转炉污泥干法脱硫新技术应用

采用转炉污泥取代铸铁屑配制焦炉煤气脱硫剂,转炉污泥与稻壳体积配比为１：２,水分３０％－４０％,ｐＨ８－１０。实践证明,脱硫效率达到９９．６％－９９．８％,既降低了煤气生产成本,减轻工人劳动强度,又提高了民用煤气质量,具有可观的环境效益与经济效益。     

水传染病原微生物的去除技术

病原原生动物如阴子虫和贾第虫及其１卵囊或囊对水源水和饮用水的污染及其危害致病，已成为国际研究的重点。其去除方法分为两大类，一为阻截去除，一为杀灭去除，过滤截留其去除病原微生物的效率与滤出水使度有关，出水浊度≤０．１ＮＴＵ的处理系统能非常有效地去除病原菌、病毒和病原原生动物虫卵，去除率分别大于６ｌｏｇ、５ｌｏｇ、４ｌｏｇ（即９９．９９９９％、９９．９９９％和９９．９９％），纳滤和反渗墓这滤，能全部去     

生化法处理煤气废水

采用Ａ／Ｏ工艺处理煤气废水的研究结果表明,该工艺能同时去除煤气废水中的有机物和氨氮,在试验确定的条件下,该工艺对煤气废水中的ＣＯＤｃｒ去除率达９１．０％,ＢＯＤ５去除率达９９．１％,ＮＨ３－Ｎ去除率达９９．２％,ＴＮ去除率达９４．７％。     

PNN破乳剂的合成及其乳化液废水处理

由氨,仲胺与伯胺及表卤代醇合成制备了合成制备了高效破乳剂ＰＮＮ,并用以处理乳化油废水,取得了较好的效果。结果表明,在ＰＨ＝６．０－７．５,投量为１．８８‰３．０‰的条件下,用ＰＮＮ处理ＣＯＤｃｒ为７１８４０ｍｇ／Ｌ、ｉｍｇ ｏ １５５３４ｍｇ／Ｌ、油为１５５３４ｍｇ／Ｌ的某乳化油废水,最佳ＣＯＤｃｒ去除率达９２．７％,最佳油去除率达９９．９％。,浊度去除率达到９９．９％,该药剂破乳后固液分离性能较     

新型无机高分子絮凝剂在制革废水处理中的应用研究

介绍了一种新型无机高分子絮凝剂－硅钙复合型聚合氯化铝铁（ＳＣＰＡＦＣ）在制革废水处理中的应用。结果表明，该产品对废水的浊度去除率为９９％，ＳＳ去除率为９５％，ＣＯＤ去除率为９０％，Ｃｒ＾３＋的去除率为８５％左右。最佳使用ｐＨ值为６．０￣９．０，最佳投药量为０．３５￣０．４０ｇ／Ｌ，最佳混凝时间为１５￣２０ｍｉｎ，在同样条件下各项性能均优于ＰＡＣ２倍以上。同时该絮凝剂还可用于生活饮水、生产用水及其他     

正交试验硫酸亚铁处理液体硫化艳绿染料废水

液体硫化染料具有内涵一致，无飞尘，无杂质，上色好，适合计算机控制连续染色，在国外广泛应用。我国也在迅速地推广之。液体硫化染料水污染重、危害大，必须经过脱硫，降解ＢＯＤ和ＣＯＤ，和除色处理，试验取液体硫化绿生产废水，经曝气脱硫，正文试验选择硫酸亚铁混凝最佳配合条件和碱析，使废水ＣＯＤ，ＢＯＤ，Ｓ＾２－，色度的去除率各达９２％，９２．９％，９８．７％，９９．９５。使高色度（２５０００倍）、高ＣＯＤ（６     

石灰—硫酸亚铁法处理高浓度砷和氟酸性废水试验研究

采用二级石灰－硫酸亚铁法处理砷和氟浓度分别高达１１０ｍｇ／Ｌ和６５０ｍｇ／Ｌ以上的酸性废水。当一、二级控制条件分别为ｐＨ９．５和９．０、Ｆｅ／Ａｓ比为２．５和１５时，一级砷和氟去除率分别可达９９．５％和９４％，二级出口砷和氟残余浓度分别可低至０．１ｍｇ／Ｌ和１３．８ｍｇ／Ｌ，Ｃｕ、Ｚｎ和Ｐｂ等重金属离子均达检不出水平。     

市政沥青混凝土生产设备烟尘的治理设计

介绍了市政沥青混凝土生产过程中烟尘采用电除尘器除尘的治理设计运用测试表明除尘效率达到了９９．７％，确保了排放气体的烟尘浓度达到国家标准。     

炼铜烟灰制取高纯度硫酸锌

采用炼钢烟灰制取高纯度硫酸锌,研究了制取条件对收率和产品质量的影响,试验结果表明,控制适宜的酸浸条件,锌浸取率≥９８％,铁浸取率可控制在０．０２％以下,当酸浸工艺条件液固比为３：１,温度８０－９０℃,硫酸加入量３９ｇ／Ｌ（酸浸液）滴酸时间１．５ｈ浸取时间２ｈ,再用空气和过氧化氢氧化除去溶液中的铁,产品中硫酸锌含量≥９９％,铁含量可降至０．５ｍｇ／Ｌ以下。     

超临界水氧化法处理高浓度有机发酵废水

对酒精废水和乙酰螺旋素废水进行了超临界氧化降解的研究,结果表明,超临界水氧化法是处理高浓度有面废水的一种有效方法,在实验的条件范围内,废水ＣＯＤ的去除率最高可达９９．２％。     

Electrogenerative gold recovery from cyanide solutions using a flow-through cell with activated reticulated vitreous carbon

An electrogenerative flow-through reactor with an activated reticulated vitreous carbon cathode was developed. The influence of palladium-tin activation of the cathode towards gold deposition was studied by cyclic voltammetry. The reactor proved to be efficient in recovering more than 99% of gold within 4 h of operation. The performance of the reactor was evaluated with initial gold concentrations of 10, 100 and 500 mg L-1 and various electrolyte flow rates. Gold recovery was found to be strongly dependent on electrolyte flow rate and initial gold concentration in the cyanide solution under the experimental conditions used.     

An electrogenerative process for the recovery of gold from cyanide solutions

Traditional methods for the recovery of gold from electronic scrap by hydrometallurgy were cyanidation followed by adsorption on activated carbon or cementation onto zinc dust and by electrowinning. In our studies, a static batch electrochemical reactor operating in an electrogenerative mode was used in gold recovery from cyanide solutions. A spontaneous chemical reaction will take place in the reactor and generate an external flow of current. In this present work, a static batch cell with an improved design using three-dimensional cathodes namely porous graphite and reticulated vitreous carbon (RVC) and two-dimensional cathode materials, copper and stainless steel plates were coupled with a zinc anode. The electrogenerative system was demonstrated and the performance of the system using various cathode materials for gold recovery was evaluated. The system resulted in more than 90% gold being recovered within 3h of operation. Activated RVC serves as a superior cathode material having the highest recovery rate with more than 99% of gold being recovered in 1h of operation. The morphology of gold deposits on various cathode materials was also investigated.     

Phosphorus recovery from fosfomycin pharmaceutical wastewater by wet air oxidation and phosphate crystallization

Fosfomycin pharmaceutical wastewater contains highly concentrated and refractory antibiotic organic phosphorus (OP) compounds. Wet air oxidation (WAO)-phosphate crystallization process was developed and applied to fosfomycin pharmaceutical wastewater pretreatment and phosphorus recovery. Firstly, WAO was used to transform concentrated and refractory OP substances into inorganic phosphate (IP). At 200 °C, 1.0 MPa and pH 11.2, 99% total OP (TOP) was transformed into IP and 58% COD was reduced. Subsequently, the WAO effluent was subjected to phosphate crystallization process for phosphorus recovery. At Ca/P molar ratio 2.0:1.0 or Mg/N/P molar ratio 1.1:1.0:1.0, 99.9% phosphate removal and recovery were obtained and the recovered products were proven to be hydroxyapatite and struvite, respectively. After WAO-phosphate crystallization, the BOD/COD ratio of the wastewater increased from 0 to more than 0.5, which was suitable for biological treatment. The WAO-phosphate crystallization process was proven to be an effective method for phosphorus recovery and for fosfomycin pharmaceutical wastewater pretreatment.     

Treatment of Halogenated Organic Vent Streams for the Reduction of Air Emissions

Abstract

This work presents a three-stage treatment system to process halogenated organic vent streams for compliance with the Hazardous Organic NESHAP (HON) Rule. The three stages are incineration, energy recovery, and wet scrubbing. In particular, this work concentrates on the design of the scrubber, which the HON Rule states must remove at least 99% of any halogens or hydrogen halides generated during the combustion step. Computerized process simulation was found to be ineffective in designing a scrubber for this application, so laboratory data on the partial pressure of the hydrogen halide species over aqueous solutions was employed. The number of overall gas transfer units required for 99% removal was found to be slightly less than 5, and the overall gas transfer unit height was found to be approximately 0.5 m.     

蒽醌生产中废硫酸的萃取脱色处理

以萃取法对蒽醌生产中的废硫酸进行脱色处理,优化选择工对脱色工艺进行初步的探讨。处理前的废硫酸色度约５０００倍,ＣＯＤ浓度约３００００ｍｇ／Ｌ,经过萃取脱色后色度低于１５０倍,去除率〉９７％,ＣＯＤ浓度约２５０ｍｇ／Ｌ,去除率约为９９％,硫酸含量约４０％。同活性炭吸附等方法相比,该萃取法具有操作简单,成本低,处理效果好的特点。     

硫酸铅在柠檬酸钠-酸体系中的浸出转化

硫酸铅可以在柠檬酸钠-乙酸体系中脱硫转化生成柠檬酸铅。考察了柠檬酸钠投加量、反应时间、固液比以及反应温度对PbSO4浸出转化的影响。实验结果表明,PbSO4的转化率随着柠檬酸钠投加量和反应时间的增加而增大,固液比和反应温度对浸出过程影响不大。溶液中溶解的铅含量随着柠檬酸钠投加量的增大而增大,其他条件对其影响不明显。最佳浸出工艺条件是：柠檬酸钠与PbSO。的物质的量之比为2：1,固液比为1／5～1／3,反应温度为25℃,反应时间为2h,此时PbSO4的转化率可达到99％左右,溶液中的铅含量为总铅的3．8％左右。PbSO4浸出得到[Pb,（C。H,O,）,]·3H2O,它在350℃左右可完全分解,得到PbO／Pb粉末。     

Enhanced Desorption of Atmospheric Samples from Activated Carbon

It has been previously shown that the desorption of either a chemisorbed or a physically adsorbed gas can be enhanced by the subsequent introduction of a foreign gas. Under conditions in which desorption recovery of butane from activated, carbon was 50 to 65%, subsequent adsorption of CCl₄ enhanced the recovery of butane to 100%. Recovery of CCl₂F₂, originally 79%, was enhanced to 99% by the same method. The method of enhanced desorption was applied to the recovery of samples from activated carbons exposed to atmospheres in Chicago, New Orleans, Philadelphia, Washington, D. C, and Cincinnati. Three different types of carbons, characterized by different distributions of pore diameters, were used simultaneously in the Cincinnati sampling. In general, the enhanced desorption technique was advantageous in providing analytical information on adsorbed samples recovered from carbon media. The enhancement effect is especially marked with hydrocarbon material. The effects of these structural attributes of the carbon media are evaluated by detailed consideration of infrared absorptions.     

支撑气膜法脱除／回收垃圾渗滤液中氨氮

利用由微孔疏水性聚丙烯中空纤维制成的工业级膜组件对垃圾渗滤液中氨氮进行支撑气膜法脱除研究,考察了泡沫分离．石灰絮凝等预处理技术对垃圾渗滤液表面张力及COD值的处理效果,在此基础上研究了物料因素和操作因素对膜传质性能的影响,并对该工艺的长期操作稳定性进行了研究。实验结果表明该预处理技术不仅可显著提高垃圾渗滤液的表面张力,还可大大降低其色度和COD值。当进料流量为100L／h、进料氨氮浓度为1000～3000mg／L、硫酸吸收液流量为200L／h、硫酸浓度为6％～10％、温度为20～30℃时,支撑气膜过程（两级膜组件串联）可有效脱除垃圾渗滤液中99％以上的氨氮,同时得到含10％～15％硫酸铵的水溶液作为副产品。工业级支撑气膜组件在连续运行的2个月内保持了良好的传质稳定性。     

The Behavior of Buoyant Merging Plumes in The Rocky Mountain Foothills

Natural gas often contains high concentrations of hydrogen sulfide which must be removed before the gas can be transmitted by pipeline. Sour gas plants extract the sulfur, by converting it to elemental sulfur through a modified Claus process. The sulfur recovery is 93% for small plants (10–100 tonnes of sulfur per day) to 99% for large plants (1000–4000 tonnes of sulfur per day). The unrecovered sulfur is Incinerated giving rise to relatively small emissions of SO₂ characterized by high buoyancy and low momentum.

Using a unique aerial probing methodology, plume dispersion studies were conducted on two plants located fn the foothills of southwestern Alberta, Canada. These studies were generally conducted under neutral conditions and with westerly air flows typical of Chinook conditions. Notable variations of the plume dispersion parameters from accepted predictive values were found, indicating that such values cannot be used with confidence to estimate plume rise and dispersion in the mountain foothills.