Polyfluoroalkyl phosphate esters and perfluoroalkyl carboxylic acids in target food samples and packaging—method development and screening

Polyfluoroalkyl phosphate mono-, di-, and tri-esters (mono-, di-, and triPAPs) are used to water- and grease-proof food packaging materials, and these chemicals are known precursors to perfluoroalkyl carboxylic acids (PFCAs). Existing analytical methods for PAPs lack sample clean-up steps in the sample preparation. In the present study, a method based on ultra performance liquid chromatography coupled to tandem mass spectrometry (UPLC/MS/MS) was developed and optimized for the analysis of mono-, di-, and triPAPs, including a clean-up step for the raw extracts. The method was applied to food samples and their PAP-containing packaging materials. The optimized UPLC/MS/MS method enabled the separation and identification of a total of 4 monoPAPs, 16 diPAPs, and 7 triPAPs in the technical mixture Zonyl®-RP. For sample clean-up, weak anion exchange solid phase extraction columns were tested. PAPs standard solutions spiked onto the columns were separated into a fraction containing neutral compounds (triPAPs) and a fraction with ionic compounds (mono- and diPAPs) with recoveries between 72–110 %. Method limits of quantification for food samples were in the sub to low picogram per gram range. For quantitative analysis of PAPs, compound-specific labeled internal standards showed to be essential as sorption and matrix effects were observed. Mono-, di-, and/or triPAPs were detected in all food packaging materials obtained from the Swedish market. Up to nine diPAPs were detected in the food samples, with the 6:2/6:2 and 6:2/8:2 diPAPs as the dominant compounds. DiPAP concentrations in the food samples ranged from 0.9 to 36 pg/g, which was comparable to individual PFCA concentrations in the same samples. Consumption of food packed in PAP-containing materials could be an indirect source of human exposure to PFCAs.     

Conservation and development in Amazonian extractive reserves: the case of Alto Juruá

Extractive reserves constitute an innovative approach to match conservation and development objectives, which were originally envisaged as part of a land struggle by forest dwellers in Brazil. In spite of the idea's popularity and the attempts to apply the concept to different tropical regions, there has been little analysis of the combined conservation and development performance of extractive reserve programs. We present a detailed analysis of deforestation and demographic and socioeconomic changes in Alto Juruá, the first extractive reserve created in Brazil in 1990. Forest cover has remained fairly stable. Population has declined slightly, with some internal displacements. The cash economy base has shifted from the original rubber production to a diversified portfolio of agriculture and livestock, and there has been a dramatic rise in nonagrarian income. We conclude that the Reserve represents a very dynamic setting with positive conservation and development outcomes during its first decade.     

Do higher education research and development expenditures affect environmental sustainability? New evidence from Chinese provinces

Environmental Science and Pollution Research - Even though higher education R&D expenditures (HEEXP) are important determinants of economic growth that facilitate science, technology, new...     

Water resources development and impact assessment in the Mekong Basin: which way to go?

The Mekong River Basin is facing rapid changes, including intensive plans for water development. While the different development projects are considered to be important for economic development, the negative impacts that they are likely to cause for ecosystems and livelihoods are estimated to be remarkable. Yet, existing impact assessment processes seem in many cases to be inadequate to capture even the actual magnitude of the impacts at different levels. This article looks at the different impact assessment processes and their challenges in the basin. It is argued that impact assessment in this kind of dynamic and complex setting requires better coordination between assessments at different levels. Basinwide impact assessment would benefit from a more adaptive, multilevel approach that makes better use of assessments from local levels up to the regional level and builds on more participatory and interdisciplinary methods. Successful impact assessment also requires the recognition of the highly political nature of water development and related planning processes.     

The dynamic analysis of renewable energy’s contribution to the dimensions of sustainable development and energy security

In sustainable development, energy is critical in human activities and shapes a sustainable future. Thus, it is an unignorable element in human development. This paper analyzes the contributions of renewable energy sources (RES)’s to the economic, environmental, and social dimensions of sustainable development. Moreover, we add energy security as a possible fourth dimension into the analysis. For the sample size, we limit the countries members of the OECD and run generalized methods of moments for the period from 1995 to 2015. This method can produce efficient estimators under the problems of endogeneity, omitted-variable bias, measurement errors, and heteroscedastic residuals. According to the results, RES has a small reducing effect (?.007%) on output in the Cobb-Douglas production function for the economic dimension. We found that RES has a positive contribution to the environmental dimension and abates the level of carbon emission (?.093%). RES also confirms the inverted-U shape of environmental Kuznets curve. In the social dimension, RES improves human development and a 1% increase in RES consumption causes to .0045% increase in human development. In the last contribution, RES has a positive effect on sustainable energy supply security in the context of electricity generation (.032%). Although the effects of RES on the environment, social, and energy security are significant, they are limited. These limitations point to barriers that can be overcome over time. Our conclusions recommend that these effects might flourish with technical developments and political support in the long run. Furthermore, public awareness, rising income level, and economies of scale are also beneficial in this process. As a result, RES might be an excellent source for a sustainable future and development. Especially, RES might have remarkable contributions to the 7th, 11th, 12th, and 13th goals of sustainable development.

     

How do long-term development and periodical changes of river-floodplain systems affect the fate of contaminants? Results from European rivers

In many densely populated areas, riverine floodplains have been strongly impacted and degraded by river channelization and flood protection dikes. Floodplains act as buffers for flood water and as filters for nutrients and pollutants carried with river water and sediment from upstream source areas. Based on results of the EU-funded “AquaTerra” project (2004-2009), we analyze changes in the dynamics of European river-floodplain systems over different temporal scales and assess their effects on contaminant behaviour and ecosystem functioning. We find that human-induced changes in the hydrologic regime of rivers have direct and severe consequences on nutrient cycling and contaminant retention in adjacent floodplains. We point out the complex interactions of contaminants with nutrient availability and other physico-chemical characteristics (pH, organic matter) in determining ecotoxicity and habitat quality, and draw conclusions for improved floodplain management.     

Toxicity of five antidepressant drugs on embryo–larval development and metamorphosis success in the Pacific oyster,Crassostrea gigas

Unlike conventional pollutants, pharmaceutical residues are continuously discharged at low levels (low to mid ng l^?1 concentrations), which results in the chronic contamination of non-target organisms, but little is known about the effects of these residues. The purpose of this study was to provide the first assessment of the ecotoxicity of five antidepressants (selective serotonin reuptake inhibitors [SSRIs] fluoxetine and sertraline, tricyclic antidepressants [TCAs] clomipramine and amitriptyline, and serotonin norepinephrine reuptake inhibitor [SNRI] duloxetine) at a wide range of concentrations from 0.1 to 100,000 μg l^?1 on two early life stages in the Pacific oyster. The toxicity was quantified in D-shaped larvae after 36 h of exposure, and in 21-day-old pediveliger larvae after 24 h of exposure using the percentage of normal larval development and the metamorphosis rate as endpoints, respectively. The embryotoxicity assays reported that the EC₅₀ values were within the same range of concentrations (67 to 192 μg l^?1) for all of the tested molecules. The metamorphosis tests revealed that the antidepressants can be ranked along an increasing severity gradient: clomipramine < amitriptyline < duloxetine ~ fluoxetine. Sertraline appeared to be the less toxic molecule on this endpoint; however, a different concentration range was used. The embryotoxicity test was more sensitive than the metamorphosis bioassay for three of the five molecules tested, but the latter test showed more practical benefits. Overall, the obtained toxicity values were at least 10,000-fold higher than the reported environmental concentrations.     

Effects of conditioning,cross‐conditioning,and microbial growth on development of enhanced biodegradation of insecticides in soil

Abstract

Pretreatment of a Drummer‐Catlin soil mixture with granular formulations of carbofuran or trimethacarb enhanced biodegradation of subsequent treatments with the technical formulations. Degradation of carbofuran was enhanced by pretreatments with trimethacarb, and degradation of trimethacarb was enhanced by pretreatments with carbofuran. Bendiocarb degradation was enhanced by pretreatments of soil with carbofuran or trimethacarb. In bioassays with southern corn rootworm larvae, biological activity of carbofuran, trimethacarb, and bendiocarb was rapidly lost in soils pretreated with granular formulations. Pretreatment of soil with granular terbufos did not enhance the biodegradation of subsequent applications of technical terbufos. Several microbial biomass assays showed an increase in specific carbofuran‐degrading bacteria in soils that were pretreated with carbofuran. Bacteria were isolated that could grow on carbofuran and apparently degrade it when present with another carbon source.     

Assessment of aquatic plants in the reservoirs of AES-tietê and development of an integrated control model for the most important species

The general objective of this work was to develop a monitoring and management model for aquatic plants that could be used in reservoir cascades in Brazil, using the reservoirs of AES-Tietê as a study case. The investigations were carried out at the reservoirs of Barra-Bonita, Bariri, Ibitinga, Promiss?o, and Nova-Avanhandava, located in the Tietê River Basin; Agua Vermelha, located in the Grande River Basin; Caconde, Limoeiro, and Euclides da Cunha, which are part of the Pardo River Basin; and the Mogi-Gua?u reservoir, which belongs to the Mogi-Gua?u River basin. The main products of this work were: development of techniques using satellite-generated images for monitoring and planning aquatic plant control; planning and construction of a boat to move coating plant masses and an airboat equipped with a DGPS navigation and application flow control system. Results allowed to conclude that the occurrence of all types of aquatic plants is directly associated with sedimentation process and, consequently, with nutrient and light availability. Reservoirs placed at the beginning of cascades are more subject to sedimentation and occurrence of marginal, floating and emerged plants, and are the priority when it comes to controlling these plants, since they provide a supply of weeds for the other reservoirs. Reservoirs placed downstream show smaller amounts of water-suspended solids, with greater transmission of light and occurrence of submerged plants.     

Do tailings from the Mariana,MG (Brazil), disaster affect the initial development of millet,maize, and sorghum?

Environmental Science and Pollution Research - The collapse of the Fundão dam in Mariana, MG, in 2015 resulted in the overflow of more than 50 million m3 of mud containing mine tailings,...     

Does improvement in the environmental sustainability rating help to reduce the COVID-19 cases? Controlling financial development,price level and carbon damages

Environmental Science and Pollution Research - The study’s objective is to evaluate the impact of environmental sustainability rating, financial development, changes in the price level and...     

The astysphere and urban geochemistry—a new approach to integrate urban systems into the geoscientific concept of spheres and a challenging concept of modern geochemistry supporting the sustainable development of planet earth

Background, aim, and scope  In 1875, the geoscientist Walter Suess introduced several spheres, such as the lithosphere and the atmosphere to promote a comprehensive understanding of the system earth. Since then, this idea became the dominating concept for the understanding of the distribution of chemical elements in the system earth. Meanwhile, due to the importance of human beings on global element fluxes, the term anthroposphere was introduced. Nevertheless, in face of the ongoing urbanization of the earth, this concept is not any more adequate enough to develop a comprehensive understanding of global element fluxes in and between solid, liquid, and gaseous phases. This article discusses a new concept integrating urbanization into the geoscientific concept of spheres. Main features  No geological exogenic force has altered the earth’s surface during the last centuries in such an extent as human activity. Humans have altered the morphology and element balances of the earth by establishing agrosystems first and urban systems later. Currently, urban systems happen to become the main regulators for fluxes of many elements on a global scale due to ongoing industrial and economic development and a growing number of inhabitants. Additionally, urban systems are constantly expanding and cover more and more former natural and agricultural areas. For nature, urban systems are new phenomena, which never existed in previous geological eras. The process of the globe’s urbanization concurrently is active with the global climate change. In fact, urban systems are a major emitter for climate active gases. Thus, beside the global changes in economy and society, urbanization is an important factor within the global change of nature as is already accepted for climate, ecosystems, and biodiversity. Results  Due to the fact that urbanization has become a global process shaping the earth and that the urban systems are globally cross-linked among each other, a new geoscientific sphere has to be introduced: the astysphere. This sphere comprises the parts of the earth influenced by urban systems. Accepting urbanization as global ongoing process forming the astysphere comprehensively copes with the growing importance of urbanization on the creation of present geologic formations. Discussion  Anthropogenic activities occur mainly in rural and urban environments. For long lasting periods of human history, human activities mainly were focused on hunting and agriculture, but since industrialization, urbanized areas became increasingly important for the material and energy fluxes of earth. Thus, it seems appropriate to classify the anthroposphere into an agriculturally and an urban-dominated sphere, which are the agrosphere (Krishna 2003) and the astysphere (introduced by Norra 2007). Conclusions  We have to realize that urban systems are deposits, consumers, and transformers of resources interacting among each other and forming a network around the globe. Since the future of human mankind depends on the sustainable use of available resources, only a global and holistic view of the cross-linked urban systems forming together the astysphere provide the necessary geoscientific background understanding for global urban material and energy fluxes. If we want to ensure worth-living conditions for future generations of mankind, we have to develop global models of the future needs for resources by the global metasystem of urban systems, called astysphere. Perspectives  The final vision for geoscientific research on the astysphere must be to design models describing the global process of urbanization of the earth and the development of the astysphere with respect to fluxes of materials, elements, and energy as well as with respect to the forming of the earth’s face. Besides that, just from the viewpoint of fundamental research, the geoscientific concept of spheres has to be complemented by the astysphere if this concept shall fully represent the system earth.

Does insurance sector development improve environmental quality? Evidence from BRICS

Environmental Science and Pollution Research - The effect of financial development measured by banks, bonds, and stocks on carbon dioxide emissions (CO2E) has been widely studied while not much is...     

Renewable energy powered membrane desalination — review of recent development

Due to current water stress, there is a problem with hygiene and sanitation in many parts of the world. According to predictions from the United Nations, more than 2.7 billion people will be challenged by water scarcity by the middle of the century. The water industry is increasingly interested in desalination of the sea, ocean, and brackish water. Desalination processes are widely classified as thermal or membrane technologies. In the Middle East, thermal desalination remains the primary technology of choice, but membrane processes, for example reverse osmosis (RO), have evolved rapidly and in many other parts of the world are currently even surpassing thermal processes. The purpose of this paper is to review the renewable energy source, the technology, desalination systems, and their possible integration with renewable energy resources and their cost. This article suggests that the most practical renewable desalination techniques to be used are the solar photovoltaic integrated RO desalination process, the hybrid solar photovoltaic-wind integrated RO desalination process, the hybrid solar photovoltaic-thermal (PVT) integrated RO desalination process, and the hybrid solar photovoltaic-thermal effect distillation (PVT-MED) desalination process. However, intensive research is still required to minimize the cost, reduce the heat loss, enhance the performance, and increase the productivity.

     

How can green building development promote carbon emission reduction efficiency of the construction industry?——Based on the dual perspective of industry and space

Environmental Science and Pollution Research - Green building development(GBD) plays an important role in improving carbon emission reduction efficiency of the construction industry(CEEOCI), and...     

Vegetation development and nutrients supply of trees in habitats with high sulfur concentration in reclaimed former sulfur mines Jeziórko (Southern Poland)

Environmental Science and Pollution Research - The paper presents an assessment of vegetation (composition and cover-abundance), nutrient supply, and especially sulfur accumulation in the trees...     

The effect of fiscal decentralization,environmental regulation,and economic development on haze pollution: empirical evidence for 270 Chinese cities during 2007–2016

The current discourse addresses fiscal issues, financial decentralization, and environmental quality and significantly affects economic development and sustainability. This investigation aims to address the research gap in fiscal decentralization and haze pollution for innovation and sustainable growth. This study uses the annual data of 270 Chinese cities from 2007 to 2016 for comprehensive analysis and employs spatial regression methods. The key findings imply that haze pollution in neighbouring cities causes further ecological issues. While the environmental regulations of China tend to have negative impacts on pollution, fiscal decentralization was found to be a key contributor to environmental pollution in Chinese cities. Overall, the study supports the validity of the pollution refuge hypothesis in China. Lastly, the conclusions allow us to conclude that China might need micro-level reforms regarding fiscal decentralization, environmental tax laws, and encouragement of cleaner production technologies.

     

A new challenge—development of test systems for the infochemical effect

Background, aim, and scope

Many—if not all—organisms depend on so-called infochemicals, chemical substances in their surroundings which inform the receivers about their biotic and abiotic environment and which allow them to react adequately to these signals. Anthropogenic substances can interfere with this complex chemical communication system. This finding is called infochemical effect. So far, it is not known to what extent anthropogenic discharges act as infochemicals and influence life and reproduction of organisms in the environment because adequate testing methods to identify chemicals which show the infochemical effect and to quantify their effects have not been developed yet. The purpose of this article is to help and find suitable test designs.

Main features

Test systems used in basic research to elucidate the olfactory cascade and the communication of environmental organisms by infochemicals are plentiful. Some of them might be the basis for a quantified ecotoxicological analysis of the infochemical effect. In principle, test systems for the infochemical effect could be developed at each step of the chemosensory signal transduction and processing cascade.

Results

Experimental set-ups were compiled systematically under the aspect whether they might be usable for testing the infochemical effect of single chemicals in standardized quantifying laboratory experiments. For an appropriate ecotoxicological assessment of the infochemical effect, experimental studies of many disciplines, such as molecular biology, neurobiology, physiology, chemical ecology, and population dynamics, should be evaluated in detail before a decision can be made which test system, respectively which test battery, might be suited best. The test systems presented here are based on the knowledge of the genetic sequences for olfactory receptors, binding studies of odorants, signal transmission, and reactions of the receivers on the level of the organisms or the populations. The following basic approaches are conceivable to identify the role of an infochemical: binding studies to the odorant-binding protein or to the odorant receptor binding protein (e.g., by in situ hybridization and immunohistochemical studies), measurement of electrical signals of the receptor cells in the tissue (e.g., electroolfactograms, electroantennograms), registration of phenotypic changes (e.g., observation under the microscope), behavioral tests (e.g., in situ online biomonitoring, use of T-shaped olfactometers, tests of avoidance responses), measurement of population changes (e.g., cell density or turbidity measurements), and multispecies tests with observation of community structure and community function. The main focus of this study is on aquatic organisms.

Discussion

It is evident that the infochemical effect is a very complex sublethal endpoint, and it needs further studies with standardized quantitative methods to elucidate whether and to what extent the ecosystem is affected. The collection of approaches presented here is far from being complete but should serve as a point of depart for further experimental research.

Conclusions

This article is the first to compare various approaches for testing the infochemical effect. The development of a suitable test system will not be easy as there are a multitude of relevant chemicals, a multitude of relevant receptors, and a multitude of relevant reactions, and it must be expected that the effective concentrations are very low. The chemical communication is of utmost importance for the ecosystem and justifies great endeavors to find solutions to these technical problems.

Recommendations and perspectives

The infochemical effect is a new chapter in ecotoxicology. Will a new endpoint, the so-called infochemical effect, be required in addition to the actual standard test battery of Annex 5 to Commission Directive 92/69/EEC (EC 1992)? Finding the answer to this question is a big challenge that could be met by a comprehensive research project.     

Does environmental engineering help rural industry development? Discussion on the impact of Taiwan’s “special act for forward-looking infrastructure” on rural industry development

Environmental Science and Pollution Research - This study investigated the impact of environmental engineering on existing venues, venues and operations management. First, the literature analysis...