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1.
A laboratory study using a bench scale model of two units operation involving coagulation process with Moringa oleifera seeds extract as a coagulant and filtration process using hollow fibre microfiltration membrane, was adopted to treat Air Hitam Sanitary Landfill leachate in Puchong, Malaysia. The performance of the microfiltration membrane in pretreated sanitary landfill leachate treatment was investigated through a continuous process. The leachate sample was passed through conventional coagulation process before being filtered through a hollow fibre microfiltration membrane of 0.1 μm surface pores. The hollow fibre microfiltration membrane decreased the turbidity, colour, total suspended solids, total dissolved solids and volatile suspended solids in the leachate by 98.30, 90.30, 99.63, 14.71 and 20%, respectively. The results showed that microfiltration is capable of removing high percentage of solids from leachate and might be considered as a polishing stage after on-site biological treatment for sanitary landfill leachate.  相似文献   

2.
Landfill leachate contains high concentrations of organic matter, color, heavy metals and toxic substances. This study presents the feasibility of a commercial nanofiltration membrane (NF-300) in the removal of pollutants from a landfill leachate generated from the Treatment Stabilization and Disposal Facility in Gujarat state of India. Two different leachate samples (Leachates A and B) were collected from the downstream side of closed landfill cells A and B. The average quality of the leachate was 67 719 mg/L COD, 217 mg/L ammonical nitrogen, 22 418 mg/L BOD, 3847 mg/L chlorides and 909 mg/L sulphate. The operating variables studied were applied pressure (4–20 atm), feed flowrate (5–15 L/min) and pH (2, 4, 5.5 and 6.7). It was observed that the solute rejection (RO) increased with increase in feed pressure and decreased with increase in feed concentration at constant feed flowrate. In the present study, the rejection of cations followed the sequence: RO (Cr3+) > RO (Ni2+) > RO (Zn2+) > RO (Cu2+) > RO (Cd2+) for leachates A and B. The order of solute rejection sequence is inversely proportional to the diffusion coefficients. The rejection of sulphate ions by the NF-300 membrane was 83 and 85%, while the rejection of chlorides was 62 and 65% for leachates A and B, respectively. The NF-300 membrane was characterized by using the combined-film theory-Spiegler–Kedem (CFSK) model based on irreversible thermodynamics and the ion transport model based on the extended Nernst–Planck equation. The membrane transport parameters were estimated using the Levenberg–Marquadt method. The estimated parameters were used to predict the membrane performance and the predicted values are in good agreement with the experimental results.  相似文献   

3.
In this study, two pilot-scale aerobic landfill reactors with (A1) and without (A2) leachate recirculation are used to obtain detailed information on the quantity and quality of leachate in aerobic landfills. The observed parameters of leachate quality are pH, chloride (Cl), chemical oxygen demand (COD), biological oxygen demand (BOD), total Kjeldahl nitrogen (TKN), ammonia nitrogen (NH3-N), and nitrate (NO3-N). pH values of the leachate increased to 7 after 50 days in reactor A1 and after 70 days in reactor A2. Cl concentrations increased rapidly to 6100 (A1) and 6900 (A2) mg/L after 80 days, from initial values of 3000 and 2800 mg/L, respectively. COD and BOD values decreased rapidly in the A1 landfill reactor, indicating the rapid oxidation of organic matter. The BOD/COD ratio indicates that leachate recirculation slightly increases the degradation of solid waste in aerobic landfills. NH3-N concentrations decreased as a result of the nitrification process. Denitrification occurred in parts of the reactors as a result of intermittent aeration; this process causes a decrease in NO3 concentrations. There is a marked difference between the A1 and A2 reactors in terms of leachate quantity. Recirculated leachate made up 53.3% of the leachate generated from the A1 reactor during the experiment, while leachate quantity decreased by 47.3% with recirculation when compared with the aerobic dry landfill reactor.  相似文献   

4.
ABSTRACT: In 1983, the City of Indianapolis, Indiana, completed construction of advanced wastewater treatment (AWT) systems to enlarge and upgrade its existing Belmont Road and South port Road secondary treatment plants. A nonparametric statistical procedure, a modified form of the Wilcoxon-Mann-Whitney rank-sum test, was used to test for trends in water quality at two upstream and two downstream sites on White River and at the two treatment plants. Results comparing the pre- (1978–1980) and post- (1983–1986) AWT periods show statistically significant improvements in the quality of the treated effluent and of the White River downstream from the plants. Water quality at sites upstream from the city was relatively constant during the period of study. Total ammonia (as N) decreased 14.6 mg/L and BOD5 (five-day biochemical oxygen demand) decreased 10 to 19 mg/L in the two effluents. Total ammonia in the river downstream from the plants decreased 0.8 to 1.9 mg/L and BOD5 decreased 2.3 to 2.5 mg/L. Nitrate (as N) increased 14.5 mg/L in the plant effluents and 2.0 to 2.4 mg/L in the river because of in-plant nitrification. Dissolved oxygen concentration in the river increased about 3 mg/L because of reduced oxygen demand for nitrification and biochemical oxidation processes.  相似文献   

5.
于清华 《四川环境》2012,31(3):9-12
为改进现有二滩库区垃圾处理填埋场垃圾渗滤液处理工艺,研究絮凝—吸附法预处理工艺,试验以聚合氯化铝作为絮凝剂,最佳投放量为600mg/L,以粉煤灰作为吸附剂,最佳投放量为200g/L。结果表明:CODcr去除率达到79.64%;NH3-N去除率达到83.23%;悬浮物去除率达到58.75%;色度去除率达到92.56%;重金属离子去除率为60.37%~96.33%;研究证明:渗滤液经预处理后可以与城市生活污水合并处理。  相似文献   

6.
为了研究车载巡回处理装置对小城镇垃圾渗滤液的处理效果,采用自制的UV-Fenton试验装置研究了pH值、FeSO_4剂量、反应时间等因素对处理效果的影响,结果表明:最佳pH值为4.0,进水中COD为825 mg/L时,FeSO_4和H_2O_2的投加量分别为0.008 mol/L和0.08 mol/L,此时COD去除率72.22%,出水COD为216 mg/L;随着FeSO_4投加量缓慢增加到一定程度后转而下降,FeSO_4最佳投加量为0.008 mol/L;不同H_2O_2和Fe~(2+)配比对COD去除效果具有影响,(10:1)时为最佳配比。经过氨吹脱和混凝沉淀预处理的渗滤液采用UV/Fenton处理工艺,出水中COD可以达到《生活垃圾填埋场污染控制标准》(GB 16889-1997)中二级标准。  相似文献   

7.
With the increase of urbanization, municipal solid waste has also increased. Therefore, the need for solid waste management is also increasing compared with earlier decades. Composting is a good option for the recycling of solid waste; however, it produces leachate, which requires proper treatment systems to prevent environmental degradation. Due to high chemical oxygen demand (COD) concentrations in compost leachate, anaerobic treatment is the best option for handling the effluent, and an anaerobic baffled reactor (ABR) is one such anaerobic reactor that can be used for its treatment. Because of high ammonia and heavy metal concentrations, as well as the possibility of sludge washout in ABRs, it is important to use proper media, such as zeolite, which can reduce inhibition effects and sludge washout from the reactor. Anaerobic treatment, especially during the methanogenesis phase, is sensitive, and pH and alkalinity are parameters that influence the treatment. Therefore, adjusting these parameters within a normal range is very important to the proper functioning of anaerobic systems. In this study, a pilot‐scale ABR was used, and the last 4 of the 8 ABR compartments were filled with zeolite. The bioreactor was operated at hydraulic retention times (HRT) of 3, 4, and 5 days, with zeolite filling ratios of 10%, 20%, and 30%, and influent COD concentrations of 10,000, 20,000, and 30,000 milligrams per liter (mg/L). In this study, pH value was 6.43 ± 0.1, 6.96 ± 0.3, and 6.96 ± 0.25 at filling ratios of 10%, 20%, and 30%, respectively. According to the results, in all filling ratios, no significant changes were observed in the pH value when the organic loading rate increased and its amount was within a constant range. Influent alkalinity was equal to 2015 ± 510, 2884 ± 505, and 4154 ± 233 milligrams of calcium carbonate per liter (mg CaCO3/L) at influent COD concentrations of 10,000, 20,000, and 30,000 mg/L, respectively, and in effluent, they were 2536 ± 336, 3379 ± 639, and 4377 ± 325 mg CaCO3/L, respectively. The amount of alkalinity in the effluent increased compared with the alkalinity in the influent. The results show that the amount of alkalinity in the influent and effluent was similar, and the alkalinity enhancement was lower when the filling ratio was increased from 10% to 20%, and 20% to 30%. Comparisons of the results from zeolite with and without biofilm showed that, in cases of zeolite with biofilm, the amounts of silica and oxygen decreased and the amount of carbon increased, and it showed the formation of biofilm on the surface of zeolite. In addition, the absence of sodium in the zeolite with the biofilm indicated that sodium was exchanged with ammonium ions. According to the results, zeolite can be used in anaerobic reactors as a medium, and it also reduces fluctuations in pH and alkalinity at different organic loading rates, providing a normal range for anaerobic treatment.  相似文献   

8.
ABSTRACT: Water hyacinth (Eichhornia crassipes L.) has shown to be effective in the treatment of municipal wastewater in a pilot study begun in January 1989 by the Pima County Wastewater Management Department and researchers associated with The University of Arizona's Office of Arid Lands Studies in the Sonoran Desert near Tucson. The influent pumped into the pilot facility's six raceways (ponds) typically has been treated secondary effluent diverted from a conventional treatment facility, although primary effluent from the same facility also has been treated. The Secondary Influent Treatment System has met the Arizona Department of Environmental Quality (ADEQ) tertiary standard for BOD5 and TSS of 10 mg/l for every month of its operation since March 1990; the Primary Influent Treatment System met the ADEQ secondary standard for BOD5 and TSS of 30 mg/1 for most of the 10 months it was in operation.  相似文献   

9.
Landfills and old waste deposits are some of the major anthropogenic sources of methane (CH4) emissions worldwide. Despite the fact that during the last 15 years the amount of carbon dioxide equivalent (CO2-eq.) emitted from German landfills was reduced by approximately two thirds, estimates show that currently more than 10 Mtonnes are still being emitted annually. As a case study, the in situ aerated former Kuhstedt Landfill (District of Rotenburg (Wümme), Germany) was assessed regarding the possibility of reducing the emitted amounts of greenhouse gases (GHG; here methane). The assessment was based on both a model calculation of the landfill gas emissions that should occur under anaerobic conditions (reference scenario) as well as using monitoring data plus extrapolations to determine the actual emissions from the landfill. It was demonstrated that more than 72% of the total GHG emissions occurring under anaerobic conditions could be avoided by altering the ambient aerobic/oxidizing conditions. By means of subsequent thermal treatment (regenerative thermal oxidation, RTO) of the extracted off-gases during the aeration process, the amount of CO2-eq. savings, as calculated from the amount of emitted methane taking into account secondary emissions for energy production, could be further increased to 96%.  相似文献   

10.
Seaweed can be anaerobically digested for the production of energy-rich methane. However, the use of seaweed digestate as a fertilizer may be restricted because of the high heavy metal content especially cadmium. Reducing the concentration of heavy metals in the digestate will enable its use as a fertilizer. In this laboratory-scale study, the potential of seaweed and its leachate in the production of methane were evaluated in batch tests. The effect of removing the heavy metals from seaweed leachate was evaluated in both batch test and treatment in an upflow anaerobic sludge blanket (UASB) reactor. The heavy metals were removed from seaweed leachate using an imminodiacetic acid (IDA) polyacrylamide cryogel carrier. The methane yield obtained in the anaerobic digestion of seaweed was 0.12 N l CH4/g VSadded. The same methane yield was obtained when the seaweed leachate was used for methane production. The IDA-cryogel carrier was efficient in removing Cd2+, Cu2+, Ni2+ and Zn2+ ions from seaweed leachate. The removal of heavy metals in the seaweed leachate led to a decrease in the methane yield. The maximum sustainable organic loading rate (OLR) attained in the UASB reactor was 20.6 g tCOD/l/day corresponding to a hydraulic retention time (HRT) of 12 h and with a total COD removal efficiency of about 81%. Hydrolysis and treatment with IDA cryogel reduced the heavy metals content in the seaweed leachate before methane production. This study also demonstrated the suitability of the treatment of seaweed leachate in a UASB reactor.  相似文献   

11.
Ambient water quality and bacterial populations in the water resources of Pulau Perhentian, a Marine Park of Malaysia, were studied during a peak tourist arrival, off-monsoon period. The overall water and bacteriological quality of swimming/boating sites in the island is at an acceptable condition, although the conductivity (0.88–60 mS m–1) due to high dissolved solid concentrations is slightly high, when compared with the recommended standard and published guidelines for the protection/maintenance of recreation water and its aesthetic enjoyment (Universiti Malaya, Department of Environment, Malaysia, 1986). However, the bacteriological quality of the drinking/bathing water wells is poor, with faecal coliform counts (2 up to 1,600 MPN per 100 ml sample water) exceeding the permissible levels defined for raw water supplies (with or without treatment). This suggests that the groundwater, seepage and run-off into the wells is contaminated. Contrary to the belief of the water users being interviewed in a social survey, the untreated drinking/bathing water is not bacteria-free. The excessive counts are attributable to deoxygenated conditions (12–42 percent corresponding to 0.9–3.3 mg l–1) prevailing in the wells, high total suspended solids (up to 202 mg l–1) which promote bacterial growth, lack of adequate sewerage systems to receive effluents from lavatories of dwellings, chalets and resorts, as well as the lack of centralised water treatment plants and storage tanks to cope with water scarcity and waterway contamination.  相似文献   

12.
Fenton treatment (Fe2+/H2O2) and different ozone-based Advanced Oxidation Processes (AOPs) (O3, O3/OH and O3/H2O2) were evaluated as pre-treatment of a mature landfill leachate, in order to improve the biodegradability of its recalcitrant organic matter for subsequent biological treatment. With a two-fold diluted leachate, at optimised experimental conditions (initial pH 3, H2O2 to Fe2+ molar ratio of 3, Fe2+ dosage of 4 mmol L−1, and reaction time of 40 min) Fenton treatment removed about 46% of chemical oxygen demand (COD) and increased the five-day biochemical oxygen demand (BOD5) to COD ratio (BOD5/COD) from 0.01 to 0.15. The highest removal efficiency and biodegradability was achieved by ozone at higher pH values, solely or combined with H2O2. These results confirm the enhanced production of hydroxyl radical under such conditions. After the application for 60 min of ozone at 5.6 g O3 h−1, initial pH 7, and 400 mg L−1 of hydrogen peroxide, COD removal efficiency was 72% and BOD5/COD increased from 0.01 to 0.24. An estimation of the operating costs of the AOPs processes investigated revealed that Fe2+/H2O2 was the most economical system (8.2 € m−3 g−1 of COD removed) to treat the landfill leachate. This economic study, however, should be treated with caution since it does not consider the initial investment, prices at plant scale, maintenance and labour costs.  相似文献   

13.
Variations in the chemical properties of landfill leachate   总被引:4,自引:0,他引:4  
Landfill leachates were collected and their chemical properties analyzed once every two months over a ten-month period from the Gin Drinkers' Bay (GDB) and Junk Bay (JB) landfills. The contents of solids, and inorganic and organic components fluctuated considerably with time. In general, the chemical properties of the two leachates correlated negatively (P<0.05) with the amounts of rainfall prior to the sampling periods. However, magnesium and pH of the leachates remained relatively constant with respect to sampling time. The JB leachate contained higher average contents of solids and inorganic and organic matter than those of GDB with the exception of trace metals. Trace metals were present in the two leachates in trace quantities (<1.0 mg/liter). The concentrations of average ammoniacal nitrogen were 1040 and 549 mg/liter, while chemical oxygen demand (COD) values were 767 and 695 mg/liter for JB and GDB leachates, respectively. These results suggest that the leachates need further treatment before they can be discharged to the coastal waters.  相似文献   

14.
Hydrodynamic cavitation (HC)-based treatments have been proposed for the degradation of phenol as a toxic pollutant. The present work aimed to optimize the degradation of phenol using HC by means of Doehlert experimental design, which has not been previously addressed. Initially, operational parameters of hydraulic characteristics of the pump, inlet pressure, solution pH, and initial concentration were optimized; later, the effects of pH solution and H2O2 loading or initial pollutant concentration on phenol degradation were explored using the Doehlert experimental design. It was observed that phenol degradation is strongly dependent on the pH of the solution. Also, the acidic condition favors the formation of hydroxyl radicals and thus, the degradation of phenol. Based on the Doehlert matrix, the 94.1% phenol degradation and 68.60% total organic carbon (TOC) were obtained in 180 min at 304.5 mg/L of hydrogen peroxide at an initial concentration of 20 mg/L, 2.0 pH, and 90 psi inlet pressure, providing a cavitational yield of 6.33 × 10−6 mg/J and minimum treatment cost of US$/L 0.13. Overall, it has been observed that HC can be a promising route for the removal of pollutants (phenol) effectively using hydrogen peroxide as an additive.  相似文献   

15.
This experimental study was conducted to evaluate a membrane sequencing batch reactor (MSBR) with mixed culture photosynthetic bacteria for dairy wastewater treatment. The study was undertaken in two steps: laboratory and pilot scale experiments. In the first step, kinetics analysis of the MSBR was carried out in a laboratory scale experiment with influent COD concentration of 2500 mg/L. The pilot scale experiment was conducted to investigate the performance of the MSBR and checked the suitability of the kinetics for an engineering design. The kinetic coefficients Ks, k, kd, Y and μm were found to be 174-mg-COD/L, 7.42/d, 0.1383/d, 0.2281/d and 1.69/d, respectively. There were some deviations of COD removal efficiency between the design value and the actual value. From the kinetics estimation, COD effluent from the design was 27 mg/L while the average actual COD effluent from the experiment was 149 mg/L. Due to the different light source condition, the factors relating to light energy (i.e. Lf and IR%) must be incorporated into engineering design and performance prediction with these kinetic coefficients of the photosynthetic MSBR.  相似文献   

16.
Effects of controlled nutrient additions on a prairie stream were studied using a before‐after‐control‐impact paired design. The site is in a reference condition with low soluble nitrate (NO3) and phosphate (soluble reactive phosphorus [SRP]) in summer (3 μg NO3‐N/L, 4 μg SRP/L). Nutrients were added to two reaches over the growing season at two levels (Low Dose — 39 μg NO3‐N/L and 4.4 SRP/L; High Dose — 119 μg NO3‐N/L and 15.6 μg SRP/L). Continuously measured dissolved oxygen (DO) and changes in aquatic flora were compared to an upstream Control. Enrichment led microalgae and filamentous algae to increase in density, areal coverage, and thickness, and the magnitude of the changes were largely concordant with dosing (more in the High Dose); algal growth also suppressed macrophytes in the High Dose. Enrichment caused significant increases in diel DO swings whose magnitudes were consistent with dosing level. In the High Dose, benthic algae flourished in the growing season and then senesced en masse in fall. The decomposing algae led DO to crash (ca. 0 mg/L on the bottom), but DO impacts were out‐of‐sync with peak algal growth and photosynthesis, which occurred weeks earlier. This finding provides a plausible explanation as to why high DO delta in streams impacts aquatic life even when concurrently measured DO is not low. When DO crashed, DO was longitudinally patchy, some areas having low DO near the bottom, others near saturation. Geomorphology and exposure to wind may have caused this pattern.  相似文献   

17.
不同物质对垃圾渗滤液中腐殖酸的吸附研究   总被引:1,自引:0,他引:1  
垃圾渗滤液是一种有毒有害的高浓度有机废水,其中含大量腐殖酸。腐殖酸具有离子交换能力、吸附能力和脱除杂质能力,因此在很多方面有实用价值。活性碳、土壤、堆肥对废水中的有机物有一定的吸附能力。本文采用正交设计的方法,研究了活性碳、土壤、堆肥在不同温度,液/固,腐殖酸初始浓度的条件下对垃圾渗滤液中腐殖酸的吸附效果。实验结果表明:四种实验因素对吸附剂的吸附能力的影响程度为:吸附剂类型〉腐殖酸的初始浓度〉吸附反应温度〉液固比。在温度为25℃,液固比为50/0.5(mL/g),腐殖酸初始浓度为41.99(mg/L),吸附剂类型为活性碳时,腐殖酸吸附量最大,为40.86mg。同时分析了响应指标随因素的变化趋势。  相似文献   

18.
Landfill leachate recirculation is efficient in reducing the leachate quantity handled by a leachate treatment plant. However, after land application of leachate, nitrification and denitrification of the ammoniacal N becomes possible and the greenhouse gas nitrous oxide (N2O) is produced. Lack of information on the effects of leachate recirculation on N2O production led to a field study being conducted in the Likang Landfill (Guangzhou, China) where leachate recirculation had been practiced for 8 yr. Monthly productions and fluxes of N2O from leachate and soil were studied from June to November 2000. Environmental and chemical factors regulating N2O production were also accessed. An impermeable top liner was not used at this site; municipal solid waste was simply covered by inert soil and compacted by bulldozers. A high N2O emission rate (113 mg m-2 h-1) was detected from a leachate pond purposely formed on topsoil within the landfill boundary after leachate irrigation. A high N2O level (1.09 micrograms L-1) was detected in a gas sample emitted from topsoil 1 m from the leachate pond. Nitrous oxide production from denitrification in leachate-contaminated soil was at least 20 times higher than that from nitrification based on laboratory incubation studies. The N2O levels emitted from leachate ponds were compared with figures reported for different ecosystems and showed that the results of the present study were 68.7 to 88.6 times higher. Leachate recirculation can be a cost-effective operation in reducing the volume of leachate to be treated in landfill. However, to reduce N2O flux, leachate should be applied to underground soil rather than being irrigated and allowed to flow on topsoil.  相似文献   

19.
Golf courses are often considered by the public to be significant nitrogen (N) and phosphorus (P) nonpoint sources but only limited information exists on nutrient concentrations and loads in golf course groundwater. In this study, we measured N and P concentrations in groundwater and available surface water at six randomly selected Iowa golf courses to assess the loading risk posed by these facilities to groundwater and local rivers. At each course, three shallow monitoring wells were installed, one each on representative tee, fairway, and rough locations. Wells and available surface water were sampled on eight occasions during 2015 and 2016. NO3‐N concentrations were not detected above 1 mg/L at three of the six courses monitored in this study and the overall mean NO3‐N concentration in Iowa golf courses was 2.2 mg/L. The mass of NO3‐N recharged to groundwater averaged 3.3 kg/ha at the six courses, which represents approximately one‐tenth of the NO3‐N load exported by the watershed that contains the course and represented approximately 0.1 to 8% of the fertilizer N applied. Groundwater orthophosphorus concentrations averaged 0.13 mg/L and were similar to those measured in a variety of settings across Iowa. Study results should prove useful in evaluating nutrient contributions from golf courses in Midwestern states where nutrient reduction strategies are being pursued.  相似文献   

20.
Pollution and self-purification trends of an urban river namely, Msimbazi River, in Dar es Salaam City, Tanzania, were investigated. Site investigations and water quality analyses were done. The river is polluted in terms of high organic and nutrient concentrations, low dissolved oxygen, and high counts of indicator organisms. Biochemical oxygen demand (BOD5) concentrations were 27– 340 mg/L. Dissolved oxygen was found to be as low as 0.9 mg O2/L. Bacteriological pollution increased with distance downstream of the river, a trend attributable to an increase in the catchment of pollution sources, which are on-site sanitation systems. Although the river has an appreciable self-purification capacity, the capacity is strained by persistent pollution overloads. The pollution plight of the river is attributable to its being flanked by expanding human habitats and vibrant industrial, institutional, and socio-economic activities. Provision for pretreatment of discharges into the river is put forward as a remedial measure for the observed pollution. Matching nontechnical and techno-social remedial measures are also recommended. These include sensitization of polluters on merits of environmental protection practices such as cleaner production and strict enforcement of environmental protection laws.  相似文献   

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