生活垃圾焚烧项目竣工环保验收中存在的问题探讨

分析了目前生活垃圾焚烧项目竣工环保验收工作存在的问题,依据建设项目竣工环保验收规范和新《生活垃圾焚烧控制标准》,提出了解决问题的对策,重点论述加强验收监测工作的规范性,为生活垃圾焚烧竣工项目环保验收工作提供合理化建议。     

建设项目竣工环保验收中公众参与的探讨

建设项目竣工环境保护验收是我国环境保护管理的重要手段。阐述了建设项目竣工环境保护验收中公众参与的法律和制度基础，竣工环保验收中公众参与不仅能维护公众的环境权益，为竣工环保验收“三同时”制度的执行提供可靠依据，还可以推动环保行政主管部门决策的民主化、科学化。研究了竣工环保验收中公众意见调查的现状及存在的问题，提出加强和规范建设项目竣工环保验收公众参与的建议。     

煤化工项目竣工环保自主验收对策建议

介绍了建设项目竣工环保自主验收制度的由来,总结了煤化工企业开展项目竣工环保自主验收面临的主要困难,提出了做好煤化工项目竣工环保自主验收工作的对策建议。指出：建设单位应从充分认识自身环保主体责任、做好排污许可证实施的技术储备、完成竣工环保示范任务、持续加强环保技术开发及投入等方面做好自主验收工作。     

输变电环境影响评价及竣工环保验收相关要点分析

通过输变电环境影响评价及竣工环保验收工作的实践,从输变电环境影响评价及竣工环保验收的基本概念和相关法律、法规出发,分析了输变电环境影响评价及竣工环保验收工作的要点,包括敏感目标调查、生态环境影响评价与监测、声环境评价重点、公众参与等,在此基础上论述了两者之间的相互关系,最后针对输变电环境影响评价及竣工环保验收工作更加科学化提出了建议。     

火电厂竣工环境保护验收工作的管理和建议

竣工环境保护验收是检查环保＂三同时＂制度执行情况的重要环节,也是环保监督管理的重要内容。从竣工环境保护验收工作的相关法律、法规出发,依据火电厂验收技术规范,并结合火电厂竣工环境保护验收工作实践,阐述了火电厂验收工作的相关规定及流程,并结合验收工作中经常出现的问题,给出改进建议。     

电网建设项目环保管理信息系统的开发与应用

针对目前电网建设项目环境保护工作管理现状，利用可视化面向对象开发技术和图形化组态的概念构建出一个图形导航、树状导航相结合的环境保护工作管理信息系统软件。系统分为电网建设项目环境保护工作基础数据管理——项目管理、电网建设项目环境保护工作管理文件查询——项目环保文件查询和国家环境保护法律和法规等文件查询、常用文件管理四部分。应用结果证明，该系统基本满足了当前电网建设项目环境保护工作管理及信息化的要求，为电网建设项目环境保护工作管理提供了更加准确、便利的工具。     

商务部门晓伟副司长一行到天津检查验收再生资源回收工作

2008年9月10日--12日，商务部商业改革司门晓伟副司长带专家组一行六人来天津市对再生资源回收体系建设试点项目进行验收，听取了天津市再生资源回收工作汇报。专家组参观了天津子牙环保工业园，对天津市社区回收网络、初级分拣加工中心、废旧不锈钢集散加工中心、废旧轮胎回收加工利用中心等再生资源回收试点建设项目进行了现场考察和验收。专家组对天津市再生资源回收工作给予了高度评价和充分肯定，指出：从最近走几个省市验收情况看，天津工作做得实，数据清楚，措施得力。再生资源回收体系建设走在了全国前列，值得推广。具体表现在：一是天津高度重视再生资源回收工作。     

火电厂"三同时"验收应当注意的问题

根据建设项目竣工环境保护验收规范要求，提出火电厂在验收过程中应当注意的几个问题。     

输变电项目竣工环保验收存在的问题及对策分析

结合输变电项目环保验收的调查实践，分析了输变电项目竣工环保验收中存在问题，提出对策及建议。     

河南省清洁生产审核验收标准设计及探讨

通过清洁生产审核验收标准的制定,来推动和规范清洁生产审核工作.依据相关的法律法规、验收经验总结、编制原则,设计清洁生产审核验收标准.采取分值法设计清洁生产审核验收标准,涵盖了清洁生产审核的程序,保证了标准的严密性、可操作性和完整性;体现了清洁生产审核的内容,反映了清洁生产实施的结果;为企业提供了审核目标,为管理部门提供了验收依据.     

Determination of the Thermal Efficiency of Pre-boilover Burning of a Slick of Oil on Water

The burning rate of a slick of oil on a water bed is calculated by a simple expression derived from a one-dimensional heat conduction equation. Heat feedback from the flame to the surface is assumed to be a constant fraction of the total energy released by the combustion reaction. The constant fraction (χ) is named the burning efficiency and represents an important tool in assessing the potential of in situ burning as a counter-measure to an oil-spill. The total heat release, as a function of the pool diameter, is obtained from an existing correlation. It is assumed that radiative heat is absorbed close to the fuel surface, that conduction is the dominant mode of heat transfer in the liquid phase and that the fuel boiling temperature remains constant. By matching the characteristic thermal penetration length scale for the fuel/water system and an equivalent single layer system, a combined thermal diffusivity can be calculated and used to obtain an analytical solution for the burning rate. Theoretical expressions were correlated with crude oil and heating oil, for a number of pool diameters and initial fuel layer thickness. Experiments were also conducted with emulsified and weathered crude oil. The simple analytical expression describes well the effects of pool diameter and initial fuel layer thickness permitting a better observation of the effects of weathering, emulsification and net heat feedback to the fuel surface. Experiments showed that only a small fraction of the heat released by the flame is retained by the fuel layer and water bed (of the order of 1%). The effect of weathering on the burning rate decreases with the weathering period and that emulsification results in a linear decrease of the burning rate with water content.     

富拉尔基发电总厂200MW机组除尘器改造

对富拉尔基发电总厂5号炉的设计条件进行了分析，针对燃用低硫煤，飞灰比电阻高，场地较小，除尘效率要求高的情况，在电除尘器的设计上采取有效措施，达到了排放要求。     

Calculation of carbon balances for evaluation of the biodegradability of polymers

Establishing carbon balances has been proven to be an applicable and powerful tool in testing biodegradability of polymers. In controlled degradation tests at a 4-L scale with the model polymer poly(-hydroxybutyrate) (PHB), it was shown that the degree of degradation could not be determined with satisfactory accuracy from CO₂ release alone. Instead, the course of degradation was characterized by means of establishing carbon balances for the degradation of PHB withAcidovorax facilis and a mixed culture derived from compost. Different analytical methods for determining the different carbon fractions were adapted to the particular test conditions and compared. Quantitative determination of biomass and residual polymer were the main problems in establishing carbon balances. Amounts of biomass derived from protein measurements depend strongly on assumptions of the protein content of the biomass. Selective oxidation of biomass with hypochlorite was used as alternative, but here problems arose from insoluble metabolic products. Determination of soluble components with the method of chemical oxygen demand (COD) also includes empirical assumptions but seems acceptable if the dissolved carbon fraction is in the range of some 10% total carbon. Results confirm both analytical assays and theoretical approaches, in ending up at values very close to 100%, within an acceptable standard deviation range under test conditions comparable to standard test practice.Paper presented at the Bio/Environmentally Degradable Polymer Society—Third National Meeting, June 6–8, 1994, Boston, Massachusetts.     

Review of the kinetics of alkaline degradation of cellulose in view of its relevance for safety assessment of radioactive waste repositories

The degradation of cellulose (a substantial component of low- and intermediate-level radioactive waste) under alkaline conditions occurs via two main processes: a peeling-off reaction and a basecatalyzed cleavage of glycosidic bonds (hydrolysis). Both processes show pseudo-first-order kinetics. At ambient temperature, the peeling-off process is the dominant degradation mechanism, resulting in the formation of mainly isosaccharinic acid. The degradation depends strongly on the degree of polymerization (DP) and on the number of reducing end groups present in cellulose. Beyond pH 12.5, the OH^- concentration has only a minor effect on the degradation rate. It was estimated that under repository conditions (alkaline environment, pH 13.3-12.5) about 10% of the cellulosic materials (average DP = 1000-2000) will degrade in the first stage (up to 10⁵ years) by the peeling-off reaction and will cause an ingrowth of isosaccharinic acid in the interstitial cement pore water. In the second stage (10⁵-10⁶ years), alkaline hydrolysis will control the further degradation of the cellulose. The potential role of microorganisms in the degradation of cellulose under alkaline conditions could not be evaluated. Proper assessment of the effect of cellulose degradation on the mobilization of radionuclides basically requires knowing the concentration of isosaccharinic acid in the pore water. This concentration, however, depends on several factors such as the stability of ISA under alkaline conditions, sorption of ISA on cement, formation of sparingly soluble ISA-salts, etc. A discussion of all the relevant processes involved, however, is far beyond the scope of the presented overview.     

Study of Aging Characteristics of Ternary Blends of Polyethylenes—II

Six film samples of low-density polypropylene (LDPE)/linear LDPE (LLDPE)/high-density polypropylene (HDPE) with varying ratios of LDPE (20–45 ... wt%) and LLDPE (25–50 wt%) having a fixed amount of HDPE at 30 wt% were prepared by blown film extrusion technique. The samples were aged at four different temperatures, 55°, 70°, 85°, and 100°C, for four different time periods in the interval of between 150 hours and up to 600 hours. The change in the structure of various constituents and the formation of various oxygenated (peroxy and hydroperoxy) and unsaturated groups during thermo-oxidative degradation was discussed by infrared spectroscopy. The visiosity-average molecular weight was found to have decreased slowly in the initial aging hours and temperatures, whereas it decreased by 10% with its previous value tensile strength that is, 100°C when aged for 600 hours. The tensile strength of the sample first increased by 67% at 55°C and 89% at 70°C up to 450 hours, whereas the values increased by 52.5% at 85°C and 33.9% at 100°C when aged for 150 hours and then decreased. The percentage elongation at break increased by 2.7% at 55°C and 10.7% at 70°C for 150 and 300 hours of aging, respectively, whereas the percentage decreased when aged at 85°C and 100°C for up to 600 hours of aging. The values of gel content (percent) increased and initial degradation temperature decreased with aging time and temperature.     

Effect of Degree of Substitution of Octenyl Succinate Starch on Enzymatic Degradation

Octenyl succinate starch of degree of substitution (ds) 0.03, 0.07, and 0.11 was synthesized in an aqueous medium. These compounds were then tested for the susceptibility to enzymatic degradation. The multiple-enzyme regime of -amylase, amyloglucosidase, and pullulanase was chosen for the evaluation. This combination of enzymes had been proven to degrade 99.5% of unmodified starch to glucose and hence was chosen for this study. It was found that even small amounts of subsituent caused a considerable decrease in the extent of degradation. The net extent of degradation decreased with increasing ds. Surprisingly, the amount of glucose from all three substituted substrates was quite similar, suggesting the effect small amounts of subtituent had on the enzymatic activity.     

Selection of adsorbents for treatment of leachate: batch studies of simultaneous adsorption of heavy metals

The simultaneous adsorption of copper (Cu), cadmium (Cd), nickel (Ni), and lead (Pb) ions from spiked deionized water and spiked leachate onto natural materials (peat A and B), by-product or waste materials (carbon-containing ash, paper pellets, pine bark, and semi-coke), and synthetic materials (based on urea-formaldehyde resins, called blue and red adsorbents) or mixtures thereof was investigated. The adsorbents that gave the highest metal removal efficiencies were peat A, a mixture of peat B and carbon-containing ash, and a mixture of peat A and blue. At an initial concentration of 5 mg/l for each metal, the removal of each species of metal ion from spiked water and spiked leachate solutions was very good (>90%) and good (>75%), respectively. When the initial concentration of each metal in the solutions was twenty times higher (100 mg/l), there was a noticeable decrease in the removal efficiency of Cu²⁺, Cd²⁺, and Ni²⁺, but not of Pb²⁺. Langmuir monolayer adsorption capacities, q_m, on peat A were found to be 0.57, 0.37, and 0.36 mmol/g for Pb²⁺, Cd²⁺, and Ni²⁺, respectively. The order of metal adsorption capacity on peat A was the same in the case of competitive multimetal adsorption conditions as it was for single-element adsorption, namely Pb²⁺ > Cd²⁺ ≥ Ni²⁺. The results show that peat alone (an inexpensive adsorbent) is a good adsorbent for heavy metal ions.     

袋式除尘器气流分布数值计算研究

采用结构化/非结构化混合网格技术、多孔介质模型及k-ε两方程湍流模型,对某袋式除尘器及进出口管道内的气体流场进行了数值计算.计算结果表明,合理布置导流板后,袋式除尘器两箱体流量偏差为1.8％;除尘器下游滤袋单元处理气量偏大,中游滤袋单元处理气量较小,最大流量与最小流量偏差为22.3％；靠近除尘器进口处灰斗内存在气流回流特性,易造成粉尘的二次附着现象.     

Kinetics of Hydrolytic Degradation of PLA

The chemical recycling of poly(lactic acid) (PLA) to its monomer is crucial to reduce both the consumption of renewable resources for the monomer synthesis and the environmental impact related to its production and disposal. In particular, the production of lactic acid from PLA wastes, rather than from virgin raw materials, it is also possible to achieve considerable primary energy savings. The focus of this work is to analyse deeply the PLA hydrolytic decomposition by means of a kinetic model based on two reactions mechanism. To this end, new experimental data have been gathered in order to investigate a wider temperature range (from 140 to 180 °C) and to extend the water/PLA ratio up to 50 % of PLA by weight. The reported results clearly highlight that more than 95 % of PLA is hydrolyzed to water-soluble lactic acid within 120 min, when it is hydrolyzed within 160–180 °C. Furthermore, the kinetic constant is highly influenced by reaction temperature. The proposed “two reactions” kinetic mechanism complies satisfactorily with the experimental data under analysis.     

Effects of temperature on the release of nutrient elements of solid organic materials under conditions of oversaturation

The effects of temperature on the release of chemical components of six solid organic materials under conditions of oversaturation were investigated in this paper. The six materials were peat moss (PM), weathered coals (WC), charred rice husks (CRH), sawdust (Sd), turfgrass clippings (TC), and chicken manure (CM). Significant differences were observed in the available nitrogen and phosphorus content of the aqueous extracts of organic materials at different temperatures. The available nitrogen content in aqueous extracts of PM and WC at 25 °C was higher than that registered at 15 °C and 35 °C. Available nitrogen content in the aqueous extracts of CRH, Sd, TC, and WC at 35 °C was higher than at 15 °C and 25 °C. The available phosphorus content in the aqueous extracts of organic materials at 35 °C was higher than that available at 15 °C and 25 °C, with the exception of Sd. In addition, the release of available phosphorus in the aqueous solution of organic materials at different temperatures varied constantly for 108 h. The release of potassium (K⁺) and sodium (Na⁺) ions in the aqueous extracts of organic materials was basically steady over time, with the exception of CM. High temperature (35 °C) may significantly hasten the release of K⁺ from organic substrates (except for WC) with low temperatures significantly inhibiting release of K⁺ in Sd and CRH. High temperatures (35 °C) might significantly facilitate the release of Na⁺ in CM and TC. However, no significant differences were manifested in the release of Na⁺ from organic substrates at different temperatures, with the exception of CM and TC. Moreover, no significant differences were observed in the release of calcium, magnesium and iron ions with time, nor were there any significant differences in the contents of iron ions in the aqueous extracts of organic materials at different temperatures. The results indicate that multiple mediums should be pretreated in water for a week before being used for planting. They should be used when all mineral elements of organic materials are steady and ignoring the effect of organic mediums.