Environmental impacts and use of brominated flame retardants in electrical and electronic equipment

Management of waste electrical and electronic equipment (WEEE) or e-waste is becoming a major issue as around 20–50 million tons of such waste is generated worldwide and increasing at a higher rate than other solid waste streams. Electrical and electronic equipment (EEE) contains over 1,000 materials of which brominated flame retardants (BFRs) such as polybrominated biphenyls (PBBs) and polybrominated diphenyl ethers (PBDEs) have been the target of the regulators forcing manufacturers to adopt halogen-free flame retardants. As far as these alternatives are concerned, key consideration should be its performance during the whole life cycle through design, use and end-of-life management. The global halogen-free flame retardant movement has reached a point of no return. The most important issue as far as the environment is concerned, for which the transformation to halogen-free retardants was initially targeted, is to make sure that life span of the EEE using the alternatives to BFRs is not shortened thereby resulting in unforeseen increases in e-waste to deal with. The aim of this article is to investigate the environmental issues and current developments related to the use of BFRs in EEE manufacture. It describes the sources, toxicity and human exposure of BFRs, EOL management such as recycling and thermal treatments, exposure of BFRs from e-waste processing facilities and the environment around them and examines the developments and feasibility of the alternatives to BFR in EEE manufacture.     

Present status of the recycling of waste electrical and electronic equipment in Korea

In Korea due to rapid economical growth followed by urbanisation, breakage of large traditional families into small nuclear families, continuous changes in equipment features and capabilities causes tremendous increase in sale of new electrical and electronic equipment (EEE) and decrease in sale of used EEE. Subsequently, the ever-increasing quantity of waste electrical and electronic equipment (WEEE) has become a serious social problem and threat to the environment. Therefore, the gradual increase in the generation of WEEE intensifies the interest for recycling to conserve the resources and protect the environment. In view of the above, a review has been made related to the present status of the recycling of waste electrical and electronic equipment in Korea. This paper describes the present status of generation and recycling of waste electrical and electronic equipment, namely TVs, refrigerators, washing machines, air conditioners, personal computers and mobile phones in Korea. The commercial processes and the status of developing new technologies for the recycling of metallic values from waste printed circuit boards (PCBs) is also described briefly. Since 1998, three recycling centers are in full operation to recycle WEEE such as refrigerators, washing machines and air conditioners, having the total capacity of 880,000 units/year. All waste TVs are recently recycled on commission basis by several private recycling plants. The recycling of waste personal computers and mobile phones is insignificant in comparison with the amount of estimated obsolete those. Korea has adopted and enforced the extended producer responsibility (EPR) system. Korea is making consistent efforts to improve the recycling rate to the standards indicated in the EU directives for WEEE. Especially environmentally friendly and energy-saving technologies are being developed to recycle metal values from PCBs of WEEE.     

生产者责任延伸制度在电子废弃物管理中的探讨

电子废弃物的污染问题日益引起人们的关注，而我国传统废弃物的处理和管理制度的不完善使大量的有用资源没有得到有效回收，不符合全民节约和循环经济原则。本文从环境经济学角度，结合其它国家和地区的生产者责任延伸制的颁布和运行情况，对我国电子废弃物的管理中施行生产责任延伸制（EPR）进行初步探讨。     

Electronic waste recycling: A review of U.S. infrastructure and technology options

The useful life of consumer electronic devices is relatively short, and decreasing as a result of rapid changes in equipment features and capabilities. This creates a large waste stream of obsolete electronic equipment, electronic waste (e-waste).Even though there are conventional disposal methods for e-waste, these methods have disadvantages from both the economic and environmental viewpoints. As a result, new e-waste management options need to be considered, for example, recycling. But electronic recycling has a short history, so there is not yet a solid infrastructure in place.In this paper, the first half describes trends in the amount of e-waste, existing recycling programs, and collection methods. The second half describes various methods available to recover materials from e-waste. In particular, various recycling technologies for the glass, plastics, and metals found in e-waste are discussed. For glass, glass-to-glass recycling and glass-to-lead recycling technologies are presented. For plastics, chemical (feedstock) recycling, mechanical recycling, and thermal recycling methods are analyzed. Recovery processes for copper, lead, and precious metals such as silver, gold, platinum, and palladium are reviewed. These processes are described and compared on the basis of available technologies, resources, and material input–output systems.     

Current Levels and Management of Solid Wastes in Nigeria

Solid waste is of serious concern in developing countries because of its high rate of generation and the low‐end quality of its management. Inefficient handling of solid wastes may result in deterioration of environmental quality, but it can also result in loss of potential resources. This study reviews current solid waste generation and management in Nigeria and the need for an effective collection, recovery, and recycling policy. Our review is based on literature searches and personal field surveys. Observations showed that uncontrolled electronic waste (e‐waste), agricultural‐waste (agro‐waste), scrap metals, waste polymers, and waste from the transportation sector are prevalent in Nigeria. Recent collection rates were less than 50% of the total solid waste generated (i.e., approximately 40% was collected). With an effective collection system and appropriate policies, the abundance of solid waste in the country could present material recovery and recycling opportunities that would boost the economy and move Nigeria closer to sustainable resource management.     

Global disposal strategies for waste cathode ray tubes

The collection and management of waste electrical and electronic appliances around the world, and the possible negative environmental consequences have been an issue of current debate. Cathode ray tubes (CRTs) used as display screen for computer monitors and televisions contains large quantities of lead, estimated at between 0.5 and 4 kg, depending on the size of the CRT and has been identified as the most polluting of all electronic waste components. Having failed the tests used in the toxicity characterization of solid wastes, CRTs have been declared ‘hazardous’ and subsequently banned from landfills and incinerators in most developed countries. Presently, large quantities of CRTs are generated globally with only few developed countries having effective take back and sound management program. Meanwhile, large quantities of CRT-containing devices are being moved across frontiers into developing countries in the name of ‘reuse’ and ‘bridging the digital divide’. With near absence of recycling infrastructure for electronic wastes in most developing countries, waste CRTs are disposed of with MSW at open dumps and unsanitary landfills. This paper reviews the current practices in the management of CRTs around the world, with emphasis on the role of regulations, availability of recycling infrastructure, recycling/reuse routes, and export into developing countries. Inappropriate disposal of waste CRTs creates the opportunity for large-scale environmental contamination with heavy metals, especially lead. Appropriate disposal routes are required globally in the management of CRTs in order to mitigate environmental contamination and human exposure to toxins.     

进口废塑料环境保护管理研究

随着塑料资源的大量消耗,废塑料的利用引起了社会的高度重视。工艺简单,投入成本少,入行门槛低导致部分废塑料加工利用企业技术水平低、管理模式差、环境污染重。为规范进口废塑料行业,通过调研统计、实验分析、咨询论证和研究了进口废塑料环境保护管理规定,对进口废塑料企业的规模、设备、人员和管理等方面提出了要求,为进一步规范提升进口废塑料行业提供技术支撑。     

Two decades,three WEEE systems: How far did EPR evolve in Korea's resource circulation policy?

Extended producer responsibility (EPR) has become a dominant policy paradigm for the management of waste electrical and electronic equipment (WEEE) in the last two decades. In South Korea the principle has guided the evolution of the resource circulation policy even before its official introduction through a revision of the recycling law in 2002. Elements of producer responsibilities could be found in the producer-based deposit refund system (DRS) a decade earlier and they were strengthened through the enactment of a new resource circulation law in 2008. This article reviews the policy changes in South Korea for the management of WEEE during the past 20 years. The focus of the analysis is on the impacts of EPR and the producers’ responses that were expressed through the quantity and the quality of material flows in the society. The findings are discussed in light of international experiences in order to outline measures to improve the effectiveness of the EPR-based resource circulation policy that could have broader implications beyond the case study.     

基于工艺过程分析的废旧塑料再生利用污染源研究

在分析废旧塑料再生利用工艺过程的基础上,确定了废塑料综合利用工艺的产污节点,并通过物流平衡和水平衡计算,得出了总的产排污量,为环境保护措施提供重要依据,以实现保护环境和资源合理再生利用。     

Implementation of Waste Electrical and Electronic Equipment Directive in Finland: Evaluation of the collection network and challenges of the effective WEEE management

Further to the European Waste Electrical and Electronic Equipment (WEEE) Directive, setting up efficient collection schemes is necessary to ensure the recovery targets set. Following the subsidiary principle, the WEEE Directive defines only the general requirements for mandatory collection and recycling objectives. The modalities of the logistics and the organisation of the take-back schemes are left to the choice of Member States. In this paper, the implementation of the WEEE Directive and the development of the WEEE recovery infrastructure in Finland are described and the challenges to the effective management of the WEEE recovery system in Finland are expressed. It can be said that the implementation of the WEEE Directive has succeeded in Finland and, at the same time, the legislative basis has been enacted. In addition, a functional WEEE recovery infrastructure has been built and, the collection requirements of the WEEE Directive have been exceeded in a relatively short time. However, the paper outlines that some inefficient practices still exist, particularly in the registration and WEEE collection stages. It is concluded that raising awareness would lead to a more environmentally sound behaviour and would, ultimately, improve WEEE recovery efficiency.     

膨胀型阻燃聚丙烯材料的耐湿热性能研究

聚丙烯(PP)以其优异的力学性能、密度小、质量轻等特点而广泛用于汽车、家电、建筑等行业.但是聚丙烯容易燃烧,其氧指数只有18左右,且燃烧时还会产生大量熔滴,极易传播火焰,这大大限制了其应用.近年来,膨胀型阻燃剂(IFR)在阻燃PP中的应用受到了人们高度的重视.本文主要介绍膨胀型阻燃剂微胶囊制备及其微胶囊在聚丙烯中阻燃性...     

Life cycle indicators for monitoring the environmental performance of European waste management

As widely recognised by EU legislation, Life Cycle Thinking (LCT) is a viable approach to support sound waste management choices. In this context, the Institute for Environment and Sustainability (IES) of the European Commission Joint Research Centre (JRC) has lead the development of macro-level, life cycle based waste management indicators to quantify and monitor the potential environmental impacts, benefits, and improvements associated with the management of a number of selected waste streams generated and treated in Europe.The waste management indicators developed make use of a combination of macro statistical waste management data combined with emissions/resource life cycle data for the different elements of the waste treatment chain. Indicators were initially calculated for the entire European Union (EU-27) and for Germany, covering several waste streams and a broad range of environmental impact categories.An indicator developed for a given waste stream captures the potential environmental impact associated with the generation and management of that waste stream. The entire waste management chain is considered, i.e. from generation to final treatment/disposal. Therefore, system boundaries for the selected waste streams include also the treatment or recycling of secondary waste (e.g. bottom ash from the incineration of household waste), and secondary products (e.g. recovered paper), as well as energy recovery.The experiences from the development of these life cycle based waste management indicators suggest that more detailed and quality-assured waste statistics are needed, especially covering the many different treatment operations and options. Also, it would be beneficial if waste statistics had a higher disaggregation level of waste categories, as well as more detailed information about waste composition. A further development of the indicators should include an increased number of waste streams, as well as calculation of the results for all Member States.     

Public participation in plastics recycling schemes

Without public contributions, recycling from domestic waste would not be possible. In order to support recycling projects it is important to try to understand who recycles, how they recycle, and why they recycle. This paper presents the results of a structured survey of 500 members of the public served by schemes to collect plastics waste for recycling. Data were gathered on the characteristics, behaviours and motivations of recyclers. The authors also sought to discover how the public perceive plastics compared to other materials, and as a recyclable material. Responses were collected in such a way that the awareness of the recyclability of materials could be compared with the recycling behaviour of respondents. An element of comparison was introduced between those served by a system of bottle banks (bring scheme) and those covered by a household collection (collect scheme). The survey results are reported and their implications for the management of post-consumer plastics waste collection schemes are discussed.     

Improvements in financing for sustainability in solid waste management

Contributing elements toward the development of a sustainable solid waste management system in Tucumán, Argentina, are described. Changes in the working environment for the wastepickers have been instrumental in providing a livable wage and diminished health and environmental risks to the wastepickers and to neighboring residents. Income levels to the wastepickers are now approximately 1.75 times minimum wages in Tucumán and are being driven almost entirely by the recycling of plastics. Educational improvements in Tucumán, which are assisting sustainability of the solid waste system, are being significantly improved by the operation of a pilot scale project, by demonstrating opportunities to government officials and school children. Improved financial sustainability to the solid waste management system is also potentially available from carbon credit trading opportunities, presenting the opportunity for 1.2 times the income available from recycling efforts.     

Transitions of municipal solid waste management. Part II: Hybrid life cycle assessment of Swiss glass-packaging disposal

In policy support of municipal solid waste (MSW) management, life cycle assessment (LCA) can serve to compare the environmental or economic impacts of two or more options for waste processing. The scope of waste management LCAs generally focuses less attention on future developments, e.g., where will recycling take place, and more on the environmental performance of prototypes, e.g., the incineration of all waste compared to recycling. To provide more robust support for Swiss waste glass-packaging disposal, scenarios of Swiss waste glass-packaging are assessed from a life cycle perspective. The scenarios consist in schemes for the disposal of the total amount of Swiss waste glass-packaging, i.e., different combinations of recycling and downcycling in Switzerland or abroad developed in Part I, Meylan et al. (2013). In this article (Part II), the disposal schemes are assessed with respect to eco-efficiency, an indicator that combines total environmental impacts and gross value added in Switzerland. Results show that no policy alternative guarantees environmental impact reductions and gross value added gains under all developments of exogenous constraints. Downcycling to foam glass in Switzerland is not only an environmentally sound disposal option, but it also buffers gross value added losses in case domestic recycling (and thus glass-packaging production in Switzerland) ceases in the future. The substitution of products based on raw materials other than Swiss cullet is the main responsible for change in environmental and economic impacts. Hence, an eco-efficiency maximizing policy should consider the products of disposal schemes. The combination of scenario analysis and eco-efficiency assessment as presented in this paper can be applied to other contexts (i.e., countries, waste fractions).     

Closed loop recycling of plastics containing Flame Retardants

Annually 2.7 million tonnes of plastics containing Flame Retardants (FRs) are globally discarded in Waste Electrical and Electronic Equipment (WEEE). Little is known on the feasibility of closing material loops for FR plastics. Therefore, series of experiments were set up to analyze the feasibility of separating plastics containing FRs from one specific product category, namely End-of-Life (EoL) Liquid Crystal Display (LCD) TVs. The characterization of the housings of this waste stream indicated a concentration of 18 wt% Bromine based (Br) FRs and 31 wt% Phosphor based (P) FRs, the remainder not containing FRs. With practical tests it was demonstrated that, after disassembly and plastic identification, the co-polymer poly-carbonate (PC)/acrylonitrile-butadiene-styrene (ABS) containing PFR can be recycled in a closed loop system. Based on the determined plastic density distributions and separation efficiencies of optical sorters, a purity of 82% was calculated for PFR PC/ABS separated from EoL LCD TVs after size-reduction (shredding). Performed miscibility tests indicated that for this fraction at least a factor 10 dilution with virgin material is required. In addition, higher waste volumes are required for a size-reduction based treatment to become economically viable and technical challenges still need to be faced, whereas closed loop recycling of PFR PC/ABS from the current waste stream of EoL LCD TVs of different brands in a disassembly based treatment is found to be technically feasible and economically viable under European boundary conditions.     

Cathode ray tube recycling

Lead and polybrominated flame retardants are the two hazardous materials that can be found in electronic appliances. Particularly, cathode ray tubes (CRT) contain leaded glasses. In a computer monitor, over 98% of the lead is in the CRT. This material is generally not accepted for reuse as a component; only those from televisions can be reused. However, this currently represents only a very small market. Envirocycle (a US company) has developed a process to recycle all glasses contained in CRTs; this process includes cleaning and sorting glass. The product obtained is used for the manufacture of new CRT glass. Some industries have used pulverized glass from CRTs in smelting processes as slagging material instead of sand or slag. In this paper, some environmental issues related to the recycling of computers and television sets, and CRTs from computers are presented and discussed. Different processes used to recycle CRTs are described along with an economic analysis.     

我国电子废弃物处理产业现状与前景探讨

电子废弃物处理产业是伴随我国近年来社会经济快速发展而产生的一个新兴产业。本文分析了电子废弃物的经济价值、处理技术和产业政策,并对我国电子废弃物处理产业的现状与前景进行了探讨。     

Decision factors for e-waste in Northern Mexico: To waste or trade

Currently, around the globe, environmental and social problems derive from the inappropriate recycling of electronic products. Moreover, improper recycling is not the only issue to address in electronic products. Others include: energy intensity in their manufacture, employment generation related to the international trade in used electronics, and access to technology by low-income communities. Nevertheless, policies and controls created to provide socially and environmentally sound management of used electronics do not match the complexity of the system. In order to understand the e-waste system, particularly used computers, as a whole, a field study was done between 2010 and 2011 in ten Mexican cities. Ninety-five diverse stakeholders were interviewed to uncover factors regarding the decision to waste or trade still-usable computers. Structured analysis was used to create Data Flow Diagrams (DFDs) to describe the critical parts of the system. The results show that perceived value and geographical location determine the rate in which computers are disposed and the opportunities to waste or trade them, including the trade of their materials. Among businesses and other organizations, legislation has a stronger effect. Technological change is another important factor, largely driving the change in materials and new products. Designing policies responding to this diversity may prevent unforeseen problems and stimulate solutions.     

Mechanical separation-oriented characterization of electronic scrap

The ever-increasing amount of electronic scrap and the steadily-decreasing contents of the precious metals used in electronics, as well as the ever-growing environmental awareness, challenges such conventional precious-metal-oriented recycling techniques as pyrometallurgy. Separation and beneficiation of various materials encountered in electronic scrap might provide a correct solution ahead. In this context, mechanical separation-oriented characterization of electronic scrap was conducted in an attempt to evaluate the amenability of mechanical separation processes. Liberation degrees of various metals from the non-metals, which are crucial for mechanical separation, were analyzed by means of a grain counting approach. It is found that the metallic particles below 2 mm achieve almost complete liberation. Particle shapes were also quantified through an image processing system. The results obtained show that the shapes of the particles, as a result of shredding, turn out to be heterogeneous, thereby complicating mechanical separation processes. In addition, separability of various materials was ascertained by a sink–float analysis. It has been shown that density-based separation techniques shall be viable in separating metals from plastics, light plastics (ABS, PS and PVC, etc.) from glass fiber reinforced resins and aluminum from heavy metals. Specifically, a high quality copper concentrate can be expected by density-based separation techniques. Moreover, FT-IR spectra of plastics pieces from the light fractions after the sink–float testing show that PC scrap primarily contains ABS, PS and PVC plastics with the density range of +1.0–1.5 g/cm³, whereas PCB scrap mainly contains glass fiber reinforced epoxy resins plastics with the density range of +1.5–2.0 g/cm³.