Fate, behavior and effects of surfactants and their degradation products in the environment

Surfactants are widely used in household and industrial products. After use, surfactants as well as their products are mainly discharged into sewage treatment plants and then dispersed into the environment through effluent discharge into surface waters and sludge disposal on lands. Surfactants have different behavior and fate in the environment. Nonionic and cationic surfactants had much higher sorption on soil and sediment than anionic surfactants such as LAS. Most surfactants can be degraded by microbes in the environment although some surfactants such as LAS and DTDMAC as well as alkylphenols may be persistent under anaerobic conditions. LAS were found to degrade in sludge amended soils with a half-lives of 7 to 33 days. Most surfactants are not acutely toxic to organisms at environmental concentrations and aquatic chronic toxicity of surfactants occurred at concentrations usually greater than 0.1 mg/L. However, alkylphenols have shown to be capable of inducing the production of vitellogenin in male fish at a concentration as low as 5 microg/L. More toxicity data are needed to assess the effects on terrestrial organisms such as plants.     

Variation in Population Parameters: Adaptation to Toxic Environmental Factors

Some mechanisms of adaptation of natural populations to toxic environmental factors are discussed. The dandelion and hole-nesting birds are used as examples for demonstrating that an increase in the variation of reproductive parameters upon chemical environmental pollution favors the survival of those individuals in the populations that are better adapted to changes in the climate and other environmental conditions. The increased variation in reproductive parameters may promote the elimination of less fit individuals from populations. The ensuing energy loss is the cost of maintaining the population size in the chemically degraded environment.     

Fate of glutaraldehyde in hospital wastewater and combined effects of glutaraldehyde and surfactants on aquatic organisms

Glutaraldehyde (GA), an aliphatic dialdehyde disinfectant, and surfactants, one of the major components of detergents, are widely used in hospitals in order to eliminate pathogenic organisms causing nosocomial infectious diseases. After their use, disinfectants and surfactants reach the wastewater network together. The discharge of chemical compounds from hospital activities into wastewater is also a well-known problem, causing pollution of water resources and constituting an ecological risk for aquatic organisms. In this study, the chemistry and toxicology of GA and surfactant mixtures were reviewed in order to estimate their fate in aquatic ecosystems. Furthermore, their joint effects on aquatic organisms were experimentally assessed in the laboratory. A simple model of the additive joint action of toxicants was used to determine combined acute toxicity effects on the bacteria luminescence and Daphnia mobility of three mixtures containing GA at 1.5 x EC50 24 h [in mg/L] on Daphnia and anionic, cationic and nonionic surfactants at twice their critical micellar concentration (CMC). The mixture of GA and a cationic surfactant gave an EC50 30 min on Vibrio fischeri of 0.158%, with a concentration of 0.04 mg GA/L and 1.04 mg CTAB/L, which provided an additive action. The interaction between GA and an anionic surfactant on V. fischeri produced an antagonistic joint action with an EC50 30 min of 3.95%, containing 1.06 mg GA/L and 33.2 mg SDS/L. A synergistic action with an EC50 30 min of 8.4% on V. fischeri was observed for the mixture containing GA and a nonionic surfactant. Antagonistic interactions were observed for the joint action between GA and the surfactants studied on Daphnia. The mixture of GA and CTAB was more toxic (EC50 24 h=0.02%) than the two other mixtures (EC50 24 h GA+SDS=6%; EC50 24 h GA+TX 100=10%). This study provides new data on the toxicity of certain hospital pollutants entering the aquatic environment and detected in surface and groundwaters. It is necessary to study the joint effects of GA and surfactant mixtures following chronic and sublethal standard bioassays in order to estimate the contribution of the additive joint action models in assessing the environmental risk of hospital wastewater (HW).     

基于SWAT模型的昌江流域土地利用变化对水环境的影响研究

土地利用快速变化对水环境带来较大影响,定量分析土地利用与水环境污染的关系是土地利用结构调整的重要依据。利用3S技术,通过SWAT模型对1983年与2012年昌江流域的水量和水质模拟,分析了土地利用时空变化,结合氨氮、总磷模拟数据,定量分析了土地利用变化下该流域的水环境污染负荷。研究结果表明:该区域林地、草地、水域、城镇及建设用地呈增加趋势,耕地则呈减小趋势。林地占比最大,为70%左右,其次为水田。水田为水环境非点源负荷贡献的第一大来源,且其占流域略多于20%的面积,贡献了该区域总磷总量的53.48%~57.01%和氨氮总量的51.86%~56.57%;农业耕作以25%的地类面积,贡献了60%~65%的非点源污染负荷;旱地的单位面积贡献污染负荷高于林地及城镇及建设用地,表明农业非点源污染是该区域水环境非点源污染的主要来源。     

自然资源、技术进步与环境库兹涅茨曲线

不可再生自然资源的约束和环境质量的不断恶化是经济可持续发展必须要面对的挑战。就环境问题而言,现实中一个特征事实是,在不同的收入水平下人们对环境质量的需求不同,只有当收入达到一定水平之后,人们才会注重生活质量的改善。基于现有研究,在考虑非再生自然资源的约束条件下,本研究将环境质量作为生产要素的一部分引入最优增长理论的分析框架,探讨了在环境污染和自然资源双重约束下的长期经济增长问题。在非再生自然资源和环境污染的双重约束下,本研究表明解决环境问题必须要采用的手段是促使技术进步的创新研发,因为技术进步是环境库兹涅茨曲线出现拐点的不可或缺的一个必要条件。在市场竞争的环境下,由于知识的非竞争性质使得研究部门的研究是次优的。因此,政府应当通过适当的财政政策和法制安排以激励私人投资者研究与开发新技术的积极性。     

影响农村公众环保参与程度的主要因子辨析

公众参与是环境保护工作的基础,通过环保公众参与可以弥补政府和市场在环境保护中的不足,减少农业环境管理的费用。为了探讨影响农村公众参与的主要因子,为提高农村公众参与水平提供政策依据,用问卷的形式对无锡市大浦镇550人进行调查。问卷设计8个项目,共计24个问题,收集了农村公众环境意识和公众参与情况的相关数据。对调查结果运用逐步多元回归分析的方法进行统计分析,提取了5个影响农村公众参与最为显著的因子,根据偏回归系数的大小,依次为环保知识水平、环保关注程度、文化程度、环保法律意识、污染感受程度建立了逐步回归方程,根据回归分析结果和大浦镇实际情况,提出把提高大浦镇居民环保知识水平、环保关注程度、环保法律意识以及加强公众对污染的感受程度作为近期提高公众参与水平的快速、有效的方法,为解决该镇农业非点源污染提供了参考。〖     

Wastewater reuse in irrigation: A microbiological perspective on implications in soil fertility and human and environmental health

The reuse of treated wastewater, in particular for irrigation, is an increasingly common practice, encouraged by governments and official entities worldwide. Irrigation with wastewater may have implications at two different levels: alter the physicochemical and microbiological properties of the soil and/or introduce and contribute to the accumulation of chemical and biological contaminants in soil. The first may affect soil productivity and fertility; the second may pose serious risks to the human and environmental health. The sustainable wastewater reuse in agriculture should prevent both types of effects, requiring a holistic and integrated risk assessment. In this article we critically review possible effects of irrigation with treated wastewater, with special emphasis on soil microbiota. The maintenance of a rich and diversified autochthonous soil microbiota and the use of treated wastewater with minimal levels of potential soil contaminants are proposed as sine qua non conditions to achieve a sustainable wastewater reuse for irrigation.     

河流渗滤系统中苯系物污染去除机理实验模拟研究

河流渗滤是一种自然净化过程，污染河水通过该过程在河流沉积层中发生各种物理、化学和生物作用，使得污染物浓度降低，河水水质得到净化，从而达到增加地下水开采量的目的。通过静态吸附实验和淋滤实验模拟了苯系物（BTEX）在河流渗滤系统中的吸附行为和降解行为。两种环境行为中吸附作用对于BTEX的净化效果较为有限，当吸附达到饱和之后，并存在电子受体的情况下，BTEX能够发生厌氧微生物降解，降解作用能够更有效的去除BTEX污染物。其中去除效率最高的是间二甲苯，其次是乙苯、甲苯，去除率最差的是苯。微生物降解作用相对于BTEX浓度变化存在一个滞后期。BTEX各组分的土壤 水吸附分配系数Kd越大，总的降解效率也就越低。通过河流渗滤系统这一自然净化过程，可以有效地去除浓度较高的BTEX混合污染，在两种电子受体的情况下各组分平均去除效率都超过了60%，最高去除率均超过了80%。对于持续不断入渗的污染河水，当土壤吸附达到饱和、微生物活性受到抑制情况下，去除效率会大大降低，从而使BTEX穿透包气带进入含水层，对地下水产生危害     

中国工业环境规制强度的行业差异及收敛性研究

针对不同行业环境规制强度的差异性,本文运用收敛理论研究了行业环境规制强度的敛散性。传统上利用单位成本或产出的污染治理费用表示的行业环境规制强度可能存在有偏性,本文基于单位污染排放的污染治理费用测算行业环境规制强度,利用Theil指数和收敛检验模型,分析了2001—2015年中国35个工业行业环境规制强度差异、收敛性质及收敛机制。研究发现:(1)一些行业的环境规制强度与其污染强度未表现出相应的强关联性。(2)中国工业行业环境规制强度差异呈现"M"型变化趋势,污染行业与清洁行业之间的环境规制强度差异呈现先发散后收敛的倒"U"型趋势。(3)泰尔指数及其分解还表明,污染行业内部的子行业间环境规制强度差异很大,且是造成工业行业环境规制强度差异的最主要来源。(4)工业行业环境规制强度存在较长时段的σ收敛和较短时长的俱乐部收敛的同时,还存在绝对β收敛和条件β收敛,即低规制行业向高规制行业看齐,不同行业环境规制强度向各自的稳态水平靠近,此外,污染行业环境规制强度收敛速度慢于清洁行业。(5)企业规模成长和市场化水平提升有利于促进企业提高环境规制水平。(6)对收敛机制的进一步研究表明,出口学习效应和进口技术溢出对行业环境规制强度变化的提升效应随着环境规制强度的提高而扩大,即两者对行业环境规制强度变化具有提升效应,但无促进其收敛的作用。扩大企业规模、提升市场化和对外开放水平,有利于提升企业应对环境规制的能力,并为下一阶段实施更为合理有效的环境规制政策提供支撑。     

Effects of heavy metal pollution on the ecological and biological characteristics of common chernozem

A detailed comprehensive study on the effects of heavy metals on the biological activity and other characteristics of common chernozem of the southern European facies was performed. This involved the analysis of various microbiological and biochemical indices characterizing soil biological activity, their dynamics, a set of several metals and their different chemical forms, and a wide range of metal concentrations in the soil. New important aspects of the effects of heavy metals on biological processes in the soil were revealed. An integral method was proposed for assessing changes in the total biological activity of the soil on the basis of informative indices used in the monitoring, diagnosis, and indication of soils polluted with heavy metals. Geographic trends in changes of soil resistance to heavy metal pollution were analyzed within the common chernozem subtype and by comparing chernozem with other soils.     

排污补贴视角下的养殖户环保投资影响因素研究——基于沪、苏、浙生猪养殖户的调查分析

随着畜牧业的发展,畜牧业污染问题日益突出。解决污染问题的关键是增强养殖户参与,鼓励他们自发进行环保投资,而政府补贴对于具有外部性的生产投资活动均具有刺激作用。为了量化分析影响农户环保投资行为的各因素的作用程度,特别是政府补贴的激烈效果,本文运用调查结合实证的研究方法,在农户模型的分析框架上,以沪、苏、浙地区394户生猪养殖户的调查数据为基础,应用有序logit模型验证排污补贴、养殖户生产经营特征、环保需求特征对养殖户环保投资的作用。研究表明除了政府补贴会刺激养殖户的环保投资外,养殖规模对环保投资有激励作用,而养殖年限却会抑制环保投资。养殖户的个人特征,对污染的认知及参与污染治理的意愿也对环保投资水平有正的影响,但作用效果不明显。在此基础上,本文提出了合理制定和推进排污补贴政策,以"离牧补助"等形式促使养殖规模和环保要求不符的养殖户退出养殖业,加大畜牧业污染危害的宣传力度以及政府加强对污染处理技术的研发投资,从而降低处理成本等政策建议。     

Removal of residual pharmaceuticals from aqueous systems by advanced oxidation processes

Over the past few years, pharmaceuticals are considered as an emerging environmental problem due to their continuous input and persistence to the aquatic ecosystem even at low concentrations. Advanced oxidation processes (AOPs) are technologies based on the intermediacy of hydroxyl and other radicals to oxidize recalcitrant, toxic and non-biodegradable compounds to various by-products and eventually to inert end-products. The environmental applications of AOPs are numerous, including water and wastewater treatment (i.e. removal of organic and inorganic pollutants and pathogens), air pollution abatement and soil remediation. AOPs are applied for the abatement of pollution caused by the presence of residual pharmaceuticals in waters for the last decade. In this light, this paper reviews and assesses the effectiveness of various AOPs for pharmaceutical removal from aqueous systems.     

资源型城市环境规制的经济增长效应及其传导机制——基于创新补偿与产业结构升级的双重视角

对于中国多数资源型城市来说,改善生态环境与促进经济增长是当前面临的重要任务。一些研究认为治理环境污染可能加重"遵循成本",进而不利于经济增长;也有研究认为环境规制会通过"创新补偿"效应,增进当地产品竞争力,弥补企业成本负担并促进经济增长;此外,还有研究认为环境标准提高有助于区域产业结构升级,进而带动经济增长。为验证中国资源型城市环境规制对经济增长的影响及其传导机制,本文基于2004—2014年资源型城市数据,以样本城市GDP为被解释变量,以工业污染治理设备运行费用为解释变量,进行了面板数据实证分析,并观察了科技行业人员比重和第三产业比重的中介效应。结果显示:(1)资源型城市工业污染物治理对GDP总量和人均GDP的影响均显著为正;(2)在环境规制与GDP(或人均GDP)的正向关系中,科技行业人员比重的提升起到了部分中介作用,即存在显著的创新补偿效应;(3)除了传统观点看到的创新补偿效应,污染治理对产业结构的积极影响也在二者正向关系中有重要的中介作用,而且比创新补偿效应的作用更显著。本文的结论是,资源型城市环境规制未对经济增长造成不利影响,主要是由于经济资源从效益不佳的工业企业流向了第三产业,同时工业部门自身的创新潜力也已逐步凸显。因此,面对经济社会持续发展的压力,资源型城市要取得经济增长与生态环境的双赢,应当强化污染治理成本对企业技术进步的倒逼机制,进一步实现创新驱动发展,同时要构建多元产业体系,促进资源型行业与现代服务业的有效对接和深度融合。     

Exploring the effect of producer services and manufacturing industrial co-agglomeration on the ecological environment pollution control in China

Based on the perspective of government-dominated and market-driven industrial co-agglomeration mode, the effect of producer services and manufacturing industrial co-agglomeration on the ecological environment pollution control is explored by using spatial Durbin model, and the mediating effect of technological innovation is further tested. The results show that: (1) At the national level, the government-dominated industrial co-agglomeration only significantly promotes the local ecological environment pollution control, while the market-driven industrial co-agglomeration also can promote the ecological environment pollution control in the surrounding region through its spatial spillover effect. Moreover, there is a significant inverted “U-shaped” curve relationship between the economic development level and ecological environment pollution. Additionally, the environment regulation is also conducive to promoting the ecological environment pollution control, while the industrial structure and foreign direct investment will lead to more serious ecological environment pollution; (2) In the east region, the government-dominated and market-driven industrial co-agglomeration can promote the ecological environment pollution control in the local and surrounding regions, and the promotion effect and spatial spillover effect of market-driven industrial co-agglomeration are greater. However, in the central and west regions, the government-dominated industrial co-agglomeration and market-driven industrial co-agglomeration only promote the local ecological environment pollution control. (3) Technological innovation has partial mediating effect in the impact of government-dominated and market-driven industrial co-agglomeration on the ecological environment pollution control, namely that the government-dominated and market-driven industrial co-agglomeration not only can directly promote the ecological environment pollution control, but also can indirectly promote the ecological environment pollution control through the mediating effect of technological innovation.

     

省以下生态转移支付制度环境保护激励效应

现有文献认为生态转移支付具有基本公共服务均等化与提升地方生态环境质量双目标,而目标的多样性会影响地方财政转移支付资金效果及目标的实现。文章基于环保支出和农林水支出的中介与调节效应,对生态转移支付的生态环境目标进行了理论分析,利用2010—2018年甘肃、贵州、湖北及河南四省的199个县的面板数据进行实证检验。实证研究表明:在样本期内,生态转移支付促进了地方生态环境质量的提升,中介效应和调节效应模型的结果表明,中国地方生态转移支付资金对辖区环境保护效果中,环境保护支出起到部分中介效应,农林水支出不仅调节了生态转移支付的地方环境保护支出效果,而且调节了环境保护支出对地方环境质量的影响。因此,由于地方政府具有环境治理信息优势,省以下制度目标更能体现辖区生态需求,省对县生态转移支付制度会有效促进地方生态环境质量的改善,环保激励效应较为明显。同时,县级地方政府应该逐步摆脱"先污染后治理"的路径依赖,逐步转向经济与环境"双目标协同发展"模式。为了协同生态转移支付的双目标,"自下而上参与式决策"可以作为环境治理的有益补充,通过地方政府多元化实践改善环境质量。     

Environment,development and sustainability of local practices in the sacred groves and shrines in Bongo District: a bio-cultural study for environmental management in Ghana

The eminent crisis threatening biological and resource diversity is a global adversity. Global resource diversities are constantly disappearing and deteriorating at quite an alarming proportion, provoking renewed thinking regarding the effectiveness of existing environmental management approaches and practices. For the past four decades, several epochs of environmental management policies and practices disregarded the cultural imperative for safeguarding efficient environmental management outcomes, particularly at the community level. Even in the rouse of this reality, issues of spirituality and how it binds local community people to their natural environment appear to be given only a window dressing attention through the recognition of sacred natural sites. Eight sacred groves and shrines in the Bongo District were investigated based on an endogenous development framework. The data were collected using focus group discussions with stakeholders at the local and district levels and individual interviews with key local natural resource managers from four selected communities. The study revealed that the way indigenous people construct the worldviews and interactions with nature using ancestors and other spirit mediums can safeguard the environment against long periods of human interference and destruction. It also demonstrates that in certain places traditional institutions are becoming malleable and open to the use of external knowledge and resources in order to sustain places of sacred significance. It concludes that cultural imperative and the issues of spirituality are critical for the sustainable management of environmental resources. The study recommends revisiting local practice and cultural values that promote good environmental management practices within the local communities.     

1990-2009年中国省际环境污染综合评价

本文以中国省级经济单元为分析对象,以环境污染为研究中心,基于"纵横向"拉开档次法的动态综合评价原理,通过构建具有"三维"特征的环境污染动态综合评价模型,计算了各省1990-2009年的环境污染综合指数,研究了影响环境污染变动的决定因素。结论认为,在样本考察期内,污染物排放最少(即环境质量最好)的省份依次为:青海、天津、北京、宁夏、新疆、甘肃、上海、吉林、福建、云南,这10个省份的环境污染综合指数都在1.50以下;要完成"十二五"主要污染物排放比2010年下降8%的减排目标,四川、河北、山东、辽宁、山西、江苏、河南、广东、湖南、广西是重点监控省份。分地区看,西部地区环境污染最小,依次为中部和东部。污染物排放变动的影响因素分析表明,提高经济发展水平、增加污染治理投资、加强企业环境管制能力对降低污染物排放具有一定的积极作用,第二产业所占比重、国有及国有控股工业所占比重及煤炭消费所占比重增加具有显著增加污染物排放的作用,外资进入对环境污染有一定的影响。据此提出了优化环境质量的对策建议。     

Negatively-charged air conditions and responses of the human psycho-neuro-endocrino-immune network

BACKGROUND: Against increasing environmental adverse effects on human health such as those associated with water and ground pollution, as well as out- and indoor air conditions, trials were conducted to support and promote human health by improving the indoor air atmosphere. This study was performed to estimate the effect of negatively-charged air conditions on human biological markers related to the psycho-neuro-endocrino-immune (PNEI) network. OBJECTIVES: After construction of negatively-charged experimental rooms (NCRs), healthy volunteers were admitted to these rooms and control rooms (CTRs) and various biological responses were analyzed. METHODS: NCRs were constructed using a fine charcoal coating and applying an electric voltage (72 V) between the backside of walls and the ground. Various biological markers were monitored that related to general conditions, autonomic nervous systems, stress markers, immunological parameters and blood flow. RESULTS: Regarding the indoor environment, only negatively-charged air resulted in the difference between the CTR and NCR groups. The well-controlled experimental model-room to examine the biological effects of negatively-charged air was therefore established. Among the various parameters, IL-2, IL-4, the mean RR interval of the heart rate, and blood viscosity differed significantly between the CTR and NCR groups. In addition, the following formula was used to detect NCR-biological responses: Biological Response Value (BRV)=0.498+0.0005 [salivary cortisol]+0.072 [IL-2]+0.003 [HRM-SD]-0.013 [blood viscosity]-0.009 [blood sugar]+0.017 [pulse rate]. CONCLUSIONS: Negatively-charged air conditions activated the immune system slightly, smoothened blood flow and stabilized the autonomic nervous system. Although this is the first report to analyze negatively-charged air conditions on human biological responses, the long-term effects should be analyzed for the general use of these artificial atmospheres.     

个人规范对农户亲环境行为的影响分析——基于拓展的规范激活理论框架

农户的亲环境行为可在一定程度上缓解农业环境污染,为改善农业环境,探寻农户实施亲环境行为的原因所在,将农户环境污染感知、环境关心和社会规范加入规范激活理论框架对其进行拓展,在此基础上,通过构建结构方程模型和层次回归模型,利用陕西、山西、甘肃、安徽和江苏5省的实地调查数据,对农户的亲环境行为进行分析。结果表明:农户的亲环境个人规范、环境污染感知和环境关心均可对其亲环境行为产生直接的正向影响,且个人规范对行为的影响程度最大;结果意识、责任归属、农户的环境污染感知和环境关心均可对其亲环境的个人规范产生直接的正向影响,且其影响程度从高到低依次为:结果意识、责任归属、环境污染感知和环境关心;农户的环境污染感知和环境关心可同时对其亲环境行为产生直接和间接影响作用,而结果意识和责任归属仅可对其亲环境行为产生间接影响作用;社会规范可正向调节个人规范对农户亲环境行为的影响。