A chemical substitution study for a wet processing textile mill in Turkey

Wet processing textile industry has many different processing stages (dyeing, sizing, de-sizing, scouring, softening, etc.). Many chemicals currently used in the wet processing textile industry affect the amount and the type of waste produced and their influence on the aquatic life of the receiving stream. One of the critical steps in pollution prevention studies is auditing the use of chemicals and making the necessary chemical substitutions. This chemical substitution study was conducted on one of the major textile factories in Turkey with a capacity of 20,000 tons of denim fabric per year. During this study, chemical consumption level, receipts applied, environmentally problematic and alternative chemicals were examined. Integrated Pollution Prevention and Control (IPPC) Reference Document on Best Available Techniques (BAT) for the Textiles Industry was accepted as main reference document and also related case studies were examined. According to the study, over 70% reduction in sulphide, which is very toxic to aquatic life, was achieved by replacing sulphur dyestuff with low sulphide content. By replacing an alternative complexing agent, the mill not only prevented the 3100 kg/month COD load to the wastewater treatment plant (WWTP), but also obtained more biodegradable wastewater generated during production. On the other hand, some of the chemical substitution options were on progress or dropped.     

水解酸化-深井曝气-脱气-二沉池工艺处理印染废水工程实例

对某纺织企业污水站进行改造,由于用地紧张,将污水站生物接触氧化工艺改造成深井曝气工艺,大大节约了土地资源,并且有较好的处理效果。深井曝气具有抗冲击能力强、氧利用率高、管理方便、运行稳定、低能耗、占地省等优点,因此越来越多的被应用到印染纺织废水的处理中。但也存在着缺点:污泥龄比较短,硝化效果比较差,导致脱氮能力不强,污泥的稳定程度比低负荷工艺低,钻井技术要求也相对较高等。总之,深井曝气工艺是一种先进的处理工业废水的新工艺,若能扬长避短,将会得到广泛应用。     

印染废水处理的工艺选择

纺织印染行业是工业废水排放大户.印染废水含有多种染料、浆料、表面活性剂等助剂,具有水量大、有机污染物浓度高、可生化性较差、色度高且多变、碱性大、水质水量变化大、成分复杂等特点.随着印染工艺和产品结构的改变,印染水质也发生了变化,印染废水的处理难度也随之加大.根据多年处理印染废水实践经验,本文总结提出:"强化生物吸附 厌氧水解酸化 好氧生化处理"工艺是比较经济适用的印染废水处理技术,并以某企业10000 m3/d印染废水处理工程为例对该工艺进行了深入的介绍.     

不同来源废水中TOC与COD相关性研究

对纺织染整、化工、制药、食品加工各行业生产废水及城镇污水厂处理设施出水中的TOC(自动仪器监测)与COD(实验室手工分析)测定值进行回归分析,并检验一元线性回归方程的显著性和有效性。结果表明,各行业生产废水中TOC与COD值均存在非常显著的相关性,且废水组成成分越单一稳定,其相关性越好,同行业废水中TOC与COD回归方程的斜率b较为接近。利用TOC自动在线监测值换算所得的COD值,准确性和稳定性高,能满足水质实时连续监测的需要。     

微电解法处理印染废水的研究

本文对微电解法处理印染废水进行了试验研究．对含有直接、活性和硫化染料的印染废水，ＣＯＤ去除率可达７０％以上，脱色率可达９０％以上．得出了电压、停留时间与处理效率和能耗之间的关系．试验说明，微电解法处理印染废水是一种高效、低耗、经济可行的方法．     

印染废水的透视度与SS色度相关性研究

文章探讨了印染废水的透视度与SS、色度的相关性。分别对活性、分散、直接染料的染色液、模拟印花浆液进行研究,发现对分散染料残液及浆液无法用单纯的过滤来去除色度与SS,必须通过混凝、电解、生化等方法来解决。     

白酒酿造污水生化处理方法研究

针对白酒酿造中产生的污水处理方法问题,文中介绍了实验材料与方法,主要包括酿酒污水来源、酿酒污水处理工艺、酿酒污水试验装置的启动和分析方法的介绍,给出了结果与讨论,主要包括污水中CODcr的变化情况、污水中总氮变化情况、污水中氨氮变化情况、污水中固形物变化情况、污水中总磷变化情况和存在的问题探讨,文中通过对间歇式活性污泥法,生物脱氮除磷法和生物氧化沟法,通过这三种处理污水的方法,得出AAO的处理效果可以利用.     

浅议污水处理厂的节能

系统地介绍并分析了污水处理厂流程中各个处理构筑的能耗情况,并针对各个构筑物提出有效的节能途径。指出了常用的污水好氧处理能耗过高的突出问题,建议改用能耗低造价低的好氧过滤等处理方法。污水再生利用也是解决污水处理能耗高的途径之一。     

混凝沉淀—水解酸化—好氧工艺处理印染废水

采用混凝沉淀--水解酸化--好氧工艺处理印染废水,可获得较好的处理效果,出水水质各项指标达到了《纺织染整工业水污染物排放标准》（GB4287-92）二级标准。运行结果表明,CODCr平均去除率为81.2%,色度平均去除率为83.3%,该工艺切实可行,具有耐冲击负荷,能耗低,易操作等优点。二沉池部分污泥回流到水解酸化池,保证了水解酸化池内具有一定的污泥浓度,从而提高了去除率。     

自愿协议式环境管理模式在荆州纺织印染行业的实践研究

自愿协议作为环境管理的必要补充日益受到重视,本文对荆州纺织印染行业践行自愿协议环境管理进行了总结,提出了自愿协议式环境管理荆州模式的实施框架和具体内容,调查分析了荆州市部分纺织印染企业履行自愿环境管理协议的具体做法和取得的初步效果。实践表明,企业采取自愿环境协议,有利提高生产效率和管理水平,减少能耗和排污量。为鼓励企业采取自愿环境管理,政府要在政策和资金上给企业予以支持,解决企业因超前环境管理行为面临的资金短缺和成本增加问题。     

废硅藻土在小城镇印染废水预处理中的应用

随着小城镇的发展,多种行业的企业不断引进,逐渐形成了城镇的多产业型格局。青岛地区周边村镇的印染企业较多,产生的废水色度较大,这对适合于村镇的土地处理法会产生很大的影响,为了保证土地处理系统的出水水质,需要对进入土地处理系统的印染废水进行一定的预处理。文章通过对啤酒厂用于过滤后的废硅藻土对印染废水的脱色实验,以期找到一种较经济的小城镇印染废水预处理方法,同时实现废物再利用。实验研究表明,废硅藻土仍有吸附能力,具有再利用价值。它对实验选取的5种染料废水脱色效率均在50%以上;对阳离子染料脱色效果达到90%,效果最佳。因此废硅藻土在部分印染废水处理中可以替代常规混凝剂,大大降低处理成本。可以预测废硅藻土在印染废水预处理中的应用有很大潜力。     

Reuse of printing and dyeing wastewater in processess assessed by pilot-scale test using combined biological process and sub-filter technology

In this work, a pilot-scale (300 m³/d) wastewater reclamation system was tested for printing and dyeing wastewater treatment from a textile factory. The wastewater was first hydrolyzed under anoxic condition, and then was treated under aerobic condition. Biologically treated wastewater was filtered by sub-filter technology (Patent: CN1308024A). The results showed that the average concentration of CODcr, color and turbidity in the effluent were less than 50 mg/L, 10 times and 2 NTU, respectively. The average CODcr, color and turbidity removal efficiencies were 91%, 92.5% and 90.9%, respectively. The treated effluent quality satisfied the requirement of water quality for printing and dyeing process. The most attracting part of the work was its extremely low color, low turbidity, low concentration of Fe and Mn, which was always demanded in textile sectors for an improved finish and better quality dyeing.     

液相高压放电降解RB5染料废水的试验研究

随着印染工艺不断更新,大量化学分子结构复杂的化工染料应用到印染行业,使得常规的水处理工艺难以降解印染废水中的染料。本文以活性黑（RB5）染料为研究对象,采用液相高压放电产生强氧化性自由基来降解染料废水,考察反应时间、初始浓度和气体流量对RB5降解的影响,研究结果表明：在外部功率相同的情况下,浓度高染料其降解率相对较低;通入氧气量增加,产生的活性自由基和活性物质数量也增加,RB5的降解率也增大,但气流量不宜过大;高压放电产生的各种活性物质容易破坏染料发色基团的分子链,使其脱色。     

利用铁粉与磁粉载体流化床反应器处理染料废水

研究了铁粉和磁粉为流化床载体,对模拟染料废水和实际染料废水进行处理,取得了不同实验条件下染料废水的脱色效果。结果表明,经铁粉处理30min后,其色度去除率达98%左右,实际染料废水的CODcr去除率为56%左右;经磁粉处理30min后,其色度去除率为95%左右,实际染料废水的CODcr去除率为34%。     

Reduction in resource consumption by process modifications in cotton wet processes

The textile sector is one of the most important industrial sectors in Turkey. It comprises several sub-sectors among which cotton is the most important. Processes in the cotton textile industry can be dry and wet. A series of cleaner production (CP) options mostly related to water and energy conservation were identified in a selected enterprise focusing on the reduction of water consumption in the regeneration process, water and chemical savings in the dyeing process, heat recovery from the blowdown which was discharged into the waste water treatment plant, and also heat recovery of process waste water. The results of the calculations made during the feasibility stage proved that these CP options were worth implementing in the company being studied.     

印染废水处理工艺的改造

对某染织厂原印染废水处理系统存在的问题及废水水质进行了分析,在充分利用现有设施的前提下,提出了气浮／水解酸化／生物接触氧化／混凝沉淀／过滤改造工艺,增加一套气浮一体化处理设备,并将初沉池改为水解酸化池,平流沉淀池改成斜管沉淀池。改造后的废水处理系统对COD、SS和色度的去除率分别达到91．2％、90．7％、87．5％,出水水质达到了《纺织染整工业水污染物排放标准》（GB4287—92）的一级标准。     

染色废水的闭路循环系统

介绍一中型染色企业采用物化 生化工艺处理染色废水,给出了工艺流程、工艺参数和处理效果。废水处理运行结果:废水可循环使用。     

印染废水处理工程设计与运行

根据印染废水水质特点．采用水解酸化、生物接触氧化、气浮脱色工艺处理印染废水。实际运行监测表明：出水COD,BOD,SS等各项指标均能达到GB4278--1992《纺织染整工业水污染物排放标准》中Ⅱ级排放标准,工程投资和运行费用较低。运行效果稳定,能广泛应用于纺织染整工业废水处理的实际工程中。     

Micelle dyeing with low liquor ratio for reactive dyes using dialkyl maleic acid ester surfactants

Micelle dyeing with low liquor ratio is novel fabric dyeing method for cleaner production. Preparation and interaction of dye-surfactant micelles using dibutyl maleic acid ester sodium sulfate surfactant were investigated by UV-Vis spectra. Dyeing properties of cellulose fabrics using micelle dyeing with low liquor ratio were discussed by color yields (K/S), color differences (ΔE), exhaustion (E), fixation (F) and reactivity (R) of three reactive dyes. The results show that reactive dye molecules could be solved in surfactant micelles and form stable dye-surfactant micelles. Micelles formed by dibutyl maleic acid ester sodium sulfate had good anti-agglomeration effect on dye solutions. Liquor ratio of micelle dyeing for cellulose fabrics could be reduced from 1:15 to 1:5. Leveling properties of three reactive dyes using micelle dyeing were good. The exhaustion, fixation and reactivity of all three dyes using micelle dyeing were similar with the conventional dyeing technology. Wet rubbing, washing and perspiration fastnesses of dyed samples using micelle dyeing were also good. Micelle dyeing with low liquor ratio can save a large amount of water and energy.     

Treatment of desizing wastewater from the textile industry by wet air oxidation

This paper describes the application of wet air oxidation to the treatment of desizing wastewater from two textile companies. A two-liter high temperature, high pressure autoclave reactor was used in the study. The range of operating temperatures examined was between 150 and 290℃, and the partial pressure of oxygen ranged from 0. 375 to 2.25 MPa. Variations in pH,CODCr and TOD content were monitored during each experiment and used to assess the extent of conversion of the process. The effects of temperature, pressure and reaction time were explored extensively. More than 90 ％ CODCr reduction and 80 ％ TOC removal have been obtained. The results have also been demonstrated that WAO is a suitable pre-treatment methods due to improvement of the BOD5/CODCr ratio of desizing wastewater. The reaction kinetics of wet air oxidation of desizing wastewater has been proved to be two steps, a fast reaction followed by a slow reaction stage.