Variation of nutrient and metal concentrations in aquatic macrophytes along the Rio Cachoeira in Bahia (Brazil)

The use of cuprous fungicides in cocoa production in the southern part of the state of Bahia (Brazil) for decades has caused an accumulation of copper in various components of the cocoa plantations, and a contamination of regional freshwater ecosystems is suspected. Urban and industrial sources are supposed to contribute to water pollution and eutrophication of the Rio Cachoeira, the main river in this region. In order to study the metal contamination and nutritional status of this freshwater ecosystem, samples of the aquatic macrophytes Eichhornia crassipes and Pistia stratiotes were collected at seven sites along the river course. The samples were analysed for their copper, aluminium, chromium, nitrogen and phosphorus concentrations. The levels of heavy metals increased in the downstream direction, particularly in the roots of water hyacinth. A dramatic increase of nitrogen and phosphorus concentrations in water as well as in plant tissues was found in samples collected downstream from the city of Itabuna. Metal input and eutrophication were attributed to agricultural, industrial and urban sources in the region. Biomonitoring of the water quality using aquatic macrophytes as accumulative indicator plants is recommended in addition to chemical water analyses.     

Triclosan in wastewaters and biosolids from Australian wastewater treatment plants

Triclosan (TCS) is an antimicrobial agent widely used in many personal care products. This study investigated the occurrence of TCS in effluents, biosolids and surface waters, and its fate in wastewater treatment plants (WWTPs). The aqueous concentrations of TCS in nineteen effluents from Australian WWTPs ranged from 23 ng/L to 434 ng/L with a median concentration of 108 ng/L, while its concentrations in nineteen biosolids ranged from 0.09 mg/kg to 16.79 mg/kg on dry weight basis with a median concentration of 2.32 mg/kg. The removal rates for TCS in five selected WWTPs were found to range between 72% and 93%. Biological degradation was believed to be the predominant removal mechanism for TCS in the WWTPs. However, adsorption onto sludge also played a significant role in the removal of TCS in the WWTPs. TCS at concentrations up to 75 ng/L was detected in surface waters (outfall, upstream, and downstream) from five rivers receiving effluent discharge from WWTPs. Preliminary risk assessment based on the worst-case scenario showed that the TCS concentrations in surface waters might lead to risks to aquatic organisms such as algae. Based on the TCS levels in the biosolids, application of biosolids on agricultural land may also cause adverse effects in the soil environment.     

Arsenic in North Carolina: public health implications

Arsenic is a known human carcinogen and relevant environmental contaminant in drinking water systems. We set out to comprehensively examine statewide arsenic trends and identify areas of public health concern. Specifically, arsenic trends in North Carolina private wells were evaluated over an eleven-year period using the North Carolina Department of Health and Human Services database for private domestic well waters. We geocoded over 63,000 domestic well measurements by applying a novel geocoding algorithm and error validation scheme. Arsenic measurements and geographical coordinates for database entries were mapped using Geographic Information System techniques. Furthermore, we employed a Bayesian Maximum Entropy (BME) geostatistical framework, which accounts for geocoding error to better estimate arsenic values across the state and identify trends for unmonitored locations. Of the approximately 63,000 monitored wells, 7712 showed detectable arsenic concentrations that ranged between 1 and 806 μg/L. Additionally, 1436 well samples exceeded the EPA drinking water standard. We reveal counties of concern and demonstrate a historical pattern of elevated arsenic in some counties, particularly those located along the Carolina terrane (Carolina slate belt). We analyzed these data in the context of populations using private well water and identify counties for targeted monitoring, such as Stanly and Union Counties. By spatiotemporally mapping these data, our BME estimate revealed arsenic trends at unmonitored locations within counties and better predicted well concentrations when compared to the classical kriging method. This study reveals relevant information on the location of arsenic-contaminated private domestic wells in North Carolina and indicates potential areas at increased risk for adverse health outcomes.     

228Ra/226Ra/224Ra and 87Sr/86Sr isotope relationships for determining interactions between ground and river water in the upper Rhine valley

Ground and river waters of the upper Rhine valley (Alsace, France) were investigated for chemical composition of the major elements, Sr isotopes and radionuclides from the U and Th series. In particular, the isotope ratios and concentrations of Ra and Sr were used as geochemical tracers to distinguish between different types of water and their interactions. The bulk chemical analyses suggest that the surface waters in the Rhine valley can be described as mixtures between Ca-Na-HCO3-rich ground water and less mineralized slightly acidic river waters which have migrated through crystalline (mainly granitic) basement rocks of the Vosges mountains. Mixing of these waters yields positive correlation between bulk Sr, U, Ca and HCO3, indicating that carbonate-rich sediments are the main source of U and (non-radiogenic) Sr in the Rhine valley aquifers. The combination of the Ra and Sr isotope systems (228Ra/226Ra, 87Sr/86Sr) shows, however, that probably three sources contribute to the surface river waters in the upper Rhine valley, i.e. (i) a highly radiogenic crystalline component, (ii) a ground water source and, (iii) a third component from infiltrating Rhine water along the flow path of the parallel running river Ill in the northerly direction. The Sr and Ra isotope systems were also used to calculate small-scale mixing fractions of tributaries along the flow path of the Ill. Mixing ratios of non-pure end-member waters were determined using three isotope diagrams (i.e. 224Ra/226Ra vs. 228Ra/226Ra) and the results obtained with the Ra isotope system were found to be consistent with the data using Sr isotope relationships (i.e. 87Sr/86Sr vs. 1/Sr).     

Contamination of groundwater and risk assessment for arsenic exposure in Ha Nam province, Vietnam

The characteristics of arsenic-contaminated groundwater and the potential risks from the groundwater were investigated. Arsenic contamination in groundwater was found in four villages (Vinh Tru, Bo De, Hoa Hau, Nhan Dao) in Ha Nam province in northern Vietnam. Since the groundwater had been used as one of the main drinking water sources in these regions, groundwater and hair samples were collected in the villages. The concentrations of arsenic in the three villages (Vinh Tru, Bo De, Hoa Hau) significantly exceeded the Vietnamese drinking water standard for arsenic (10 microg/L) with average concentrations of 348, 211, and 325 microg/L, respectively. According to the results of the arsenic speciation testing, the predominant arsenic species in the groundwater existed as arsenite [As(III)]. Elevated concentrations of iron, manganese, and ammonium were also found in the groundwater. Although more than 90% of the arsenic was removed by sand filtration systems used in this region, arsenic concentrations of most treated groundwater were still higher than the drinking water standard. A significant positive correlation was found between the arsenic concentrations in the treated groundwater and in female human hair. The risk assessment for arsenic through drinking water pathways shows both potential chronic and carcinogenic risks to the local community. More than 40% of the people consuming treated groundwater are at chronic risk for arsenic exposure.     

Recent advances in the bioremediation of arsenic-contaminated groundwater

The biological treatment of groundwater is used primarily to remove electron donors from water sources, providing (biologically) stable drinking water, which preclude bacterial regrowth during subsequent water distribution. To the electron donors belong also the dissolved metal cations of ferrous iron and manganese, which are common contaminants found in most (anaerobic) groundwater. The removal of iron and manganese is usually accomplished by the application of chemical oxidation and filtration. However, biological oxidation has recently gained increased importance and application due to the existence of certain advantages, over the conventional physicochemical treatment. The oxidation of iron and manganese is accelerated by the presence of certain indigenous bacteria, the so-called "iron and manganese oxidizing bacteria." In the present paper, selected long-term experimental results will be presented, regarding the bioremediation of natural groundwater, containing elevated concentrations of iron and arsenic. Arsenic is considered as a primary pollutant in drinking water due to its high toxicity. Therefore, its efficient removal from natural waters intended for drinking water is considered of great importance. The application of biological processes for the oxidation and removal of dissolved iron was found to be an efficient treatment technique for the simultaneous removal of arsenic, from initial concentrations between 60 and 80 microg/l to residual (effluent) arsenic concentrations lower than the limit of 10 microg/l. The paper was focused on the removal of As(III) as the most common species in anaerobic groundwater and generally is removed less efficiently than the oxidized form of As(V). To obtain information for the mechanism of As(III) removal, X-ray photoelectron spectroscopy (XPS) analyses were applied and it was found that As(III) was partially oxidized to As(V), which enabled the high arsenic removal efficiency over a treatment period of 10 months.     

Nutrient chemistry of River Pinios (Thessalia, Greece)

The impact of human activities with 3-year monitoring on the fluctuation of nutrients along the Pinios River and its tributaries were studied. Their seasonal variations throughout the years 1996-1998 were also presented. High temperatures, from June to August, cause a restriction of the water flow, an enhancement of nutrient concentration with the subsequent increase of eutrophication. High concentrations of nutrients were observed first in winter (wet period), caused by leaching of fertilizers from terrestrial systems after heavy rainfall, later during the warm months due to low water flow of the river, and at last in autumn when plant organisms began to decompose. The intensive algal and macrophyte growth (spring, summer) resulted in severe depletion of nutrients. Organic carbon showed no seasonal trend but its values were high near the estuaries. Nitrate fluxes were high at the initial station (sources) and the Titarisios tributary, whereas nitrites and ammonium were low. In contrary, the Kalentzis tributary with relatively low nitrate values showed increased values of nitrite ammonium or total nitrogen. On the other hand, the Enipeas tributary showed high SO4 values. Phosphates are remarkably present mainly after the city of Larissa, where sewage and industrial discharges occur. None of the nutrients measured in the Pinios River and its tributaries showed a clear seasonal cycle of concentration. Concentrations of nutrients and organic carbon increased as a consequence of anthropogenic inputs, particularly point discharges from sewage treatment plants (i.e. showing distinct, but variable, concentration peaks), as well as diffuse urban and/or agricultural runoff over long areas during storm events. The agricultural management, the urban pollution, mainly from Larissa City, and the climate conditions in the catchment basin (Thessalia Plain) of Pinios River and its tributaries greatly affect the chemical composition of their waters.     

Occurrence, distribution and possible sources of organochlorine pesticide residues in tropical coastal environment of India: an overview

Organochlorine pesticides (OCPs) are an important potential component of chemical pollutants used extensively for agriculture and sanitation purposes in India as these are comparatively cheap and effective. These persistent organic compounds such as HCH isomers, DDT and its metabolites are the predominant chemical contaminants found along the Indian coast and thus constitute both alluring and grave areas of scientific research. Our objective in the paper is to provide a comprehensive account of the distribution of organochlorine pesticides in biotic and abiotic compartments of the Indian coastal environment, make some comments on their environmental sources, their movement through the food chain and possible ecotoxicological risk of health in biota including humans. The prevalent HCH, DDT and HCB concentrations differ markedly in eastern and western coast of India reflecting differing agricultural and other usage and their ultimate input into the coastal environment by several rivers and the bioturbation activities of macrozoobenthos (bivalve mollusks, polychaetous annelids, etc.). In several cases, the DDT levels exceeded the effects range-low (ER-L) and could thus cause acute biological impairments, in comparison with the sediment quality guidelines. Contributions of DDT metabolites (DDT, DDD and DDE residues) vary in different Indian coastal regions predominated by pp'-DDT and pp'-DDD. Measured concentrations of HCHs were lower than DDTs that might be due to higher water solubility, vapor pressure and biodegradability of the latter. HCH and DDT residues in fish in India were lower than those in the temperate countries indicating a lower accumulation in tropical fish, which might be related to rapid volatilization of this insecticide in the tropical environment. The concentrations of other chlorinated pesticides (aldrin, dieldrin, eldrin, methoxychlor, endosulfan sulphate) were lower and not generally of great concern.     

Contamination of drinking water resources in the Mekong delta floodplains: arsenic and other trace metals pose serious health risks to population

This study presents a transnational groundwater survey of the 62,000 km(2) Mekong delta floodplain (Southern Vietnam and bordering Cambodia) and assesses human health risks associated with elevated concentrations of dissolved toxic elements. The lower Mekong delta generally features saline groundwater. However, where groundwater salinity is <1 g L(-)(1) Total Dissolved Solids (TDS), the rural population started exploiting shallow groundwater as drinking water in replacement of microbially contaminated surface water. In groundwater used as drinking water, arsenic concentrations ranged from 0.1-1340 microg L(-)(1), with 37% of the studied wells exceeding the WHO guidelines of 10 microg L(-)(1) arsenic. In addition, 50% exceeded the manganese WHO guideline of 0.4 mg L(-)(1), with concentrations being particularly high in Vietnam (range 1.0-34 mg L(-)(1)). Other elements of (minor) concern are Ba, Cd, Ni, Se, Pb and U. Our measurements imply that groundwater contamination is of geogenic origin and caused by natural anoxic conditions in the aquifers. Chronic arsenic poisoning is the most serious health risk for the ~2 million people drinking this groundwater without treatment, followed by malfunction in children's development through excessive manganese uptake. Government agencies, water specialists and scientists must get aware of the serious situation. Mitigation measures are urgently needed to protect the unaware people from such health problems.     

Particulate and dissolved elemental loads in the Kuji River related to discharge rate

In order to investigate influences of discharge rates on fluvial transport behavior of elements in the Kuji River, Japan, suspended and dissolved phase concentrations in the river water were measured together with the water flow rates. The concentrations of suspended particulate matter (SPM) increased by two or three orders of magnitude with the water discharge, and also had seasonal variations. Adsorptive elements or heavy metal elements, which tend to form insoluble compounds, were present generally as suspended forms in the river waters, and their dissolved form concentrations tended to increase with the water discharge. On the other hand, non-adsorptive elements such as alkali and alkaline-earth elements were present as dissolved forms under a normal flow rate condition, but equivalent quantity of suspended species also occurred under a high flow condition. In this case, the dissolved form concentrations decreased with the water discharge. Characterization of SPM with analyses of chemical compositions, scanning electron microscopy (SEM) and X-ray diffractometry (XRD) indicated that clay mineral such as montmorillonite would be the main carrier material of trace and major elements during the fluvial transport in the Kuji River. Variations of contents of selected elements in SPM with the water discharge indicated that river bottom sediments, which are probably potential sources of SPM added due to high water flow rates, would be different in chemical compositions from SPM floating under a normal flow condition. Variations of chemical compositions of SPM as well as of suspended or dissolved form concentrations of elements in the river waters were formulated as a function of the water discharge rates.     

Arsenic concentrations in rice, vegetables, and fish in Bangladesh: a preliminary study

Arsenic contaminating groundwater in Bangladesh is one of the largest environmental health hazards in the world. Because of the potential risk to human health through consumption of agricultural produce grown in fields irrigated with arsenic contaminated water, we have determined the level of contamination in 100 samples of crop, vegetables and fresh water fish collected from three different regions in Bangladesh. Arsenic concentrations were determined by hydride generation atomic absorption spectrophotometry. All 11 samples of water and 18 samples of soil exceeded the expected limits of arsenic. No samples of rice grain (Oryza sativa L.) had arsenic concentrations more than the recommended limit of 1.0 mg/kg. However, rice plants, especially the roots had a significantly higher concentration of arsenic (2.4 mg/kg) compared to stem (0.73 mg/kg) and rice grains (0.14 mg/kg). Arsenic contents of vegetables varied; those exceeding the food safety limits included Kachu sak (Colocasia antiquorum) (0.09-3.99 mg/kg, n=9), potatoes (Solanum tuberisum) (0.07-1.36 mg/kg, n=5), and Kalmi sak (Ipomoea reptoms) (0.1-1.53 mg/kg, n=6). Lata fish (Ophicephalus punctatus) did not contain unacceptable levels of arsenic. These results indicate that arsenic contaminates some food items in Bangladesh. Further studies with larger samples are needed to demonstrate the extent of arsenic contamination of food in Bangladesh.     

Drugs of abuse in surface and tap waters of the Tagus River basin: Heterogeneous photo-Fenton process is effective in their degradation

This work investigates for the first time the occurrence of drugs of abuse and metabolites in surface waters from the Tagus River on its way through the province of Toledo (downstream Madrid metropolitan area) and in drinking waters in two nearby cities. Some of the studied drugs are used for therapeutic purposes but they can also be consumed as illicit drugs. The results of this preliminary study have revealed the presence of 12 out of 22 drugs of abuse analyzed in fluvial water at concentrations ranging from 1.14 to 40.9 ng/L. The largest concentrations corresponded to the anxiolytics diazepam and lorazepam, the cocaine metabolite benzoilecgonine, the amphetamine-like compound ephedrine, and the methadone metabolite EDDP. All these substances, except for lorazepam, were detected in all the sampling points. Traces of methadone and ephedrine were detected in some samples of tap water. Despite the low concentrations of these pollutants, effects on wildlife or human health cannot be disregarded, especially on vulnerable population. Thus, the treatment of these substances using a heterogeneous photo-Fenton process has been evaluated, rendering a remarkable effectiveness for their degradation.     

九龙江流域河水溶解态碳的时空变化

为了研究九龙江流域河流中溶解碳变化规律，分别于2017年7月与2018年1月对九龙江河水溶解无机碳（DIC）与溶解有机碳（DOC）进行了分析。丰水季河水DIC浓度为7.50~49.04 mg/L，平均值为22.12 mg/L，枯水季DIC浓度为8.84~84.91 mg/L，平均浓度41.17 mg/L，丰水季河水中的DOC浓度为0.54~2.89 mg/L，平均值为1.04 mg/L，枯水季河水中DOC浓度变化在1.34~3.56 mg/L之间，平均值为2.34 mg/L，据此计算了九龙江河水DOC、DIC的入海通量。研究结果表明九龙江河水中溶解碳具有显著的时空变化特征，通过与中国其他河流溶解碳数据对比，解释了碳酸盐岩的风化、气候变化、河流中浮游植物以及人类活动对九龙江河流溶解碳浓度的影响。     

An evaluation of a river health using the index of biological integrity along with relations to chemical and habitat conditions

We evaluated the health condition of a temperate river during June-November 1999 through applications of the index of biological integrity (IBI) using fish assemblages and qualitative habitat evaluation index (QHEI) as well as chemical analyses. Overall IBI values ranged from 13 to 37 and averaged 23 (n = 25, standard error = 1.16), indicating a "poor" or "very poor" condition according to the criteria of modified Karr [Fisheries 6 (1981) 21]. The values of mean IBI declined at a rate of 0.22 km(-1) (R2 = 0.91, p < 0.05) along the longitudinal distance from the headwaters to the downstream sites. Reduced IBI values at downstream sites reflected low forest cover, high population density and high nutrient enrichments. Ecotoxicity tests using the river water also showed that toxic impacts were evident in the downriver sites. These factors resulted in decreases of riffle benthic species and insectivores and increases of tolerant species, anormalies and exotic species in the river. Spatial pattern in IBI agreed with QHEI values, which showed a linear relation (R2 = 0.998, p < 0.001) with species richness. Field measurements of conductivity and pH, an indicators for variation of conservative ions, showed that the river water was diluted by 40% fold by summer monsoon rain and surface run-off from the watershed, resulting in a physical and chemical instability during the monsoon. For these reasons, average IBI values during the monsoon and postmonsoon decreased >20% compared to the premonsoon, indicating that IBI values were also affected by flow regime. Based on the overall physico-chemical data and IBI values, the river health is rapidly degrading due to the combined effect of chemical contaminations and habitat modifications.     

Evaluation of the concentration of HCH, DDT, HCB, PCB and PAH in the sediments along the lower stretch of Hugli estuary, West Bengal, northeast India

Detailed analyses of persistent organic pollutants (POPs) such as hexachlorocyclohexane (HCH) isomers (HCHs), dichlorodiphenyltrichloro ethane (DDT) and its metabolites (DDTs), hexachlorobenzene (HCB) and congeners of polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs) in surface sediments from the coastal estuarine environment of West Bengal, northeast India allowed the evaluation of the contamination status, distribution and possible pollution sources. HCH, DDT, HCB, PCB and PAH were identified compounds in all the samples, whereas the concentrations of chlorinated pesticides (trans-eptachlorepoxide, dieldrin, endrin, metaoxychlor and mirex) were below the detection limits and were not of great concern. The pesticides did demonstrate markedly different distributions reflecting different agricultural and domestic usage in the region. The range of concentrations of HCH, HCB, DDT and PCBs in the sediments were 0.11-0.40, <0.05-0.98, 0.18-1.93 and 0.18-2.33 ng/g dry wt, respectively. Overall elevated levels of HCB, DDT and PCB were recorded at Babughat, a very closely located site of the metropolitan megacity Calcutta. Fluoranthene (flu) and pyrene (py), the dominant 4-ring PAHs, also showed an abrupt elevated concentrations at Babughat with values of 214 and 144 ng/g dry wt, respectively. Among the isomers and metabolites of HCH, DDT and PCB, alpha-HCH, pp'-DDT and PCB (101), PCB (118), PCB(153) and PCB (138) were found to be dominant. High ratios of metabolites of DDT to SigmaDDTs reveal recent use of DDT in this coastal environment. Fluoranthene, pyrene, 1,2-benzo(a)anthracene and chrysene formed the dominant congeners out of 19 identified PAHs. The sources of contamination are closely related to human activities such as domestic and industrial discharge, automobile exhausts, street runoff, slum sewage, agricultural chemicals and soil erosion due to deforestation as well as atmospheric transport. This study is compared to other coastal and estuarine environments in India and abroad. The baseline data can be used for regular ecological monitoring, considering the industrial and agricultural growth around this important estuarine ecosystem.     

Contamination of settling ponds and rivers as a result of discharge of radium-bearing waters from Polish coal mines

Saline waters from underground coal mines in Poland often contain natural radioactive isotopes, mainly 226Ra from the uranium decay series and 228Ra from the thorium series. Approximately 40% of the total amount of radium remains underground as radioactive deposits, but 225 MBq of 226Ra and 400 MBq of 228Ra are released daily into the rivers along with the other mine effluents from all Polish coal mines. Technical measures such as inducing the precipitation of radium in gobs, decreasing the amount of meteoric inflow water into underground workings, etc. have been undertaken in several coal mines, and as a result of these measures, the total amount of radium released to the surface waters has diminished by about 60% during the last 5-6 years. Mine water can have a severe impact on the natural environment, mainly due to its salinity. However, associated high levels of radium concentration in river waters, bottom sediments and vegetation have also been observed. Sometimes radium concentrations in rivers exceed 0.7 kBq/m3, which is the permitted level for waste waters under Polish law. The extensive investigations described here were carried out for all coal mines and on this basis the total radium balance in the effluents has been calculated. Measurements in the vicinity of mine settling ponds and in rivers have given us an opportunity to study radium behaviour in river waters and to assess the degree of contamination. Solid waste materials with enhanced natural radioactivity have been produced in huge amounts in the power and coal industries in Poland. As a result of the combustion of coal in power plants, low-radioactive waste materials are produced, with 226Ra concentration seldom exceeding a few hundreds of Bq/kg. A different situation is observed in coal mines, where, as a result of precipitation of radium from radium-bearing waters, highly radioactive deposits are formed. Sometimes the radioactivity of such materials is extremely high; precipitates from coal mines may have radium concentrations of 400,000 Bq/kg--equivalent to 3% uranium ore. Usually, such deposition takes place underground, but sometimes co-precipitation of radium with barium takes place on the surface, in settling ponds and in rivers. Therefore management of solid waste with technologically enhanced natural radioactivity (TENR) is a very important subject.     

乌东德水库水温预测及低温水减缓措施

乌东德水库为季调节水库,采用宽度平均的立面二维水温数学模型对水库水温结构进行预测,结果表明:乌东德水库水温结构呈季节性分层特征,电站运行对下游水温过程有一定程度的春季低温水和冬季高温水影响。如果采用单层取水方案,在2~8月的下泄水温低于坝址现状水温,最大降幅为2.0℃,下泄低温水将对坝下鱼类产卵繁殖产生不利影响。乌东德水电站拟采取分层取水的措施,对低温水较为敏感的鱼类产卵期3~6月采用叠梁门取水。相比于单层取水,叠梁门方案对低温水的改善效果较明显,下泄水温提高了0.8~1.1℃,能一定程度地减缓升温期水温延迟效应。     

Ecological footprints and shadows in an urban estuary, Narragansett Bay, RI (USA)

Because the rise of cities in North America was much later than in many other parts of the world, their connections to the hinterland were influenced early in their development by railroads and steam-powered water transport. These fossil fuel-based links made it possible to widely separate the ??upstream?? autotrophic supporting systems from the heterotrophic cities. Here, we take a different look at the connection between a city (Providence, RI, USA) and its supporting natural systems by focusing on the export of industrial and metabolic wastes from the city to the ??downstream?? coastal ecosystem in Narragansett Bay. In this way, we can track the history of a city by examining the concentrations of nutrients, metals, and hydrocarbons in the water and sediments of the estuary. In the greater Providence metropolitan area at the head of Narragansett Bay, there was rapid population and industrial expansion during the 1800s without the proper infrastructure to deal with water supply for public safety and health. On the other hand, the absence of a public water supply kept industrial and metabolic wastes largely on land. However, from the fall of 1871, on with the construction of a public water supply and sewer system, human wastes began flowing into the estuary. By reconstructing the historical record of metals and other pollutants, we illustrate clear temporal and spatial gradients of urban impact on the bay. Unfortunately, while numerous studies during the 1970s and 1980s focused on documenting metal and hydrocarbon pollution in the bay, there has been little effort to quantify the impact of mitigation efforts that have greatly reduced the input of metals and hydrocarbons to the system. Nutrient reductions are more recent and ongoing.     

Cosmogenic 22Na as an index of the residence time of water in freshwater basins: a review

The goal of this review is to draw attention to an opportunity for the use of cosmogenic (22)Na for dating young surface and underground waters. After 1961 when a significant quantity of (22)Na was released into the environment as a result of nuclear weapon tests, its concentrations in river waters were greatly increased, and a return to natural (cosmogenic) levels took until the mid-1980s. The studies made during this non-steady-state period showed that the one-box model for freshwater basin correctly describes the experimental data. For the 19 studied basins of Russia, the Baltic States and Japan, a calculation based on this model gave values for the mean residence time of water in the range from 4 to 23 years. Now, only cosmogenic (22)Na is in the environment, and it is the single cosmogenic radionuclide at present, which can serve as a steady-state tracer for dating young waters (up to some decades).     

汉水流域水环境安全管理对策探讨

汉水是长江中游北岸跨省级行政区的一级支流。汉水流域上游的丹江口水库为规划中的南水北调中线工程水源地 ;流域中下游工农业生产发达 ,人口密集。因此 ,汉水流域水环境安全问题备受人们关注。初步研究了汉水流域水环境安全管理问题 ,首先探讨流域水环境质量的时空变化特征 ,然后就流域水环境安全的主要点源和非点源压力因素进行了识别。结果表明 :在时间上 ,汉水流域水质总体上有逐年恶化的趋势 ,枯水期存在点源污染问题 ,丰水期存在点源和非点源污染问题 ;在空间上 ,上游干流个别江段和整个流域多数支流水质污染严重 ,丹江口水库水质良好 ,中下游干流水质时有污染现象 ;河南 -湖北省界水体存在水质污染问题。最后 ,根据汉水流域水环境质量特征及存在的问题 ,从流域水资源保护体制、法制建设、管理的理论与方法、监测和评价的内容与方法、流域水环境规划与科研、流域生态建设、行政区之间利益分配、现代高新技术的应用等方面提出了国家层次和流域层次的水环境安全管理对策