邛海水质变化趋势及保护对策研究

本文通过对邛海流域现状污染源进行调查,邛海流域COD、氨氮、总氮和总磷产生量分别为5892.1t/a、995.6t/a、2888.2t/a和1105.1t/a,污染负荷主要来自面源污染.通过2002 ～ 2011年邛海水质监测数据分析,邛海水质近10年总体保持Ⅱ～Ⅲ类,处于中营养状态,2004～ 2006年水质相对较差,2006年以后水质逐渐好转.总磷、总氮是邛海主要污染因子,海河口是邛海污染最严重的区域.为实现邛海水质和流域生态环境持续改善,从产业结构优化、流域污染源治理、生态保育和流域生态环境综合监管等方面提出对策建议.     

濛阳河流域(成都段)污染源解析及对策研究

为改善濛阳河流域(成都段)水环境现状,提出合理有效的水环境治理措施,根据实测数据对流域水质现状进行分析,并参照《全国水环境容量核定技术指南》中规定的计算方法,对流域主要入河污染物的量进行计算。结果表明,濛阳河流域彭州出境断面水质不稳定达标,主要超标污染物为总磷,COD、氨氮不稳定达标。流域内COD、氨氮、总磷总入河量分别为805.41t/a、129.96t/a、31.17t/a。按污染源分类,生活污染源对COD、氨氮、总磷的贡献率最大,分别为60.60%、48.82%、43.27%,其次是农田面源。按区县分类,濛阳镇和九尺镇对流域污染负荷贡献较大。根据污染源解析结果,有针对性的提出污染治理对策,为濛阳河流域水环境治理提供依据和思路。     

城市流域综合整治及环境经济损益分析

随着社会的进步和经济的发展，随之带来的城市污染也日益严重，进行城市流域科学、合理的规划和综合整治，具有十分重要的意义。本文以重庆市清水溪流域为例，在分析流域现状的基础上，结合重庆市总体规划，提出了城市流域综合整治的措施：沿岸两例污水管网建设、两岸垃圾整治、河道清淤及防洪、两岸绿化带及景点建设、水土保持、水源地涵养区规划与建设等。并从生态、社会和经济方面进行分析，对产生的环境效益进行评价：整治工程建成后清水溪流域接纳的污染物CODcr将削减857lt／a、总磷削减160t/a、SS削减6156t／a；流域生态环境大大改善；同时将带来巨大的直接经济效益；整治工程是为民造福的民心工程。     

红枫湖流域主要入湖污染物调查与分析评价

为研究红枫湖流域主要入湖污染物情况,采用现场调查、资料收集等方法计算红枫湖流域主要入湖污染物,并分析各污染物的各类型污染源贡献率、各支流贡献率、内源和外源比值等情况。结果表明:在各种降水情景下,入湖的各污染物总量大小顺序均为COD总氮氨氮总磷;各污染物(COD、氨氮、总磷、总氮)入湖量贡献率均是羊昌河最大、麦包河最小,其贡献率范围分别为46.33%~76.6%和0.4%~0.6%;入湖主要污染物(COD、总氮、总磷)主要以外源为主,氨氮则以内源污染为主;研究为红枫湖水环境质量改善、治理方向提供技术支撑。     

蒙溪河流域水环境污染及演变趋势研究

研究采用Arc GIS确定蒙溪河流域研究范围,在此基础上进行水环境污染现状及演变趋势分析、污染源调查和水环境容量计算。结果表明:蒙溪河流域水质超标情况较严重,主要超标因子为:COD、TN和TP,COD和TP的压力主要集中在平水期,TN压力主要集中在枯水期;污染源汇入主要集中在4#-9#点位之间。蒙溪河流域污染物入河量从大到小依次为:农业面源、城镇生活污水、农村生活污水、规模化畜禽养殖、畜禽散养和底泥污染。蒙溪河流域达标需削减污染物量:COD为217.755t/a,NH_3-N为24.683t/a,TN为75.710t/a,TP为10.774t/a。     

基于污染溯源分析的汤水河考核断面水质达标方案研究

基于水文、水质和污染源资料,建立了汤水河流域一维水环境数学模型。利用控制断面达标法计算得到汤水河水环境容量,根据水文水质同步监测资料进行了后桥头路桥考核断面污染溯源分析,进而制定出近远期水质达标方案,为汤水河乃至秦淮流域的水环境综合治理提供技术支撑。结果表明:2020年后桥头路桥断面水质稳定达标时,汤水河COD、氨氮、总磷水环境容量分别为197.39t/a、18.50t/a、2.22t/a。后桥头路桥断面污染主要源自于句容市和淳化街道,建议两地协作配合,共同促进汤水河的水环境改善。     

降雨径流对柴河水库总磷、总氮的水质影响分析

为研究降雨产生的地表径流对水库水质中总磷、总氮的影响,以铁岭市入柴河水库的柴河流域集雨面积内的降雨径流为研究对象,分别在雨季汛期的三个时期(雨前、雨时及雨后)对柴河流域下游入库前的柴河堡断面采集水样进行分析,以期为铁岭市柴河水库的面源污染治理提供科学依据。     

缓冲带:为湖泊划出保护圈

<正>湖泊缓冲带能够截留、净化陆域面源污染物,可以很好地发挥缓冲净化功能,改善湖泊水质,减少水体污染负荷的流出。这是权威机构对太湖竺山湾缓冲带进行为期4年半的研究而得出的结论。通过实施竺山湾缓冲带生态修复示范工程,缓冲带内的支浜水质得到显著改善,水体内TN(总氮)削减量在40%以上、TP(总磷)削减     

福建省兰溪流域水环境的整治措施与成效评价

流域整治前,排入福建省南安市兰溪流域的CODCr总量1320.319t/a、氨氮总量113.905t/a、磷总量24.231t/a,远高于水环境容量CODCr807.7t/a、氨氮42.5t/a、总磷8.5t/a的理论值。针对流域主要污染源是生活污水、农业面源和养殖污水的源解析成果,采取了强化村镇生活污水收集治理,严格整治养殖业污染,加强农业面源污染防治的针对性措施,历经两年的整治,兰溪水质已从劣V类基本恢复到Ⅲ类水平。     

南京市入江总磷通量计算及方法对比研究

长江是南京市最主要的供水水源地,为减缓水环境压力,分析流域水污染物排放分布特征和污染来源,计算入江总磷通量有着重要意义。根据收集到的南京地区各区县的32个雨量站1962~2015年的逐日降雨量资料计算,2014年南京市的环境统计资料,对南京市入江总磷进行了计算分析,对通量法和污染物负荷法计算结果进行了对比校核,根据通量法以及污染物负荷法计算的入江总磷通量分别为为1 972.87t,为1 866.67t,计算误差为5.4%。     

氮肥形态对坡耕地雨季土壤养分流失的影响

为了明确氮肥形态对土壤养分流失通量及途径的影响,采用随机区组试验设计,利用模拟径流小区观测的方法,研究在地膜覆盖与不覆盖情况下氮肥形态对坡耕地雨季土壤养分流失通量及途径的影响。研究结果表明：壤中流氮、磷和钾的流失量分别占总径流流失量的71.30%、6.36%和8.85%,说明磷和钾流失的主要途径是地表径流,而氮流失的主要途径是壤中流,地膜覆盖降低酰胺态氮肥和缓控释肥处理氮素流失量,其中酰胺态氮肥处理地膜覆盖较不覆盖壤中流氮流失浓度和径流氮素流失量分别降低40.40%和29.32%。在无覆盖条件下,各处理径流氮素流失顺序表现为：酰胺态氮肥〉铵态氮肥〉缓控释肥〉硝态氮肥,施用硝态氮肥氮素流失量最低,较施用酰胺态氮肥氮素流失少40.86%。在地膜覆盖条件下,各处理径流中氮素流失顺序表现为：铵态氮肥〉酰胺态氮肥〉硝态氮肥〉缓控释肥,施用缓控释肥氮素流失量最低,较施用铵态氮肥氮素流失少59.60%。结果表明在四川紫色丘陵区为了有效控制水土养分流失,在肥料形态的选择上,以无覆盖条件下施用硝态氮肥较好,以地膜覆盖条件下施用缓控释肥较好。     

Nutrient and sediment losses under simulated rainfall following manure incorporation by different methods

Incorporation of manure into cultivated soils is generally recommended to minimize nutrient losses. A 3-yr study was conducted to evaluate sediment and nutrient losses with different tillage methods (moldboard plow, heavy-duty cultivator, double disk, and no-incorporation) for incorporation of beef cattle manure in a silage barley (Hordeum vulgare L.) cropping system. Runoff depths, sediment losses, and surface and subsurface nutrient transfers were determined from manured and unmanured field plots at Lethbridge, Alberta, Canada. A Guelph rainfall simulator was used to generate 30 min of runoff. Sediment losses among our tillage treatments (137.4-203.6 kg ha(-1)) were not significantly different due to compensating differences in runoff depths. Mass losses of total phosphorus (TP) and total nitrogen (TN) in surface runoff were greatest from the no-incorporation (NI) treatments, with reductions in TP loads of 14% for double disk (DD), 43% for cultivator (CU), and 79% for moldboard plow (MP) treatments. Total N load reductions in 2002 were 26% for DD, 70% for CU, and 95% for MP treatments compared to the NI treatments. Nutrient losses following incorporation of manure with the DD or CU methods were not significantly different from the NI treatments. Manure treatments generally had lower runoff depths and sediment losses, and higher phosphorus and nitrogen losses than the control treatments. Subsurface concentrations of NH4-N, NO3-N, and TN were greatest from the MP treatments, whereas subsurface phosphorus concentrations were not affected by tillage method. Tillage with a cultivator or double disk minimized combined surface and subsurface nutrient losses immediately after annual manure applications.     

Estimating Relevance of Organic Carbon,Nitrogen, and Phosphorus Loads to a Blackwater River Estuary1

Abstract: In blackwater river estuaries, a large portion of external carbon, nitrogen, and phosphorus load are combined in complex organic molecules of varying recalcitrance. Determining their lability is essential to establishing the relationship between anthropogenic loads and eutrophication. A method is proposed in which organic C, N, and P are partitioned into labile and refractory forms, based upon first‐order decay estimated by biochemical oxygen demand relative to total organic carbon, and C:N and C:P ratios as a function of organic carbon lability. The technique was applied in developing total maximum daily loads for the lower St. Johns, a blackwater Atlantic coastal plain river estuary in Northeast Florida. Point source organic nutrients were determined to be largely labile. Urban runoff was found to have the highest relative labile organic N and P content, followed by agricultural runoff. Natural forest and silviculture runoff were high in refractory organic N and P. Upstream labile C, N, and P loads were controlled by autochthonous production, with 34‐50% of summer total labile carbon imported as algal biomass. Differentiation of labile and refractory organic forms suggests that while anthropogenic nutrient enrichment has tripled the total nitrogen load, it has resulted in a 6.7‐fold increase in total labile nitrogen load.     

TRANSPORT AND DISTRIBUTION OF NUTRIENTS IN THE LOXAHATCHEE RIVER ESTUARY,SOUTHEASTERN FLORIDA, 1979–811

ABSTRACT: Concentrations of total nitrogen, total phosphorus, and total organic carbon in the Loxahatchee River estuary decreased with increasing salinity in a manner indicating that mixing and dilution of freshwater by seawater was the primary process controlling the down-stream concentrations of nutrients. Most of the nutrients in the surface freshwater inflows entered the estuary from five major tributaries; however, about 10 percent of the total nitrogen and 32 percent of the total phosphorus were from urban stormwater runoff. The input of nutrients was highly seasonal and storm related. During a 61-day period of above average rainfall that included Tropical Storm Dennis, the major tributaries discharged 2.7 metric tons of total phosphorus, 75 metric tons of total nitrogen, and 1,000 metric tons of organic carbon to the estuary. This period accounted for more than half of the total nutrient load from the major tributaries during the 1981 water year (October 1, 1980, through September 30, 1981). Inorganic phosphorus and nitrogen increased relative to total phosphorus and nitrogen during storm runoff. Nutrient yield from the basin, expressed as grams per square meter of basin area, was relatively low. However, because the basin area (544 square kilometers) is large compared with the volume of the estuary, the basin might be expected to contribute significantly to estuarine enrichment were it not for tidal flushing. Approximately 60 percent of the total volume of the estuary is flushed on each tide. Because the estuary is well flushed, it probably has a large tolerance for nutrient loading.     

Phosphorus losses in simulated rainfall runoff from manured soils of Alberta

Manure applied to agricultural land at rates that exceed annual crop nutrient requirements can be a source of phosphorus in runoff. Manure incorporation is often recommended to reduce phosphorus losses in runoff. A small plot rainfall simulation study was conducted at three sites in Alberta to evaluate the effects of manure rate and incorporation on phosphorus losses. Treatments consisted of three solid beef cattle manure application rates (50, 100, and 200 kg ha(-1) total phosphorus), an unmanured control, and two incorporation methods (nonincorporated and incorporated with one pass of a double disk). Simulated rain was applied to soils with freshly applied and residual (1 yr after application) manure at 70 mm h(-1) to produce 30 min of runoff. Soil test phosphorus (STP), total phosphorus (TP), and dissolved reactive phosphorus (DRP) concentrations in runoff increased with manure rate for fresh and residual manure. Initial abstraction and runoff volumes did not change with manure rate. Initial abstraction, runoff volumes, and phosphorus concentrations did not change with manure incorporation at Lacombe and Wilson, but initial abstraction volumes increased and runoff volumes and phosphorus concentrations decreased with incorporation of fresh manure at Beaverlodge. Phosphorus losses in runoff were directly related to phosphorus additions. Extraction coefficients (slopes of the regression lines) for the linear relationships between residual manure STP and phosphorus in runoff were 0.007 to 0.015 for runoff TP and 0.006 to 0.013 for runoff DRP. While incorporation of manure with a double disk had no significant effect on phosphorus losses in runoff from manure-amended soils 1 yr after application, incorporation of manure is still recommended to control nitrogen losses, improve crop nutrient uptake, and potentially reduce odor concerns.     

POTENTIAL PHOSPHORUS LOAD REDUCTIONS UNDER THE LAKE OKEECHOBEE REGULATORY PROGRAM1

ABSTRACT: Nutrient loading from beef pastures located within the northern Lake Okeechobee watershed in Florida, has been identified as a source of phosphorus contributing to the accelerated eutrophication of the lake. Since 1989 within the watershed, 557 agricultural drainage sites, mainly beef pasture, have been monitored for compliance under a regulatory program. Of those sites, 154 were actively monitored for phosphorus concentrations from October 1, 1998, to September 30, 1999. Of these 154 sites, 77 were considered to be out of compliance (OOC). An OOC site is defined as having runoff with a 12‐month average phosphorus concentration exceeding the permitted discharge limit. The average annual phosphorous load from the 77 OOC sites for an eight‐year study period from October 1, 1991, to September 30, 1999, was estimated using measured concentration values and simulated runoff obtained from an agricultural nonpoint source pollution model, CREAMS‐WT. The 77 OOC sites produced an estimated average annual 46 metric tonnes of phosphorus load, of which an estimated 22 tonnes of phosphorus reached Lake Okeechobee on an average annual basis. The remaining estimated average annual 24 tonnes of phosphorus load was retained by streams and wetlands in the discharge transport system between the sites and the lake. The estimated average annual load reaching Lake Okeechobee from the OOC sites represented 11 percent of the phosphorus load above a five‐year average annual target load for the lake. However, the OOC site drainage areas represented only 3 percent of the northern watershed that drains into the lake. Of the 77 OOC sites, 12 sites had an average annual phosphorus loading rate equal to or greater than 3.0 kg/ha and were placed on the priority list for the Critical Restoration Project in the Lake Okeechobee watershed. To estimate the possible phosphorus load reductions from the 77 sites, two scenarios were modeled. The first scenario reduced phosphorus concentrations in runoff to the permitted discharge limits under the Lake Okeechobee regulatory program. The second scenario changed current land uses to native rangeland with an estimated annual offsite total phosphorus areal loading rate of 0.114 kg/ha. These two scenarios are hypothetical with assumed concentration values and loading rate. Model results showed that the first management scenario reduced the average annual phosphorus load to the lake by an estimated 15 tonnes. The second scenario reduced the average annual phosphorus load to the lake by an estimated 21 tonnes.     

广西坡耕地主要经济作物施肥与养分径流流失初探

为研究广西坡耕地主要经济作物甘蔗、玉米和花生农民常规施肥及不施肥处理对植株生长情况、经济产量及养分径流流失的影响,探寻提高广西经济作物经济效益、减少成本、减少环境污染的最佳施肥量,在坡耕地,观测降雨过程的养分径流流失,运用SPSS统计分析软件对试验数据进行分析,寻找成本低、效益高的种植方法。结果表明,对照与常规施肥相比,甘蔗、玉米、花生作物的生长情况差异不明显。对照处理的玉米经济产量、生物产量、淀粉含量分别为851．42kg·667m-2 3640．4kg·667m-2．68．40％;比玉米（常规施肥）高100．62kg·667m-2．485．98kg·667m-2 7．5％;花生对照的粗脂肪比其常规施肥高了45g·kg-1;径流养分总氮、总磷、总钾、硝态氮、铵态氮径流流失总量最高的均是花生常规施肥,其次是甘蔗对照,最少的玉米对照。径流量与总氮、总磷、总钾、硝态氮、铵态氮的相关系数,常规施肥处理偏高于对照。玉米对照的养分径流流失总量最少;花生常规施肥养分径流率最大;玉米比花生更适合在广西肥沃的坡耕地中种植。     

GENERALIZED WATERSHED LOADING FUNCTIONS FOR STREAM FLOW NUTRIENTS1

ABSTRACT: Loading functions are proposed as a general model for estimating monthly nitrogen and phosphorus fluxes in stream flow. The functions have a simple mathematical structure, describe a wide range of rural and urban nonpoint sources, and couple surface runoff and ground water discharge. Rural runoff loads are computed from daily runoff and erosion and monthly sediment yield calculations. Urban runoff loads are based on daily nutrient accumulation rates and exponential wash off functions. Ground water discharge is determined by lumped parameter unsaturated and saturated zone soil moisture balances. Default values for model chemical parameters were estimated from literature values. Validation studies over a three-year period for an 850 km² watershed showed that the loading functions explained at least 90 percent of the observed monthly variation in dissolved and total nitrogen and phosphorus fluxes in stream flow. Errors in model predictions of mean monthly fluxes were: dissolved phosphorus - 4 percent; total phosphorus - 2 percent; dissolved nitrogen - 18 percent; and total nitrogen - 28 percent. These results were obtained without model calibration.     

Modeling Climate Change Impacts on Hydrology and Nutrient Loading in the Upper Assiniboine Catchment1

Shrestha, Rajesh R., Yonas B. Dibike, and Terry D. Prowse, 2011. Modeling Climate Change Impacts on Hydrology and Nutrient Loading in the Upper Assiniboine Catchment. Journal of the American Water Resources Association (JAWRA) 48(1): 74‐89. DOI: 10.1111/j.1752‐1688.2011.00592.x Abstract: This paper presents a modeling study on climate‐induced changes in hydrologic and nutrient fluxes in the Upper Assiniboine catchment, located in the Lake Winnipeg watershed. The hydrologic and agricultural chemical yield model, Soil and Water Assessment Tool (SWAT) was employed to model a 21‐year baseline (1980‐2000) and future (2042‐2062) periods with model forcings for future climates derived from three regional climate models (RCMs) and their ensemble means. The modeled future scenarios reveal that potential future changes in the climatic regime are likely to modify considerably hydrologic and nutrient fluxes. The effects of future changes in climatic variables, especially precipitation and temperature, are clearly evident in the resulting snowmelt and runoff regimes. The future hydrologic scenarios consistently show earlier onsets of spring snowmelt and discharge peaks, and higher total runoff volumes. The simulated nutrient loads closely match the dynamics of the future runoff for both nitrogen and phosphorus, in terms of earlier timing of peak loads and higher total loads. However, nutrient concentrations could decrease due to the higher rate of runoff increase. Overall, the effects of these changes on the nutrient transport regime need to be considered together with possible future changes in land use, crop type, fertilizer application, and transformation processes in the receiving water bodies.     

流域非点源分布式模型AnnAGNPS参数的不确定性研究

流域非点源分布式模型的不确定性研究成为目前的热点问题之一。本研究以宁波市章溪河流域为研究区，通过GIS软件AreView和AnnAGNPS模型，集成利用莫里斯分类筛选法，选取临界源面积、SCS曲线系数、水土保持因子、饱和导水率、氮磷吸收率、施肥量等6个因子进行敏感性分析。模拟结果表明，土壤饱和导水率、水土保持因子和径流曲线CN值对模型输出结果影响较大；水土保持因子对泥沙、总磷和总有机碳负荷的模拟结果影响最大，均呈显著负效应；径流曲线CN值对总氮负荷计算结果影响最大，呈显著正效应。