these deposits, their contributions to dissolved uranium budget of the headwaters of the Ganga and the Indus in the Himalaya and to assess the impact of weathering on (238)U-(234)U-(230)Th radioactive equilibrium in them. (238)U concentrations in Precambrian carbonates range from 0.06 to 2.07 microg g(-1). The 'mean' U/Ca in these carbonates is 2.9 ng U mg(-1) Ca. This ratio, coupled with the assumption that all Ca in the Ganga-Indus headwaters is of carbonate origin and that U and Ca behave conservatively in rivers after their release from carbonates, provides an upper limit on the U contribution from these carbonates, to be a few percent of dissolved uranium in rivers. There are, however, a few streams with low uranium concentrations, for which the carbonate contribution could be much higher. These results suggest that Precambrian carbonates make only minor contributions to the uranium budget of the Ganga-Indus headwaters in the Himalaya on a basin wide scale, however, they could be important for particular streams. Similar estimates of silicate contribution to uranium budget of these rivers using U/Na in silicates and Na* (Na corrected for cyclic and halite contributions) in river waters show that silicates can contribute significantly (approximately 40% on average) to their U balance. If, however, much of the uranium in these silicates is associated with weathering resistant minerals, then the estimated silicate uranium component would be upper limits.Uranium concentration in black shales averages about 37 microg g(-1). Based on this concentration, supply of U from at least approximately 50 mg of black shales per liter of river water is needed to balance the average river water U concentration, 1.7 microg L(-1) in the Ganga-Indus headwaters. Data on the abundance and distribution of black shales in their drainage basin are needed to test if this requirement can be met. (234)U/(238)U activity ratios in both carbonates and black shales are at or near equilibrium, thus preferential mobilization of (234)U from these deposits, if any, is within analytical uncertainties. (230)Th is equivalent to or in excess of (238)U in most of the carbonates. (230)Th/(238)U>1 indicates that during weathering, uranium is lost preferentially over Th. (232)Th concentrations in carbonates are generally quite low, <0.5 microg g(-1), though with a wide range, 0.01-4.8 microg g(-1). The variation in its concentrations seem to be regulated by aluminosilicate content of the carbonates as evident from the strong positive correlation between (232)Th and Al.     

The potential for sand dams to increase the adaptive capacity of East African drylands to climate change

Drylands are home to more than two billion people and are characterised by frequent, severe droughts. Such extreme events are expected to be exacerbated in the near future by climate change. A potentially simple and cost-effective mitigation measure against drought periods is sand dams. This little-known technology aims to promote subsoil rainwater storage to support dryland agro-ecosystems. To date, there is little long-term empirical analysis that tests the effectiveness of this approach during droughts. This study addresses this shortcoming by utilising multi-year satellite imagery to monitor the effect of droughts at sand dam locations. A time series of satellite images was analysed to compare vegetation at sand dam sites and control sites over selected periods of drought, using the normalised difference vegetation index. The results show that vegetation biomass was consistently and significantly higher at sand dam sites during periods of extended droughts. It is also shown that vegetation at sand dam sites recovers more quickly from drought. The observed findings corroborate modelling-based research which identified related impacts on ground water, land cover, and socio-economic indicators. Using past periods of drought as an analogue to future climate change conditions, this study indicates that sand dams have potential to increase adaptive capacity and resilience to climate change in drylands. It therefore can be concluded that sand dams enhance the resilience of marginal environments and increase the adaptive capacity of drylands. Sand dams can therefore be a promising adaptation response to the impacts of future climate change on drylands.     

长江三峡水库水污染控制若干问题

论述了三峡水库几个重要水环境问题,对近年来三峡水库水污染控制科学研究工作进行回顾,评述了一些重要研究成果,就三峡水库水质模拟、水体富营养化、水库泥沙截留淤积和重金属污染等问题进行了深入探讨。基于国际水协会最新推出的河流水质模型,提出了三峡水库水环境模拟研究的观点和方法;基于湖泊（水库）生态动力学模型原理,在对水体中磷元素预测的基础上,从营养盐含量、水深、流速、温度因素等与富营养化非线性映射关系出发,初步建立三峡水库水体富营养化人工神经网络模型,对三峡水库水体富营养化潜势进行研究,分析讨论了一些初步结果;论述了水库泥沙截留淤积及其与水体中污染物,特别是重金属污染的相互作用;建议三峡水库近期内应予以重视的一些重要水环境科学问题。     

Contribution of the sugar cane industry to reduce carbon dioxide emissions in the energy sector: the case of Mauritius

The aim of this paper was to present the contribution of the sugar cane industry to reduce carbon dioxide emissions in the energy sector. Mauritius is taken as a case study. Sugar cane was introduced in Mauritius during the seventeenth century and production of sugar started around 60 years later. Since then, the cane industry has been one of the economic pillars of the country. Bagasse, a by-product of sugar cane, is used as fuel in cogeneration power plants to produce process heat and electricity. This process heat and the generated electricity are used by an annexed sugar mills for the production of sugar, while the remaining electricity is exported to the national grid. In fact, Mauritius is a pioneer in the field of bagasse-based cogeneration power plant; the first bagasse-based cogeneration power plant that was commissioned in the world was in Mauritius in 1957. The contribution of the cane industry in the electricity sector has been vital for the economic development of Mauritius and also in terms of mitigating carbon dioxide emissions by displacing fossil fuels in electricity generation, as bagasse is classified as a renewable source. Data obtained from Statistics Mauritius on electricity production for the past 45 years were analysed, and carbon dioxide emissions were calculated based on international norms. It is estimated that savings on heavy fuel oil importation were by 1.5 million tons of oil—representing a value of 2.9 billion dollars—thus avoiding 4.5 million tons of carbon dioxide emissions. This figure can be further increased if molasses, a by-product of sugar cane juice, is used to produce bio-ethanol to be used as fuel in vehicles.     

Strategic assessment of the magnitude and impacts of sand mining in Poyang Lake, China

Planning for the extraction of aggregates is typically dealt with at a case to case basis, without assessing environmental impacts strategically. In this study we assess the impact of sand mining in Poyang Lake, where dredging began in 2001 after sand mining in the Yangtze River had been banned. In April 2008 concern over the impact on the biodiversity led to a ban on sand mining in Poyang Lake until further plans could be developed. Planning will require consideration of both sand extraction in relation to available sediment resources and also environmental impacts within the context of future demand for sand in the lower Yangtze Valley. We used pairs of near-infrared (NIR) Aster satellite imagery to estimate the number of vessels leaving the lake. Based on this we calculated a rate of sand extraction of 236 million m³ year⁻¹ in 2005–2006. This corresponds to 9% of the total Chinese demand for sand. It qualifies Poyang Lake as probably the largest sand mining operation in the world. It also indicates that sand extraction currently dominates the sediment balance of the lower Yangtze River. A positive relation between demand for sand and GDP, revealed by historic data from the USA, suggests that the current per capita demand for sand in China might increase in the near future from 2 to 4 m³ year⁻¹. We review various environmental impacts and question whether it will be possible to preserve the rich biodiversity of the lake, while continuing at the same time satisfying the increasing Chinese demand for sand. Finally we review alternative options for sand mining, in order to relieve the pressure from the Poyang Lake ecosystem.     

Determination of depleted uranium in environmental samples by gamma-spectroscopic techniques

The military use of depleted uranium initiated the need for an efficient and reliable method to detect and quantify DU contamination in environmental samples. This paper presents such a method, based on the gamma spectroscopic determination of 238U and 235U. The main advantage of this method is that it allows for a direct determination of the U isotope ratio, while requiring little sample preparation and being significantly less labor intensive than methods requiring radiochemical treatment. Furthermore, the fact that the sample preparation is not destructive greatly simplifies control of the quality of measurements. Low energy photons are utilized, using Ge detectors efficient in the low energy region and applying appropriate corrections for self-absorption. Uranium-235 in particular is determined directly from its 185.72 keV photons, after analyzing the 235U-226Ra multiplet. The method presented is applied to soil samples originating from two different target sites, in Southern Yugoslavia and Montenegro. The analysis results are discussed in relation to the natural radioactivity content of the soil at the sampling sites. A mapping algorithm is applied to examine the spatial variability of the DU contamination.     

Sand winning in Dormaa as an interlocking of livelihood strategies with environmental governance regimes

In this article, the attempt is made to address regime interaction in environmental governance by emphasising human livelihood action as a causal factor in this interaction. The paper elucidates how governing human behaviour on environmental resources is a process of interaction between different environmental governance regimes. With a qualitative case study of sand winning in the Dormaa Municipality and Dormaa East district in midwestern Ghana, the article shows strategic ways landowners and sand vendors pursue and legitimise their livelihood, and in the process bring about interaction between a tax regime on sand winning and the customary property rights regime of the area. It notes therefore that regime interaction is not only caused by differences in the structure of institutions, but also through the ways humans act to pursue their livelihoods. Based on this, the paper highlights the need for consciousness towards livelihoods of people and how such livelihoods are pursued as important contexts within which regimes function and interact. In this way, environmental governance can be more responsive to the well-being of people.     

环保产业：实现可持续发展的朝阳产业

可持续发展的绿色需求是促进环保产业成为朝阳产业的根本动力，本文在分析国内外绿色需求与绿色市场状况的基础上，提出了甸发展绿色高科技等建议。     

Characteristics, spatial distribution and vertical profile of gamma-ray emitting radionuclides in the coastal environment of North Sinai

Radionuclide concentrations of beach and dune sand from various sites in Al-Arish city and surrounding area, North Sinai, Egypt, were measured. The sampling sites included locations in the local harbor, Al-Arish valley and Zaranik protected area. The results indicate that the activities of the products of (232)Th and (226)Ra series in samples from the harbor and along the beach were higher than those from non-coastal sites. The activity concentrations of (232)Th for beach sand ranged from 2.3 to 506.5 Bq/kg with an average of 83.4 Bq/kg, while that for dune sand ranged from 2.2 to 15.1 Bq/kg with an average of 6.4 Bq/kg. The average activity concentration of (226)Ra for beach sand was 56.0 Bq/kg (2.9-261.5 Bq/kg), while that for dune sand was 6.5 Bq/kg (3.0-14.7 Bq/kg). The average activity concentrations of (40)K for beach and dune sand were 88.1 Bq/kg and 178.4 Bq/kg, respectively. Six depth profiles in the harbor area were measured up to a depth of 1m within more than two years. These sets of measurements allowed the determination of the migration rate of black sand to be 0.094 cm/day. Samples with the smallest grain size (<0.2 mm) were found to have the highest level of activities, which were attributed to their high content of black sand. No risk exists for public health based on the calculated effective dose equivalent and the recommended limit of 5 mSv/y. On the other hand, local children and adults may receive doses higher than this recommended limit in two locations in the Zaranik protected area according to a model developed in this study.     

Comparative assessment of natural radioactivity in fallout samples from Patras and Megalopolis, Greece

Bulk deposition samples were collected simultaneously from two Greek cities, Patras and Megalopolis, with different emission sources of natural radioactivity, on a monthly basis, during a whole year. Gross beta-activity and 238U- and 232Th-activities were determined in a total of 95 samples of deposited dust. The results were statistically analyzed in order to determine the natural radioactivity levels and their variations in the above cities. No significant difference was found in deposited dust amount between the two cities, while the values of gross beta-, 238U- and 232Th-activities were about 3, 71 and 4 times higher in Megalopolis than in Patras, respectively. This was attributed to the operation of lignite power plants A and B in the vicinity of the city of Megalopolis, while natural radioactivity concentrations in Patras' fallout samples were of natural sources.     

Policy-adaptation for a smarter and more sustainable EU electricity distribution industry: a foresight analysis

The European Union (EU) transition to a smarter and more sustainable electricity sector is driven by climate change adaptation and technological developments. For the electricity distribution industry, this has contributed to a growing need to understand how these network monopolies should adapt their role, activities, and responsibilities for a redesigned electricity market, given the growth of distributed generation, and the increased control and monitoring capabilities. Considering this, a foresight study on business model innovation, technological adaptation, and market design policy alternatives is presented. A Policy Delphi method was applied, involving two iterative survey rounds and 207 European experts, which assessed 57 policy alternatives. The results highlight adaptation challenges for implementing new technologies and business practices. Experts support innovation and transition to new roles, and innovative services, while warranting that core electricity distribution activities are secured. This shift in roles is expected to be achieved through research and development (R&D) support policies, innovation friendly regulatory frameworks, and concerted actions at the EU and Member States level. The results provide policy-adaptation guidelines for electricity distribution industry stakeholders.     

Removal of hydrocarbons from Nile water

The need to remove hydrocarbons from water supply sources raises questions on the efficiency of the present water treatment processes in removing hydrocarbons. Therefore, the effectiveness of physicochemical processes involving chlorination, chemical coagulation and sand filtration were investigated. The effect of variable filtration media was also examined. In addition, the use of an activated carbon column was considered, and the effect of different retention times was evaluated. Results of this study showed that chemical coagulation using alum and Nalco removed only 32% of the total hydrocarbons and 80% of turbidity. Use of sand and a mixture of anthracite and sand filters showed additional removal of hydrocarbons and turbidity during the continuous filtration process. Increasing the anthracite depth relative to the total effective filtration depth increases the efficiency of the filter. Adsorption on granular activated carbon was shown to be an effective means for the removal of hydrocarbons. Results obtained indicated that the carbon adsorption capacity increases linearly as the retention time increases.     

农户对生物质能源产业参与意愿实证分析——以湖北省为例

生物质能源一直是人类赖以生存的重要能源，它是仅次于煤炭、石油和天然气而居于世界能源消费总量第四位的能源，在整个能源系统中占有重要地位。生物质能源产业的发展不仅仅需要产品生产企业、政府相关机构的参与，微观个体农户同样扮演着至关重要的角色。农户对生物质能源产业的态度和行为，会对政府和生产者的行为选择产生深刻影响。以湖北农户对生物质能源产业的参与意愿的调查为例，运用因子分析法，对农户对生物质能源产业参与意愿和参与行为的影响因素进行分析。分析结果表明：预期收益、年均纯收入、环保意识、文化程度、配套设备生产情况、产品技术成熟度、相关政策支持、商品能源使用率、当地生物质资源量9个因素会影响农户参与意愿。提出了相应的建议：一是提高农户对生物质能源的预期收益和农户收入水平；二是从根本上提高农户综合素质，增强环境保护意识；三是完善生物质能源产业技术、政策支撑体系，合理开发利用生物质资源     

Transuranium radionuclide pollution in the waters of the La Maddalena National Marine Park

Following the grounding and subsequent explosion, in October 2003, of a nuclear submarine in the waters of the La Maddalena National Marine Park, fears arose of possible radioactive leakages. However, isotopic analyses on algae showed that the gamma-ray emitting artificial radionuclides that one might expect to leak from a damaged nuclear reactor (such as U-235, I-131, Cs-137) were absent, and that U-238/U-234 activities were in equilibrium with values typical of sea water; this excluded any direct anthropogenic contamination as a result of the accident. We used alpha autoradiographic techniques to detect possible traces of transuranium radionuclides; 160 samples of algae, granites, sea urchins, gastropods, limpets, cuttlefish and jellyfish were collected from the area, as well as from other Mediterranean coastlines and the Baltic Sea. All samples were autoradiographed, and selected samples further analysed by alpha spectrometry. There were no alpha track concentrations above background levels in our control Mediterranean specimens. In the samples from the La Maddalena and Baltic areas two different track distributions were observed: --those homogeneously distributed over the surfaces examined; --groups (10 to over 500) of radially distributed alpha tracks (forming "star" bursts, or "hot spots") emanating from point sources. By comparing radionuclide activities measured by alpha spectroscopy with alpha track densities, we extrapolated Pu activities for all samples. About 74% of algae had Pu activities of less than 1 Bq/kg and 0.25 Bq/kg, 16% had accumulated Pu to levels between 1 and 2 Bq/kg, and a very few specimens had concentrations between 2 and 6 Bq/kg. Plots showed that alpha tracks and stars concentrate around the northern and eastern margins of the Rada (Basin) di Santo Stefano, sites facing the nuclear submarine base on the eastern shore of the island of Santo Stefano. What is the source of these nuclides: last century's atmospheric nuclear testing, Chernobyl or a local source? Their concentrated, extremely localised occurrence seems difficult to explain in terms of left-over worldwide nuclear pollution. A local source seems more plausible.     

Energy efficiency in the automotive industry evidence from Germany and Colombia

This paper presents an analysis of energy efficiency performance in the automotive industry from evidence of Germany and Colombia in order to show important features in energy use between countries with the different income between 1998 and 2007. We found that the automotive industry improved its energy efficiency in each country. In order to understand the driving forces behind these trends, the concept of the production function is used to obtain the elasticities of substitutions and the relationships between several variables and energy efficiency performance in German and Colombian motor vehicle industries. In both countries, we found that the variables of energy prices and sizes of companies each have a positive influence on the efficiency of the gross production/energy ratio. These results show that, in the motor vehicle industry, energy efficiency performance depends on different factors. Hence, variables such as energy prices, energy taxes, economies of scale and technology changes have played a crucial role in the improvements in productivity and rational energy use.     

快递废弃物回收产业链演化仿真研究

近年来,随着电子商务的迅速崛起,快递废弃物激增所带来的环境污染、资源浪费程度日趋严重,营建快递废弃物回收产业链,促进快递废弃物循环使用的呼声日益急促。快递废弃物的循环使用涉及到多方利益相关者,本文基于利益主体协同演化视角,分别构建未引入政府约束机制和引入政府约束机制的"快递企业-消费者"演化博弈模型,借以探索政府、消费者及快递企业在快递废弃物回收产业链营建过程中所扮演的角色,借助复制动态方程得到利益相关方的演化稳定策略和规律,并进一步应用MATLAB仿真工具进行仿真模拟,研究结果表明:未引入政府约束机制下,博弈系统难以依靠市场调节快速演化到理想状态,快递企业和消费者会反复权衡参与营建快递废弃物回收产业链的收益和成本,根据净收益进行策略选择,当二者净收益大于0时,博弈系统会逐渐演化为理想状态,反之,博弈系统则会逐渐演化为不良状态。引入政府约束机制可以快速的引导快递企业和消费者向理想状态演化,加大对快递企业营建回收产业链的补贴力度以及对营建回收产业链怠工的罚款程度能够促进快递废弃物回收产业链营建的快速高效执行。本文的研究对快递废弃物回收产业链的营建起到一定的启示作用:1从政府的角度出发,快递废弃物回收产业链的成功营建能够带来社会环境资源福利的增加,所以不应仅仅依靠市场行为,政府应当充分发挥其在营建过程中的引导作用;2从快递企业的角度出发,快递企业是回收产业链的实施方,应将环境保护作为企业发展的责任,积极主动参与回收产业链的营建;3从消费者的角度出发,作为回收产业链运行的初始点,消费者应该从自身做起,提高环保意识,责任意识,积极推动回收产业链的营建。