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Malik Summaira Iqbal Asim Imran Asma Usman Muhammad Nadeem Muhammad Asif Saira Bokhari Awais 《Environmental science and pollution research international》2021,28(26):34017-34026
Environmental Science and Pollution Research - The utilization of economic capabilities to raise production in the economy enhances the industrial activities and use of transportation. These... 相似文献
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Bajwa Ali Ahsan Zulfiqar Usman Sadia Sehrish Bhowmik Prasanta Chauhan Bhagirath Singh 《Environmental science and pollution research international》2019,26(6):5357-5371
Environmental Science and Pollution Research - Chenopodium album and C. murale are cosmopolitan, annual weed species of notable economic importance. Their unique biological features, including high... 相似文献
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Muhammad Usman Oriane Tascone Pierre Faure Khalil Hanna 《Environmental science and pollution research international》2017,24(17):14748-14757
This is the first study describing the chemical oxidation of hexachlorocyclohexanes (HCHs) in contaminated soil under water saturated and unsaturated flow through conditions. Soil contaminated with β-HCH (45 mg kg?1) and γ-HCH (lindane, 25 mg kg?1) was sampled from former lindane waste storage site. Efficiency of following treatments was tested at circumneutral pH: H2O2 alone, H2O2/FeII, Na2S2O8 alone, Na2S2O8/FeII, and KMnO4. Experimental conditions (oxidant dose, liquid/solid ratio, and soil granulometry) were first optimized in batch experiments. Obtained results revealed that increasing dose of H2O2 improved the oxidation efficiency while in Na2S2O8 system, maximum HCHs were removed at 300 mM. However, oxidation efficiency was slightly improved by FeII-activation. Increasing the solid/liquid ratio decreased HCH removal in soil samples crushed to 500 μm while an opposite trend was observed for 2-mm samples. Dynamic column experiments showed that oxidation efficiency followed the order KMnO4 > Na2S2O8/FeII > Na2S2O8 whatever the flow condition, whereas the removal extent declined at higher flow rate (e.g., ~50% by KMnO4 at 0.5 mL/min as compared to ~30% at 2 mL/min). Both HCH removal and oxidant decomposition extents were found higher in saturated columns than the unsaturated ones. While no significant change in relative abundance of soil mineral constituents was observed before and after chemical oxidation, more than 60% of extractable organic matter was lost after chemical oxidation, thereby underscoring the non-selective behavior of chemical oxidation in soil. Due to the complexity of soil system, chemical oxidation has rarely been reported under flow through conditions, and therefore our findings will have promising implications in developing remediation techniques under dynamic conditions closer to field applications. 相似文献
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M. Usman P. Faure C. Lorgeoux C. Ruby K. Hanna 《Environmental science and pollution research international》2013,20(1):22-30
Soil pollution by hydrocarbons (aromatic and aliphatic hydrocarbons) is a major environmental issue. Various treatments have been used to remove them from contaminated soils. In our previous studies, the ability of magnetite has been successfully explored to catalyze chemical oxidation for hydrocarbon remediation in batch slurry system. In the present laboratory study, column experiments were performed to evaluate the efficiency of magnetite catalyzed Fenton-like (FL) and activated persulfate (AP) oxidation for hydrocarbon degradation. Flow-through column experiments are intended to provide a better representation of field conditions. Organic extracts isolated from three different soils (an oil-contaminated soil from petrochemical industrial site and two soils polluted by polycyclic aromatic hydrocarbon (PAH) originating from coking plant sites) were spiked on sand. After solvent evaporation, spiked sand was packed in column and was subjected to oxidation using magnetite as catalyst. Oxidant solution was injected at a flow rate of 0.1 mL min?1 under water-saturated conditions. Organic analyses were performed by GC–mass spectrometry, GC–flame ionization detector, and micro-Fourier transform infrared spectroscopy. Significant abatement of both types of hydrocarbons (60–70 %) was achieved after chemical oxidation (FL and AP) of organic extracts. No significant by-products were formed during oxidation experiment, underscoring the complete degradation of hydrocarbons. No selective degradation was observed for FL with almost similar efficiency towards all hydrocarbons. However, AP showed less reactivity towards higher molecular weight PAHs and aromatic oxygenated compounds. Results of this study demonstrated that magnetite-catalyzed chemical oxidation can effectively degrade both aromatic and aliphatic hydrocarbons (enhanced available contaminants) under flow-through conditions. 相似文献
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Heavy-metal fractionation and distribution in soil profiles short-term-irrigated with sewage wastewater 总被引:1,自引:0,他引:1
Six soil profiles irrigated and non-irrigated with sewage wastewater were investigated for soil pH, electrical conductivity (EC), organic matter (OM), and CaCO3. The distributions and chemical fractions of Cu, Zn, Cd, and Pb, and their lability were also studied. The results indicated that pH, EC, OM, and CaCO3, as well as metal fractionation in soil profiles were affected by wastewater irrigation, especially in the surface layer. The surface layer (0-15 cm) irrigated with wastewater exhibited a 0.6 unit decrease in soil pH, a 40.6% decrease in CaCO3, and a 200% increase in EC as compared with that of the non-irrigated soil. The soil OM increased from 0.04% to 0.35% in the surface layer. The irrigation of soil with wastewater resulted in transformation of metals from the carbonate fraction (CARB) towards the exchangeable (EXCH), Fe-Mn oxide (ERO), and organic (OM) fraction for Zn, towards the EXCH, the OM, and residual fraction for Cu, and towards the exchangeable (EXCH) fraction for Cd. It was concluded that the use of sewage wastewater led to salt accumulation and an increase in the readily labile fraction of Zn, Cu, and Cd in the surface layer. Therefore, this reason may limit the use of wastewater under arid and semi-arid conditions. 相似文献
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Usman Muhammad Kousar Rakhshanda Yaseen Muhammad Rizwan Makhdum Muhammad Sohail Amjad 《Environmental science and pollution research international》2020,27(31):38995-39018
Environmental Science and Pollution Research - This study investigates the causal connection between economic growth, foreign direct investment, primary and renewable energy utilization, trade... 相似文献
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Anser Muhammad Khalid Usman Muhammad Godil Danish Iqbal Shabbir Malik Shahzad Sharif Arshian Tabash Mosab Ismail Lopez Lydia Bares 《Environmental science and pollution research international》2021,28(37):51119-51119
Environmental Science and Pollution Research - A Correction to this paper has been published: https://doi.org/10.1007/s11356-021-15192-8 相似文献
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Usman Muhammad Murtaza Behzad Natasha Natasha Imran Muhammad Abbas Ghulam Amjad Muhammad Shahid Muhammad Ibrahim Sobhy M. Owens Gary Murtaza Ghulam 《Environmental monitoring and assessment》2022,194(2):1-30
Environmental Monitoring and Assessment - Few estuaries remain unaffected by water management and altered freshwater deliveries. The Caloosahatchee River Estuary is a perfect case study for... 相似文献
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Application of magnetite-activated persulfate oxidation for the degradation of PAHs in contaminated soils 总被引:2,自引:0,他引:2
In this study, feasibility of magnetite-activated persulfate oxidation (AP) was evaluated for the degradation of polycyclic aromatic hydrocarbons (PAHs) in batch slurry system. Persulfate oxidation activated with soluble Fe(II) (FP) or without activation (SP) was also tested. Kinetic oxidation of PAHs was tracked in spiked sand and in aged PAH contaminated soils at circumneutral pH. Quartz sand was spiked with: (i) single model pollutant (fluorenone) and (ii) organic extract isolated from two PAH contaminated soils (H and NM sampled from ancient coking plants) and was subjected to oxidation. Oxidation was also performed on real H and NM soils with and without an extraction pretreatment. Results indicate that oxidation of fluorenone resulted in its complete degradation by AP while abatement was very low (<20%) by SP or FP. In soil extracts spiked on sand, significant degradation of 16 PAHs was observed by AP (70-80%) in 1 week as compared to only 15% by SP or FP systems. But no PAH abatement was observed in real soils whatever the treatment used (AP, FP or SP). Then soils were subjected to an extraction pretreatment but without isolation of organic extract from soil. Oxidation of this pretreated soil showed significant abatement of PAHs by AP. On the other hand, very low degradation was achieved by FP or SP. Selective degradation of PAHs was observed by AP with lower degradation efficiency towards high molecular weight PAHs. Analyses revealed that no by-products were formed during oxidation. The results of this study demonstrate that magnetite can activate persulfate at circumneutral pH for an effective degradation of PAHs in soils. However, availability of PAHs and soil matrix were found to be the most critical factors for degradation efficiency. 相似文献