火电厂脱硝技术现状及产业与市场发展预测

概述了我国火电厂脱硝的背景及国家发布的有关技术政策和相关标准,介绍了国内火电脱硝技术及脱硝产业的发展现状,对火电脱硝市场的发展进行了预测。     

选择性催化还原法烟气脱硝催化剂市场分析

目前控制氮氧化物排放的主流技术是选择性催化还原法(SCR),因此SCR脱硝用催化剂存在着很大的市场。本文从国家政策、污染状况、电力发展情况,对SCR脱硝用催化剂的市场需求进行了分析,以期给SCR脱硝用催化剂产业的发展提供参考。     

中国动态

燃煤电厂脱硝电价政策全面实施环保部和国家发改委近日联合印发《关于加快燃煤电厂脱硝设施验收及落实脱硝电价政策有关工作的通知》。《通知》对验收程序和验收时限提出了明确要求,并规定了享受脱硝电价补贴的3项条件。自2013年1月1日起,脱硝电价政策由14个省份试点扩大到全国所有省份。脱硝电价政策的全面实施,将大大推进全国氮氧化物减排。     

“十三五”除尘脱硫脱硝行业政策导向及发展趋势

从除尘脱硫脱硝行业发展现状和近几年国家有关热点政策出发,分析判断"十三五"期间脱硫脱硝行业发展趋势,提出火电超低排放改造、废脱硝催化剂处理处置、燃煤工业锅炉大气污染治理、非电重点行业除尘脱硫脱硝及第三方专业化治理等方向将成为"十三五"除尘脱硫脱硝行业发展的重要趋势。     

2021年脱硫脱硝行业发展评述及展望

归纳了2021年有关脱硫脱硝领域的主要政策,简介了脱硫脱硝行业的发展概况,并对2022年脱硫脱硝行业及技术的发展进行了展望.     

水泥行业氮氧化物减排技术及市场展望

介绍了我国水泥行业的发展概况及NOx排放情况、排放标准和水泥窑脱硝技术路线,以及几个典型的工程案例,并对水泥行业脱硝市场进行了展望。     

超低排放背景下煤电机组氨管控存在的问题及对策探析

近年来,我国大气污染防治成效显著,煤电机组超低排放政策实施对此做出了突出贡献。氮氧化物是煤电机组超低排放中的重要控制指标之一。然而,受现有氮氧化物排放监测和喷氨控制技术的精度、反馈时效等因素的限制,为提高脱硝效率保证性,电厂在实际运行中存在过量喷氨现象,未完全反应的氨进入大气后可能造成二次颗粒物增加。针对这一现象,本文回顾了我国火电行业氮氧化物排放标准和治理措施的演化及实施效果,对煤电机组氨排放现状和存在的问题进行了深入分析,提出在推进氮氧化物超低排放过程中应开展脱硝过量喷氨现状调研,鼓励企业开展脱硝系统优化,加强复杂烟气环境下氨监测技术研发,完善脱硝氨逃逸日常环境监管,推动氨排放全生命周期转化规律基础研究和大气环境效应评估,进一步提升煤电机组超低排放政策实施的综合环境效益,也对其他行业超低排放政策推进起到示范作用。     

水泥脱硝综合评估分析——以四川省某水泥企业为例

在分析四川省某水泥企业两条新型干法生产线分别采用低氮燃烧技术、SNCR烟气脱硝工程技术特点的基础上,评估了综合采用控制NO X措施后的运行效果,脱硝的经济技术可行性,并从NO X控制技术、环境管理、环境标准以及环境经济等方面提出相关的配套政策建议。     

我国脱硫脱硝行业2013年发展综述

综述了2013年我国脱硫脱硝行业的发展环境及发展概况;重点介绍了火电行业、钢铁行业、水泥行业脱硫脱硝产业发展现状;分析了行业市场特点及重要动态;针对行业发展中存在的主要问题提出了解决对策和建议.     

水泥炉窑用SNCR脱硝技术分析及市场展望

燃煤工业锅炉脱硝为"十二五"期间的重点环保项目,介绍了国内水泥炉窑的脱硝现状,以及现有的脱硝工艺及优缺点;提出选择性非催化还原(SNCR)脱硝工艺作为水泥企业的首选工艺,具有脱硝效率高、氨逃逸率低、设备成本及运行成本低等诸多优点,将成为水泥脱硝技术的主流。     

火电厂烟气脱硝关键技术的优化创新

燃煤烟气中的氮氧化物（NOX）脱除，国际上主要采用SCR法，但SCE催化剂制备工艺技术是制约我国脱硝技术产业化的瓶颈。对催化剂配方和成型工艺进行优化和创新研制的TZ型板式催化剂填补了国内空白。     

In situ push-pull method to determine ground water denitrification in riparian zones

To quantify ground water denitrification in discrete locations of riparian aquifers, we modified and evaluated an in situ method based on conservative tracers and 15N-enriched nitrate. Ground water was "pushed" (i.e., injected) into a mini-piezometer and then "pulled" (i.e., extracted) from the same mini-piezometer after an incubation period. This push-pull method was applied in replicate mini-piezometers at two Rhode Island riparian sites, one fresh water and one brackish water. Conservative tracer pretests were conducted to determine incubation periods, ranging from 5 to 120 h, to optimize recovery of introduced plumes. For nitrate push-pull tests, we used two conservative tracers, sulfur hexafluoride and bromide, to provide insight into plume recovery. The two conservative tracers behaved similarly. The dosing solutions were amended with 15N-enriched nitrate that enabled us to quantify the mass of denitrification gases generated during the incubation period. The in situ push-pull method detected substantial denitrification rates at a site where we had previously observed high denitrification rates. At our brackish site, we found high rates of ground water denitrification in marsh locations and minimal denitrification in soils fringing the marsh. The push-pull method can provide useful insights into spatial and temporal patterns of denitrification in riparian zones. The method is robust and results are not seriously affected by dilution or degassing from ground water to soil air. In conjunction with measurements of ground water flow-paths, this method holds promise for evaluating the influence of site and management factors on the ground water nitrate removal capacity of riparian zones.     

Subsurface application of manures slurries for conservation tillage and pasture soils and their impact on the nitrogen balance

Injection of cattle and swine slurries can provide soil incorporation in no-till and perennial forage production. Injection is expected to substantially reduce N loss due to ammonia (NH3) volatilization, but a portion of that N conservation may be offset by greater denitrification and leaching losses. This paper reviews our current knowledge of the impacts of subsurface application of cattle and swine slurries on the N balance and outlines areas where a greater understanding is needed. Several publications have shown that liquid manure injection using disk openers, chisels, or tines can be expected to Sreduce NH, emissions by at least 40%, and often by 90% or more, relative to broadcast application. However, the limited number of studies that have also measured denitrification losses have shown that increased denitrification with subsurface application can offset as much as half of the N conserved by reducing NH3 emissions. Because the greenhouse gas nitrous oxide (N2O) is one product of denitrification, the possible increases in N2O emission with injection require further consideration. Subsurface manure application generally does not appear to increase leaching potential when manure is applied at recommended rates. Plant utilization of conserved N was shown in only a portion of the published studies, indicating that further work is needed to better synchronize manure N availability and crop uptake. At this time in the United States, the economic and environmental benefits from reducing losses of N as NH3 are expected to outweigh potential liability from increases in denitrification with subsurface manure application. To fully evaluate the trade-offs among manure application methods, a detailed environmental and agricultural economic assessment is needed to estimate the true costs of potential increases in NO2O emissions with manure injection.     

烟气同时脱硫脱硝技术探讨

开发先进的烟气治理技术,控制二氧化硫和氮氧化物排放是国内外脱硫脱硝研究的一大热点。本文简述了同时脱硫脱硝技术的工作机理及其优缺点,从反应机理、技术特点和工程应用等方面,介绍了烟气同时脱硫脱硝技术的研究进展情况,并对其应用前景进行了预测。     

同步硝化好氧反硝化生物脱氮机理分析及其研究进展

通过对比传统生物脱氮理论，提出同步硝化好氧反硝化技术优点，对好氧反硝化的机理进行了初步探讨，并从不同角度做了理论分析。同时阐述了同步硝化反硝化技术的控制因素及其研究进展。并对好氧反硝化的应用前景作了展望，提出了好氧反硝化今后的研究方向。     

燃煤电厂烟气脱硫主要工艺

简要介绍燃煤电厂烟气脱硫（FGD）的湿法，半干法，干法，可回收工艺和联合SO2／NOx工艺等五类主要工艺，并对我国烟气脱硫技术的进展进行了探讨，指出我国烟气脱硫技术的发展应走国产化的道路。     

高浓度氨氮废水好氧反硝化反应的基本条件

文章通过室内实验,对高浓度氨氮废水(垃圾渗滤液)间歇曝气,在只存在有机碳、无机氮的条件下进行好氧反硝化脱氮研究。实验结果表明:垃圾渗滤液中存在好氧反硝化土著微生物菌落;发生好氧反硝化的基本条件为在溶解氧充足的条件下间歇曝气;碳源不仅是厌氧反硝化所必须的,同样也是好氧反硝化的必要条件。     

短程硝化反硝化生物脱氮的实现途径

短程硝化反硝化是近年来开发的一项新的生物脱氮技术,它具有节约曝气量、节省有机碳源和减少污泥产量等优点,实现短程硝化反硝化生物脱氮技术的关键就是将硝化控制在亚硝酸阶段,阻止亚硝酸盐的进一步氧化。简要介绍了短程硝化反硝化生物脱氮技术的原理和技术特点,通过对短程硝化反硝化影响因素的分析来介绍其实现途径,阐述了温度控制途径、溶解氧控制途径、pH值控制途径、投加抑制剂途径、泥龄控制途径以及纯种分离与固定化技术途径的控制机理及其局限性,并提出了今后的研究方向。     

Denitrification and availability of carbon and nitrogen in a well-drained pasture soil amended with particulate organic carbon

A well-drained soil in N-fertilized dairy pasture was amended with particulate organic carbon (POC), either sawdust or coarse woody mulch, and sampled every 4 wk for a year to test the hypothesis that the addition of POC would increase denitrification activity by increasing the number of microsites where denitrification occurred. Overall mean denitrifying enzyme activity (DEA), on a gravimetric basis, was 100% greater for the woody mulch treatment and 50% greater for the sawdust treatment compared with controls, indicating the denitrifying potential of the soil was enhanced. Despite differences in DEA, no difference in denitrification rate, as measured by the acetylene block technique, was detected among treatments, with an average annual N loss of ～22 kg N ha yr Soil water content overall was driving denitrification in this well-drained soil as regression of the natural log of volumetric soil water content (VWC) against denitrification rate was highly significant ( = 0.74, < 0.001). Addition of the amendments, however, had significant effects on the availability of both C and N. An additional 20 to 40 kg N ha was stored in POC-amended treatments as a result of increases in the microbial biomass. Basal respiration, as a measure of available C, was 400% greater than controls in the sawdust treatment and 250% greater than controls in the mulch. Net N mineralization, however, was significantly lower in the sawdust treatment, resulting in significantly lower nitrate N levels than in the control. We attribute the lack of measured response in denitrification rate to the high temporal variability in denitrification and suggest that diffusion of nitrate may ultimately have limited denitrification in the amended treatments. Our data indicate that manipulation of denitrification by addition of POC may be possible, particularly when nitrate levels are high, but quantifying differences in the rate of denitrification is difficult because of the temporal nature of the process (particularly the complex interaction of N availability and soil water content).     

福建省沿海电厂脱硫技术的选择

相对于钙法、氨法脱硫技术,海水脱硫在脱硫、脱氮效果、一次性投入、综合运行费用和避免二次污染方面有一定优势,在我国沿海电厂具有广阔的应用前景。本文重点介绍了海水脱硫技术,并对福建省今后SO2减排治理工作提出了建议。