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1.
The facility with which hydrocarbons can be removed from soils varies inversely with aging of soil samples as a result of weathering. Weathering refers to the result of biological, chemical and physical processes that can affect the type of hydrocarbons that remain in a soil. These processes enhance the sorption of hydrophobic organic contaminants (HOCs) to the soil matrix, decreasing the rate and extent of biodegradation. Additionally, pollutant compounds in high concentrations can more easily affect the microbial population of a recently contaminated soil than in a weathered one, leading to inhibition of the biodegradation process. The present work aimed at comparing the biodegradation efficiencies obtained in a recently oil-contaminated soil (spiked one) from Brazil and an weathered one, contaminated for four years, after the application of bioaugmentation and biostimulation techniques. Both soils were contaminated with 5.4% of total petroleum hydrocarbons (TPHs) and the highest biodegradation efficiency (7.4%) was reached for the weathered contaminated soil. It could be concluded that the low biodegradation efficiencies reached for all conditions tested reflect the treatment difficulty of a weathered soil contaminated with a high crude oil concentration. Moreover, both soils (weathered and recently contaminated) submitted to bioaugmentation and biostimulation techniques presented biodegradation efficiencies approximately twice as higher as the ones without the aforementioned treatment (natural attenuation).  相似文献   

2.
This paper offers physical and statistical arguments that lead to the representation of the probability density function of a scalar diffusing in a turbulent flow as a mixture of two probability density functions. Particular attention is given to the high-concentration tails which are consistently observed to be described accurately by a generalized Pareto distribution. A 4-parameter construct, using a mixture of beta densities, is shown to provide an adequate representation of measured concentration distributions of wind-tunnel, grid turbulence, plume data. By using either measured or theoretically predicted moments to conduct statistical inference, it is expected that the proposed model will be flexible enough to apply to a wide variety of experimental data sets, including those obtained from large-scale environmental flows.  相似文献   

3.
The simultaneous presence of distinct compounds in the aquatic environment can be causative of various toxicological interactions. This scenario challenges ecotoxicologists, since the assessment of toxicological effects caused by the simultaneous presence of multiple substances is by far more complicated. An illustrative example can be given by mentioning the anticholinesterasic compounds: by studying the level of cholinesterase impairment of an exposed organism, it is possible to ascertain the level of exposure to all anticholinesterasics (despite their chemical classes and natures) that the organism was subjected to. In this work, we describe the effects of three chemically different, albeit mechanistically, and toxicologically similar compounds (copper, chlorfenvinphos, and pyridostigmine) on cholinesterases of the fish Gambusia holbrooki. The results showed that the combinatorial effects may be of considerable extent, even for levels of exposure that are close to the ones already reported in the wild, for each isolated compound.  相似文献   

4.
Responses to ozone of insects feeding on a crop and a weed species   总被引:1,自引:0,他引:1  
The influence of ozone on insect herbivore growth and population development was investigated. Fumigation of both pea (Pisum sativum L.) and dock (Rumex obtusifolius L.) at a range of O(3) concentrations between 21-206 nl litre(-1) produced changes in mean relative growth rates of the aphids Acyrthosiphon pisum Harris and Aphis rumicis L. of between 24 and -6% relative to controls. However, there was no evidence of a dose-related response to O(3) fumigation and no clear differences in aphid response when fumigated with the plant on prefumigated or previously unfumigated plant material. It is suggested that this may, in part, be due to the presence of NO contamination during O(3) fumigation. However, the MRGR of dock aphids was found to be greater on new compared to old leaves as well as the increase on the new growth and decrease on the old growth of fumigated plants relative to unfumigated controls. The size of egg batches of the chrysomelid beetle Gastrophysa viridula Degeer were found to be larger, survival and productivity of larvae was higher, and the food consumption lower on R. obtusifolius fumigated with 70 nl litre(-1) O(3) compared with unfumigated controls. This meant that these beetle larvae consumed less leaf area per mg of production on fumigated leaves probably because of their better nutritional quality and/or reduced leaf defences. However, the rate of development of larvae was similar on fumigated and control plants.  相似文献   

5.
Abstract

Over a six-week period, eleven tests were performed at the U.S. EPA Incineration Research Facility (IRF) in Jefferson, Arkansas to evaluate the fate of trace metals fed to a rotary kiln incinerator equipped with a Calvert Flux-Forcer/Condensation Scrubber pilot plant as the primary air pollution control system (APCS). Test variables were kiln temperature, ranging from 538 °C to 927 °C; waste feed chlorine content, ranging from 0% to 3.4%; and scrubber pressure drop, ranging from 8.2 kPa to 16.9 kPa. Mercury was among the six hazardous constituent trace metals fed to the IRF’s pilotscale rotary kiln incineration system as part of a synthetic waste feed. This paper focuses on the test results solely with respect to mercury.

As expected, mercury behaved as a very volatile metal throughout the tests; it was not detected in any kiln ash samples. Scrubber collection efficiency for mercury ranged from 67% to >99%, averaging 87%; this was somewhat lower than expected and may be attributable to low scrubber loadings.

The ability to collect and analyze representative scrubber water samples appears to have been affected by the waste feed chlorine content; detection of mercury at higher concentrations during high waste-chlorine-content tests is thought to be largely the result of the formation of mercuric chloride, a more water-soluble species, during those tests. As a result, no firm conclusions may be drawn regarding the true impact of waste feed chlorine content on mercury partitioning to the scrubber water. As expected, no significant relationship was observed between kiln exit-gas temperature and mercury partitioning, nor was there a significant relationship with scrubber pressure drop.  相似文献   

6.
Musca domestica L. (Diptera: Muscidae), commonly called the house fly, is a major domestic, medical and veterinary pest that causes irritation, spoils food and acts as a vector for many pathogenic organisms. In this paper, the social and health problems related to housefly are introduced with the associated need to control its population. Physical and chemical methods of house fly control are briefly discussed. The main focus of this review is on the biological control methods for house fly control, that comprise botanical, fungal, bacterial and parasitoid agents. Although several biocontrol agents are still in the nascent stage, some of them (especially fungal and parasitoid agents) have shown reliable field performance and seem to be suitable candidates for commercialization. However, the majority of these laboratory and field studies have been conducted in the temperate region. It remains to be seen whether the application of biocontrol agents would be feasible in tropical environments. The integrated pest management practices, which can provide more reliable field performance, have also been discussed. A multi-dimensional approach that exerts control on all the life stages of house fly, but simultaneously preserves the fly's natural enemies could be an ecologically sustainable way of maintaining the fly populations below maximally acceptable limits.  相似文献   

7.
This paper describes the modeling of the hydrogeochemical effects of deep well recharge of oxic water into an anoxic pyrite-bearing aquifer. Kinetic expressions have been used for mineral dissolution-precipitation rates and organic matter oxidation. Hydrological and chemical parameters of the model were calibrated to field measurements. The results showed that oxidation of pyrite (FeS(2)) and, to a lesser extent, organic matter dominate the changes in quality of the recharged water during its passage through the aquifer. The recharge leads to the consumption of oxygen and nitrate and the formation of sulfate and ferrihydrite. Complexation reactions, cation exchange and precipitation and dissolution of calcite, siderite and rhodochrosite were also identified through the modeling. Despite problems of non-uniqueness of the calibrated parameters, the model was used successfully to depict the geochemical processes occurring in the aquifer. Non-uniqueness can be avoided by constraining the model as much as possible to measurements and/or data from literature, although they cannot be considered always as fixed values and should be considered as stochastic variables instead.  相似文献   

8.
The activity of microorganisms often plays an important role in dynamic natural attenuation or engineered bioremediation of subsurface contaminants, such as chlorinated solvents, metals, and radionuclides. To evaluate and/or design bioremediated systems, quantitative reactive transport models are needed. State-of-the-art reactive transport models often ignore the microbial effects or simulate the microbial effects with static growth yield and constant reaction rate parameters over simulated conditions, while in reality microorganisms can dynamically modify their functionality (such as utilization of alternative respiratory pathways) in response to spatial and temporal variations in environmental conditions. Constraint-based genome-scale microbial in silico models, using genomic data and multiple-pathway reaction networks, have been shown to be able to simulate transient metabolism of some well studied microorganisms and identify growth rate, substrate uptake rates, and byproduct rates under different growth conditions. These rates can be identified and used to replace specific microbially-mediated reaction rates in a reactive transport model using local geochemical conditions as constraints. We previously demonstrated the potential utility of integrating a constraint-based microbial metabolism model with a reactive transport simulator as applied to bioremediation of uranium in groundwater. However, that work relied on an indirect coupling approach that was effective for initial demonstration but may not be extensible to more complex problems that are of significant interest (e.g., communities of microbial species and multiple constraining variables). Here, we extend that work by presenting and demonstrating a method of directly integrating a reactive transport model (FORTRAN code) with constraint-based in silico models solved with IBM ILOG CPLEX linear optimizer base system (C library). The models were integrated with BABEL, a language interoperability tool. The modeling system is designed in such a way that constraint-based models targeting different microorganisms or competing organism communities can be easily plugged into the system. Constraint-based modeling is very costly given the size of a genome-scale reaction network. To save computation time, a binary tree is traversed to examine the concentration and solution pool generated during the simulation in order to decide whether the constraint-based model should be called. We also show preliminary results from the integrated model including a comparison of the direct and indirect coupling approaches and evaluated the ability of the approach to simulate field experiment.  相似文献   

9.
In the aftermath of the 9/11 disaster, Mayor Bloomberg of New York City unveiled an aggressive budget plan that included the temporary suspension of glass and plastics recycling. This was considered by many to be anti-environmental, but the results of this study show that for lack of markets, even at zero or negative prices, nearly 90% of the plastic and glass set aside by thoughtful New Yorkers was transported to materials recovery facilities (MRFs) and from there to landfills. Sending bales of plastics to landfills is not limited to New York City. It is an environmental paradox that the United States is digging up new oil fields in pristine areas and, at the same time, continues to convert greenfields to brownfields by burying nearly 20 million tons of plastic fuel annually. The study also determined that at the present rate of source separation, estimated to be less than 30% of the available recyclables in 1999, building large, modern MRFs may increase substantially the rate of New York City recycling and also allow single-stream collection of commingled recyclables, as is done in Phoenix, AZ. Single-stream collection simplifies separation at the source by citizens and increases the amount of collected recyclables. Also, because collection represents a large fraction of the costs of waste management, it may have a significant economic advantage.  相似文献   

10.
A radiotracer study was conducted in a creosote-contaminated aquifer beneath the Fraser River, British Columbia Canada to investigate the in situ degradation of naphthalene. The groundwater is anaerobic, with abundant methane, ferrous iron and carbon dioxide. This study followed earlier work at the site where the contaminant distribution could only be explained by invoking a mass loss through degradation, even though extensive field and laboratory microcosm studies closer to the source zone onshore could not confirm degradation. Accordingly, 14C-naphthalene was injected into the aquifer offshore, further from the source zone where modeling suggested degradation was occurring. During the 230-day monitoring period, 14CO2 was detected, confirming the degradation of the radio-labeled naphthalene tracer. A zero-order degradation rate of naphthalene of 5 microg/L-day was estimated based on the decrease in 14C-naphthalene concentration with time. While the degradation pathway could not be determined from the radiotracer study alone, the geochemistry of the site suggests that either iron reduction or methanogenesis is the terminal electron accepting processes responsible for naphthalene oxidation.  相似文献   

11.
Background Due to the bovine spongiform encephalopathy (BSE), specified risk material (SRM) as well as animal meat and bone meal (MBM) are banned from the food and feed chain because of a possible infection with pathogenic prions (PrPSc). Nowadays, prions are widely accepted to be responsible for TSE(transmissible spongiform encephalopathies)-caused illnesses like BSE and scrapie, and especially for the occurrence of the new variant of CJD in humans. Presently, SRM and MBM are burnt under high temperatures to avoid any hazards for humans, animals or the environment. The aim of this study was to evaluate a method using animal fat separated from Category I material which includes SRM and the carcasses of TSE-infected animals, or animals suspected of being infected with TSE, as a source for producing biodiesel by transesterification, analogous to the biodiesel process using vegetable oil. Methods For this purpose, animal fat was spiked with scrapie-infected hamster brain equivalents – as representative for a TSE-infected animal – and the biodiesel manufacturing process was downscaled and performed under lab-scale conditions. Results and Discussion The results analysed by Western blotting showed clearly that almost each single step of the process leads to a significant reduction of the concentration of the pathogenic prion protein (PrPSc) in the main and side-products. Conclusion The data revealed that the biodiesel production, even from material with a high concentration of pathogenic prions, can be considered as safe. Recommendations and Outlook The obtained results indicated that biodiesel produced from prion-contaminated fat was safe under the tested process conditions. However, it has to be pointed out that the results cannot be generalized because a different process control using other conditions may lead to different results and then has to be analysed independently. It is clear that the production of biodiesel from high risk material represents a more economic usage than the combustion of such material.  相似文献   

12.
The Bio-response Operational Testing and Evaluation (BOTE) Project was a cross-government effort designed to operationally test and evaluate a response to a biological incident (release of Bacillus anthracis [Ba] spores, the causative agent for anthrax) from initial public health and law enforcement response through environmental remediation. The BOTE Project was designed to address site remediation after the release of a Ba simulant, Bacillus atrophaeus spp. globigii (Bg), within a facility, drawing upon recent advances in the biological sampling and decontamination areas. A key component of response to a biological contamination incident is the proper management of wastes and residues, which is woven throughout all response activities. Waste is generated throughout the response and includes items like sampling media packaging materials, discarded personal protective equipment, items removed from the facility either prior to or following decontamination, aqueous waste streams, and materials generated through the application of decontamination technologies. The amount of residual contaminating agent will impact the available disposal pathways and waste management costs. Waste management is an integral part of the decontamination process and should be included through “Pre-Incident” response planning. Overall, the pH-adjusted bleach decontamination process generated the most waste from the decontamination efforts, and fumigation with chlorine dioxide generated the least waste. A majority of the solid waste generated during pH-adjusted bleach decontamination was the nonporous surfaces that were removed, bagged, decontaminated ex situ, and treated as waste. The waste during the two fumigation rounds of the BOTE Project was associated mainly with sampling activities. Waste management activities may represent a significant contribution to the overall cost of the response/recovery operation. This paper addresses the waste management activities for the BOTE field test.Implications: Management of waste is a critical element of activities dealing with remediation of buildings and outdoor areas following a biological contamination incident. Waste management must be integrated into the overall remediation process, along with sampling, decontamination, resource management, and other important response elements, rather than being a stand-alone activity. The results presented in this paper will provide decision makers and emergency planners at the federal/state/tribal/local level information that can be used to integrate waste management into an overall systems approach to planning and response activities.  相似文献   

13.
ABSTRACT

Photochemical air quality simulation models are now used widely in evaluating the merits of alternative emissions control strategies on spatial scales from metropolitan to sub-continental. Greatly varying levels of resources have been available to support modeling, from relatively comprehensive databases and evaluation of performance to a paucity of aerometric data for developing model inputs. Where data are sparse, many alternative outcomes are consistent with the knowledge at hand. Where performance evaluation is inadequately supported, the probability of error may be high. In each instance, uncertainties may be large when compared with the signal of interest, and thus confidence in the reliability of the model as an estimator of future air quality may come into question.

This paper proposes a qualitative procedure for assessing whether a particular application of a modeling system is likely to be potentially unreliable, suggesting that either (1) modification and further evaluation is needed, if supportable, prior to adoption for regulatory application; or (2) the model should not be used if improvement is not supportable. The procedure is proposed for use by policy-makers, staffs of public agencies, air quality managers, environmental staffs of industrial organizations, and other interested parties. The proposed use of the procedure is (1) to assess, a priori, whether a proposed application is likely to be judged questionable or unacceptably uncertain in outcome; and (2) to provide, a posteriori, a basis for judging quickly the likely quality of model performance. The procedure is presented with tropospheric ozone as the pollutant of concern. With adjustments, however, the procedure should be applicable for particu-late matter and other pollutants of interest.  相似文献   

14.
White croaker (Genyonemus lineatus), collected from a highly contaminated site in San Pedro Bay and from a reference site 80 km away (Dana Point), were induced to spawn in the laboratory. Forty-one per cent of San Pedro Bay females and 54% of Dana Point females spawned. Examination of the ovaries of non-spwaning females revealed that spawning was imminent in the remainder of Dana Point fish but only in 16% of the San Pedro Bay fish. The remainder of the San Pedro Bay fish (43%) contained only immature, yolky oocytes. No croakers containing more than 3.8 ppm ovarian total DDT could be induced to spawn whereas 36% of a contemporaneous San Pedro Bay sample had ovarian total DDT residues in excess of 4 ppm. This suggests that the inability to induce spawning in white croaker may be associated with an ovarian total DDT threshold of about 4 ppm. These data, coupled with observed decreases in fecundity (32%), fertility (14%), and early oocyte loss (30%) relative to reference fish, could partially explain the population declines observed for many southern California fishes since the 1940s.  相似文献   

15.
Biofilters are becoming an increasingly popular treatment device for odors and other volatiles found at wastewater treatment plants. A seashell media based biofilter was installed in April 2011 at Lake Wildwood Wastewater Treatment Plant located in Penn Valley, California. It was sampled seasonally to examine its ability to treat odorous compounds found in the air above the anaerobic equalization basin at the front end of the plant and to examine the properties of the biofilter and its recirculating water system. The odor profile method sensory panels found mainly sulfide odors (rotten eggs and rotten vegetable) and some fecal odors. This proved to be a useful guidance tool for selecting the required types of chemical sampling. The predominant odorous compounds found were hydrogen sulfide, methyl mercaptan and dimethyl sulfide. These compounds were effectively removed by the biofilter at greater than 99% removal efficiency therein reducing the chemical concentrations to below their odor thresholds. Aldehydes found in the biofilter were below odor thresholds but served as indicators of biological activity. Gas chromatography with mass spectrometry and gas chromatography with sensory detection showed the presence of dimethyl disulfide and dimethyl trisulfide as well, but barely above their respective odor thresholds. The neutrality of the pH of the recirculating water was variable depending on conditions in the biofilter, but a local neutral pH was found in the shells themselves. Other measurements of the recirculating water indicated that the majority of the bio-activity takes place in the first stage of the biofilter. All measurements performed suggest that this seashell biofilter is successful at removing odors found at Lake Wildwood. This study is an initial examination into the mechanism of the removal of odorous compounds in a seashell biofilter.

Implications:?This paper presents a thorough examination of a seashell media biofilter, a sustainable treatment technology used to remove reduced sulfide compounds. The durable performance of the seashell biofilter ensures that odors will be adequately controlled, preventing odor nuisance to surrounding residences, which is an emerging problem faced by waste management facilities. The odor profile method technique used in this study can be applied in many situations by waste management facilities and regulatory air management organizations for source tracking in relation to prevention and management of odor complaints, respectively.  相似文献   

16.
This paper examines the nature of ecological economics, arguing that it comprises two aspects, the qualitative framework within which it operates and the quantitative techniques which it uses to measure sustainability, evaluate policies and assist decision-making. The former is distinct to ecological economics, whereas the latter is largely shared with environmental economics. Although these have co-existed for some time, it is contended that the qualitative aspect needs to be developed if ecological economics is to realise its potential. The paper first offers a Schumpeterian 'pre-analytic' vision of ecological economics. Ecological economics, it is argued, necessarily implies a fundamental change in the way problems are perceived and in how they should be addressed. Second, the paper discusses the quantitative aspect of ecological economics, arguing that the overlap with environmental economics in the techniques used is one reason why the two have frequently not been seen as sufficiently distinct. The paper concludes that a development of the qualitative, procedural aspect of ecological economics is needed if its full potential for influencing policy-making is to be realised.  相似文献   

17.
Evaluating a drinking-water waste by-product as a novel sorbent for arsenic   总被引:3,自引:0,他引:3  
Makris KC  Sarkar D  Datta R 《Chemosphere》2006,64(5):730-741
Arsenic (As) carcinogenicity to humans and other living organisms has promulgated extensive research on As treatment technologies with varying levels of success; generally, the most efficient methods come with a significantly higher cost burden and they usually perform better in removing As(V) than As(III) from solution. In the reported study, a novel sorbent, a waste by-product of the drinking-water treatment process, namely, drinking-water treatment residuals (WTRs) were evaluated for their ability to adsorb both As(V) and As(III). Drinking-WTRs can be obtained free-of-charge from drinking-water treatment plants, and they have been successfully used to reduce soluble phosphorus (P) concentrations in poorly P-sorbing soils. Phosphate and arsenate molecules have the same tetrahedral geometry, and they chemically behave in a similar manner. We hypothesized that the WTRs would be effective sorbents for both As(V) and As(III) species. Two WTRs (one Fe- and one Al-based) were used in batch experiments to optimize the maximum As(V) and As(III) sorption capacities, utilizing the effects of solid:solution ratios and reaction kinetics. Results showed that both WTRs exhibited high affinities for soluble As(V) and As(III), exhibiting Freundlich type adsorption with no obvious plateau after 2-d of reaction (15000 mg kg-1). The Al-WTR was highly effective in removing both As(V) and As(III), although As(III) removal was much slower. The Fe-WTR showed greater affinity for As(III) than for As(V) and reached As(III) sorption capacity levels similar to those obtained with the Al-WTR-As(V) system (15000 mg kg-1). Arsenic sorption kinetics were biphasic, similar to what has been observed with P sorption by the WTRs. Minimal (<3%) desorption of sorbed As(III) and As(V) was observed, using phosphate as the desorbing ligand. Dissolved Fe2+ concentrations measured during As(III) sorption were significantly correlated (r2=0.74, p<0.005) with the amount of As(III) sorbed by the Fe-WTR. Lack of correlation between Fe2+ in solution and sorbed As(V) (r2=0.2) suggests reductive dissolution of the Fe-WTR mediating As(III) sorption. Results show promising potential for the WTRs in irreversibly retaining As(V) and As(III) that should be further tested in field settings.  相似文献   

18.
In this study an attempt is made to investigate the prevailing meteorological conditions during days with high concentrations of PM10 (particles with diameter < 10 microns), collected in the Eordea mountain basin. This is an industrial area in the northwestern mountainous region of Greece. Over the 4-year data-gathering period, the days in which the United States Environmental Protection Agency 24-h PM10 standard was exceeded (episode days), were identified in relation to prevailing synoptic scale and local meteorological conditions. The results indicated that days with increased PM10 concentrations in this area can be grouped into four categories in relation to their synoptic circulation characteristics. The highest concentrations were found to be associated with stagnant conditions. Under these conditions, local circulations developed in the area, resulting in recirculation and accumulation of pollutants.  相似文献   

19.
The intrinsic difficulties in building realistic climate models and in providing complete, reliable and meaningful observational datasets, and the conceptual impossibility of testing theories against data imply that the usual Galilean scientific validation criteria do not apply to climate science. The different epistemology pertaining to climate science implies that its answers cannot be singular and deterministic; they must be plural and stated in probabilistic terms. Therefore, in order to extract meaningful estimates of future climate change from a model, it is necessary to explore the model's uncertainties. In terms of societal impacts of scientific knowledge, it is necessary to accept that any political choice in a matter involving complex systems is made under unavoidable conditions of uncertainty. Nevertheless, detailed probabilistic results in science can provide a baseline for a sensible process of decision-making.  相似文献   

20.
Phosphorous control in a eutrophied reservoir   总被引:1,自引:0,他引:1  
Water in lakes and reservoirs accumulate phosphorous (P) from both internal and external loads. The external P load (EPL) coming from the watershed is considered to be the main cause of eutrophication of water bodies, and control strategies therefore focus on its reduction. However, algae blooms and anoxic conditions often continue even after EPL have been controlled, being the internal P load (IPL) originating from the sediment the main sources of P. To assess the efficiency of the adsorbent Phoslock (a modified bentonite) in controlling P concentrations in water and immobilize releasable P in sediments, mesocosm trials were carried out in a eutrophied reservoir and a model was described and applied that determines the amount of adsorbent and the application frequency necessary to control P concentrations in a eutrophied reservoir. The mesocosm trials confirm that Phoslock reduced P concentrations to or below the limits that define water in mesotrophic state, in approximately 2 weeks. The modeling results suggest that periodic reapplications of the adsorbent are required, unless EPL is reduced by 36 %, which allows the P concentrations in the water column to be constant. Such reduction in EPL would allow future applications of the adsorbent to be required only for control of IPL. The developed model allows planning remediation actions by determining quantities and frequencies for application of adsorbents for P control in eutrophied lakes and reservoirs.  相似文献   

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