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1.
应用固相萃取技术分析全血中阿米替林,多虑平药物 总被引:3,自引:1,他引:3
本文用国产大孔径树脂GDX-403固相柱富集分离全血中的阿米替林、多虑平药物,并用GC/NPD毛细管气相色谱技术进行检测,在1.0ml全血中加入2.0μg药物,回收率分别为83.6%和39.7%,CV值为4.44%和3.32%,检出限为25ng.ml^-1和30ng.ml^-1。研究结果经动物实验验证,获得满意的结果。 相似文献
2.
本文研究了有机磷农药甲基1605和毒死蜱对^1O2探针性物质二乙基二硫醚,萜品烯及ROO和RO探针性物质2,6-二叔丁基-4-甲基苯酚和1,2,3,4-四氢萘光降解的敏化作用。结果表明基态氧直接参与了DES和α-terp的光解;在甲基1605的作用下,1/Kexptl与「αterp」的关系表明,α-terp的降解不为^1O2历程。 相似文献
3.
离子色谱法测定饮用水和面包中的溴酸根 总被引:24,自引:0,他引:24
选用AS9-HC高容量阴离子交换色谱柱,不需处理除去干扰离子,可直接进样。测定了两种水样,其中一种检出溴酸根,方法检出根0.005mg.1^-1水样加标回收率91.3-93.4%。采用全新的自动化样品处理技术-加速溶剂萃取萃取面包中的溴酸根。经AS9-SC阴离子交换色谱柱分离,选择最佳淋洗条件。电导检测,方法检 0.07mg.1^-1,对十二种市售包进行测定,均未检出溴酸根,样品加标回收率79.9 相似文献
4.
铬(Ⅲ)和铬(Ⅵ)的离子色谱分析 总被引:7,自引:0,他引:7
本文对水样中Cdr和Cr的离子色谱分析结果表明:Cr经柱前衍生,与CCrtO^2-4状态存在的Cr在阴离子交换柱上分离,用光度法检测。Cr和Cr以最低检出限分别为30μg.l^-1和1μg.l^-1,常见阴,阳离子不干扰。 相似文献
5.
低压离子色谱法测定水和酸雨样品中F^—,Cl^—,NO^—3,SO^2—4离子 总被引:4,自引:0,他引:4
本文介绍了低压离子色谱法测定水样和酸雨中氟,氯,硝酸根,硫酸根离子的方法,欲测阴离子在阴离子交换柱上被分离,同时用1.2mol.l^-1Na2CO3溶液作流动相,流速为1.6ml.min^-1。各离子的流分用电导检测。 相似文献
6.
聚苯乙烯基硫代磺酸钾树脂对水中卤代物的选择性结构分析 总被引:5,自引:0,他引:5
本文用聚苯乙烯基硫代磺酸钾树脂为选择性试剂与水中卤代物作用,排除水体中其它化合物对结构分析的干扰,采用动态恒温柱法及C-18柱富集法作为该反应发生的途径,结果表明:前一种途径的检测结果由样品反应活性决定,而后者检测结果还受到萃取率的影响,两种方法均可达到10-20mg·l^-1的检测水平。 相似文献
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8.
本文主要介绍在含酸及其相应盐的废液中分离酸和盐的一种方法。将含酸及其相应盐的废液,通过装有强碱性阴离子交换树脂柱,其中的酸受到阻滞,而相应的盐能顺利通过,然后用水洗脱,则流出的是含酸的溶液,使酸和相应的盐得到了分离。经FeSO4-H2SO4和ZnSO4-H2SO4两组废液的试验,均能使酸和金属得到回收。分离后的废水,可达标排放,废液得到了处理。酸阻滞法简单易行,易于投产使用,不受规模大小的限制。 相似文献
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10.
三种空气微生物采样方法的比较 总被引:2,自引:0,他引:2
在室内自然条件下,对三种空气微生物采样方法进行比较。结果表明,ANDERSEN采样器法,LWC-1笄样器法和平皿沉降法测定的室内空气微生物粒子浓度分别为2634个/m^%3,2395个/m^3和1380个/m^3,LWC-1型和ANDERSEN二种采样器的采样结果之间没有明显差异,二种采样器的采样结果均明显高于平皿沉降法的采样结果。ANDERSEN采样器的采样效率高,且可同时测定空气微生物粒子的浓 相似文献
11.
D201树脂对双组分萘系化合物的吸附分离 总被引:1,自引:0,他引:1
用D201强碱性阴离子交换树脂自双组分水溶液中选择吸附分离1-氨基-2-萘酚-4-磺酸(1,2,4-酸)和2-萘酚,考察了溶液pH值、浓度、温度、树脂床高及流速等因素对吸附和分离系数的影响.结果表明,在pH 3—6时,树脂对1,2,4-酸有较高的吸附量及吸附选择性,利于1,2,4-酸与2-萘酚的选择性吸附分离.温度对吸附的影响较小,等温吸附规律符合Freundlich模型.动态吸附表明,至1,2,4-酸的泄漏点时,吸附流出液中几乎只含2-萘酚,1,2,4-酸被吸附于树脂上.随着树脂床层的增长或初始浓度和流速的减小,都使泄漏点推迟及分离系数提高.载酚酸的树脂柱可用15%质量比的NH4Cl和20%体积比的乙醇混合液定量洗脱1,2,4-酸. 相似文献
12.
Zhigang Liu Ying Wang Yansheng Li Hui Chang 《Frontiers of Environmental Science & Engineering》2008,2(4):410-414
Electro-assisted regeneration (EAR) for the mixed bed of strongly acidic cation and weakly basic anion exchange resins with the Al(OH)3 suspension in a three-compartment cell was investigated. The desalination experiments were carried out to evaluate the characteristic of the regenerated mixed resins. Experimental results showed that the efficiency of resin regeneration was strictly dependent on the voltage, regeneration time, and feed regenerant flow rate. The amount of the effluent reached 50 times the volume of the resins bed, and the conductivity was less than 1.0 μs/cm. Compared to the conventional ER, the total effluent volume of EAR was about 1000 mL more than that of ER under the same conditions, and the outlet conductivity was significantly lower. The desalination and regeneration reaction mechanisms of the mixed resins indicated the regeneration efficiency of resin with Al(OH)3 as the regenerant was much higher than that with H2O. 相似文献
13.
Yufeng Liao Mengmeng Tang Mengyuan Li Peng Shi Aimin Li Yangyang Zhang Yang Pan 《Frontiers of Environmental Science & Engineering》2023,17(10):125
14.
Qing ZHOU Mengqiao WANG Aimin LI Chendong SHUANG Mancheng ZHANG Xiaohan LIU Liuyan WU 《Frontiers of Environmental Science & Engineering》2013,7(3):412-419
A novel hyper-crosslinked resin (MENQ) modified with an anion exchange group was prepared using divinylbenzene (DVB) and methyl acrylate (MA) as comonomers via four steps: suspension polymerization, post-crosslinking, ammonolysis and alkylation reactions. The obtained resin had both a high specific surface area (793.34 m2·g-1) and a large exchange capacity (strong base anion exchange capacity, SEC: 0.74 mmol·g-1, weak base anion exchange capacity, WEC: 0.45 mmol·g-1). XAD-4 was selected as an adsorbent for comparison to investigate the adsorption behavior of tetracycline (TC) and humic acid (HA) onto the adsorbents. The results revealed that MENQ could effectively remove both TC and HA. The adsorption capacity of XAD-4 for TC was similar to that of MENQ, but XAD-4 exhibited poor performance for the adsorption of HA. The adsorption isotherms of TC and HA were well-fitted with the Freundlich model, which indicated the existence of heterogeneous adsorption through cation-π bonding and π–π interactions. The optimal solution condition for the adsorption of TC was at a pH of 5–6, whereas the adsorption of HA was enhanced with increasing pH of the solution. 相似文献
15.
Zhigang LIU Shaomin ZHU Yansheng LI 《Frontiers of Environmental Science & Engineering》2012,6(1):45-50
A novel method for the regeneration of cation exchange resins by aluminum (Al) salts was investigated in order to improve the regeneration efficiency of resins and reduce the dosage of regenerant. The influences of Al3+ concentration and the pH of regeneration solution on resin transformation had been studied. The desalination experiments were carried out to evaluate the characteristics of the Al form resins. Experimental results showed that the regeneration rate of resins was strictly dependent on Al3+ concentration and the pH of the solution. Compared to the conventional regeneration method, the Al form mixed bed exhibited the same desalination capability as the H form mixed bed (MB), and the total organic carbon (TOC) removal was up to 90%, clearly higher than that of the H form. Al salt solution could be utilized repeatedly to regenerate Al form resins. 相似文献
16.
阳离子染料废水的脱色方法及其机理的研究 总被引:18,自引:2,他引:18
本文以阳离子染料碱性品红为代表,采用PFAS混凝剂对其水溶液进行脱色处理,在处理过程加入适量的十二烷基苯磺酸钠做助剂,脱色率最高可达99%以上。本文还研究pH值及盐效应对脱色率的影响。脱色机理的研究结果表明:阳离子染料在水溶液中与十二烷基苯磺酸钠之间发生化学作用,靠氢键及静电键结合,使原来带正电荷的阳离子染料粒子转变为带负电荷的粒子,再与带正电荷的PFAS混凝剂的胶体作用产生絮凝沉淀。 相似文献
17.
化学品的快速生物降解性直接影响其在环境中的迁移、转化和归宿,是鉴别其环境危害性和持久性的基本指标,是政府管理部门对化学品进行风险管理的重要科学依据,在生态毒理测试中具有非常重要的地位。为探讨试验方法、接种物来源以及两者的交互效应对苯甲酸钠生物降解率的影响,2013~2015年间以广州地区2个主要处理生活污水的污水处理厂(DTS、LD)为接种物来源,采用OECD 301系列试验方法(301B、301D和301F)进行了苯甲酸钠的快速生物降解性试验,共获得89个标准化测试数据。统计分析结果显示,接种物来源、试验方法与接种物来源的交互效应对苯甲酸钠生物降解率影响不显著,但试验方法单一因素的影响显著。本研究表明,当受试物为易生物降解时,接种物来源、试验方法和接种物来源的交互效应对该受试物的生物降解率无显著的影响,但在同一条件下,选择不同的试验方法往往会导致最终生物降解率出现明显差异。 相似文献
18.
化学品的快速生物降解性直接影响其在环境中的迁移、转化和归宿,是鉴别其环境危害性和持久性的基本指标,是政府管理部门对化学品进行风险管理的重要科学依据,在生态毒理测试中具有非常重要的地位。为探讨试验方法、接种物来源以及两者的交互效应对苯甲酸钠生物降解率的影响,2013—2015年间以广州地区2个主要处理生活污水的污水处理厂(DTS、LD)为接种物来源,采用OECD 301系列试验方法(301B、301D和301F)进行了苯甲酸钠的快速生物降解性试验,共获得89个标准化测试数据。统计分析结果显示,接种物来源、试验方法与接种物来源的交互效应对苯甲酸钠生物降解率影响不显著,但试验方法单一因素的影响显著。本研究表明,当受试物为易生物降解时,接种物来源、试验方法和接种物来源的交互效应对该受试物的生物降解率无显著的影响,但在同一条件下,选择不同的试验方法往往会导致最终生物降解率出现明显差异。 相似文献
19.
Dorota Jermakowicz-Bartkowiak 《Environmental geochemistry and health》2010,32(4):317-320
Vinylbenzyl chloride/divinylbenzene gel copolymer beads have been modified using piperidine, hexamethyleneimine, piperazine,
1-(2-aminoethyl)piperazine, and N-cyclohexyl-1,3-propanediamine. These resins were then tested for the sorption of noble metal ions, namely, Re(VII), Pd(II),
Pt(IV), and Au(III), from a 0.1 M HCl solution. The effect of these resins on the sorption of other coexisting ions, such
as Cu, Ni and Fe, was also studied. Of the resins tested, resin 4 [1-(2-aminoethyl)piperazine groups] showed the highest sorption
capacity for Pt(IV) and Re(VII) from single and multicomponent solutions, with the sorption of Pt(IV) from the multicomponent
solution (Re, Au, Pd, Pt, Cu, Ni Fe) in 0.1 M HCl reaching 68 mg Pt/g. 相似文献
20.
Xinjiao D 《Journal of environmental biology / Academy of Environmental Biology, India》2006,27(4):639-643
In this paper, adsorption properties of a pretreated of Cladosporium sp. for Cu2 were studied. The fungi pretreated with some chemical reagents exhibited higher Cu2+ removal capacities than native biomass. The optimum chemical reagent was 0.2M NaOH. After 0.2M NaOH pretreatment, optimum conditions of biosorption were found to be pH 5.0, temperature 35 degrees C, and stirring speed of 100rpm. Equilibrium isotherms were obtained from adsorption experiments and the biosorption maximun capacity obtained was at 28.31mg/g. The biosorbed metal ions were effectively eluted by 0.05M HNO3 solution. After eluting, the biosorbed metal ions biomass was regenerated by washing with deionized water and then contacted with a solution containing 0. 1M of Ca2+, Mg2+ ions before further adsorption tests. The pretreated fungi biomass could be used for three cycles: biosorption, elution of biosorbed ion, regeneration of biomass. 相似文献