我国烟气脱硫技术进展

概述了我国烟气脱硫技术应用和研究开发进展,对发展中国式烟气脱硫道路提出了建议。     

Chemical and physical properties of dry flue gas desulfurization products

Beneficial and environmentally safe recycling of flue gas desulfurization (FGD) products requires detailed knowledge of their chemical and physical properties. We analyzed 59 dry FGD samples collected from 13 locations representing four major FGD scrubbing technologies. The chemistry of all samples was dominated by Ca, S, Al, Fe, and Si and strong preferential partitioning into the acid insoluble residue (i.e., coal ash residue) was observed for Al, Ba, Be, Cr, Fe, Li, K, Pb, Si, and V. Sulfur, Ca, and Mg occurred primarily in water- or acid-soluble forms associated with the sorbents or scrubber reaction products. Deionized water leachates (American Society for Testing and Materials [ASTM] method) and dilute acetic acid leachates (toxicity characteristic leaching procedure [TCLP] method) had mean pH values of >11.2 and high mean concentrations of S primarily as SO(2-)4 and Ca. Concentrations of Ag, As, Ba, Cd, Cr, Hg, Pb, and Se (except for ASTM Se in two samples) were below drinking water standards in both ASTM and TCLP leachates. Total toxicity equivalents (TEQ) of dioxins, for two FGD products used for mine reclamation, were 0.48 and 0.53 ng kg(-1). This was similar to the background level of the mine spoil (0.57 ng kg(-1)). The FGD materials were mostly uniform in particle size. Specific surface area (m2 g(-1)) was related to particle size and varied from 1.3 for bed ash to 9.5 for spray dryer material. Many of the chemical and physical properties of these FGD samples were associated with the quality of the coal rather than the combustion and SO2 scrubbing processes used.     

钢铁行业烧结烟气脱硫技术的发展

烧结烟气脱硫是钢铁行业减排的重点,减排形势日趋严峻。本文比较了各种烧结烟气脱硫方法的优劣势、适用范围,分析了目前烧结烟气脱硫技术的发展动态,指出了未来烧结烟气脱硫技术的发展方向。     

规流塔技术在钢铁行业烧结烟气脱硫中的应用

烧结烟气脱硫是钢铁行业减排的重点,减排形势日趋严峻。本文介绍了一种新型的烧结烟气脱硫技术及其特点与优势,指出FS-04脱硫塔技术在烧结烟气脱硫排放控制方面具有较好的应用前景。     

氨法烟气脱硫工艺在燃煤锅炉的应用

介绍了氨法脱硫技术在国内外的应用情况以及氨法烟气脱硫工艺的工作原理和工程应用难点;分析了热电厂煤粉锅炉烟气脱硫的工艺路线特点及新型氨法脱硫工艺应用后取得了的显著效果;提出了氨法脱硫工艺存在的问题和发展前景。     

软锰矿烟气脱硫反应过程研究

研究了软锰矿浆体系中SO2和软锰矿的宏观动力学反应过程，考察了搅拌速度、温度、浓度、矿粉粒度、固体浓度等因素对反应速度的影响，应用了反应过程中粒径不断缩小的缩芯模型描述反应过程，计算出此反应的活化能。最终揭示了SO2与软锰矿反应的宏现动力学的数学模型，为工业装置的设计和操作提供了动力学理论依据，为本工艺的工业化应用打下了坚实的基础。     

Tillage, cropping systems, and nitrogen fertilizer source effects on soil carbon sequestration and fractions

Quantification of soil carbon (C) cycling as influenced by management practices is needed for C sequestration and soil quality improvement. We evaluated the 10-yr effects of tillage, cropping system, and N source on crop residue and soil C fractions at 0- to 20-cm depth in Decatur silt loam (clayey, kaolinitic, thermic, Typic Paleudults) in northern Alabama, USA. Treatments were incomplete factorial combinations of three tillage practices (no-till [NT], mulch till [MT], and conventional till [CT]), two cropping systems (cotton [Gossypium hirsutum L.]-cotton-corn [Zea mays L.] and rye [Secale cereale L.]/cotton-rye/cotton-corn), and two N fertilization sources and rates (0 and 100 kg N ha(-1) from NH(4)NO(3) and 100 and 200 kg N ha(-1) from poultry litter). Carbon fractions were soil organic C (SOC), particulate organic C (POC), microbial biomass C (MBC), and potential C mineralization (PCM). Crop residue varied among treatments and years and total residue from 1997 to 2005 was greater in rye/cotton-rye/cotton-corn than in cotton-cotton-corn and greater with NH(4)NO(3) than with poultry litter at 100 kg N ha(-1). The SOC content at 0 to 20 cm after 10 yr was greater with poultry litter than with NH(4)NO(3) in NT and CT, resulting in a C sequestration rate of 510 kg C ha(-1) yr(-1) with poultry litter compared with -120 to 147 kg C ha(-1) yr(-1) with NH(4)NO(3). Poultry litter also increased PCM and MBC compared with NH(4)NO(3). Cropping increased SOC, POC, and PCM compared with fallow in NT. Long-term poultry litter application or continuous cropping increased soil C storage and microbial biomass and activity compared with inorganic N fertilization or fallow, indicating that these management practices can sequester C, offset atmospheric CO(2) levels, and improve soil and environmental quality.     

Overexpression of ATP sulfurylase in Indian mustard: effects on tolerance and accumulation of twelve metals

Indian mustard [Brassica juncea (L.) Czern.] transgenics overexpressing ATP sulfurylase (APS plants) were shown previously to have higher levels of total thiols, S, and Se. The present study explores the effect of ATP sulfurylase overexpression on tolerance and accumulation of other metals, both oxyanions and cations, reasoning that some anions may react directly with ATP sulfurylase, while other ions may be bound by its thiol end products. The APS transgenics were compared with wild-type plants with respect to tolerance and accumulation of As, Cd, Cr, Cu, Hg, Mn, Mo, Ni, Pb, V, W, and Zn, supplied individually in agar medium (seedlings) or in hydroponics (mature plants). At the seedling stage, APS transgenics were more tolerant than wild type to As(III), As(V), Cd, Cu, Hg, and Zn, but less tolerant to Mo and V. The APS seedlings had up to 2.5-fold higher shoot concentrations of As(III), As(V), Hg, Mo, Pb, and V, and somewhat lower Cr levels. Mature APS plants contained up to 2.5-fold higher shoot concentrations of Cd, Cr, Cu, Mo, V, and W than wild type. They also contained 1.5- to 2-fold higher levels of the essential elements Fe, Mo, and S in most of the treatments. Mature APS plants showed no differences in metal tolerance compared with the wild type. Overexpression of ATP sulfurylase may be a promising approach to create plants with enhanced phytoextraction capacity for mixtures of metals.     

烟气脱硫方法简介

结合目前国内主要的几种燃煤烟气的脱硫方法,如干法、半干法、湿法等,介绍了新型的烟气循环流化床的脱硫工艺及主要特点,并对其在烟气处理领域应用的前景进行了展望。     

Effect of flue gas desulfurization (FGD) by-product on water quality at an underground coal mine

In this paper, a field study was carried out to examine the effect of flue gas desulfurization (FGD) by-product on water quality at an underground coal mine in central-eastern Ohio. Flue gas desulfurizalion by-product was injected into the down-dip portions of the Robert-Dawson mine in an attempt to seal major seeps exiting the mine and to coat exposed pyritic surfaces. Immediately following grout injection, significant increases in acidity, iron, aluminum, sulfur, and calcium were observed at most surface and ground water locations near where grouting was carried out. Following this initial flush of elements, concentrations of most constituents have decreased to near pre-grouting levels. Data from the site and geochemical modeling suggest that an increase in water level or rerouting of drainage flow resulted in the dissolution of iron and aluminum sulfate salts and ferrihydrite. Dissolution of the FGD grout material resulted in increases in calcium and sulfate concentrations in the drainage waters. Water within the mine voids was saturated with respect to calcium sulfate and gypsum immediately following grout injection. Based on an analysis of core samples obtained from the site, acid mine drainage (AMD) was in contact with at least some portions of the grout and this resulted in grout weathering. Subsequent transport of calcium and sulfate to the underclay, perhaps by fracture flow, has resulted in the deposition of gypsum and calcium sulfate solids.     

Long-term biosolids application effects on metal concentrations in soil and bermudagrass forage

The long-term application of biosolids that periodically contained elevated metal concentrations has raised questions about potential effects on animal health. To address these concerns, we determined metal concentrations (As, Cd, Cu, Pb, Hg, Mo, Ni, Se, and Zn) in both soil and bermudagrass [Cynodon dactylon (L.) Pers.] forage from 10 fields in the following categories of biosolids application: six or more years (>6YR), less than six years (<6YR), and no applications (NS). Soil metal concentrations in all groups were similar to values reported for mineral soils in Georgia, and well below USEPA cumulative limits. Average metal concentrations in the forage were below the maximum tolerable level (MTL) for beef cattle, although two biosolids-amended fields in the >6YR group produced forage that was at or near the MTL for Cd and Mo, and one field in the <6YR group produced forage above the MTL for Cd. The Cu to Mo ratios in forage decreased with increasing time of sludge application, with the average in the >6YR group at a proposed 5:1 Cu to Mo ratio limit to protect ruminant health. Sulfur concentrations in the forage from all three groups was near the MTL of 4 g kg(-1). The study indicated that toxic levels of metals have not accumulated in the soils due to long-term biosolids application. Overall forage quality from the biosolids-amended fields was similar to that of commercially fertilized fields; however, due to the relatively high S and potential for a low Cu to Mo ratio, Cu supplements should be used to ensure ruminant health.     

Irrigation of broccoli and canola with boron- and selenium-laden effluent

Selenium (Se), boron (B), and salinity contamination of agricultural drainage water is potentially hazardous for water reuse strategies in central California. To demonstrate the feasibility of using plants to extract Se from drainage water, Se accumulation was determined in canola (Brassica napus L.) and broccoli (Brassica oleracea L.) irrigated with drainage effluent in the San Joaquin Valley, California. In the 2-yr field study, both crops were irrigated with a typical drainage water containing Se (150 microg L(-1)), B (5 mg L(-1)), and a sulfate dominated salinity (EC of 7 dS m(-1)). Total dry matter yields were at least 11 Mg ha(-1) for both canola and broccoli, and plant tissue Se concentrations did not exceed 7 mg kg(-1) DM for either crop. Based on the amount of soluble Se applied to crops with drainage water and the estimated amount of soluble Se remaining in soil to a depth of 90 cm at harvest, both canola and broccoli accumulated at least 40% of the estimated soluble Se lost from the soil for both years. Applied Se not accounted for in plant tissue or as soluble Se in the soil was presumably lost by biological volatilization. This study suggests that irrigating two high value crops such as canola and broccoli with Se-laden effluent helps manage Se-laden effluent requiring treatment, and also produces economically viable Se-enriched crops. Future research should focus on managing residual salt and B in the soil for sustaining long time water reuse strategies.     

资源回收型湿式氨法烟气脱硫技术

阐述了资源回收型湿式氨法烟气脱硫技术的原理和适用范围;介绍了该技术在电力行业、化工行业的应用情况及应用前景;指出回收型湿式氨法烟气脱硫工艺成熟、适用煤种广、脱硫效率高、运行稳定,其副产品硫酸铵的品质符合农用化肥标准,可完全满足农业应用要求,是一种可实现循环经济的绿色脱硫工艺。     

沼渣连续施用对土壤微生物量碳、氮剖面分布的影响

通过"棉花+小麦"轮作施用沼渣的定位试验,研究不同年限的沼渣施用对土壤剖面微生物量C、N(MBC、MBN)分布特征的影响。结果表明:在0~50cm剖面上,施用沼渣1年对0~30cm土壤的MBC、MBN影响较大,能显著提高30~40cm土层土壤MBC、MBN的含量,施用沼渣5年时对40~50cm土层MBC、MBN无明显影响。土壤MBC、MBN含量总体随施用沼渣年限的延长而增加,各土层MBC、MBN含量增幅随着施用年限的延长呈现不同趋势。施用沼渣1年,耕层土壤的MBC/MBN值较习惯耕作增加,施用沼渣3年后,其值呈降低趋势。各土层的MBC/TOC、MBN/TN和MBC的变化趋势基本一致,总体随着沼渣施用年限的延长而增加。针对"棉花+小麦"轮作模式,持续施用沼渣3年更有利于改善0~40cm土层土壤肥力。     

极端严寒地区湿法烟气脱硫系统的设计

通过实例,介绍了如何通过设计优化,使湿法烟气脱硫系统(FGD)在我国北方极端严寒地区的脱硫工程中得到稳定、可靠的运行.     

广东省火电厂烟气脱硫装置的经济技术分析

简要介绍了广东省7个火电厂现有的5种烟气脱硫技术装置：海水脱硫、荷电干式烟气脱硫、湿式石灰石／石膏法烟气脱硫、DCL燃煤固硫剂脱硫及烟气循环流化床脱硫技术，对它们的经济、技术性进行了分析比较。     

Simulated effects of crop rotations and residue management on wind erosion in Wuchuan,west-central Inner Mongolia,China

For decades, wind erosion has triggered dust and sand storms, buffeting Beijing and areas of northwestern China to the point of being hazardous to human health while rapidly eroding crop and livestock productivity. The EPIC (Environmental Policy Integrated Climate) field-scale simulation model was used to assess long-term effects of improved crop rotations and crop residue management practices on wind erosion in Wuchuan County in Inner Mongolia. Simulation results indicate that preserving crop stalks until land is prepared by zone tillage for the next year's crop in lieu of using them as a source of heating fuel or livestock fodder significantly reduces wind erosion by 60%. At the same time, grain and potato (Solanum tuberosum L.) yields were maintained or improved. Significant reductions in erosion, 35 to 46%, also resulted from delaying stalk removal until late January through late April. Yearly wind erosion was concentrated in April and May, the windiest months. Additionally, the use of alternative crop rotations resulted in differences in wind erosion, largely due to a difference in residue stature and quality and differences in biomass produced. As a result, altering current crop rotation systems by expanding corn (Zea mays L.), wheat (Triticum aestivum L.), and millet [Sorghum bicolor (L.) Moench] and reducing potato and pea (Pisum sativum L.) production significantly reduced simulated wind erosion, thus diminishing the severity of dust and sand storms in northwestern China. Saving and protecting topsoil over time will sustain land productivity and have long-term implications for improving conditions of rural poverty in the region.     

FGD脱硫废水处理工艺及其优化设计

阐述了脱硫废水中污染物的去除机理,介绍了化学-机械沉降去除脱硫废水中悬浮物、重金属元素等物质的废水处理工艺,并对脱硫废水处理系统的优化设计进行了重点论述。     

Source-separated municipal solid waste compost application to Swiss chard and basil

A growth room experiment was conducted to evaluate the bioavailability of Cu, Mn, Zn, Ca, Fe, K, Mg, P, S, As, B, Cd, Co, Cr, Hg, Mo, Na, Ni, Pb, and Se from a sandy loam soil amended with source-separated municipal solid waste (SSMSW) compost. Basil (Ocimum basilicum L.) and Swiss chard (Beta vulgaris L.) were amended with 0, 20, 40, and 60% SSMSW compost to soil (by volume) mixture. Soils and compost were sequentially extracted to fractionate Cu, Pb, and Zn into exchangeable (EXCH), iron- and manganese-oxide-bound (FeMnOX), organic-matter (OM), and structurally bound (SB) forms. Overall, in both species, the proportion of Cu, Pb, and Zn levels in different fractions followed the sequence: SB > OM > FeMnOX > EXCH for Cu; FeMnOX = SB > OM > EXCH for Pb; and FeMnOX > SB = EXCH > OM for Zn. Application of SSMSW compost increased soil pH and electrical conductivity (EC), and increased the concentration of Cu, Pb, and Zn in all fractions, but not EXCH Pb. Basil yields were greatest in the 20% treatment, but Swiss chard yields were greater in all compost-amended soils relative to the unamended soil. Basil plants in 20 or 40% compost treatments reached flowering earlier than plants from other treatments. Additions of SSMSW compost to soil altered basil essential oil, but basil oil was free of metals. The results from this study suggest that mature SSMSW compost with concentrations of Cu, Pb, Mo, and Zn of 311, 223, 17, and 767 mg/kg, respectively, could be used as a soil conditioner without phytotoxic effects on agricultural crops and without increasing the normal range of Cu, Pb, and Zn in crop tissue. However, the long-term effect of the accumulation of heavy metals in soils needs to be carefully considered.     

Availability of arsenic, copper, lead, thallium, and zinc to various vegetables grown in slag-contaminated soils

To anticipate a possible hazard resulting from the plant uptake of metals from slag-contaminated soils, it is useful to study whether vegetables exist that are able to mobilize a given metal in the slag to a larger proportion than in an uncontaminated control soil. For this purpose, we studied the soil to plant transfer of arsenic, copper, lead, thallium, and zinc by the vegetables bean (Phaseolus vulgaris L. 'dwarf bean Modus'), kohlrabi (Brassica oleracea var. gongylodes L.), mangold (Beta vulgaris var. macrorhiza ), lettuce (Lactuca sativa L. 'American gathering brown'), carrot (Daucus carota L. 'Rotin', 'Sperlings's'), and celery [Apium graveiolus var. dulce (Mill.) Pers.] from a control soil (Ap horizon of a Entisol) and from a contaminated soil (1:1 soil-slag mixtures). Two types of slags were used: an iron-rich residue from pyrite (FeS2) roasting and a residue from coal firing. The metal concentrations in the slags, soils, and plants were used to calculate for each metal and soil-slag mixture the plant-soil fractional concentration ratio (CRfractional,slag), that is, the concentration ratio of the metal that results only from the slag in the soil. With the exception of TI, the resulting values obtained for this quantity for As, Cu, Pb, and Zn and for all vegetables were significantly smaller than the corresponding plant-soil concentration ratios (CRcontrol soil) for the uncontaminated soil. The results demonstrate quantitatively that the ability of a plant to accumulate a given metal as observed for a control soil might not exist for a soil-slag mixture, and vice versa.