Soil-erosion and runoff prevention by plant covers in a mountainous area (se spain): Implications for sustainable agriculture

In the Mediterranean region the intensities and amounts of soil loss and runoff on sloping land are governed by rainfall pattern and vegetation cover. Over a two-year period (1998–1999), six wild species of aromatic and mellipherous plants (Thymus serpylloides subsp. Gadorensis, Thymus baeticus Boiss, Salvia lavandulifolia Vahl., Santolina rosmarinifolia L., Lavandula stoechas L. and Genista umbellata Poiret) were selected for erosion plots to determine their effectiveness in reducing water erosion on hillslopes of the Sierra Nevada Mountain (SE Spain). The erosion plots (including a bare-soil plot as control), located at 1,345 m in altitude, were 2 m² (2 m × 1 m) in area and had 13% incline. The lowest runoff and soil erosion rates, ranging from 9 to 26 mm yr⁻¹ and from 0.01 to 0.31 Mg ha⁻¹ yr⁻¹, respectively, over the entire study period, were measured under the Thymus serpylloides. Lavandula stoechas L. registered the highest rates among the plant covers tested, runoff ranging from 77 to 127 mm yr⁻¹ and erosion from 1.67 to 3.50 Mg ha⁻¹ yr⁻¹. In the bare-soil plot, runoff ranged from 154 to 210 mm yr⁻¹ and erosion from 4.45 to 7.82 Mg ha⁻¹ yr⁻¹. According to the results, the lowest-growing plant covers (Thymus serpylloides and Salvia lavandulifolia Vahl.) discouraged the soil erosion and runoff more effectively than did the taller and open medium-sized shrubs (Santolina rosmarinifolia L., Genista umbellata Poiret, Thymus baeticus Boiss and Lavandula stoechas L.). Monitoring allowed more direct linkage to be made between plant covers and the prevention of erosion, with implications for sustainable mountain agriculture and environmental protection.     

Impact of Vegetative Cover on Runoff and Soil Erosion at Hillslope Scale in Lanjaron, Spain

Soil loss and surface runoff patterns over a four-year period (1997–2000) were studied in erosion plots from three hillslopes under different vegetative covers (Rosmarinus officinalis, Triticum aestivum and natural-spontaneous vegetation) in Lanjaron (Alpujarras) on the south flank of the Sierra Nevada of southeast Spain. The erosion plots were located on the hillslopes at 35.5% incline, at 1,480 m in altitude and with 41.8 m² (21 m×1.9 m) in area. The vegetative covers were tested for effectiveness in controlling the surface runoff and soil loss production. The highest runoff and erosion values, ranging from 114.1 to 1.7 mmyr^–1 and from 14,564.3 to 6.6 kgha^–1yr^–1, respectively, over the entire study period, were measured under the Triticum aestivum. In the Rosmarinus officinalis, runoff ranged from 7.9 to 1.3 mmyr^–1 and erosion from 156.4 to 2.3 kgha^–1yr^–1, while on the hillslope under natural-spontaneous vegetation, runoff ranged from 4.4 to 0.9 mmyr^–1 and erosion from 322.3 to 2.2 kgha^–1yr^–1. According to the results the vegetative covers of Rosmarinus officinalis and natural-spontaneous vegetation reduced the soil losses by 99 and 98%, with respect to the Triticum aestivum, and the runoff losses by 94 and 96%, respectively. Also, the Rosmarinus officinalis and natural-spontaneous plants influenced infiltration by intercepting much of the rainfall water respect to the Triticum aestivum. Monitoring allowed more direct linkages to be made between management practices and their impacts on runoff and soil erosion, thereby enabling to identify problems and take appropriate preventive measures to improve the management practices.     

Soil erosion under different vegetation covers in the Venezuelan Andes

This comparative study of soil erosion considered different environments in an ecological unit of the Venezuelan Andes. The soils belong to an association of typic palehumults and humic dystrudepts. Soil losses were quantified by using erosion plots in areas covered by four types of vegetation, including both natural and cultivated environments. The highest soil erosion rate evaluated corresponded to horticultural crops in rotation: reaching a value of 22 Mg ha^–1 per year. For apple tree (Malus sylvestris Miller) plots, soil losses reached values of 1.96 Mg ha^–1 per year. Losses from pasture (Pennisetum clandestinum Hochst. ex Chiov.) plots, without livestock grazing, were as high as 1.11 Mg ha^–1 during the second year of the experiment. The highest soil losses generated from plots under natural forest were equal to 0.54 Mg ha^–1 per year. Environmental factors such as total and effective rainfall, runoff, and some soil characteristics as those related to soil losses by water erosion were evaluated. The type of management applied to each site under different land use type and the absence of conservation practices explain, to a large extent, the erosive processes and mechanisms.     

Seasonality of Soil Erosion Under Mediterranean Conditions at the Alqueva Dam Watershed

The Alqueva reservoir created the largest artificial lake of Western Europe in 2010. Since then, the region has faced challenges due to land-use changes that may increase the risk of erosion and shorten the lifetime of the reservoir, increasing the need to promote land management sustainability. This paper investigates the aspect of seasonality of soil erosion using a comprehensive methodology that integrates the Revised Universal Soil Loss Equation (RUSLE) approach, geographic information systems, geostatistics, and remote-sensing. An experimental agro-silvo pastoral area (typical land-use) was used for the RUSLE factors update. The study confirmed the effect of seasonality on soil erosion rates under Mediterranean conditions. The highest rainfall erosivity values occurred during the autumn season (433.6 MJ mm ha^?1 h^?1), when vegetation cover is reduced after the long dry season. As a result, the autumn season showed the highest predicted erosion (9.9 t ha^?1), contributing 65 % of the total annual erosion. The predicted soil erosion for winter was low (1.1 t ha^?1) despite the high rainfall erosivity during that season (196.6 MJ mm ha^?1 h^?1). The predicted annual soil loss was 15.1 t ha^?1, and the sediment amount delivery was 4,314 × 10³ kg. Knowledge of seasonal variation would be essential to outline sustainable land management practices. This model will be integrated with World Overview of Conservation Approaches and Technologies methods to support decision-making in that watershed, and it will involve collaboration with both local people and governmental institutions.     

The use of 137Cs to establish longer-term soil erosion rates on footpaths in the UK

There is increasing awareness of the damage caused to valuable and often unique sensitive habitats by people pressure as degradation causes a loss of plant species, disturbance to wildlife, on-site and off-site impacts of soil movement and loss, and visual destruction of pristine environments. This research developed a new perspective on the problem of recreational induced environmental degradation by assessing the physical aspects of soil erosion using the fallout radionuclide caesium-137 (¹³⁷Cs). Temporal sampling problems have not successfully been overcome by traditional research methods monitoring footpath erosion and, to date, the ¹³⁷Cs technique has not been used to estimate longer-term soil erosion in regard to sensitive recreational habitats. The research was based on-sites within Dartmoor National Park (DNP) and the South West Coast Path (SWCP) in south-west England. ¹³⁷Cs inventories were reduced on the paths relative to the reference inventory (control), indicating loss of soil from the path areas. The Profile Distribution Model estimated longer-term erosion rates (ca. 40 years) based on the ¹³⁷Cs data and showed that the combined mean soil loss for all the sites on ‘paths’ was 1.41 kg m^?2 yr^?1 whereas the combined ‘off path’ soil loss was 0.79 kg m^?2 yr^?1, where natural (non-recreational) soil redistribution processes occur. Recreational pressure was shown to increase erosion in the long-term, as greater soil erosion occurred on the paths, especially where there was higher visitor pressure.     

Natural vs. plantation forests: A case study of land reclamation strategies for the humid tropics

Biomass and productivity were compared in two plantations and in one stand of natural regeneration on similar sites in a premontane moist forest region of Puerto Rico. While initial growth rates of plantation species were higher, after four decades productivity of the natural regeneration plots was equal to or greater than productivity of the plantations. For the first 44 years, aboveground biomass of natural regeneration increased at an average annual rate of 3.8t·ha^–1·yr^–1, but the last year of the study it was 14.7t·ha^–1. Biomass increment of a pine plantation averaged between 8 and 10.5t·ha^–1·yr^–1 except for one year when the rate was much lower, possibly because of hurricane damage. A tropical hardwood plantation averaged close to 4t·ha^–1·yr^–1 for 41 years. It is suggested that in countries where funds for land reclamation are limited, intensive plantations may not always be the best strategy. Natural regeneration or shelterbelt plantations may be suitable alternatives.     

Soil erosion vulnerability under scenarios of climate land-use changes after the development of a large reservoir in a semi-arid area

Climate and land-use/cover changes (LUCC) influence soil erosion vulnerability in the semi-arid region of Alqueva, threatening the reservoir storage capacity and sustainability of the landscape. Considering the effect of these changes in the future, the purpose of this study was to investigate soil erosion scenarios using the Revised Universal Soil Loss Equation (RUSLE) model. A multi-agent system combining Markov cellular automata with multi-criteria evaluation was used to investigate LUCC scenarios according to delineated regional strategies. Forecasting scenarios indicated that the intensive agricultural area as well as the sparse and xerophytic vegetation and rainfall-runoff erosivity would increase, consequently causing the soil erosion to rise from 1.78 Mg ha^?1 to 3.65 Mg ha^?1 by 2100. A backcasting scenario was investigated by considering the application of soil conservation practices that would decrease the soil erosion considerably to an average of 2.27 Mg ha^?1. A decision support system can assist stakeholders in defining restrictive practices and developing conservation plans, contributing to control the reservoir's siltation.     

Slope and pig slurry rate may increase the transfer of chemical elements by surface water runoff

There is a need to evaluate the interference of pig slurry rate and the terrain slope in the chemical elements losses from the soil. This work aimed to quantify water and chemical element losses by surface runoff due to terrain slope and pig slurry rate (PS) in two soils with contrasting textures. Two trials were evaluated in 2018 and 2019 in Cambisol and Nitisol. Rates of 0, 22.5, 45, and 90 m³ ha⁻¹ yr⁻¹ of PS were applied superficially in sites with slopes ranging from 10% to 35%. Perennial forage grass Tifton 85 (Cynodon dactylon) was grown as summer crop and ryegrass (Lolium multiflorum) was sown in the cold seasons in a field environment. Were determined the runoff, the volume of water, and chemical elements (Al, Ca, P, Mg, Cd, Cr, Cu, Mn, Fe, Pb, and Zn) lost by the surface runoff after natural rainfall. Increasing land slope elevated water losses substantially, on average 23.4 times in Cambisol and 10.8 times in Nitisol. This increase resulted in average increases of 27.6 and 12.4 times in the losses of the chemical elements analyzed for Cambisol and Nitisol, respectively. There was a reduction in water losses by surface runoff due to increased PS rates applied in both sites. The increased PS rate affected the losses of Cr and Cu in Cambisol and P, Mg, Cd, and Cu in Nitisol. The clayey soil potentiated the water and chemical elements losses by surface runoff in relation to the soil with lower clay content. Regardless of the soil, water and chemical element losses are maximized at higher slopes.     

Assessment of soil erosion under rainfed sugarcane in KwaZulu‐Natal,South Africa

Soil erosion from agricultural land use runoff is a major threat to the sustainability of soil composition and water resource integrity. Sugarcane is an important cash and food security crop in South Africa, subjected to an intensive soil erosion, and consequently, severe land degradation. This study aimed to investigate soil erosion and associated soil and cover factors under rainfed sugarcane, in a small catchment, KwaZulu‐Natal, South Africa. Three replicated runoff plots were installed at different slope positions (down, mid and upslope) within cultivated sugarcane fields to monitor soil erosion during the 2016–2017 rainy season. On average, annual runoff (RF) was significantly greater from 10 m² plots with 1163.77 ± 2.63 l/m/year compared to 1 m² plots. However, sediment concentration (SC) was significantly lower in 10 m² (0.34 ± 0.04 g/l) compared to 1 m² (6.94 ± 0.24 g/l) plots. The annual soil losses (SL) calculated from 12 rainfall events was 58.36 ± 0.77 and 8.84 ± 0.20 t/ha from 1 m² and 10 m² plots, respectively. The 1 m² plot, SL (2.4 ± 1.41 ton/ha/year) in the upslope experienced 33% more loss than the midslope and 50% more loss than the downslope position. SL was relatively lower from the 10 m² plots than the 1 m² plots, which is explained by high sediment deposition at the greater plot scale. SL was negatively correlated with the soil organic carbon stocks (r = ?0.82) and soil surface cover (r = ?0.55). RF decreased with the increase of slope gradient (r = ?0.88) and soil infiltration rate (r = ?0.87). There were considerable soil losses from cultivated sugarcane fields with low organic matter. These findings suggest that to mitigate soil erosion, soil organic carbon stocks and vegetation cover needs to be increased through appropriate land management practices, particularly in cultivated areas with steep gradients.     

Evaluating Terrestrial Carbon Sequestration Options for Virginia

Changes in forest and agricultural land management practices have the potential to increase carbon (C) storage by terrestrial systems, thus offsetting C emissions to the atmosphere from energy production. This study assesses that potential for three terrestrial management practices within the state of Virginia, USA: afforestation of marginal agricultural lands; afforestation of riparian agricultural lands; and changing tillage practices for row crops; each was evaluated on a statewide basis and for seven regions within the state. Lands eligible for each practice were identified, and the C storage potential of each practice on those lands was estimated through a modeling procedure that utilized land-resource characteristics represented in Geographic Information System databases. Marginal agricultural lands’ afforestation was found to have the greatest potential (1.4 Tg C yr⁻¹, on average, over the first 20 years) if applied on all eligible lands, followed by riparian afforestation (0.2 Tg C yr⁻¹ over 20 years) and tillage conversion (0.1 Tg C yr⁻¹ over 14 years). The regions with the largest potentials are the Ridge and Valley of western Virginia (due to extensive areas of steep, shallow soils) and in the Mid-Atlantic Coastal Plain in eastern Virginia (wet soils). Although widespread and rapid implementation of the three modeled practices could be expected to offset only about 3.4% of Virginia’s energy-related CO₂ emissions over the following 20 years (equivalent to about 8.5% of a Kyoto Treaty–based target), they could contribute to achievement of C-management goals if implemented along with other mitigation measures.     

Application of polyacrylamide to reduce phosphorus losses from a Chinese purple soil: A laboratory and field investigation

Use of anionic polyacrylamide (PAM) to control phosphorus (P) losses from a Chinese purple soil was studied in both a laboratory soil column experiment and a field plot experiment on a steep slope (27%). Treatments in the column study were a control, and PAM mixed uniformly into the soil at rates of 0.02, 0.05, 0.08, 0.10, and 0.20%. We found that PAM had an important inhibitory effect on vertical P transport in the soil columns, with the 0.20% PAM treatment having the greatest significant reduction in leachate soluble P concentrations and losses resulting from nine leaching periods. Field experiments were conducted on 5 m wide by 21 m long natural rainfall plots, that allowed collection of both surface runoff and subsurface drainage water. Wheat was planted and grown on all plots with typical fertilizer applied. Treatments included a control, dry PAM at 3.9 kg ha^?1, dry PAM at 3.9 kg ha^?1 applied together with lime (CaCO₃ at 4.9 t ha^?1), and dry PAM at 3.9 kg ha^?1 applied together with gypsum (CaSO₄·2H₂O at 4 t ha^?1). Results from the field plot experiment in which 5 rainfall events resulted in measurable runoff and leachate showed that all PAM treatments significantly reduced runoff volume and total P losses in surface runoff compared to the control. The PAM treatments also all significantly reduced water volume leached to the tile drain. However, total P losses in the leachate water were not significantly different due to the treatments, perhaps due to the low PAM soil surface application rate and/or high experimental variability. The PAM alone treatment resulted in the greatest wheat growth as indicated by the plant growth indexes of wheat plant height, leaf length, leaf width, grain number per head, and dried grain mass. Growth indexes of the PAM with Calcium treatments were significantly lesser. These results indicate that the selection and use of soil amendments need to be carefully determined based upon the most important management goal at a particular site (runoff/nutrient loss control, enhanced plant growth, or a combination).     

SPRING RUNOFF AND DRAINAGE N AND P LOSSES FROM HOG-MANURED CORN1

ABSTRACT: A two-year study was conducted to assess the effect of hog manure on the losses of nitrogen and phosphorus in runoff and drainage from grain-corn (Zea mays L.) plots, and the importance of spring versus annual loads. Treatments consisted of mineral N-P-K fertilizer applied at rates of 152 kg N ha^-1, 35 kg P ha^-1, and 86 kg K ha^-1; and hog (Sus scrofa domestica L.) manure applied preplant or post-emergence (six-to-eight leaf stage), at 152 kg N ha^-1, 39 kg P ha^-1, and 112 kg K ha^-1. The plots were rototilled (7 cm depth) in spring to incorporate fertilizer and preplant hog manure, and fall chisel-plowed (15 cm depth) to incorporate chopped corn residues. They were arranged in a completely randomized plot design. Flow volumes and nutrient levels in runoff and drainage waters were monitored year round but occurred mainly during the snowmelt (March 25-April 9), and post.snowmelt (April 10-May 13) periods. Of the total amount of water lost during snowmelt, 90 percent was in runoff, while 92 percent occurred as drainage in the post-snowmelt period. Sixty-five percent of the total annual volume of water lost was lost during these two periods as runoff and drainage. Treatments did not affect the annual snowmelt or post-snowmelt N and P loads. Total annual loads averaged 8.0 kg TKN ha^-1, 1.8 kg NH₄-N ha^-1, 43 kg NO₃-N ha^-1, 0.4 kg TP ha^-1, and 0.15 kg PO₄-P ha^-1. Spring (snowmelt and ost-snowmelt) runoff and drainage loads averaged 2.9 kg TKN ha^-1, 1.2 kg NH₄-N ha^-1, 18 kg NO₃-N ha^-1, 0.25 kg TP ha^-1, and 0.04 kg PO₄-P ha^-1, which were 40 percent to 70 percent of the yearly nutrient loads. Therefore, the hog manure management systems examined were of no greater threat to the environment than mineral fertilizers. However, spring N and P losses do represent an important part of the annual nutrient loss budget, even with conservation practices.     

17β-Estradiol and testosterone in drainage and runoff from poultry litter applications to tilled and no-till crop land under irrigation

Thirteen metric tons of poultry litter are produced annually by poultry producers in the U.S. Poultry litter contains the sex hormones estradiol and testosterone, endocrine disruptors that have been detected in surface waters. The objective of this study was to evaluate the potential impact of poultry litter applications on estradiol and testosterone concentrations in subsurface drainage and surface runoff in irrigated crop land under no-till and conventional-till management. We conducted an irrigation study in fall of 2001 and spring of 2002. Four treatments, no-till plus poultry litter, conventional-till plus poultry litter, no-till plus conventional fertilizer, and conventional-till plus conventional fertilizer, were evaluated. Flow-weighted concentration and load ha⁻¹ of the two hormones were measured in drainage and runoff. Soil concentrations of estradiol and testosterone were measured. Based on comparisons to the conventional fertilizer (and control) treatments, poultry litter did not add to the flow-weighted concentration or load ha⁻¹ of either estradiol or testosterone in subsurface drainage or surface runoff. Significant differences were, however, observed between tillage treatments: flow-weighted concentrations of estradiol were greater for no-till than conventional-till plots of the June irrigation; and runoff loads of both estradiol and testosterone were less from no-till than conventional-till plots for the November irrigation. Although the differences between no-till and conventional-tillage appeared to affect the hydrologic transport of both hormones, the differences appeared to have inconsequential environmental impact.     

Nitrogen critical loads and management alternatives for N-impacted ecosystems in California

Empirical critical loads for N deposition effects and maps showing areas projected to be in exceedance of the critical load (CL) are given for seven major vegetation types in California. Thirty-five percent of the land area for these vegetation types (99,639 km²) is estimated to be in excess of the N CL. Low CL values (3–8 kg N ha^?1 yr^?1) were determined for mixed conifer forests, chaparral and oak woodlands due to highly N-sensitive biota (lichens) and N-poor or low biomass vegetation in the case of coastal sage scrub (CSS), annual grassland, and desert scrub vegetation. At these N deposition critical loads the latter three ecosystem types are at risk of major vegetation type change because N enrichment favors invasion by exotic annual grasses. Fifty-four and forty-four percent of the area for CSS and grasslands are in exceedance of the CL for invasive grasses, while 53 and 41% of the chaparral and oak woodland areas are in exceedance of the CL for impacts on epiphytic lichen communities. Approximately 30% of the desert (based on invasive grasses and increased fire risk) and mixed conifer forest (based on lichen community changes) areas are in exceedance of the CL. These ecosystems are generally located further from emissions sources than many grasslands or CSS areas. By comparison, only 3–15% of the forested and chaparral land areas are estimated to be in exceedance of the NO₃^? leaching CL. The CL for incipient N saturation in mixed conifer forest catchments was 17 kg N ha^?1 yr^?1. In 10% of the CL exceedance areas for all seven vegetation types combined, the CL is exceeded by at least 10 kg N ha^?1 yr^?1, and in 27% of the exceedance areas the CL is exceeded by at least 5 kg N ha^?1 yr^?1. Management strategies for mitigating the effects of excess N are based on reducing N emissions and reducing site N capital through approaches such as biomass removal and prescribed fire or control of invasive grasses by mowing, selective herbicides, weeding or domestic animal grazing. Ultimately, decreases in N deposition are needed for long-term ecosystem protection and sustainability, and this is the only strategy that will protect epiphytic lichen communities.     

PRECIPITATION RETENTION AND SOIL EROSION UNDER VARYING CLIMATE,LAND USE,AND TILLAGE AND CROPPING SYSTEMS1

ABSTRACT: Nonirrigated crop yields and forage production are limited by low and variable precipitation in the southern Great Plains. Precipitation variation involves production risks, which can be reduced by considering probability of precipitation, precipitation retention, and soil erosion under various production systems. The objective of this study was to probabilistically quantify the impact of precipitation variations, land use, cropping, and tillage systems on precipitation retention and soil erosion. Five 1.6 ha watersheds that had 3 to 4 percent slopes, and similar silt loam soils were selected. One was kept in native grass, and the others were planted into winter wheat (Triticum aestivum L.) under different cropping and tillage systems. Daily runoff and soil erosion were measured at the outlet of each watershed. Precipitation distributions exhibited great seasonal and interannual variations, and precipitation retention distributions resembled those of precipitation. Cropping and tillage systems affected precipitation retention but much less than did precipitation variations. Available soil water storage, which was largely controlled by ET, played an important role in retaining precipitation. This indicates that cropping systems should be adjusted to precipitation patterns, if predictable, for better soil water use. Land use and cropping and tillage systems had a much greater impact on soil erosion than on precipitation retention. Soil erosion risks, which were proportional to the levels of tillage disturbance, were mainly caused by a few large storms in summer, when surface cover was low. This study explored a novel approach for evaluating production risks associated with insufficient precipitation retention and excessive soil erosion for certain crops or cropping systems under assumed precipitation conditions.     

Acid-forming emissions in Alberta,Canada

The sulphur dioxide and nitrogen oxides emissions from all sources in Alberta, Canada, during 1982 amounted to 488,297 and 353,511 tonnes, respectively. During this year deposition of wet sulphate from all stations in the province, 8 kg ha^–1 yr^–1, compares well with the five-year average (1978–1982) value of 10 kg ha^–1 yr^–1. These measurements are about one-half of the wet sulphate deposition criteria of 20 kg ha^–1 yr^–1 established for protecting the moderately sensitive aquatic ecosystem in eastern Canada. Due to dry, cold, continental climate conditions of Alberta, dry sulphate or sulphur deposition is equally or more important than wet deposition. No effects of the long-range transport of atmospheric pollutants (LRTAP) on the ecosystems in Alberta have been observed to date. Atmospheric deposition target loadings of SO₄ ^–2, NO₃ ^–, and H⁺ for Alberta and western Canadian environmental conditions should be developed to protect the highly sensitive ecosystems. Some future research and monitoring priorities for Alberta and western Canada are outlined.     

Back to the basics – Estimating the sensitivity of freshwater to acidification using traditional approaches

This study examines the effects of acidifying sulphur emissions on freshwater ecosystems in the traditional territory of Treaty 8 First Nations in British Columbia (BC). Due to the absence of detailed water chemistry data for most lakes in the region, revised empirical methods for estimating freshwater sensitivity to acidification are formulated using linear regression relationships between individual chemical measurements, and critical loads of acidity calculated using the Steady State Water Chemistry (SSWC) model. Lake alkalinity is the most effective chemical indicator of acidification sensitivity in northeast BC. Critical loads of acidity (CL(A)) estimated using alkalinity range from 0.0827 to 9.48 keq ha^?1 yr^?1. Sulphur deposition estimates range from 0.0113 to 0.303 keq ha^?1 yr^?1 and do not exceed the estimated CL(A) at any of the study lakes. The spatial situation of both the lakes and the emission sources is responsible for the lack of exceedances, and expanded/continued monitoring is recommended to account for geological variability and source proliferation. Measurements of lake conductivity and alkalinity provide a means of community monitoring for freshwater acidification sensitivity as part of cumulative effects management strategies.     

Organic carbon diminution and estimates of carbon dioxide release from plantation soil

Summary This paper evaluates the rates of organic carbon diminution in the soil under monospecific tree plantations of teak, gmelina, rubber, oil palm, cashew and coffee. The differences between the organic carbon status of their soils and soil under nearby natural rain forest vegetation are compared. Annual rates of organic carbon decrease for the 0–10 cm soil layer, varied from 82.1 kg ha^–1 for cashew to 316.7 kg ha^–1 for oil palm. The tree plantations appear to release more carbon dioxide from the soil into the atmosphere than the natural forest. They therefore, appear to have the potential of contributing towards global warming — a threat they are supposed to mitigate.     

Adsorptive removal of Cd(II) and Pb(II) ions from aqueous solutions by using Turkish illitic clay

The ability of Turkish illitic clay (TIC) in removal of Cd(II) and Pb(II) ions from aqueous solutions has been examined in a batch adsorption process with respect to several experimental conditions including initial solution pH, contact time, initial metal ions concentration, temperature, ionic strength, and TIC concentration, etc. The characterization of TIC was performed by using FTIR, XRD and XRF techniques. The maximum uptake of Cd(II) (11.25 mg g⁻¹) and Pb(II) (238.98 mg g⁻¹) was observed when used 1.0 g L⁻¹ of TIC suspension, 50 mg L⁻¹ of initial Cd(II) and 250 mg L⁻¹ of initial Pb(II) concentration at initial pH 4.0 and contact time of 240 min at room temperature. The experimental data were analyzed by the Langmuir, Freundlich, Temkin and Dubinin Radushkevich (D-R) isotherm models. The monolayer adsorption capacity of TIC was found to be 13.09 mg g⁻¹ and 53.76 mg g⁻¹ for Cd(II) and Pb(II) ions, respectively. The kinetics of the adsorption was tested using pseudo-first-order, pseudo-second-order, Elovich and intraparticle diffusion models. The results showed that the adsorption of Cd(II) and Pb(II) ions onto TIC proceeds according to the pseudo-second-order model. Thermodynamic parameters including the Gibbs free energy (ΔG), enthalpy (ΔH), and entropy (ΔS) changes indicated that the present adsorption process was feasible, spontaneous and endothermic in the temperature range of 5–40 °C.