中晚全新世六盘山流域土壤侵蚀的湖泊沉积记录

流域土壤侵蚀是流域水文—气候—生态的集中表现之一,对生态、环境等有着重大影响,重建过去流域土壤侵蚀强度对理解区域人类活动具有重要意义.本文选取黄土高原西南部高山湖泊——六盘山天池沉积岩芯为研究对象,基于XRF岩芯元素数据分析,结合可靠的AMS 14C年代序列,重建了中晚全新世以来六盘山流域土壤侵蚀强度变化记录.结果显示:5570?—?1600 cal BP,流域土壤侵蚀整体较强,侵蚀强度逐渐减弱,其主要受控于降水变化,也受植被覆盖等因素的影响;随着晚全新世气候逐渐变干,1600 cal BP之后的侵蚀强度整体弱于前一时期,此时段由于人类活动的显著影响,加剧了流域的土壤侵蚀.太阳辐射可能是研究区土壤侵蚀强度变化的初始驱动力,ENSO通过驱动亚洲季风变化影响区域降水,进而直接影响流域土壤侵蚀的强度变化.     

太阳活动和ENSO控制南岭东部有效降水变化

在我国东南地区,器测时代之前的气候环境变化是否与ENSO活动有关还未见报道.本文在210Pb定年基础上,重建了南岭东部过去150 a(分辨率1.86 a)的石笋δ18O记录.对比器测指标,发现该石笋δ18O记录与当地有效降水变化密切相关,并以此重建了南岭东部地区过去150 a有效降水变化历史.南岭东部有效降水变化与ENSO活动密切相关,El Ni?o态对应有效降水增加和石笋δ18O变轻,La Ni?a态对应有效降水减少和石笋δ18O变重.有效降水变化长期趋势受到太阳活动控制,太阳活动减弱时南岭东部有效降水增加,反之亦然.ENSO和太阳活动变化引起的雨带位置和西北太平洋副热带高压变化主导了南岭东部有效降水的变化.本研究结果表明,石笋可能成为研究这一地区ENSO影响下年际—年代际尺度上降水变化的有力工具.     

河南神农山过去162年树轮季节降水重建

采用河南神农山白皮松轮宽序列,重建了该地区1850—2011 年上年9 月至当年6 月降 水量序列,重建方程方差解释量为42.4%。重建序列显示,在过去162 年中,神农山地区经历了 4 次持续时间超过5 年的严重干旱时段：1860—1879,1888—1913,1917—1945,1992—1998, 以及三次较为湿润的时段：1882—1893,1946—1991,1999—2006。发现研究区在1945 年之前 干旱频发,且持续时间较长。在1945 年之后,持续性干旱事件较少发生,降水量有上升趋势。 神农山降水重建序列与由历史文献记录划分的洛阳和郑州二地旱涝指数及亚洲– 太平洋涛动指 数（APO）相关显著。序列中的干旱事件发生时间与陕西、甘肃、宁夏等地的干旱出现较为一致。 空间相关分析结果显示,重建序列和观测序列分别与CRU TS3.10.01 降水序列相关显著且表现出 相似的空间相关模式,表明神农山降水重建序列较为可靠,在一定程度上能代表更大空间范围 的降水变化。功率谱分析表明,降水重建序列存在2.69 年,2.47 年,2.06 年的准周期,暗示研 究区降水变化可能受到与海陆耦合相关的准两年波动和ENSO 的影响。     

1960-2006年闽江流域径流演变特征

基于闽江流域1960-2006年逐月径流、降水以及气温等资料,应用Mann-Kendall趋势分析、经验模态分解等方法,探讨流域径流演变规律及其对气象要素变化的响应特征。结果表明:①闽江流域年径流呈上升趋势,其上升主要来自非汛期径流的贡献;秋季和冬季径流始终以上升趋势为主;夏季径流20世纪90年代以来呈上升趋势,而春季径流则呈现下降趋势。②流域降水和气温均存在上升趋势,尤以气温上升为显著;径流的上升趋势比降水显著。③径流和降水变化均存在多尺度特征,降水变化周期大于径流;80年代以来,径流和降水的年代际变化振荡幅度有所减弱,而年际变化的波动幅度在加强。分析表明,闽江流域径流上升趋势较降水显著的原因,一方面是由于流域蒸发的减少和降水强度的增大;另一方面是流域下垫面特征改变等因素的影响。     

青藏高原夏季500hPa纬向风昼夜差异及其影响

论文利用NCEP/NCAR再分析资料及中国142 个测站12 小时降水资料,采用线性倾向估计、合成分析、相关分析等方法,对青藏高原夏季500 hPa 纬向风的昼夜变化特征及其影响进行了分析。结果表明：自1950 年以来,高原夏季500 hPa 昼、夜纬向风均呈现整体减弱趋势,且减弱趋势夜间比白天明显,纬向风日较差呈增大趋势。高原昼、夜纬向风在1967 年均存在减弱突变,纬向风日较差存在1965 年的减小突变和1975 年的增大突变,纬向风日较差具有4~6 a 及16~23 a 的显著周期。高原昼夜纬向风异常,使得高原东侧及其以东地区出现异常的上升或下沉气流,且高原纬向风减弱时,长江以北的我国大部分地区降水偏少,长江以南地区降水偏多,降水对高原纬向风异常响应的昼夜差异主要表现在四川盆地东西部降水异常的昼夜差异上。     

1961-2009年四川极端强降水变化趋势与周期性分析

利用四川1961-2009年141个站点逐日降水资料和1998-2007年灾情资料,采用气候倾向率、Mann-Kendall检验、复Morlet小波、Gumbel分布、信息扩散等方法,分析了7个区域5个指数的变化趋势、突变特征和周期性特点,以及重现期降水极值和洪灾损失风险的区域差异,其主要结论是:川西南山地极端降水呈显著增多增强趋势,并在1980年代初发生了突变,盆地东北部和川西高原南部也有增多增强趋势,但不显著,盆地西北部、盆地南部和川西高原北部则有减少减弱趋势,盆地中部则表现出频数增多强度减弱的变化趋势;多数区域和多数指数都存在25 a左右的长周期和6~9 a的短周期,从25 a的长周期看,目前极端降水正处于增多增强的变化过程之中;用Gumbel分布拟合的日最大降水量,其极值区位于盆周山区和高原与盆地的过渡带,3个极值中心主要位于盆地西南部、西北部和东北部,50 a一遇的日雨量在230 mm以上;盆地大部50 a一遇的洪灾损失率在38%左右,盆地东北部可达45%,广元西南部可达60%。     

过去50年中国森林资源和降水变化的统计分析

论文对过去50年中国森林资源和降水变化进行了统计分析，以期在大尺度上寻找森林资源与降水变化之间的关系。主要结论为：①建国以来我国的森林覆盖率呈上升趋势；②过去50年全国、林区、非林区降水量均呈减少趋势，干旱化趋势明显；③对建国后历次森林资源调查（清查）时段内降水差值（以百分数为单位）、森林覆盖率（以相邻两次变化百分数为单位）变化关系的分析表明，二者的统计关系并不显著，即：过去50年我国森林资源的变化对降水没有显著的影响；④森林影响降水是一个复杂的系统问题，该研究还存在着许多不确定性因素，需进一步实验验证与理论探讨。     

煤炭资源型城市生态系统服务功能的时空变化特征分析——来自2006—2015年安徽省淮南市的经验证据

考虑到生态系统的品质性和稀缺性,对价值当量因子法模型进行拓展,并基于典型煤炭资源型城市淮南市2006—2015年的经验证据,系统分析了该地区生态系统服务功能的时空变化特征,研究结果表明,从时间角度来看,该地区生态系统服务功能价值总体在降低,主要是由于水源涵养、废物循环和气候调节这3种类型生态系统服务功能价值的减弱,不过下降趋势逐步减缓.从空间角度来看,该地区生态系统服务功能强度呈现东部、南部高,中部和北部偏低的格局,说明目前采煤区域的生态系统服务功能仍较脆弱,而传统矿区的生态系统服务功能正在得到恢复提高.     

利用沉积色素恢复湖泊古紫外强度研究综述

自从南极臭氧空洞被发现以来,平流层臭氧浓度下降导致到达地表的紫外辐射增强的现象引起了人们的广泛关注,目前这一状况还在不断加剧并将在未来很长一段时间里持续下去。为了更好地理解这种现象在长时间尺度上的意义以及合理预测未来地球表面紫外环境的变化以及生态系统的响应过程,科学家开始尝试恢复历史时期地球表面紫外辐射的变化。Scytonemin是蓝绿藻细胞外鞘上的一种抗UV色素,高UV强度照射能够促使细胞合成更多的这种色素以保护细胞免受紫外辐射的伤害,并且这种色素在湖泊沉积物中能够很好地保存。因此,我们可以通过分析不同时间段蓝绿藻细胞的scytonemin含量来反映历史时期湖泊紫外环境的变化。进一步的研究可以推测造成这种变化的原因以及生态系统对这些过程的响应,为预测未来地表紫外环境的变化及生态系统的响应提供合适的理论和证据。     

我国沙尘暴的气候成因及未来发展趋势

利用EOF和环流合成统计方法,分析了我国北方近40年来沙尘暴日数变化的时空异常特征及其气候成因.结果表明,20世纪80年代以来的太阳活动加强,全球气候变暖,青藏高原地面加热场强度加强,欧亚西风急流轴北移,西太平洋副热带高压偏北偏西,强度加强,蒙古气旋减弱,西北西部的沙尘源区降水增加,是中国北方沙尘暴减少的主要原因.20世纪末到21世纪初太阳活动进入新一轮的减弱期,引起气候变暖趋势减弱,气温逐渐降低,青藏高原地面加热场强度减弱,蒙古气旋逐渐加强.预计未来中国北方沙尘暴将在波动中逐渐增加,进入新一轮的相对活跃期.     

Toxic effects of acetochlor, methamidophos and their combination on nifH gene in soil

Toxic effects of two agrochemicals on nifH gene in agricultural black soil were investigated using denaturing gradient gel electrophoresis （DGGE） and sequencing approaches in a microcosm experiment. Changes of soil nifH gene diversity and composition were examined following the application of acetochlor, methamidophos and their combination. Acetochlor reduced the nifH gene diversity （both in gene richness and diversity index values） and caused changes in the nifH gene composition. The effects of acetochlor on nifH gene were strengthened as the concentration of acetochlor increased. Cluster analysis of DGGE banding patterns showed that nifH gene composition which had been affected by low concentration of acetochlor （50 mg/kg） recovered firstly. Methamidophos reduced nifH gene richness that except at 4 weeks. The medium concentration of methamidophos （150 mg/kg） caused the most apparent changes in nifH gene diversity at the first week while the high concentration of methamidophos （250 mg/kg） produced prominent effects on nifH gene diversity in the following weeks. Cluster analysis showed that minimal changes of nifH gene composition were found at 1 week and maximal changes at 4 weeks. Toxic effects of acetochlor and methamidophos combination on nifH gene were also apparent. Different nifH genes （bands） responded differently to the impact of agrochemicals： four individual bands were eliminated by the application of the agrochemicals, five bands became predominant by the stimulation of the agrochemicals, and four bands showed strong resistance to the influence of the agrochemicals. Fifteen prominent bands were partially sequenced, yielding 15 different nifH sequences, which were used for phylogenetic reconstructions. All sequences were affiliated with the alpha- and beta-proteobacteria, showing higher similarity to eight different diazotrophic genera.     

EDTA-enhanced phytoremediation of lead contaminated soil by Bidens maximowicziana

Phytoremediation is a potential cleanup technology for the removal of heavy metals from contaminated soils.Bidens maximowicziana is a new Pb hyperaccumulator,which not only has remarkable tolerance to Pb but also extraordinary accumulation capacity for Pb.The maximum Pb concentration was 1509.3 mg/kg in roots and 2164.7 mg/kg in overground tissues.The Pb distribution order in the B. maximowicziana was:leaf>stem>root.The effect of amendments on phytoremediation was also studied.The mobility of soil Pb and the Pb concentrations in plants were both increased by EDTA application.Compared with CK(control check),EDTA application promoted translocation of Pb to overground parts of the plant.The Pb concentrations in overground parts of plants was increased from 24.23-680.56 mg/kg to 29.07-1905.57 mg/kg.This research demonstrated that B.maximowicziana appeared to be suitable for phytoremediation of Pb contaminated soil,especially,combination with EDTA.     

Distribution and ecological effect of mercury in Laogang landfill, Shanghai, China

Laogang landfill near Shanghai is the largest landfill in China, and receives about 10000 t of daily garbage per day, Samples of topsoil and plants were analyzed to evaluate mercury pollution from the landfill. For topsoil samples, there were significant correlations among total mercury （HgT）, combinative mercury （Hgc） and gaseous mercury （HgG）, and content of total organic carbon （TOC）, but, no significantly relationship was found between Hg content and filling time. Hg content changes in vertical profiles with time showed that the average Hgv of profiles 1992, 1996, and 2000 was similar, but their average HgG was quite different. HgT was significantly correlated with Hgc in profile 1992 and 2000, and Hgv was significantly correlated with Hg6 in profile 1996. HgG/Hgv ratio in profile samples decreased in the order of （HgG,/HgT）1992〉（HgG/HgT）1996〉〉（HgG/HgT）2000. A simple outline of Hg release in landfill could be drawn： with increasing of filling time, degradation undergoes different biodegradation, accordingly, gaseous mercury goes through small, more, and small proportion to total mercury. Distribution of Hg in plants was inhomogeneous, following the order of leaf〉root〉stem. The highest value of leaf may be associated with higher atmospheric Hg from landfill. Ligneous plants （e.g. Phyllostachys glanca, Prunus salicina and Ligustrum lucidum） are capable of enriching more Hg than herbaceous plants.     

Arsenic uptake by arbuscular mycorrhizal maize （Zea mays L.） grown in an arsenic-contaminated soil with added phosphorus

The effects of arbuscular mycorrhizal (AM) fungus (Glomus mosseae) and phosphorus (P) addition (100 mg/kg soil) on arsenic (As) uptake by maize plants (Zea mays L.) from an As-contaminated soil were examined in a glasshouse experiment.Non-mycorrhizal and zero-P addition controls were included.Plant biomass and concentrations and uptake of As,P,and other nutrients,AM colonization,root lengths,and hyphal length densities were determined.The results indicated that addition of P significantly inhibited root colonization and development of extraradical mycelium.Root length and dry weight both increased markedly with mycorrhizal colonization under the zero-P treatments,but shoot and root biomass of AM plants was depressed by P application.AM fungal inoculation decreased shoot As concentrations when no P was added,and shoot and root As concentrations of AM plants increased 2.6 and 1.4 times with P addition,respectively.Shoot and root uptake of P,Mn,Cu,and Zn increased,but shoot Fe uptake decreased by 44.6%,with inoculation, when P was added.P addition reduced shoot P,Fe,Mn,Cu,and Zn uptake of AM plants,but increased root Fe and Mn uptake of the nonmycorrhizal ones.AM colonization therefore appeared to enhance plant tolerance to As in low P soil,and have some potential for the phytostabilization of As-contaminated soil,however,P application may introduce additional environmental risk by increasing soil As mobility.     

Enzymatic oxidation of aqueous pentachlorophenol

The influence of the nonionic surfactant Tween 80 on pentachlorophenol （PCP） oxidation catalyzed by horseradish peroxidase was studied. The surfactant was tested at concentrations below and above its critical micelle concentration （CMC）. Enhancement of PCP removal was observed at sub-CMCs. The presence of Tween 80 in the reaction mixture reduced enzyme inactivation which occurred through a combination of free radical attack and sorption by precipitated products. A simple first-order model was able to simulate time profiles for enzyme inactivation in the presence or absence of Tween 80. At supra-CMCs, the surfactant caused noticeable reductions in PCP removal, presumably through micelle partitioning of PCP which precluded the hydrophobic PCP molecule from interacting with the enzyme.     

Decomposition of alachlor by ozonation and its mechanism

Decomposition and corresponding mechanism of alachlor, an endocrine disruptor in water by ozonation were investigated. Results showed that alachlor could not be completely mineralized by ozone alone. Many intermediates and final products were formed during the process, including aromatic compounds, aliphatic carboxylic acids, and inorganic ions. In evoluting these products, some of them with weak polarity were qualitatively identified by GC-MS. The information of inorganic ions suggested that the dechlorination was the first and the fastest step in the ozonation of alachlor.     

Degradation of metabolites accumulated of benzo[a]pyrene by coupling Penicillium Chrysogenum with KMnO4

Several main metabolites of benzo[a]pyrene （BaP） formed by Penicillium chrysogenum, Benzo[a]pyrene-1,6-quinone （BP 1,6- quinone）, trans-7,8-dihydroxy-7,8-dihydrobenzo[a]pyrene （BP 7,8-diol）, 3-hydroxybenzo[a]pyrene （3-OHBP）, were identified by high-performance liquid chromatography （HPLC）. The three metabolites were liable to be accumulated and were hardly further metabolized because of their toxicity to microorganisms. However, their further degradation was essential for the complete degradation of BaP. To enhance their degradation, two methods, degradation by coupling Penicillium chrysogenum with KMnO4 and degradation only by Penicillium chrysogenum, were compared; Meanwhile, the parameters of degradation in the superior method were optimized. The results showed that （1） the method of coupling Penicillium chrysogenum with KMnO4 was better and was the first method to be used in the degradation of BaP and its metabolites; （2） the metabolite, BP 1,6-quinone was the most liable to be accumulated in pure cultures; （3） the effect of degradation was the best when the concentration of KMnO4 in the cultures was 0.01% （w/v）, concentration of the three compounds was 5 mg/L and pH was 6.2. Based on the experimental results, a novel concept with regard to the bioremediation of BaP-contaminated environment was discussed, considering the influence on environmental toxicity of the accumulated metabolites.     

Impact of atrazine and nitrogen fertilizers on the sorption of chlorotoluron in soil and model sorbents

Sorption of chlorotoluron in ammonium sulfate, urea and atrazine multi-solutes system was investigated by batch experiments. The results showed application of nitrogen fertilizers to the soil could affect the behavior of chlorotoluron. At the same concentration of N, sorption of chlorotoluron decreased as the concentration of atrazine increased on the day 0 and 6 in soil, respectively. The sorption of chlorotoluron increased from 0 to 6 d when soils were preincubated with deionized water, ammonium sulfate and urea solution for 6 d. That indicated incubation time was one of the most important factors for the sorption of chlorotoluron in nitrogen fertilizers treatments. The individual sorption isotherms of chlorotoluron in rubbery polymer and silica were strictly linear in single solute system, but there were competition sorption between pesticides or between pesticides and nitrogen fertilizers. That indicated the sorption taken place by concurrent solid-phase dissolution mechanism and sorption on the interface of water-organic matter or water-mineral matter.     

基于综合水质标识指数和对应分析法的校园河道水质评价

以三峡大学的校园河道求索溪为研究对象,利用综合水质标识指数法确定求索溪水质类别,分析其水质时空变化规律,并利用对应分析法得出求索溪中不同监测点的主要污染因子.研究结果表明:求索溪整体的综合水质标识指数为7.423,整体水质为劣V类(地表水环境质量标准GB 3838-2002)且黑臭.从时间变化来看,求索溪4月份的水质最差,5月份次之,4、5月份所有监测点的水质都劣于V类且黑臭;8月份水质最好,水质为Ⅳ类;从空间分布来看,8个监测点综合水质标识指数均超过6.0,水质为劣V类,其中6号监测点的水质相对最好,监测点3号的水质相对最差;对应分析法得出求索溪的整体水体污染程度受总氮因子的影响最大,其次为总磷.该研究拟为求索溪及类似校园河道的水环境治理研究提供基础依据和参考.     

Potential of plant polyphenol oxidases in the decolorization and removal of textile and non-textile dyes

In this study an effort has been made to use plant polyphenol oxidases; potato （Solanum tuberosum） and brinjal （Solanum melongena）, for the treatment of various important dyes used in textile and other industries. The ammonium sulphate fractionated enzyme preparations were used to treat a number of dyes under various experimental conditions. Majority of the treated dyes were maximally decolorized at pH 3.0. Some of the dyes were quickly decolorized whereas others were marginally decolorized. The initial first hour was sufficient for the maximum decolorization of dyes. The rate of decolorization was quite slow on long treatment of dyes. Enhancement in the dye decolorization was noticed on increasing the concentration of enzymes. The complex mixtures of dyes were treated with both preparations of polyphenol oxidases in the buffers of varying pH values. Potato polyphenol oxidase was significantly more effective in decolorizing the dyes to higher extent as compared to the enzyme obtained from brinjal polyphenol oxidase. Decolorization of dyes and their mixtures, followed by the formation of an insoluble precipitate, which could be easily removed simply by centrifugation.